CN106833017A - A kind of blue active dye composition and its production and use - Google Patents
A kind of blue active dye composition and its production and use Download PDFInfo
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- CN106833017A CN106833017A CN201611064510.0A CN201611064510A CN106833017A CN 106833017 A CN106833017 A CN 106833017A CN 201611064510 A CN201611064510 A CN 201611064510A CN 106833017 A CN106833017 A CN 106833017A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
- C09B67/0052—Mixtures of two or more reactive monoazo dyes
- C09B67/0054—Mixtures of two or more reactive monoazo dyes all the reactive groups not being directly attached to a heterocyclic system
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
- D06P1/384—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes reactive group not directly attached to heterocyclic group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/10—Material containing basic nitrogen containing amide groups using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/24—Polyamides; Polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
- D06P3/666—Natural or regenerated cellulose using reactive dyes reactive group not directly attached to heterocyclic group
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
A kind of blue active dye composition and its production and use, the composition include formula (I) compound in one or more compound groups into component A, formula (II) compound in one or more compound groups into component B, formula (III) compound in one or more compound groups into component C and optional auxiliary agent.The blue active dye composition be applied to cotton, fiber crops, regenerated fiber or their yarn fabric printing and dyeing, or Fypro, protein fibre or their yarn fabric printing and dyeing.The blue active dye composition has degree of fixation high, the characteristics of every good color fastness.
Description
Technical field
The present invention relates to a kind of blue active dye composition and its production and use.
Background technology
With continually developing for cellulose fibre kind and continuing to develop for staining technique, reactive dye are being used to fiber
Cellulose fiber colour when, the application performance to reactive dye proposes higher and higher requirement, this all promote reactive blue dye to
Improve application performance aspect development.Reactive blue dye is used as the larger color kind of market share amount, it is desirable to cost performance higher
And excellent performance.Therefore the patent of many research reactive blue compositions is occurred in that in industry, as disclosed in CN 104448927A
Anthraquinone type composite reactive blue dye shown in formula (1), (2), formula (3), (4), (5), (6) are shown disclosed in CN 103952014A
Azo-type composite reactive blue dye, but at present many blue active dye compositions of exploitation be difficult to have concurrently degree of fixation it is high,
The combination property such as fastness properties are excellent, its resultant effect is difficult to reach the desired value of people, therefore, research and development are a kind of comprehensive
Performance more preferably, the reactive blue dye that can simultaneously meet above-mentioned characteristic requirements it is significant.But it will be understood by those skilled in the art that
Influence blue active dye degree of fixation, solubility, the factor of every color fastness are very more, are related to selection, the auxiliary agent of dye monomer
Selection, complex process flow in multiple links, dyeing in multiple steps etc., the wherein selection of dye monomer needs
How the problems such as considering coloured light, cost, compatibility, improve degree of fixation, solubility, every color fastness of dye composite
Not usually can simply be foreseen, can rather than the dye monomer for simply selecting corresponding coloured light according to color theory
With.
The content of the invention
The present invention provides a kind of blue active dye composition, and the composition has degree of fixation high, every color fastness
Can be excellent the advantages of.In addition, present invention also offers the Preparation method and use of the composition.
The present invention provides a kind of blue active dye composition, it is characterised in that including it is a kind of in formula (I) compound or with
Upper compound group into component A, formula (II) compound in one or more compound groups into component B, formula (III) compound in
One or more compound groups into component C and optional auxiliary agent：
Wherein：M1、M2、M3It is each independently hydrogen, potassium, sodium, lithium or ammonium；X1、X2、X3It is each independently halogen；
R1、R2、R3It is each independently C1~C4Alkoxy, amino ,-NHR7OH、-NHR7SO3M、
R4、R5It is each independently H ,-SO3M、-COOM、C1~C4Alkyl, C1~C4Alkoxy, amino ,-SO2CH=
CH2、-SO2C2H4OSO3M or R6-X4, R6It is C1~C4Alkylidene, X4It is H, halogen or amino, R7It is C1~C4Alkyl；
Each M is each independently M1、M2Or M3；Alternatively, the halogen is selected from chlorine, fluorine or bromine.
Alternatively, in above-mentioned blue active dye composition, the component A is selected from formula (I-1)~(I-20) compound
In one or more：
Alternatively, component B described in above-mentioned blue active dye composition is selected from formula (II-1)~(II-26) compound
In one or more：
Alternatively, in above-mentioned blue active dye composition, the component C is selected from formula (III-1)~(III-23) chemical combination
One or more in thing：
In the present invention, the selection to the auxiliary agent is not particularly limited, and can be conven-tional adjuvants.
Alternatively, above-mentioned auxiliary agent is selected from least one in dispersant, filler, other performance improvement auxiliary agents.
Alternatively, above-mentioned dispersant is selected from least one in Dispersant MF, dispersant NNO.
Alternatively, above-mentioned filler is glauber salt.
Alternatively, above-mentioned other performance improvement auxiliary agents are selected from least one in dust-proofing agent, solubility improver.
Alternatively, in above-mentioned blue active dye composition, the content of the component A is 10~90 weight portions, is chosen as
12~85 weight portions, are chosen as 14~80 weight portions, are chosen as 16~75 weight portions.
Alternatively, in above-mentioned blue active dye composition, the content of the component B is 8~80 weight portions, is chosen as 10
~75 weight portions, are chosen as 12~70 weight portions, are chosen as 14~65 weight portions.
Alternatively, in above-mentioned blue active dye composition, the content of the component C is 8~80 weight portions, is chosen as 10
~75 weight portions, are chosen as 12~70 weight portions, are chosen as 14~65 weight portions.
Alternatively, in above-mentioned blue active dye composition, the content of the auxiliary agent is 0~80 weight portion, it is chosen as 0~
75 weight portions, are chosen as 0~70 weight portion, are chosen as 0~65 weight portion.
The present invention a kind of preparation method of above-mentioned blue active dye composition is also provided, it is characterised in that including by than
Be mixed to prepare for component A, component B, component C and optional auxiliary agent by example.
Alternatively, the preparation method is included in proportion by the dry powder or slurry of component A, the dry powder of component B or slurry, group
Divide the dry powder or slurry of C and optional auxiliary agent mixing, be obtained by directly mixing or optional drying process.
In the present invention, there is no particular limitation for the equipment for being mixed to the dry powder, alternatively, using taper, rolling
The blender of cartridge type or pears blade is mixed, and test analysis are qualified after being well mixed packs again.In addition, being mixed to the slurry
There is no particular limitation for conjunction method, alternatively, mixing is stirred in a reservoir.What the present invention was used to the drying process
Also without special restriction, optional being dried using spray tower, drying room or flash distillation dryer etc. obtains granular or powdery to equipment
Product.
The present invention also provides purposes of the above-mentioned blue active dye active compound as reactive blue dye.
Alternatively, above-mentioned reactive blue dye is used for fiber or the printing and dyeing of its yarn fabric.
Alternatively, above-mentioned reactive blue dye is used for cellulose fibre, Fypro, protein fibre or their weaving
The printing and dyeing of thing.
Alternatively, above-mentioned cellulose fibre includes cotton fiber, flaxen fiber, regenerated fiber.
Alternatively, above-mentioned printing and dyeing include dyeing and/or stamp.
Alternatively, above-mentioned reactive blue dye is used for the printing and dyeing of cotton fiber or regenerated fiber.
Blue active dye composition of the invention, with advantages below：Degree of fixation is high, and compatibility is good, and cost performance is high, each
Item fastness properties are excellent, and also with the advantage that low cost, cost performance are high, batch production will significantly improve economic benefit.This hair
Bright blue active dye composition is suitable for the printing and dyeing of cellulosic fibre material, such as cotton, fiber crops, regenerated fiber and its yarn fabric
Printing and dyeing, the printing and dyeing of Fypro, protein fibre and its yarn fabric are also applied in addition.
Specific embodiment
With reference to specific embodiment, the present invention is described in detail.It should be appreciated that described herein specific
Illustrate to being for illustration only property of implementation method, but protection scope of the present invention is not limited to this.
Compound employed in following embodiments can be synthesized by existing method, can also use commercially available prod.
Embodiment 1
By the component B of the component A of 39.5 weight portion formulas (I-3) and 20.5 weight portion formulas (II-18), 20 weight portion formulas
(III-10) component C and the glauber salt of 20 weight portions carries out dry powder blend by blender, obtains final product blue active dye combination
Thing 1, using the composition as reactive blue dye, by cotton dyeing au bleu.
Embodiment 2
By the component A of 40 weight portion formulas (I-16), the component B of 20 weight portion formulas (II-1), 20 weight portion formulas (III-1)
Component C and the glauber salt of 20 weight portions dry powder blend is carried out by blender, blue active dye composition 2 is obtained final product, by institute
Composition is stated as reactive blue dye, by cotton dyeing au bleu.
Embodiment 3
By the component A of 37.5 weight portion formulas (I-3), the component B of 22.5 weight portion formulas (II-1), 22.5 weight portion formulas
(III-1) component C and the glauber salt of 17.5 weight portions carries out dry powder blend by blender, obtains final product blue active dye combination
Thing 3, using the composition as reactive blue dye, by cotton dyeing au bleu.
Embodiment 4
By the component A of 49.5 weight portion formulas (I-5) and the component B and 26 weight portion formulas of 24.5 weight portion formulas (II-3)
(III-1) component C carries out dry powder blend by blender, obtains final product blue active dye composition 4, using the composition as
Reactive blue dye, by cotton dyeing au bleu.
Comparative example 1
By the glauber salt of the component A of 43.4 weight portion formulas (IV), the component B of 36.7 weight portion formulas (V) and 19.9 weight portions
Dry powder blend is carried out by blender, blue active dye composition 5 is obtained final product, using the composition as reactive blue dye, will
Cotton dyeing au bleu.
Dye test：
To the blue active dye group that the blue active dye composition 1-4, comparative example 1 that are obtained by embodiment 1-4 are obtained
Each 2g of compound 5 respectively with each 1000g of dye liquor that 45g sodium chloride is made in, be separately added into 100g baftas, be warmed up to 1 DEG C/minute
It is the sodium carbonate liquor of 20g/L to 100g concentration is added in each dye liquor after 60 DEG C, and dyes at this temperature 1 hour, then will
Dyeing and weaving thing is rinsed, and is rinsed again after being soaped 15 minutes with nonionic detergent and dried.Respectively according to GB/T 2391-2014,
GB/T 3920-2008, GB/T 3921-2008 and GB/T 3922-2013 carry out test its degree of fixation, rub resistance, it is water-fastness and
Colour fastness to perspiration, the results are shown in Table 1：
Table 1
Cost performance compares：
The cost of the reactive blue dye of the embodiment of the present invention 3 and comparative example 1 is shown in Table 2, and data are one ton of dyestuff (standard of production
Product control under intensity for needed for 100%) each component cost (unit).
Table 2
As shown in Table 1, blue active dye composition of the invention, when being applied to dyeing as reactive blue dye, three kinds
The cooperative effect of component makes it have degree of fixation and more excellent every fastness properties higher.Additionally, as shown in Table 2,
When intensity under standard control is 100%, blue active dye composition of the invention is applied to as reactive blue dye
During dyeing, cost performance produces 1 ton of dyestuff compared to higher, often and can economize in raw materials 5006.8 yuan of cost, and batch production will be significantly improved
Economic benefit, hence it is evident that better than the reactive blue dye shown in comparative example 1, thus with more excellent combination property.
Claims (10)
1. a kind of blue active dye composition, it is characterised in that including one or more compound groups in formula (I) compound into
Component A, formula (II) compound in one or more compound groups into component B, formula (III) compound in one or more change
The component C and optional auxiliary agent of compound composition：
Wherein：M1、M2、M3It is each independently hydrogen, potassium, sodium, lithium or ammonium；X1、X2、X3It is each independently halogen；
R1、R2、R3It is each independently C1~C4Alkoxy, amino ,-NHR7OH、-NHR7SO3M、R4、R5Each solely
It is on the spot H ,-SO3M、-COOM、C1~C4Alkyl, C1~C4Alkoxy, amino ,-SO2CH=CH2、-SO2C2H4OSO3M or R6-
X4, R6It is C1~C4Alkylidene, X4It is H, halogen or amino, R7It is C1~C4Alkyl；
Each M is each independently M1、M2Or M3；Alternatively, the halogen is selected from chlorine, fluorine or bromine.
2. blue active dye composition according to claim 1, it is characterised in that the component A be selected from formula (I-1)~
(I-20) one or more in compound：
3. blue active dye composition according to claim 1 and 2, it is characterised in that the component B is selected from formula (II-
1)~(II-26) one or more in compound：
4. the blue active dye composition according to any one of claims 1 to 3, it is characterised in that the component C choosings
One or more from formula (III-1)~(III-23) compound：
5. the blue active dye composition according to any one of Claims 1 to 4, it is characterised in that the auxiliary agent choosing
At least one in self-dispersing agent, filler, other performance improvement auxiliary agents；Alternatively, the dispersant is selected from Dispersant MF, divides
At least one in powder NNO；Alternatively, the filler is glauber salt；Alternatively, described other performance improvement auxiliary agents are selected from
At least one in dust-proofing agent, solubility improver.
6. the blue active dye composition according to any one of Claims 1 to 5, it is characterised in that in the blueness
In reactive dye compound, the content of component A is 10~90 weight portions, is chosen as 12~85 weight portions, is chosen as 14~80 weights
Amount part, is chosen as 16~75 weight portions；The content of component B is 8~80 weight portions, is chosen as 10~75 weight portions, is chosen as 12
~70 weight portions, are chosen as 14~65 weight portions；The content of component C is 8~80 weight portions, is chosen as 10~75 weight portions, can
Elect 12~70 weight portions as, be chosen as 14~65 weight portions；The content of auxiliary agent is 0~80 weight portion, is chosen as 0~75 weight
Part, 0~70 weight portion is chosen as, it is chosen as 0~65 weight portion.
7. the preparation method of the blue active dye composition according to any one of claim 1~6, it is characterised in that
Including component A, component B, component C and optional auxiliary agent are mixed to prepare in proportion；Alternatively, the preparation method include press than
Example mixes the dry powder or slurry of component A, the dry powder of component B or slurry, the dry powder of component C or slurry and optional auxiliary agent, leads to
Cross directly mixing or optional drying process is obtained.
8. the blue active dye composition according to any one of claim 1~6 as reactive blue dye purposes.
9. purposes according to claim 8, it is characterised in that the reactive blue dye is used for fiber or the print of its yarn fabric
Dye.
10. purposes according to claim 8 or claim 9, it is characterised in that the reactive blue dye is used for cellulose fibre, poly-
The printing and dyeing of nylon, protein fibre or their yarn fabric；Alternatively, the cellulose fibre includes that cotton fiber, fiber crops are fine
Peacekeeping regenerated fiber；Optionally, the printing and dyeing include dyeing and/or stamp；Alternatively, the reactive blue dye is used for cotton fibre
Dimension, the printing and dyeing of regenerated fiber.
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| CN201611064510.0A CN106833017B (en) | 2016-11-28 | 2016-11-28 | A kind of blue active dye composition and its preparation method and application |
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| CN201611064510.0A CN106833017B (en) | 2016-11-28 | 2016-11-28 | A kind of blue active dye composition and its preparation method and application |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108467607A (en) * | 2018-04-11 | 2018-08-31 | 江苏安诺其化工有限公司 | A kind of dye composite, preparation method and application |
| CN108640883A (en) * | 2018-04-11 | 2018-10-12 | 江苏安诺其化工有限公司 | A kind of azo compound, preparation method and application |
| CN111349348A (en) * | 2018-12-21 | 2020-06-30 | 湖北丽源科技股份有限公司 | Reactive dark blue dye and synthetic method thereof |
| WO2020246342A1 (en) * | 2019-06-06 | 2020-12-10 | 日本化薬株式会社 | Ink composition and ink-jet recording method including using same |
| CN112662199A (en) * | 2020-12-10 | 2021-04-16 | 上海雅运新材料有限公司 | Black dye compound and preparation method and dyeing application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108467607A (en) * | 2018-04-11 | 2018-08-31 | 江苏安诺其化工有限公司 | A kind of dye composite, preparation method and application |
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| CN111349348B (en) * | 2018-12-21 | 2021-11-23 | 湖北丽源科技股份有限公司 | Reactive dark blue dye and synthetic method thereof |
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| CN112662199A (en) * | 2020-12-10 | 2021-04-16 | 上海雅运新材料有限公司 | Black dye compound and preparation method and dyeing application thereof |
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| Publication number | Publication date |
|---|---|
| CN106833017B (en) | 2018-09-11 |
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