CN102516815B - Disperse orange dye mixture - Google Patents
Disperse orange dye mixture Download PDFInfo
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- CN102516815B CN102516815B CN 201110454296 CN201110454296A CN102516815B CN 102516815 B CN102516815 B CN 102516815B CN 201110454296 CN201110454296 CN 201110454296 CN 201110454296 A CN201110454296 A CN 201110454296A CN 102516815 B CN102516815 B CN 102516815B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
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Abstract
A disperse orange dye mixture comprises a dye part and an auxiliary part which are mixed with each other, and is characterized in that the dye part is formed by mixing at least four dyes adopting the structures as follows: one of the three dyes is a dye adopting the chemical structural formula I, and is 2 to 80 percent of the dye part by weight; the second of the three dyes is a dye adopting the chemical structural formula II, and is 2 to 80 percent of the dye part by weight; and the last dye is a dye adopting the chemical structural formula III, and is 2 to 80 percent of the dye part by weight.
Description
Technical field
The present invention relates to a kind of dispersed dye that are applicable to polyster fibre or dyeing fabric, particularly good the and inexpensive environment-friendly type disperse orange dyes mixture of a kind of alkali resistance.
Background technology
Dispersed dye are a kind of starting stages in dyeing course, are the class nonionic dye that dispersion state dyes to hydrophobic fibre under the effect of dispersion agent.Dispersed dye have complete chromatogram, lovely luster, and coloring intensity is high, and has good economy.Association adds up according to dyestuff Industry in China, the first place that China's dispersed dye consumption row occupy various dyestuffs, and the usage quantity 60% of whole world dispersed dye is produced outlet by China.
In the past in orange disperse dye commonly used, international Colour index number is the dyestuff of C.I. DISPERSE ORANGE 30 200 1, C.I. DISPERSE ORANGE 30 200 3, C.I. DISPERSE ORANGE 30 200 37, C.I. DISPERSE ORANGE 30 200 76, C.I. DISPERSE ORANGE 30 200 61, C.I. DISPERSE ORANGE 30 200 29, C.I. DISPERSE ORANGE 30 200 30, C.I. DISPERSE ORANGE 30 200 41, C.I. DISPERSE ORANGE 30 200 62 and C.I. DISPERSE ORANGE 30 200 73, can be used as basic middle dark color at home and abroad supporting, with DISPERSE NAVY BLUE EXSF 300﹠ BLUE 56 100 colour system and dispersed ruby colour system and the black mutual colorant match of dispersion.But the most frequently used in above disperse orange dye kind is the C.I. DISPERSE ORANGE 30 200 30 of gold-tinted and the C.I. DISPERSE ORANGE 30 200 61 of ruddiness.
At present, along with the continuous enhancing of mankind's environmental consciousness, environmentfriendly products standard universally acknowledged in dye field is also more and more stricter.Not only European Oeko-Tex Standard (OEKO-TEX Standard 100) is strict gradually to the restriction of detrimental impurity in dyestuff (as sensitization dye and polystream phenol etc.), and in recent years Europe and Japan all worked out severeer restriction halogen rules.Some industry standards (" IEC61249-2-21 ", " JPCA-ES012003 " and " IPC 4101 ") from present Europe and Japan's issue, in general acceptable environmentfriendly products, bromine content is no more than 900ppm, cl content is no more than 900ppm, and the total content of halogen mostly is 1500ppm most.If still use C.I. DISPERSE ORANGE 30 200 1, C.I. DISPERSE ORANGE 30 200 3, C.I. DISPERSE ORANGE 30 200 37, C.I. DISPERSE ORANGE 30 200 76 and C.I. DISPERSE ORANGE 30 200 61 in dispersed dye now, the sensitization dyestuff that can detect in the textiles that will cause dyeing and bromo element severe overweight.If the organochlorine compound severe overweights such as chlorophenesic acid, Trichlorophenol, chlorophenosic acid and pentachlorophenol that can detect in the textiles that now still uses C.I. DISPERSE ORANGE 30 200 29, C.I. DISPERSE ORANGE 30 200 30, C.I. DISPERSE ORANGE 30 200 41, C.I. DISPERSE ORANGE 30 200 62, C.I. DISPERSE ORANGE 30 200 73 in dispersed dye will cause dyeing, and alkali resistance is relatively poor, when dyeing in the above medium of pH7, coloured light reddens, and causes textiles colour cast (lacking gold-tinted).This shows, in order to overcome the deficiencies in the prior art, satisfy the needs of domestic and international market, the disperse orange dye kind of using at present remains further to be upgraded.
Summary of the invention
The invention provides a kind of disperse orange dyes mixture, its objective is and to develop a kind of environmental requirement recognized in the world that both met, has again alkali resistance, and inexpensive disperse orange dye product, be the dyestuff of C.I. DISPERSE ORANGE 30 200 1, C.I. DISPERSE ORANGE 30 200 3, C.I. DISPERSE ORANGE 30 200 37, C.I. DISPERSE ORANGE 30 200 76, C.I. DISPERSE ORANGE 30 200 61, C.I. DISPERSE ORANGE 30 200 29, C.I. DISPERSE ORANGE 30 200 30, C.I. DISPERSE ORANGE 30 200 41, C.I. DISPERSE ORANGE 30 200 62 and C.I. DISPERSE ORANGE 30 200 73 thereby substitute international Colour index number in the past commonly used.
In order to achieve the above object, the technical solution used in the present invention is: a kind of disperse orange dyes mixture, formed by dyestuff and the mixing of auxiliary agent two portions, and it is characterized in that: described dyestuff part is comprised of the dyestuff mixing of following four kinds of structures at least:
One is for meeting the dyestuff of chemical structural formula (I), and content is the 2-80% of dyestuff part gross weight,
The dyestuff example that meets chemical structural formula (I) has the Wenzhou City to increase income, and the golden yellow SE-3R of dispersion and China Patent No. that chemical industrial company produces are 96108715.3, name is called the dyestuff of " Yellow disperse dyes of azo-diphenylamines " (Granted publication CN1052496C), and its chemical structural formula is formula (I-1):
It is two for meeting the dyestuff of chemical structural formula (II), and content is the 2-80% of dyestuff part gross weight,
For example " DISPERSE ORANGE 30 200 288 " dyestuff of Zhejiang Province Runtu intercalated Co., Ltd's product just meets chemical formula (II);
It is three for meeting the dyestuff of chemical structural formula (III), and content is the 2-80% of dyestuff part gross weight,
The dyestuff that meets chemical structural formula (III) is that international Colour index number is the dyestuff of C.I. DISPERSE ORANGE 30 200 44;
It is four for meeting the dyestuff of the following chemical structure formula (VII), and content is the 0.1-2% of dyestuff part gross weight,
Related content in technique scheme is explained as follows:
1. in such scheme, meet being inexpensive and having complementary middle high temperature modification dyestuff of dyestuff (for example Zhejiang Province Runtu intercalated Co., Ltd produce " DISPERSE ORANGE 30 200 288 ") representative of chemical structural formula (II).It is orange as the basis with C.I. DISPERSE ORANGE 30 200 44 dye combinations that meet chemical structural formula (III), then carries out the adjusting of sodium yellow with the yellow dye that meets chemical structural formula (I) with corresponding compatibility, just can realize the present invention.But make it approach in the past the most frequently used C.I. DISPERSE ORANGE 30 200 30(gold-tinted in order further to regulate coloured light) and C.I. DISPERSE ORANGE 30 200 61(ruddiness) dye species, good dispersive red dye carries out the adjusting of red light can to add a small amount of alkali resistance, adds simultaneously a small amount of dispersed blue dye to carry out the adjusting of grey half-light.Wherein, the dispersive red dye that adds is for meeting the dyestuff of the following chemical structure formula (IV) or chemical structure formula V or chemical structural formula (VI), and content is the 0.1-5% of dyestuff part gross weight,
The dyestuff that meets chemical structural formula (IV) is that international Colour index number is the dyestuff of C.I. disperse red 73;
The dyestuff that meets the chemical structure formula V is that international Colour index number is the dyestuff of C.I. Red-1 200 45;
The dyestuff that meets chemical structural formula (VI) is that international Colour index number is the dyestuff of C.I. Red-1 200 79.
The dispersed blue dye that adds is for meeting the dyestuff of chemical structural formula (VII), example is the EX-SF DISPERSE BLUE EX-SF 300 SE-BR that the luxuriant Fine Chemical Co., Ltd of penglai City, shangdong Province China produces, China Patent No. is 200410021247.8, and name is called the dyestuff of " being used for the azo type disperse dyes that acid-alkaline is bathed dyeing " (Granted publication CN1227299C).
2. in such scheme, more preferably technical scheme is:
The dyestuff that meets chemical structural formula (I), content are the 5-70% of dyestuff part gross weight;
The dyestuff that meets chemical structural formula (II), content are the 5-50% of dyestuff part gross weight;
The dyestuff that meets chemical structural formula (III), content are the 5-60% of dyestuff part gross weight.
3. in such scheme, preferred technical scheme is:
The dyestuff that meets chemical structural formula (I), content are the 10-60% of dyestuff part gross weight;
The dyestuff that meets chemical structural formula (II), content are the 10-45% of dyestuff part gross weight;
The dyestuff that meets chemical structural formula (III), content are the 10-50% of dyestuff part gross weight.
4. in the name form of dispersed dye of the present invention, the C.I. of head is English Color Index abbreviation, i.e. Colour Index, and middle portion represents color type, such as DISPERSE ORANGE 30 200, Disperse Red, EX-SF DISPERSE BLUE EX-SF 300 etc., afterbody is the dyestuff numbering.This naming method is the dyestuff popular name, and is general both at home and abroad, by (the Society of Dyers and Colorists of association of Britain dyeing man; SDC) with (the American Association of Textile Chemists and Colorists of AATCC; AATCC) compile in collaboration with.
5. in such scheme, described " dyestuff part " refers to the material of pure dye in dye mixture of the present invention, do not comprise the auxiliary agent part.As everyone knows, the former dyestuff of synthetic dispersed dye is processed in commodity dispersed dye process, need to add a large amount of auxiliary agents, for example dispersion agent (sodium lignosulfonate B and import sodium lignosulfonate 85A are produced in Anyang), diffusant (dispersing agent MF and NNO) and a small amount of dust-proofing agent (dust-proofing agent JH2112).Obviously, on mass ratio basis between each dyestuff of the dye mixture of the invention described above, add the product that the auxiliary agent dilution obtains and remain within protection of the present invention.
6. in the present invention program, refer to the content of pure dye as the content of dyestuff as described in not indicating especially.And the general industry formula is to adopt former dyestuff dry product content, and owing to containing impurity in former dyestuff dry product, therefore the digital approximation of former dyestuff dry product content replaces pure dye content.The former dyestuff wet cake that is synthesized can be converted to former dyestuff dry product and measure (former dyestuff wet cake obtains former dyestuff dry product by oven dry).Some industry formula also calculates content with the quality of the standard model of certain trade mark commodity dispersed dye that contains a large amount of auxiliary agents (for example staining power 100% or 200% standard model), and this content can be scaled pure dye content.
Due to the utilization of technique scheme, adopt the present invention to make disperse orange dyes mixture and have the following advantages:
1. has good dyeing compatibleness (middle high temperature modification);
2. has good alkali resistance;
3. has cheap price in order to participate in market competition;
4. do not contain the chlorophenesic acid, Trichlorophenol, chlorophenosic acid, pentachlorophenol and the sensitization dyestuff that exceed standard in dyeing product, do not contain the halogens such as the bromine that exceeds standard and chlorine, meet the ecological product index of generally acknowledging in the world at present;
5. make in the Mixed Pinyin process at dyestuff and can adjust neatly the coloured light that the user wishes, the finished product of furnishing gold-tinted orange (coloured light that is equivalent to C.I. DISPERSE ORANGE 30 200 30 dyestuffs) for example, but the also finished product of furnishing ruddiness orange (coloured light that is equivalent to C.I. DISPERSE ORANGE 30 200 61 dyestuffs) is to facilitate the user of Dyeing-finishing Industry.
In a word, disperse orange dyes mixture of the present invention is keeping having solved the problems such as environmental protection, dyeing compatibleness and coloured light adjusting on good alkaline resistance properties basis, and the characteristics such as it is low to have price, and the market competitiveness is strong.
Embodiment
The invention will be further described below in conjunction with embodiment:
Embodiment one: a kind of disperse orange dyes mixture and preparation thereof
1, formula
2, dye mixture preparation
By formula with each dyestuff content be scaled former dyestuff wet cake weight get the raw materials ready (such as in former dyestuff wet cake 40% for dyestuff content, 60% is moisture, according to this relation, each dyestuff content is scaled former dyestuff wet cake weight).With each former dyestuff wet cake and dispersion agent sodium lignosulfonate B and sodium lignosulfonate 85A, dispersing agent MF and NNO, the mixing and water adding sand milling is through spraying drying and use a small amount of dust-proofing agent JH2112 prevent dust processing and obtain finished product.
Embodiment two: a kind of disperse orange dyes mixture and preparation thereof
1, formula
2, the dye mixture preparation is with embodiment one.
Embodiment three: a kind of disperse orange dyes mixture and preparation thereof
1, formula
2, the dye mixture preparation is with embodiment one.
Embodiment four: a kind of disperse orange dyes mixture and preparation thereof
1, formula
2, the dye mixture preparation is with embodiment one.
Embodiment five: a kind of disperse orange dyes mixture and preparation thereof
1, formula
2, the dye mixture preparation is with embodiment one.
Embodiment six: a kind of disperse orange dyes mixture and preparation thereof
1, formula
2, the dye mixture preparation is with embodiment one.
Embodiment seven: a kind of disperse orange dyes mixture and preparation thereof
1, formula
2, dye mixture preparation
The dye mixture preparation is with embodiment one.
Embodiment eight: a kind of disperse orange dyes mixture and preparation thereof
1, formula
2, the dye mixture preparation is with embodiment one.
Embodiment nine: a kind of disperse orange dyes mixture and preparation thereof
1, formula
2, the dye mixture preparation is with embodiment one.
The related problems of the embodiment of the present invention are described as follows:
1, in above embodiment one to nine, the dyestuff part is mixed by five kinds of dyestuffs and is formed, and wherein, fourth, fifth is to regulate product dyeing coloured light.The embodiment of the present invention one to nine is mainly for substituting the most frequently used C.I. DISPERSE ORANGE 30 200 30(gold-tinted) and C.I. DISPERSE ORANGE 30 200 61(ruddiness) and design.
2, in above embodiment one to nine, specifically provided the content of each dyestuff component, but those skilled in the art are under the inspiration of above-described embodiment, and the content of easily understanding each dyestuff component allows to change in the disclosed maximum level scope of specification sheets, also can obtain identical or akin effect.
3, in above embodiment one to nine, what auxiliary agent used is dispersion agent and diffusant, has also used dust-proofing agent after spraying drying.Wherein, dispersion agent has been selected domestic sodium lignosulfonate Type B or/and import sodium lignosulfonate 85A.Diffusant has selected domestic MF or/and NNO.Dust-proofing agent has been selected JH2112.But one skilled in the art will appreciate that and often contain a large amount of auxiliary agents in the commodity admixture of disperse dyes, quantity, kind and the content of auxiliary agent use are all more flexible in practice, are difficult to the more comprehensive of summary.On the other hand; character from dispersed dye; auxiliary agent does not have substantial effect to fast light property, resistance to acids and bases and the sublimation fastness of shining of the present invention; auxiliary agent is high temperature dispersibility and the low temperature diffusion degree of impact in the dyestuff use procedure just; therefore both made the auxiliary agent that uses in a kind of disperse orange dyes mixture not in the listed scope of the embodiment of the present invention; as long as its dyestuff part is identical, be substance identical, remain within protection scope of the present invention.
Above-described embodiment only is explanation technical conceive of the present invention and characteristics, and its purpose is to allow person skilled in the art scholar can understand content of the present invention and implement according to this, can not limit protection scope of the present invention with this.All equivalences that spirit is done according to the present invention change or modify, within all should being encompassed in protection scope of the present invention.
Claims (5)
1. a disperse orange dyes mixture, be comprised of dyestuff and the mixing of auxiliary agent two portions, it is characterized in that: described dyestuff part is comprised of the dyestuff mixing of following four kinds of structures at least:
One is the dyestuff that meets the chemical structure formula I, and content is the 2-80% of dyestuff part gross weight,
It is two for meeting the dyestuff of chemical structure formula II, and content is the 2-80% of dyestuff part gross weight,
It is three for meeting the dyestuff of chemical structure formula III, and content is the 2-80% of dyestuff part gross weight,
It is four for meeting the dyestuff of the following chemical structure formula (VII), and content is the 0.1-2% of dyestuff part gross weight,
2. disperse orange dyes mixture according to claim 1, it is characterized in that: described dyestuff partly contains the dyestuff that meets the following chemical structure formula IV or chemical structural formula (V) or chemical structure formula VI, and content is the 0.1-5% of dyestuff part gross weight
3. disperse orange dyes mixture according to claim 1 is characterized in that:
The dyestuff that meets the chemical structure formula I, content are the 5-70% of dyestuff part gross weight;
The dyestuff that meets the chemical structure formula II, content are the 5-50% of dyestuff part gross weight;
The dyestuff that meets the chemical structure formula III, content are the 5-60% of dyestuff part gross weight.
4. disperse orange dyes mixture according to claim 3 is characterized in that:
The dyestuff that meets the chemical structure formula I, content are the 10-60% of dyestuff part gross weight;
The dyestuff that meets the chemical structure formula II, content are the 10-45% of dyestuff part gross weight;
The dyestuff that meets the chemical structure formula III, content are the 10-50% of dyestuff part gross weight.
5. disperse orange dyes mixture according to claim 1, it is characterized in that: described auxiliary agent comprises diffusant and dispersion agent, diffusant selects MF or/and NNO, and dispersion agent is selected the sodium lignosulfonate class, the surplus of the consumption of diffusant and dispersion agent after for deduction dyestuff part gross weight.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110454296 CN102516815B (en) | 2011-12-30 | 2011-12-30 | Disperse orange dye mixture |
| PCT/CN2012/070605 WO2013097315A1 (en) | 2011-12-30 | 2012-01-19 | Dispersed orange dye mixture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110454296 CN102516815B (en) | 2011-12-30 | 2011-12-30 | Disperse orange dye mixture |
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| CN102516815A CN102516815A (en) | 2012-06-27 |
| CN102516815B true CN102516815B (en) | 2013-06-05 |
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Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103571229B (en) * | 2013-10-18 | 2014-12-10 | 浙江山峪染料化工有限公司 | Intermediate temperate type high-fastness dispersed orange dye |
| CN104119698B (en) * | 2014-08-05 | 2016-03-30 | 浙江山峪染料化工有限公司 | A kind of ash is to black disperse dye mixture |
| CN104151863B (en) * | 2014-08-30 | 2015-07-29 | 浙江花蝶化学股份有限公司 | A kind of high alkaline-resisting Disperse black dye composition |
| CN104592782B (en) * | 2014-12-22 | 2016-09-14 | 浙江闰土研究院有限公司 | Be suitable to the azo type disperse dyes of dyeing in acid-alkaline bath, prepare and apply |
| CN106147291A (en) * | 2015-04-08 | 2016-11-23 | 上海汇友精密化学品有限公司 | A kind of disperse dye composition |
| CN104947355B (en) * | 2015-06-29 | 2017-08-29 | 无锡爱依特纺织有限公司 | Integrated dye addictive delivery system and technique |
| CN118530605A (en) * | 2024-05-14 | 2024-08-23 | 蓬莱嘉信染料化工股份有限公司 | Azo disperse dye and preparation method and application thereof |
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| US5201922A (en) * | 1990-12-18 | 1993-04-13 | Hoechst Mitsubishi Kasei Co., Ltd. | Disperse dye mixture and dyeing method employing it: orange and yellow azo disperse dye mixture for polyester fibers |
| JP3311170B2 (en) * | 1994-09-29 | 2002-08-05 | 日本化薬株式会社 | Orange disperse dye composition and method for dyeing hydrophobic fiber material using the same |
| JPH10251534A (en) * | 1997-03-11 | 1998-09-22 | Daisutaa Japan Kk | Mixture of orange color-based disperse dye |
| GB2336852A (en) * | 1998-05-01 | 1999-11-03 | Yorkshire Chemicals Plc | Dye composition for dyeing fibres based on mixture of at least three N-ethyl-N-substituted 4-(2-halo-4-nitro-6-[halo/nitro]phenyl)azoaniline derivatives |
| CN1227299C (en) * | 2004-04-06 | 2005-11-16 | 蓬莱华茂精细化工有限公司 | Azo type disperse dyes in use for coloration in acid-alkalinity bath |
| CN1274769C (en) * | 2004-11-10 | 2006-09-13 | 浙江龙盛集团股份有限公司 | Composite disperse orange dye |
| CN1995154B (en) * | 2006-12-21 | 2010-05-19 | 浙江龙盛集团股份有限公司 | Dispersing orange dye composition and dispersing dye |
| CN100569866C (en) * | 2008-01-28 | 2009-12-16 | 吴江市绿洲染料化工有限公司 | A kind of environment-friendly type and alkaline-resisting type disperse orange dyes mixture |
| CN101275039B (en) * | 2008-03-21 | 2010-12-15 | 上虞市金冠化工有限公司 | Disperse orange dye composition |
| CN101307191B (en) * | 2008-06-28 | 2011-11-30 | 浙江龙盛集团股份有限公司 | Disperse dye composition and disperse dyes |
| CN101649129B (en) * | 2009-07-30 | 2013-02-13 | 浙江龙盛染料化工有限公司 | Disperse dye composition suitable for basic dyeing |
| CN102031017B (en) * | 2010-11-16 | 2014-07-16 | 玛德(上虞)染料有限公司 | Disperse dye composition and application thereof |
| CN102161839B (en) * | 2011-02-24 | 2013-05-29 | 浙江万丰化工有限公司 | Composition of disperse dyes |
| CN102153889B (en) * | 2011-02-24 | 2013-04-17 | 浙江万丰化工有限公司 | Orange disperse dye compound |
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2011
- 2011-12-30 CN CN 201110454296 patent/CN102516815B/en active Active
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2012
- 2012-01-19 WO PCT/CN2012/070605 patent/WO2013097315A1/en active Application Filing
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| CN102516815A (en) | 2012-06-27 |
| WO2013097315A1 (en) | 2013-07-04 |
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