CN102516815A - Disperse orange dye mixture - Google Patents
Disperse orange dye mixture Download PDFInfo
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- CN102516815A CN102516815A CN2011104542960A CN201110454296A CN102516815A CN 102516815 A CN102516815 A CN 102516815A CN 2011104542960 A CN2011104542960 A CN 2011104542960A CN 201110454296 A CN201110454296 A CN 201110454296A CN 102516815 A CN102516815 A CN 102516815A
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- dyestuff
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- 0 CCN(*)C1C=C(*)C(N=Nc([s]c2c3)nc2ccc3[N+]([O-])=O)=CC1 Chemical compound CCN(*)C1C=C(*)C(N=Nc([s]c2c3)nc2ccc3[N+]([O-])=O)=CC1 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
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- Organic Chemistry (AREA)
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Abstract
A disperse orange dye mixture comprises a dye part and an auxiliary part which are mixed with each other, and is characterized in that the dye part is formed by mixing at least three dyes adopting the structures as follows: one of the three dyes is a dye adopting the chemical structural formula I, and is 2 to 80 percent of the dye part by weight; the second of the three dyes is a dye adopting the chemical structural formula II, and is 2 to 80 percent of the dye part by weight; and the last dye is a dye adopting the chemical structural formula III, and is 2 to 80 percent of the dye part by weight.
Description
Technical field
The present invention relates to a kind of dispersed dye that are applicable to polyster fibre or dyeing fabric, the environment-friendly type disperse orange dyes mixture that particularly a kind of alkali resistance is good and inexpensive.
Background technology
Dispersed dye are a kind of starting stages in dyeing course, under the effect of dispersion agent, be dispersion state hydrophobic fibre is carried out painted one type of nonionic dye.Dispersed dye have complete chromatogram, lovely luster, and coloring intensity is high, and has good and economic.According to dyestuff Industry in China association statistics, the first place that China's dispersed dye consumption row occupy various dyestuffs, the usage quantity 60% of whole world dispersed dye is produced outlet by China.
In the orange disperse dye commonly used in the past; International Colour index number is the dyestuff of C.I. DISPERSE ORANGE 30 200 1, C.I. DISPERSE ORANGE 30 200 3, C.I. DISPERSE ORANGE 30 200 37, C.I. DISPERSE ORANGE 30 200 76, C.I. DISPERSE ORANGE 30 200 61, C.I. DISPERSE ORANGE 30 200 29, C.I. DISPERSE ORANGE 30 200 30, C.I. DISPERSE ORANGE 30 200 41, C.I. DISPERSE ORANGE 30 200 62 and C.I. DISPERSE ORANGE 30 200 73; It is supporting to can be used as basic middle dark color at home and abroad, with DISPERSE NAVY BLUE EXSF 300& BLUE 56 100 colour system and dispersed ruby colour system and the black mutual colorant match of dispersion.But the most frequently used in above disperse orange dye kind is the C.I. DISPERSE ORANGE 30 200 30 of gold-tinted and the C.I. DISPERSE ORANGE 30 200 61 of ruddiness.
At present, along with the continuous enhancing of human environmental consciousness, environmentfriendly products standard universally acknowledged in dye field is also more and more stricter.Not only European ecological textile standard (OEKO-TEX Standard 100) is strict gradually to the restriction of detrimental impurity in the dyestuff (like sensitization dye and polystream phenol or the like), and European in recent years rules of all having worked out severeer restriction halogen with Japan.See from present Europe and some industry standards (" IEC 61249-2-21 ", " JPCA-ES01 2003 " and " IPC 4101 ") that Japan issues; Bromine content is no more than 900ppm in the general acceptable environmentfriendly products; Cl content is no more than 900ppm, and the total content of halogen is at most 1500ppm.If now still use C.I. DISPERSE ORANGE 30 200 1, C.I. DISPERSE ORANGE 30 200 3, C.I. DISPERSE ORANGE 30 200 37, C.I. DISPERSE ORANGE 30 200 76 and the C.I. DISPERSE ORANGE 30 200 61 in the dispersed dye, will cause can detected sensitization dyestuff and bromo element severe overweight in the painted textiles.Can detected NSC 2879 if still use now C.I. DISPERSE ORANGE 30 200 29, C.I. DISPERSE ORANGE 30 200 30, C.I. DISPERSE ORANGE 30 200 41, C.I. DISPERSE ORANGE 30 200 62, C.I. DISPERSE ORANGE 30 200 73 in the dispersed dye will cause in the painted textiles, organochlorine compound severe overweights such as Trichlorophenol 98, chlorophenosic acid and pentachlorophenol; And alkali resistance is relatively poor; Coloured light reddens when in the above medium of pH7, dyeing, and causes textiles colour cast (lacking gold-tinted).This shows, in order to overcome the deficiency of prior art, satisfy the needs of domestic and international market, the disperse orange dye kind of using at present remains further to be upgraded.
Summary of the invention
The present invention provides a kind of disperse orange dyes mixture; Its objective is and to develop a kind of universally acknowledged environmental requirement at present that both met; Has alkali resistance again; And inexpensive disperse orange dye product, be the dyestuff of C.I. DISPERSE ORANGE 30 200 1, C.I. DISPERSE ORANGE 30 200 3, C.I. DISPERSE ORANGE 30 200 37, C.I. DISPERSE ORANGE 30 200 76, C.I. DISPERSE ORANGE 30 200 61, C.I. DISPERSE ORANGE 30 200 29, C.I. DISPERSE ORANGE 30 200 30, C.I. DISPERSE ORANGE 30 200 41, C.I. DISPERSE ORANGE 30 200 62 and C.I. DISPERSE ORANGE 30 200 73 thereby substitute international Colour index number commonly used in the past.
In order to achieve the above object, the technical scheme that the present invention adopts is: a kind of disperse orange dyes mixture, form by dyestuff and the mixing of auxiliary agent two portions, and it is characterized in that: said dyestuff part is made up of the dyestuff mixing of following three kinds of structures at least:
One of which is the dyestuff that meets the chemical structure formula I, and content is 2 ~ 80% of dyestuff part gross weight,
?(Ⅰ)
The dyestuff instance that meets the chemical structure formula I have the Wenzhou City to increase income golden yellow SE-3R of dispersion that chemical industrial company produces and Chinese patent number are 96108715.3; Name is called the dyestuff of " Yellow disperse dyes of azo-diphenylamines " (Granted publication CN1052496C), and its chemical structural formula is formula (I-1):
It is two for meeting the dyestuff of chemical structure formula II, and content is 2 ~ 80% of dyestuff part gross weight,
For example " DISPERSE ORANGE 30 200 288 " dyestuff of Zhejiang Province Runtu intercalated Co., Ltd's product just meets chemical formula II;
It is three for meeting the dyestuff of chemical structure formula III, and content is 2 ~ 80% of dyestuff part gross weight,
The dyestuff that meets the chemical structure formula III is that international Colour index number is the dyestuff of C.I. DISPERSE ORANGE 30 200 44.
Related content in the technique scheme is explained as follows:
1. in the such scheme, meet being inexpensive and having complementary middle high temperature modification dyestuff of dyestuff (for example Zhejiang Province Runtu intercalated Co., Ltd produce " DISPERSE ORANGE 30 200 288 ") representative of chemical structure formula II.It is orange as the basis with C.I. DISPERSE ORANGE 30 200 44 dye combinations that meet the chemical structure formula III, carries out the adjusting of sodium yellow with the yellow dye that meets the chemical structure formula I with corresponding compatibility again, just can realize the present invention.But make it near the most frequently used in the past C.I. DISPERSE ORANGE 30 200 30 (gold-tinted) and C.I. DISPERSE ORANGE 30 200 61 (ruddiness) dye species in order further to regulate coloured light; Good dispersive red dye carries out the adjusting of red light can to add a spot of alkali resistance, can add the adjusting that a spot of dispersed blue dye carries out grey half-light simultaneously.Wherein, the dispersive red dye of adding is for meeting the dyestuff of the following chemical structure formula IV or chemical structural formula (V) or chemical structure formula VI, and content is 0.1 ~ 5% of dyestuff part gross weight,
(Ⅳ)
The dyestuff that meets the chemical structure formula IV is that international Colour index number is the dyestuff of C.I. Disperse Red 73;
(Ⅴ)
The dyestuff that meets chemical structural formula (V) is that international Colour index number is the dyestuff of C.I. Red-1 200 45;
The dyestuff that meets the chemical structure formula VI is that international Colour index number is the dyestuff of C.I. Red-1 200 79.
The dispersed blue dye that adds is for meeting the dyestuff of the following chemical structure formula (VII), and content is 0.1 ~ 2% of dyestuff part gross weight,
The dyestuff instance that meets chemical structural formula (VII) is the EX-SF DISPERSE BLUE EX-SF 300 SE-BR that Shandong Province Penglai Huamao Fine Chemical Industry Co., Ltd produces; Chinese patent number is 200410021247.8, and name is called the dyestuff of " be used for acid-alkaline and bathe painted azo type disperse dyes " (Granted publication CN1227299C).
2. in the such scheme, more preferably technical scheme is:
The dyestuff that meets the chemical structure formula I, content are 5 ~ 70% of dyestuff part gross weight;
The dyestuff that meets the chemical structure formula II, content are 5 ~ 50% of dyestuff part gross weight;
The dyestuff that meets the chemical structure formula III, content are 5 ~ 60% of dyestuff part gross weight.
3. in the such scheme, preferred technical scheme is:
The dyestuff that meets the chemical structure formula I, content are 10 ~ 60% of dyestuff part gross weight;
The dyestuff that meets the chemical structure formula II, content are 10 ~ 45% of dyestuff part gross weight;
The dyestuff that meets the chemical structure formula III, content are 10 ~ 50% of dyestuff part gross weight.
4. in the name form of dispersed dye of the present invention, the C.I. of head is English Color Index abbreviation, i.e. Colour Index, and middle portion is represented color type, such as DISPERSE ORANGE 30 200, Disperse Red, EX-SF DISPERSE BLUE EX-SF 300 etc., afterbody is the dyestuff numbering.This naming method is the dyestuff popular name, and is general both at home and abroad, by Britain (the Society of Dyers and Colorists of tame association that dyes; SDC) with (the American Association of Textile Chemists and Colorists of AATCC; AATCC) compile in collaboration with.
5. in the such scheme, said " dyestuff part " is meant the material of pure dye in the dye mixture of the present invention, do not comprise the auxiliary agent part.As everyone knows; The former dyestuff of synthetic dispersed dye well is processed in the commodity dispersed dye process; Need to add a large amount of auxiliary agents, for example dispersion agent (sodium lignosulfonate B and import sodium lignosulfonate 85A are produced in Anyang), diffusant (dispersing agent MF and NNO) and a spot of dust-proofing agent (dust-proofing agent JH2112).Obviously, on mass ratio basis between each dyestuff of the dye mixture of the invention described above, add the product that the auxiliary agent dilution obtains and remain within protection of the present invention.
6. among the present invention program, be meant the content of pure dye like the content that does not indicate said dyestuff especially.And the general industry prescription is to adopt former dyestuff dry product content, owing to contain impurity in the former dyestuff dry product, therefore the digital approximation of former dyestuff dry product content replaces pure dye content.The former dyestuff wet cake that is synthesized can be converted to former dyestuff dry product and measure (former dyestuff wet cake obtains former dyestuff dry product through oven dry).The industry that has prescription also calculates content with the quality of the standard model of certain trade mark commodity dispersed dye that contains a large amount of auxiliary agents (for example staining power 100% or 200% standard model), and this content can be scaled pure dye content.
Because the utilization of technique scheme is adopted the present invention to process disperse orange dyes mixture and is had the following advantages:
1. has good dyeing compatibleness (middle high temperature modification);
2. has good alkali resistance;
3. has cheap price so that participate in market competition;
4. do not contain the NSC 2879, Trichlorophenol 98, chlorophenosic acid, pentachlorophenol and the sensitization dyestuff that exceed standard in the dyeing finished product, do not contain halogens such as the bromine that exceeds standard and chlorine, meet the ecological product index of generally acknowledging in the world at present;
5. make to mix in the assembly process at dyestuff and can adjust the coloured light that the user hopes neatly; The finished product of furnishing gold-tinted orange (coloured light that is equivalent to C.I. DISPERSE ORANGE 30 200 30 dyestuffs) for example; But the also finished product of furnishing ruddiness orange (coloured light that is equivalent to C.I. DISPERSE ORANGE 30 200 61 dyestuffs) is to make things convenient for the user of dyeing and finishing industry.
In a word, disperse orange dyes mixture of the present invention is keeping having solved problems such as environmental protection, dyeing compatibleness and coloured light adjusting on the good alkaline resistance properties basis, and characteristics such as it is low to have price, and the market competitiveness is strong.
Embodiment
Below in conjunction with embodiment the present invention is further described:
Embodiment one: a kind of disperse orange dyes mixture and preparation thereof
1, prescription
Form content
(1) yellow dye of chemical structural formula (I-1) (the pure dye dry product is heavy) 20%
(2) Zhejiang Province Runtu intercalated Co., Ltd's DISPERSE ORANGE 30 200 288 (the pure dye dry product is heavy) 15%
(3) C.I. DISPERSE ORANGE 30 200 44 dyestuffs (the pure dye dry product is heavy) 10%
(4) C.I. Red-1 200 79 dyestuffs (the pure dye dry product is heavy) 1%
(5) dispersed blue dye of chemical structural formula (VII) (the pure dye dry product is heavy) 0.1%
(6) dispersion agent sodium lignosulfonate and diffusant class 53.9%
2, dye mixture preparation
By prescription with each dyestuff content be scaled former dyestuff wet cake weight get the raw materials ready (such as in the former dyestuff wet cake 40% for dyestuff content, 60% is moisture, according to this relation each dyestuff content is scaled former dyestuff wet cake weight).With each former dyestuff wet cake and dispersion agent sodium lignosulfonate B and sodium lignosulfonate 85A, dispersing agent MF and NNO, the mixing and water adding sand milling is through spraying drying and use a small amount of dust-proofing agent JH2112 prevent dust processing and obtain finished product.
Embodiment two: a kind of disperse orange dyes mixture and preparation thereof
1, prescription
Form content
(1) yellow dye of chemical structural formula (I-1) (the pure dye dry product is heavy) 17%
(2) Zhejiang Province Runtu intercalated Co., Ltd's DISPERSE ORANGE 30 200 288 (the pure dye dry product is heavy) 15%
(3) C.I. DISPERSE ORANGE 30 200 44 dyestuffs (the pure dye dry product is heavy) 13%
(4) C.I. Red-1 200 79 dyestuffs (the pure dye dry product is heavy) 2%
(5) dispersed blue dye of chemical structural formula (VII) (the pure dye dry product is heavy) 0.2%
(6) dispersion agent sodium lignosulfonate and diffusant class 52.8%
2, the dye mixture preparation is with embodiment one.
Embodiment three: a kind of disperse orange dyes mixture and preparation thereof
1, prescription
Form content
(1) yellow dye of chemical structural formula (I-1) (the pure dye dry product is heavy) 15%
(2) Zhejiang Province Runtu intercalated Co., Ltd's DISPERSE ORANGE 30 200 288 (the pure dye dry product is heavy) 17%
(3) C.I. DISPERSE ORANGE 30 200 44 dyestuffs (the pure dye dry product is heavy) 15%
(4) C.I. Red-1 200 79 dyestuffs (the pure dye dry product is heavy) 3%
(5) dispersed blue dye of chemical structural formula (VII) (the pure dye dry product is heavy) 0.3%
(6) dispersion agent sodium lignosulfonate and diffusant class 49.7%
2, the dye mixture preparation is with embodiment one.
Embodiment four: a kind of disperse orange dyes mixture and preparation thereof
1, prescription
Form content
(1) yellow dye of chemical structural formula (I-1) (the pure dye dry product is heavy) 20%
(2) Zhejiang Province Runtu intercalated Co., Ltd's DISPERSE ORANGE 30 200 288 (the pure dye dry product is heavy) 15%
(3) C.I. DISPERSE ORANGE 30 200 44 dyestuffs (the pure dye dry product is heavy) 10%
(4) C.I. Disperse Red 73 dyestuffs (the pure dye dry product is heavy) 0.8%
(5) dispersed blue dye of chemical structural formula (VII) (the pure dye dry product is heavy) 0.3%
(6) dispersion agent sodium lignosulfonate and diffusant class 53.9%
2, the dye mixture preparation is with embodiment one.
Embodiment five: a kind of disperse orange dyes mixture and preparation thereof
1, prescription
Form content
(1) yellow dye of chemical structural formula (I-1) (the pure dye dry product is heavy) 17%
(2) Zhejiang Province Runtu intercalated Co., Ltd's DISPERSE ORANGE 30 200 288 (the pure dye dry product is heavy) 15%
(3) C.I. DISPERSE ORANGE 30 200 44 dyestuffs (the pure dye dry product is heavy) 13%
(4) C.I. Disperse Red 73 dyestuffs (the pure dye dry product is heavy) 1.6%
(5) dispersed blue dye of chemical structural formula (VII) (the pure dye dry product is heavy) 0.6%
(6) dispersion agent sodium lignosulfonate and diffusant class 52.8%
2, the dye mixture preparation is with embodiment one.
Embodiment six: a kind of disperse orange dyes mixture and preparation thereof
1, prescription
Form content
(1) yellow dye of chemical structural formula (I-1) (the pure dye dry product is heavy) 15%
(2) Zhejiang Province Runtu intercalated Co., Ltd's DISPERSE ORANGE 30 200 288 (the pure dye dry product is heavy) 17%
(3) C.I. DISPERSE ORANGE 30 200 44 dyestuffs (the pure dye dry product is heavy) 15%
(4) C.I. Disperse Red 73 dyestuffs (the pure dye dry product is heavy) 2.4%
(5) dispersed blue dye of chemical structural formula (VII) (the pure dye dry product is heavy) 0.9%
(6) dispersion agent sodium lignosulfonate and diffusant class 49.7%
2, the dye mixture preparation is with embodiment one.
Embodiment seven: a kind of disperse orange dyes mixture and preparation thereof
1, prescription
Form content
(1) yellow dye of chemical structural formula (I-1) (the pure dye dry product is heavy) 20%
(2) Zhejiang Province Runtu intercalated Co., Ltd's DISPERSE ORANGE 30 200 288 (the pure dye dry product is heavy) 15%
(3) C.I. DISPERSE ORANGE 30 200 44 dyestuffs (the pure dye dry product is heavy) 10%
(4) C.I. Red-1 200 45 dyestuffs (the pure dye dry product is heavy) 1.2%
(5) dispersed blue dye of chemical structural formula (VII) (the pure dye dry product is heavy) 0.5%
(6) dispersion agent sodium lignosulfonate and diffusant class 53.3%
2, dye mixture preparation
The dye mixture preparation is with embodiment one.
Embodiment eight: a kind of disperse orange dyes mixture and preparation thereof
1, prescription
Form content
(1) yellow dye of chemical structural formula (I-1) (the pure dye dry product is heavy) 17%
(2) Zhejiang Province Runtu intercalated Co., Ltd's DISPERSE ORANGE 30 200 288 (the pure dye dry product is heavy) 15%
(3) C.I. DISPERSE ORANGE 30 200 44 dyestuffs (the pure dye dry product is heavy) 13%
(4) C.I. Red-1 200 45 dyestuffs (the pure dye dry product is heavy) 2.4%
(5) dispersed blue dye of chemical structural formula (VII) (the pure dye dry product is heavy) 1%
(6) dispersion agent sodium lignosulfonate and diffusant class 51.6%
2, the dye mixture preparation is with embodiment one.
Embodiment nine: a kind of disperse orange dyes mixture and preparation thereof
1, prescription
Form content
(1) yellow dye of chemical structural formula (I-1) (the pure dye dry product is heavy) 15%
(2) Zhejiang Province Runtu intercalated Co., Ltd's DISPERSE ORANGE 30 200 288 (the pure dye dry product is heavy) 17%
(3) C.I. DISPERSE ORANGE 30 200 44 dyestuffs (the pure dye dry product is heavy) 15%
(4) C.I. Red-1 200 45 dyestuffs (the pure dye dry product is heavy) 3.6%
(5) dispersed blue dye of chemical structural formula (VII) (the pure dye dry product is heavy) 1.5%
(6) dispersion agent sodium lignosulfonate and diffusant class 47.9%
2, the dye mixture preparation is with embodiment one.
The related problems of the embodiment of the invention are explained as follows:
1, in above embodiment one to nine, dyestuff part is mixed by five kinds of dyestuffs and is formed, i.e. the first five items of each Example formulations, and first three items is to constitute the requisite composition of the present invention in fact, fourth, fifth is to be used for regulating the product coloured light that dyes.The embodiment of the invention one to nine mainly is to design to substituting the most frequently used C.I. DISPERSE ORANGE 30 200 30 (gold-tinted) and C.I. DISPERSE ORANGE 30 200 61 (ruddiness).Therefore, first three items also can be used for constituting the embodiment of the invention separately, and those skilled in the art should be understood that.
2, in above embodiment one to nine; Specifically provided the content of each dyestuff component; But those skilled in the art are under the inspiration of the foregoing description, and the content of understanding each dyestuff component easily allows in the disclosed maximum level scope of specification sheets, to change, and also can obtain identical or akin effect.
3, in above embodiment one to nine, what auxiliary agent used is dispersion agent and diffusant, after spraying drying, has also used dust-proofing agent.Wherein, dispersion agent has been selected homemade sodium lignosulfonate Type B or/and import sodium lignosulfonate 85A.Diffusant has selected homemade MF or/and NNO.Dust-proofing agent has been selected JH2112.But one skilled in the art will appreciate that and in the commodity admixture of disperse dyes, often contain a large amount of auxiliary agents that quantity, kind and the content of auxiliary agent use all compare flexibly in practice, are difficult to generalized more comprehensive.On the other hand; From the character of dispersed dye, auxiliary agent does not have substantial effect to fast light property, resistance to acids and bases and the sublimation fastness property of shining of the present invention, and auxiliary agent is the dispersed and low temperature diffusion degree of the high temperature of influence in the dyestuff use just; Therefore both made in a kind of disperse orange dyes mixture employed auxiliary agent not in the listed scope of the embodiment of the invention; As long as its dyestuff part is identical, be substantive identical, remain within protection scope of the present invention.
The foregoing description only is explanation technical conceive of the present invention and characteristics, and its purpose is to let the personage who is familiar with this technology can understand content of the present invention and enforcement according to this, can not limit protection scope of the present invention with this.All equivalences that spirit is done according to the present invention change or modify, and all should be encompassed within protection scope of the present invention.
Claims (6)
1. a disperse orange dyes mixture is made up of dyestuff and the mixing of auxiliary agent two portions, it is characterized in that: said dyestuff part is made up of the dyestuff mixing of following three kinds of structures at least:
One of which is the dyestuff that meets the chemical structure formula I, and content is 2 ~ 80% of dyestuff part gross weight,
?(Ⅰ);
It is two for meeting the dyestuff of chemical structure formula II, and content is 2 ~ 80% of dyestuff part gross weight,
It is three for meeting the dyestuff of chemical structure formula III, and content is 2 ~ 80% of dyestuff part gross weight,
2. disperse orange dyes mixture according to claim 1; It is characterized in that: said dyestuff partly contains the dyestuff that meets the following chemical structure formula IV or chemical structural formula (V) or chemical structure formula VI; And content is 0.1 ~ 5% of dyestuff part gross weight
?
(Ⅴ);
3. disperse orange dyes mixture according to claim 1 and 2 is characterized in that: said dyestuff partly contains the dyestuff that meets the following chemical structure formula (VII), and content is 0.1 ~ 2% of dyestuff part gross weight,
(Ⅶ)。
4. disperse orange dyes mixture according to claim 1 is characterized in that:
The dyestuff that meets the chemical structure formula I, content are 5 ~ 70% of dyestuff part gross weight;
The dyestuff that meets the chemical structure formula II, content are 5 ~ 50% of dyestuff part gross weight;
The dyestuff that meets the chemical structure formula III, content are 5 ~ 60% of dyestuff part gross weight.
5. disperse orange dyes mixture according to claim 4 is characterized in that:
The dyestuff that meets the chemical structure formula I, content are 10 ~ 60% of dyestuff part gross weight;
The dyestuff that meets the chemical structure formula II, content are 10 ~ 45% of dyestuff part gross weight;
The dyestuff that meets the chemical structure formula III, content are 10 ~ 50% of dyestuff part gross weight.
6. disperse orange dyes mixture according to claim 1; It is characterized in that: said auxiliary agent comprises diffusant and dispersion agent; Diffusant selects MF or/and NNO, and dispersion agent is selected the sodium lignosulfonate class, and the consumption of diffusant and dispersion agent is for deducting the surplus after the dyestuff part gross weight.
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CN 201110454296 CN102516815B (en) | 2011-12-30 | 2011-12-30 | Disperse orange dye mixture |
PCT/CN2012/070605 WO2013097315A1 (en) | 2011-12-30 | 2012-01-19 | Dispersed orange dye mixture |
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CN104592782A (en) * | 2014-12-22 | 2015-05-06 | 浙江闰土研究院有限公司 | Azoic disperse dye suitable for dyeing in acidic-alkaline bath as well preparation method and application thereof |
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CN101649129A (en) * | 2009-07-30 | 2010-02-17 | 浙江龙盛染料化工有限公司 | Disperse dye composition suitable for basic dyeing |
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CN103571229A (en) * | 2013-10-18 | 2014-02-12 | 浙江山峪染料化工有限公司 | Intermediate temperate type high-fastness dispersed orange dye |
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