CN102827492A - Performance-improved disperse blue dye mixture - Google Patents

Performance-improved disperse blue dye mixture Download PDF

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Publication number
CN102827492A
CN102827492A CN2012103675616A CN201210367561A CN102827492A CN 102827492 A CN102827492 A CN 102827492A CN 2012103675616 A CN2012103675616 A CN 2012103675616A CN 201210367561 A CN201210367561 A CN 201210367561A CN 102827492 A CN102827492 A CN 102827492A
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dye
dyestuff
disperse
blue
disperse blue
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蒋金根
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WUJIANG CITY LUZHOU DYESTUFF CHEMICAL CO Ltd
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WUJIANG CITY LUZHOU DYESTUFF CHEMICAL CO Ltd
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Abstract

The invention relates to a disperse blue dye mixture which is resistant to water washing and sun drying. The disperse blue dye mixture is prepared by mixing a dye part and an assistant part. The disperse blue dye mixture is characterized in that the dye part is at least prepared by mixing the following three dyes having different structures: a first dye which has a chemical structural general formula (I) and accounts for 30-70% of the total weight of the dye part; a second dye which has a chemical structural formula (II) and accounts for 10-30% of the total weight of the dye part; and a third dye which has a chemical structural formula (III) and accounts for 10-45% of the total weight of the dye part, wherein the chemical structural general formula (I), the chemical structural formula (II) and the chemical structural formula (III) are shown in the specification; and in the chemical structural general formula (I), n is an integer from 1 to 4, and R is a group NH or O.

Description

Performance boost type blue disperse dye mixture
Technical field
The present invention relates to a kind of blue disperse dye mixture, be specifically related to a kind of performance boost type blue disperse dye mixture that is applicable to polyster fibre or dyeing fabric.
Background technology
Along with the raising of living standards of the people, people have had new requirement to function, the quality of textile garment, and what followed up synchronously in textile dyeing and finishing and clothes processing industry and the world at present speeds up, but in the actual production course of processing, has but found many problems.One of them is exactly in the textile dyeing processing, because existing dyestuff performance is not comprehensive, causes dyeing quality and grade not to reach requirement, and therefore dyestuff updates and to promote performance imperative to having now.
The dyestuff that international Colour index number is a C.I. EX-SF DISPERSE BLUE EX-SF 300 77 is a kind of high temperature modification dispersed dye, and coloured light is dark royalblue (dark royalblue).In the prior art, usually C.I. EX-SF DISPERSE BLUE EX-SF 300 77 and C.I. disperse red 86 and C.I. DISPERSE YELLOW 163 are made up colorant match as three primary colors, be used for polyster fibre and lining are carried out middle deep colour dyeing.C.I. the performance of EX-SF DISPERSE BLUE EX-SF 300 77, C.I. disperse red 86 and C.I. DISPERSE YELLOW 163 sees the following form 1:
Table 1:
Figure 678535DEST_PATH_IMAGE001
Can find out that from the performance data of table 1 C.I. EX-SF DISPERSE BLUE EX-SF 300 77 has sublimation fastness and washing fastness preferably, also has fabulous light, but the deficiency that exists is that colouring speed is slow, level-dyeing property is relatively poor.After using this dyestuff as the blue dyes in the three primary colors and other two primary colour dyes colorant match; In middle deep colour dyeing process; Too slow because of the colouring speed of C.I. EX-SF DISPERSE BLUE EX-SF 300 77, level-dyeing property is relatively poor, and obviously has the problem of matching difference between other two primary colour dye; In dyeing, cause the look flower easily, cause dyeing quality not good.For above-mentioned reasons; Use C.I. EX-SF DISPERSE BLUE EX-SF 300 77 and C.I. disperse red 86 and C.I. DISPERSE YELLOW 163 to constitute knit fabric (thread count the is lower) dyeing that three primary colors only can be applied to non-clothes class usually at present; Spin Curtains Fabrics puggaree, sandy beach parasol lining or the like such as automobile inner decoration facing, family, and can not be applied to woven fabric (thread count the is higher) dyeing of clothes class.
Summary of the invention
The present invention provides a kind of performance boost type blue disperse dye mixture; Its objective is in the time of to solve at present in polyster fibre and lining are carried out deep colour dyeing; Because of C.I. EX-SF DISPERSE BLUE EX-SF 300 77 colouring speed slow; Level-dyeing property is poor, carries out the matching problem that caused behind the three primary colors colorant match with C.I. disperse red 86 and C.I. DISPERSE YELLOW 163.
In order to achieve the above object, the technical scheme that the present invention adopts is: a kind of performance boost type blue disperse dye mixture, to form by dyestuff and the mixing of auxiliary agent two portions, and said dyestuff part is made up of the dyestuff mixing of following three kinds of structures at least:
One of which is for meeting the dyestuff of chemical structure of general formula (I), and content is 30 ~ 70% of dyestuff part gross weight,
Figure 828894DEST_PATH_IMAGE002
(Ⅰ)
In the chemical structure of general formula (I), n is one of integer of 1 to 4, and R is group NH or O;
It is two for meeting the dyestuff of chemical structure formula II, and content is 10 ~ 30% of dyestuff part gross weight,
(Ⅱ);
It is three for meeting the dyestuff of chemical structure formula III, and content is 10 ~ 45% of dyestuff part gross weight,
Figure 435772DEST_PATH_IMAGE004
(Ⅲ)。
Related content in the technique scheme is explained as follows:
1. in the such scheme, chemical structure of general formula (I) expression be dye, when R is group O (an oxygen base), n is 3 o'clock, is C.I Disperse Blue-60 dyestuff, its chemical structural formula is:
Figure 681815DEST_PATH_IMAGE005
(I-1);
C.I Disperse Blue-60 dyestuff is a kind of middle high temperature modification dispersed dye; Last colour temperature is the end since 120 ℃ to 130 ℃ generally, and molecular weight is 379.37, and coloured light is gorgeous greenish blue; Have sublimation fastness (4-5 level) and washing fastness (4 grades) preferably; Have fabulous light (more than 6 grades), and colouring speed is medium, level-dyeing property is general.
When R is group NH (amido), also be a kind of middle high temperature modification dispersed blue dye, coloured light dark partially on gorgeous greenish blue basis (ruddiness partially), the dyestuff performance is near the C.I Disperse Blue-60.This dyestuff can exist singly, also can mix existence with the C.I Disperse Blue-60, is exactly C.I EX-SF DISPERSE BLUE EX-SF 300 87 when this dyestuff mixes when existing with the C.I Disperse Blue-60.
2. in the such scheme, the chemical structure formula II is C.I 63 ,DIS,PER,SE ,Vio,let, 63 57 dyestuffs.C.I 63 ,DIS,PER,SE ,Vio,let, 63 57 dyestuffs are a kind of middle high temperature modification dispersed dye; Last colour temperature generally begins to 130 ℃ of end from 120-125 ℃, and molecular weight is 409.41, and coloured light is ruddiness blue (blue light is purple); Have sublimation fastness (4-5 level) and washing fastness (4 grades) preferably; Have fabulous light (more than 6 grades), and colouring speed is medium, level-dyeing property is general.
3. in the such scheme, the chemical structure formula III is C.I. EX-SF DISPERSE BLUE EX-SF 300 77 dyestuffs.C.I. EX-SF DISPERSE BLUE EX-SF 300 77 dyestuffs are a kind of high temperature modification dispersed dye, and last colour temperature is the end since 125 ℃ to 132 ℃ generally, wherein when 130 ℃ of left and right sides, paint in a large number; And other temperature section colouring is less, and molecular weight is 376.32, and coloured light is dark royalblue (dark royalblue); Have sublimation fastness (4-5 level) and washing fastness (4 grades) preferably; Have fabulous light (more than 6 grades), but colouring speed is too slow, level-dyeing property is relatively poor.
4. the C.I. of dispersed dye head is English Color Index abbreviation in the present invention, i.e. Colour Index, and middle portion is represented color type, such as DISPERSE ORANGE 30 200, Disperse Red, EX-SF DISPERSE BLUE EX-SF 300 etc., afterbody is the dyestuff numbering.This name form is the dyestuff popular name, and is general both at home and abroad, by Britain (the Society of Dyers and Colorists of tame association that dyes; SDC) with (the American Association of Textile Chemists and Colorists of AATCC; AATCC) compile in collaboration with.
5. in the such scheme, said " dyestuff part " is meant the material of pure dye in the dye mixture of the present invention, do not comprise the auxiliary agent part.As everyone knows; The former dyestuff of synthetic dispersed dye well is processed in the commodity dispersed dye process; Need to add a large amount of auxiliary agents, for example dispersion agent (sodium lignosulfonate B and import sodium lignosulfonate 85A are produced in Anyang), diffusant (dispersing agent MF and NNO) and a spot of dust-proofing agent (dust-proofing agent JH2112).The surplus of the consumption of diffusant and dispersion agent after for deduction dyestuff part gross weight obviously, on mass ratio basis between each dyestuff of the dye mixture of the invention described above, added the product that the auxiliary agent dilution obtains and remained within protection of the present invention.
6. in the such scheme, the percentage composition of said " dyestuff part " is meant removes auxiliary agent and outer, the percentage composition of pure dye dry product.And the general industry prescription is to adopt former dyestuff dry product content, owing to contain impurity in the former dyestuff dry product, therefore the digital approximation of former dyestuff dry product content replaces pure dye dry product content.The former dyestuff wet cake that is synthesized can be converted to former dyestuff dry product and measure (former dyestuff wet cake obtains former dyestuff dry product through oven dry).The industry that has prescription also calculates content with the quality of the standard model of certain trade mark commodity dispersed dye that contains a large amount of auxiliary agents (for example staining power 100% or 200% standard model), and this content can be scaled pure dye dry product content.
Design concept of the present invention and mechanism are: slow because of colouring speed in order to solve existing C.I. EX-SF DISPERSE BLUE EX-SF 300 77, level-dyeing property is poor, carry out the three primary colors colorant match with C.I. disperse red 86 and C.I. DISPERSE YELLOW 163 after, the matching problem that when middle deep colour dyeing, is caused.The present invention has added C.I Disperse Blue-60 and C.I 63 ,DIS,PER,SE ,Vio,let, 63 57 on the basis of C.I. EX-SF DISPERSE BLUE EX-SF 300 77, constituted a kind of new blue disperse dye mixture through mixing.This new blue disperse dye mixture has following mechanism and characteristics:
1. aspect coloured light; Owing to there is the adjustability of blue coloured light between the coloured light of C.I Disperse Blue-60 and C.I 63 ,DIS,PER,SE ,Vio,let, 63 57; Can control coloured light through the adjusting of C.I Disperse Blue-60 and C.I 63 ,DIS,PER,SE ,Vio,let, 63 57 ratios, thereby on coloured light, keep the consistence with C.I. EX-SF DISPERSE BLUE EX-SF 300 77.
2. aspect matching; Because the last colour temperature of C.I Disperse Blue-60 and C.I 63 ,DIS,PER,SE ,Vio,let, 63 57 all is lower than the last colour temperature of C.I. EX-SF DISPERSE BLUE EX-SF 300 77; After C.I. EX-SF DISPERSE BLUE EX-SF 300 77 and C.I Disperse Blue-60 and 57 triplicitys of C.I 63 DISPERSE Violet 63, in general, in the characteristics that can satisfy aspect the last colour temperature in differing temps Duan Junneng colouring; Overcome in the past C.I. EX-SF DISPERSE BLUE EX-SF 300 77 and when 130 ℃ of left and right sides, painted in a large number, and other temperature section colouring less defects; Aspect level-dyeing property; Because the level-dyeing property of C.I Disperse Blue-60 and C.I 63 ,DIS,PER,SE ,Vio,let, 63 57 is better than C.I. EX-SF DISPERSE BLUE EX-SF 300 77; Remedied the deficiency of C.I. EX-SF DISPERSE BLUE EX-SF 300 77 after the triplicity; Improved the level dyeing performance on the whole, improved whole level-dyeing property, enabled better and other two primary colour dye matees.
3. aspect sublimation fastness, washing fastness and light; Because C.I. EX-SF DISPERSE BLUE EX-SF 300 77, C.I Disperse Blue-60 and C.I 63 ,DIS,PER,SE ,Vio,let, 63 57 threes' performance is all better, can keep sublimation fastness and washing fastness performance and good light performance preferably on the whole.
4. aspect planeness; Because the molecular weight of C.I Disperse Blue-60 is 379.37; The molecular weight of C.I 63 ,DIS,PER,SE ,Vio,let, 63 57 is 409.41, and the molecular weight of C.I EX-SF DISPERSE BLUE EX-SF 300 77 is 376.32, and the molecular weight between the three is different; And large, medium and small branch is arranged, so behind the dyeing of triplicity to fiber or cloth cover opacifying property better.
Because the utilization of technique scheme, the present invention compares with existing C.I EX-SF DISPERSE BLUE EX-SF 300 77 and has the following advantages and effect:
Blue disperse dye mixture of the present invention is a kind of upgraded product that can substitute existing C.I EX-SF DISPERSE BLUE EX-SF 300 77, and coloured light is dark royalblue (dark royalblue).After utilizing this blue disperse dye mixture and C.I. disperse red 86 and C.I. DISPERSE YELLOW 163 to carry out the three primary colors colorant match, when middle deep colour dyeing, can be good at solving the matching problem of in the past using C.I EX-SF DISPERSE BLUE EX-SF 300 77 to be caused separately.
Provide blue disperse dye mixture of the present invention, C.I. DISPERSE YELLOW 163 and C.I. disperse red 86 dyestuff colouring speed and level-dyeing property test data below respectively, see the following form 2:
Table 2:
? 90 ℃ of cloth specimen degree of depth 100 ℃ of cloth specimen degree of depth 110 ℃ of cloth specimen degree of depth 115 ℃ of cloth specimen degree of depth 120 ℃ of cloth specimen degree of depth 125 ℃ of cloth specimen degree of depth 130 ℃ of cloth specimen degree of depth 130 ℃ of 30min cloth specimen degree of depth
Embodiment 2 Dye uptake 5% Dye uptake 10% Dye uptake 25% Dye uptake 50% Dye uptake 75% Dye uptake 85% Dye uptake 93% Dye uptake 98%
DISPERSE YELLOW 163 Dye uptake 5% Dye uptake 10% Dye uptake 25% Dye uptake 40% Dye uptake 50% Dye uptake 80% Dye uptake 90% Dye uptake 98%
Disperse red 86 Dye uptake 5% Dye uptake 10% Dye uptake 25% Dye uptake 35% Dye uptake 45% Dye uptake 75% Dye uptake 93% Dye uptake 98%
Can find out that from last table 2 embodiment of the invention 2 blue disperse dye mixtures are better with the matching of C.I. DISPERSE YELLOW 163 and C.I. disperse red 86 aspect colouring speed and level-dyeing property.
In a word; Blue disperse dye mixture of the present invention has kept the coloured light of C.I EX-SF DISPERSE BLUE EX-SF 300 77 and the advantage of aspect of performance; Overcome the deficiency of C.I EX-SF DISPERSE BLUE EX-SF 300 77 aspect last colour temperature and level-dyeing property; Be the upgraded product that can substitute existing C.I EX-SF DISPERSE BLUE EX-SF 300 77 in the market, have the market application foreground of wide expansion.
Embodiment
Below in conjunction with embodiment the present invention is further described:
Before describing embodiment; Need to specify: the content of each component is meant with the blue disperse dye mixture gross weight to be the weight percentage of benchmark in following examples prescription; Wherein, the blue disperse dye mixture gross weight is all each dyestuff weight and all each auxiliary agent weight sums.And the percentage composition that the front is put down in writing in the technical scheme of summary of the invention be with except that auxiliary agent and dyestuff part gross weight be the weight percentage of benchmark.There is conversion relation between the two.
Embodiment 1: a kind of performance boost type blue disperse dye mixture and preparation method thereof
1. fill a prescription
Form weight percentage (%)
(1) C.I. Disperse Blue-60 staining power 240% commercial dye 42.5;
(2) C.I. 63 ,DIS,PER,SE ,Vio,let, 63 57 staining powers 200% commercial dye 18.0;
(3) C.I. EX-SF DISPERSE BLUE EX-SF 300 77 staining powers 200% commercial dye 38.5;
(4) dispersion agent, diffusant and dust-proofing agent surplus;
Wherein: the weight of pure dye dry product is 50% in the commercial dye of C.I. Disperse Blue-60; The weight of pure dye dry product is 50% in the commercial dye of C.I. 63 ,DIS,PER,SE ,Vio,let, 63 57; The weight of pure dye dry product is 30% in the commercial dye of C.I. EX-SF DISPERSE BLUE EX-SF 300 77.In above-mentioned three kinds of commercial goods dyestuffs except that the pure dye dry product and, all the other are auxiliary agent.Above-mentioned dispersion agent can select Anyang to produce sodium lignosulfonate B or/and import sodium lignosulfonate 85A.Above-mentioned diffusant can select MF or/and NNO).Above-mentioned dust-proofing agent can be selected JH2112.
2. dye mixture preparation
Above three kinds of commercial goods dyestuffs and dispersion agent and diffusant are weighed by requirement, drop into stirrer mixing stirring, up to stirring, and then spray into a small amount of dust-proofing agent JH2112 processing of preventing dust, be packaged to be finished product at last.
Embodiment 2: a kind of performance boost type blue disperse dye mixture and preparation method thereof
1. fill a prescription
Form weight percentage (%)
(1) C.I. Disperse Blue-60 pure dye dry product 21.25;
(2) C.I. 63 ,DIS,PER,SE ,Vio,let, 63 57 pure dye dry products 9.00;
(3) C.I. EX-SF DISPERSE BLUE EX-SF 300 77 pure dye dry products 11.55;
(4) dispersion agent, diffusant and dust-proofing agent surplus;
Wherein: the selection of dispersion agent, diffusant and dust-proofing agent is identical with embodiment 1.
2. dye mixture preparation
By prescription various pure dye dry product weight being scaled former dyestuff wet cake weight gets the raw materials ready; (such as: 40% is dyestuff in the former dyestuff wet cake; 60% is moisture; According to this relation each pure dye dry product weight is scaled former dyestuff wet cake weight); With each former dyestuff wet cake and dispersion agent sodium lignosulfonate B and the 85A of sodium lignosulphonate, dispersing agent MF and NNO mixing and water adding sand milling, through spraying drying and use a small amount of dust-proofing agent JH2112 processing of preventing dust, pack then and obtain finished product.
The embodiment of the invention 1 and embodiment 2 be from being seen as two embodiment in form, but from the composition of pure dye dry product with contain that to take temperature be substantive identical.The concrete contrast as follows:
Embodiment 1 pure dye dry product embodiment 2 pure dye dry products
C.I. Disperse Blue-60 42.5% * 50%=21.25% 21.25%;
C.I. 63 ,DIS,PER,SE ,Vio,let, 63 57 18.0% * 50%=9.00% 9.00%;
C.I. EX-SF DISPERSE BLUE EX-SF 300 77 38.5% * 30%=8.90% 11.55%.
Can conversing each dye component among embodiment 1 and the embodiment 2 thus, to account for the percentage composition of dyestuff part gross weight following:
C.I. Disperse Blue-60 21.25 ÷ 41.8 * 100%=50.84%;
C.I. 63 ,DIS,PER,SE ,Vio,let, 63 57 9.00 ÷ 41.8 * 100%=21.53%;
C.I. EX-SF DISPERSE BLUE EX-SF 300 77 11.55 ÷ 41.8 * 100%=27.63%.
The percentage composition that accounts for dyestuff part gross weight according to each dye component in the blue disperse dye mixture below provides embodiment 3 ~ embodiment 11, sees the following form 3:
Table 3
? C.I. Disperse Blue-60 C.I. 63 ,DIS,PER,SE ,Vio,let, 63 57 C.I. EX-SF DISPERSE BLUE EX-SF 300 77
Content range 30~70% 10~30% 10~45%
Embodiment 3 32% 28% 40%
Embodiment 4 34% 29% 37%
Embodiment 5 30% 26% 44%
Embodiment 6 36% 22% 42%
Embodiment 7 68% 11% 21%
Embodiment 8 69% 20% 11%
Embodiment 9 65% 13% 22%
Embodiment 10 40% 27% 33%
Embodiment 11 50% 25% 25%
Embodiment 3 ~ embodiment 11 except each dye component account for the percentage composition of dyestuff part gross weight different and, other content can adopt the form of embodiment 1, also can adopt the form of embodiment 2 to prepare, and no longer is repeated in this description here.
The related problems of the embodiment of the invention are explained as follows:
1. in above enforcement; The dyestuff part is mixed by C.I. Disperse Blue-60, C.I. 63 ,DIS,PER,SE ,Vio,let, 63 57 and 77 3 kinds of dyestuffs of C.I. EX-SF DISPERSE BLUE EX-SF 300 and is formed; C.I. Disperse Blue-60, C.I. 63 ,DIS,PER,SE ,Vio,let, 63 57 and 77 3 kinds of dyestuffs of C.I. EX-SF DISPERSE BLUE EX-SF 300 are to constitute the requisite composition of the present invention in the present invention in fact; For the coloured light of regulating dyestuff can add other dispersed dye that can mate in right amount in above each embodiment; At least a such as in C.I. DISPERSE YELLOW 163, C.I. DISPERSE YELLOW 114, C.I. disperse red 86, C.I. Disperse Red 92, the C.I. Red-1 200 46 etc., add-on can be controlled in the pure dye gross weight 10% in.This shows that the present invention can also produce more embodiment on this basis, be used for opening statement in the supporting technology scheme.And the foregoing description 1 ~ embodiment 11 is by the requisite three kinds of embodiment that the dyestuff adding assistant is constituted of the present invention, and those skilled in the art should be understood that.
2. in above enforcement; All be to be that example is explained with C.I Disperse Blue-60 dyestuff, and the C.I Disperse Blue-60 be in the chemical structure of general formula (I) R be that group O (oxygen base), n are 3 o'clock chemical structure, in chemical structure of general formula (I); When R is group NH (amido); Because near the C.I Disperse Blue-60, can being used for replacing the C.I Disperse Blue-60, the dyestuff performance constitutes new embodiment, such as adopting C.I EX-SF DISPERSE BLUE EX-SF 300 87 to replace C.I Disperse Blue-60 etc.
3. in above embodiment; Specifically provided the content of each dye component; But those skilled in the art are under the inspiration of the foregoing description, and the content of understanding each dye component easily allows in the disclosed maximum level scope of specification sheets, to change, and also can obtain identical or akin effect.
4. in above embodiment, what auxiliary agent used is dispersion agent and diffusant, after spraying drying, has also used dust-proofing agent.Wherein, dispersion agent has been selected homemade sodium lignosulfonate Type B or/and import sodium lignosulfonate 85A.Diffusant has selected homemade MF or/and NNO.Dust-proofing agent has been selected JH2112.But one skilled in the art will appreciate that and in the commodity admixture of disperse dyes, often contain a large amount of auxiliary agents that quantity, kind and the content of auxiliary agent use all compare flexibly in practice, are difficult to generalized more comprehensive.On the other hand; From the character of dispersed dye, auxiliary agent is the dispersed and low temperature diffusion degree of the high temperature of influence in the dyestuff use just, contributes part not have substantial effect to the present invention; Therefore both made in a kind of blue disperse dye mixture employed auxiliary agent not in the listed scope of the embodiment of the invention; As long as its dyestuff part is identical, be substantive identical, remain within protection scope of the present invention.
The foregoing description only is explanation technical conceive of the present invention and characteristics, and its purpose is to let the personage who is familiar with this technology can understand content of the present invention and enforcement according to this, can not limit protection scope of the present invention with this.All equivalences that spirit is done according to the present invention change or modify, and all should be encompassed within protection scope of the present invention.

Claims (2)

1. a performance boost type blue disperse dye mixture is made up of dyestuff and the mixing of auxiliary agent two portions, it is characterized in that: said dyestuff part is made up of the dyestuff mixing of following three kinds of structures at least:
One of which is for meeting the dyestuff of chemical structure of general formula (I), and content is 30 ~ 70% of dyestuff part gross weight,
Figure 649208DEST_PATH_IMAGE001
(Ⅰ)
In the chemical structure of general formula (I), n is one of integer of 1 to 4, and R is group NH or O;
It is two for meeting the dyestuff of chemical structure formula II, and content is 10 ~ 30% of dyestuff part gross weight,
(Ⅱ);
It is three for meeting the dyestuff of chemical structure formula III, and content is 10 ~ 45% of dyestuff part gross weight,
Figure 281495DEST_PATH_IMAGE003
(Ⅲ)。
2. blue disperse dye mixture according to claim 1; It is characterized in that: said auxiliary agent comprises diffusant and dispersion agent; Diffusant selects MF or/and NNO, and dispersion agent is selected the sodium lignosulfonate class, and the consumption of diffusant and dispersion agent is for deducting the surplus after the dyestuff part gross weight.
CN2012103675616A 2012-09-28 2012-09-28 Performance-improved disperse blue dye mixture Pending CN102827492A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111621167A (en) * 2020-05-13 2020-09-04 浙江博澳新材料股份有限公司 High light fastness type gray-to-black dispersed anthraquinone dye mixture

Citations (4)

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Publication number Priority date Publication date Assignee Title
JP2004168950A (en) * 2002-11-21 2004-06-17 Dystar Japan Ltd Disperse dye mixture having high color fastness to light
CN1902286A (en) * 2003-07-04 2007-01-24 德意志戴斯达纺织品及染料两合公司 Disperse dye mixtures which have a high degree of light fastness
JP2007239111A (en) * 2006-03-06 2007-09-20 Sakai Ovex Co Ltd Sueded artificial leather
CN101309975A (en) * 2005-11-16 2008-11-19 纪和化学工业株式会社 Disperse die, disperse die composition, ink for ink-jet printing, and staining method and stained material using the die, composition or ink

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004168950A (en) * 2002-11-21 2004-06-17 Dystar Japan Ltd Disperse dye mixture having high color fastness to light
CN1902286A (en) * 2003-07-04 2007-01-24 德意志戴斯达纺织品及染料两合公司 Disperse dye mixtures which have a high degree of light fastness
CN101309975A (en) * 2005-11-16 2008-11-19 纪和化学工业株式会社 Disperse die, disperse die composition, ink for ink-jet printing, and staining method and stained material using the die, composition or ink
JP2007239111A (en) * 2006-03-06 2007-09-20 Sakai Ovex Co Ltd Sueded artificial leather

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111621167A (en) * 2020-05-13 2020-09-04 浙江博澳新材料股份有限公司 High light fastness type gray-to-black dispersed anthraquinone dye mixture

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Application publication date: 20121219