CN105602286B - A kind of Black reactive dye composition and its production and use - Google Patents
A kind of Black reactive dye composition and its production and use Download PDFInfo
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- CN105602286B CN105602286B CN201610153288.5A CN201610153288A CN105602286B CN 105602286 B CN105602286 B CN 105602286B CN 201610153288 A CN201610153288 A CN 201610153288A CN 105602286 B CN105602286 B CN 105602286B
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- 0 CC(*)=C(C(O)=C(C([C@@](C(S(O)(=O)=O)=C1)N=Nc2cc(*=C)ccc2)N)C1=C)N=N[C@]1C=C(*=C)C=CC1 Chemical compound CC(*)=C(C(O)=C(C([C@@](C(S(O)(=O)=O)=C1)N=Nc2cc(*=C)ccc2)N)C1=C)N=N[C@]1C=C(*=C)C=CC1 0.000 description 3
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/004—Mixtures of two or more reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
- D06P1/382—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes reactive group directly attached to heterocyclic group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
- D06P1/384—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes reactive group not directly attached to heterocyclic group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/10—Material containing basic nitrogen containing amide groups using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/14—Wool
- D06P3/148—Wool using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/24—Polyamides; Polyurethanes
- D06P3/248—Polyamides; Polyurethanes using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
- D06P3/663—Natural or regenerated cellulose using reactive dyes reactive group directly attached to heterocyclic group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
- D06P3/666—Natural or regenerated cellulose using reactive dyes reactive group not directly attached to heterocyclic group
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
A kind of Black reactive dye composition and its production and use, the Black reactive dye composition contain the component A shown in formula (I), the component B shown in formula (II), the component C shown in formula (III), the component D shown in formula (IV) and optional auxiliary agent.The Black reactive dye composition is applied to the dyeing of various fibrous materials, and degree of fixation is high, and every fastness properties are excellent, have more excellent combination property.
Description
Technical field
The present invention relates to reactive dyestuff field, in particular it relates to a kind of Black reactive dye composition and preparation method thereof
And purposes.
Background technology
With the development of fiber species and staining technique, Dyestuff Market is required also increasingly the dyeability of reactive dye
Height, this also promotes reactive dye to develop in terms of application performance is improved.Black and active dye exploitation is always dye industry
Focus because the yield of black and active dye account for whole reactive dye yield more than half.Black and active dye is as city
The field larger color kind of occupancy volume, good fastness to rubbing, washing fastness and fastness to perspiration are not only required, and required
With higher degree of fixation.However, after existing black and active dye kind is printed and dyed to fiber, various performance indications are difficult to reach
The requirement of people.Therefore, developing a kind of performance can more preferably meet that the black and active dye kind of above-mentioned characteristic requirements is drawn simultaneously
The concern and attention of people are played.
The content of the invention
The present invention is difficult to reach to overcome existing black and active dye to exist to various performance indications after fiber printing and dyeing
The problem of people require, there is provided a kind of degree of fixation is high, and the excellent black of every color fastness such as rub resistance, water-fastness and sweat proof are damp is lived
Property dye composite, and the preparation method and purposes of said composition.
The first aspect of the present invention, there is provided a kind of Black reactive dye composition, wherein, the black and active dye combination
Thing contains the component A shown in formula (I), the component B shown in formula (II), the component C shown in formula (III), the component D shown in formula (IV)
And optional auxiliary agent；
Wherein, M1、M2、M3It is each independently hydrogen, potassium, sodium, lithium or ammonium；R1For-CH=CH2Or-C2H4OSO3M1；R2、R3
It is each independently-CH=CH2Or-C2H4OSO3M2；R4For-CH=CH2Or-C2H4OSO3M3；X1、X2Be each independently chlorine or
Fluorine.
Preferably, in described Black reactive dye composition component A be selected from formula (I-1)~(I-8) compound in one
Kind is a variety of；
Preferably, the component B is selected from the one or more in formula (II -1)~(II -6) compound；
。
Preferably, component C is selected from formula (III -1)~(III -12) compound in described Black reactive dye composition
It is one or more；
Preferably, component D is selected from formula (IV -1)~(IV -7) compound in described Black reactive dye composition
It is one or more；
In the present invention, there is no particular limitation for the selection to the auxiliary agent, can be conven-tional adjuvants, including dispersant,
Filler and other performance improvement auxiliary agents.The dispersant is preferably selected from Dispersant MF, one kind in dispersant NNO or more
Kind, the filler is glauber salt, other described performance improvement auxiliary agents in dust-proofing agent, solubility improver at least one
Kind.
In the Black reactive dye composition, component A content is preferably 30-83 parts by weight, more preferably 31-82
Parts by weight, more preferably 32-81 parts by weight, more preferably 33-80 parts by weight；Component B content is 1-30 parts by weight, excellent
Elect 1-28 parts by weight, more preferably 1-26 parts by weight, more preferably 1-24 parts by weight as；Component C content is preferably 1-
68 parts by weight, more preferably 1-67 parts by weight, more preferably 1-66 parts by weight, more preferably 1-65 parts by weight；Component D's
Content is preferably 1-20 parts by weight, more preferably 1-18 parts by weight, more preferably 1-16 parts by weight, more preferably 1-14 weights
Measure part；The content of auxiliary agent is preferably 0-50 parts by weight, more preferably 0-45 parts by weight, more preferably 0-40 parts by weight, further
Preferably 0-35 parts by weight.
The second aspect of the present invention, there is provided the preparation method of above-mentioned Black reactive dye composition, including：Take said components
A, component B, component C, component D dry powder and optional auxiliary agent, are mixed in proportion, obtain solid black and active dye group
Compound；Or said components A, component B, component C, component D slurry and optional auxiliary agent are taken, mixing system is carried out in proportion
Material, liquid black reactive dye compound is obtained, or the black dye composition is carried out using optional drying process
Dry, obtain solid Black reactive dye composition.
In the present invention, there is no particular limitation for the equipment mixed to the dry powder, it is preferable that using taper, rolling
The blender of cartridge type or pears blade is mixed, and test analysis is qualified after being well mixed packs again.In addition, the slurry is mixed
There is no particular limitation for conjunction method, it is preferable that is stirred mixing in a reservoir.In addition, the present invention is to carrying out the drying
Equipment limits also without special, it is preferred to use spray tower, drying room or flash distillation dryer are dried to obtain granular or powdery black
Color reactive dye compound.
The third aspect of the present invention, there is provided purposes of the above-mentioned Black reactive dye composition as black and active dye.
Preferably, the black and active dye is used for dyeing or the stamp of fiber or yarn fabric；It is highly preferred that the black
Reactive dye be used for cotton fiber, wool fiber, regenerated fiber, Fypro, cellulose fibre, protein fibre or they
The dyeing of yarn fabric or stamp.
The Black reactive dye composition of the present invention, has advantages below：Degree of fixation is high, and dye stability is good, rub resistance,
Every color fastness such as water-fastness and perspiration resistance are excellent.The Black reactive dye composition of the present invention is suitable for cellulose fibre material
The dyeing of material or stamp, such as the printing and dyeing of cotton, fiber crops, viscose rayon and its yarn fabric, Fypro, protein are also applied in addition
The dyeing of fiber and its yarn fabric or stamp.
Embodiment
In Black reactive dye composition of the present invention, used component A, component B and component C can be pressed easily
Mode well known to those skilled in the art synthesizes, and is such as prepared according to the diazotising of routine, couling process, can also use commercially available production
Product.
Embodiment 1
By the component A of 60 parts by weight formulas (I-1), the component B of 15 parts by weight formulas (II -1), 20 parts by weight formulas (III -6) group
Divide C and the component D cone blenders of 5 parts by weight formulas (IV -1) to carry out dry powder blend, produce composition J1, the composition is made
, can be by cotton dyeing into black for black and active dye.
Embodiment 2
By the component A containing 52 parts by weight formulas (I-1) that gives money as a gift, the slurry for the component B containing 20 parts by weight formulas (II -1) that gives money as a gift, folding
The dry component C containing 20 parts by weight formulas (III -6) slurry and the slurry agitation for the component D containing 8 parts by weight formulas (IV -5) that gives money as a gift are uniform
Afterwards, dried in drying room, produce composition J2, can be by cotton dyeing into black using the composition as black and active dye
Color.
Embodiment 3
By the component A of 45 parts by weight formulas (I-1), the component B of 5 parts by weight formulas (II -1), 17 parts by weight formulas (III -6) group
Divide C, the component D of 3 parts by weight formulas (IV -1) and 30 parts by weight glauber salt to carry out dry powder blend by cone blender, produce group
Compound J3, can be by cotton dyeing into black using the composition as black and active dye.
Comparative example 1
The component A of 80 parts by weight formulas (I-1), 20 parts by weight formulas (II -9) component B are done by cone blender
Powder mixes, and produces composition D1, can be by cotton dyeing into black using the composition as black and active dye.
Comparative example 2
The component C of 65 parts by weight formulas (III -6) and the glauber salt of 35 parts by weight are carried out into dry powder by cone blender to mix
Close, produce composition D2, can be by cotton dyeing into black using the composition as black and active dye.
Dye test
The black activity dye obtained to the Black reactive dye composition J1-J3 and comparative example that are obtained by embodiment 1-3
Each 2g of feed composition D1-D2 respectively with 45g sodium chloride made of in each 1000g of dye liquor, be separately added into 100g baftas, with 1 DEG C/
Divide after being warming up to 60 DEG C, then add 100g concentration into each dye liquor and be 20g/L sodium carbonate liquor, and dye 1 at this temperature
Hour, then dyeing and weaving thing is rinsed, rinses and dries again after being soaped 15 minutes with nonionic detergent.Respectively according to GB/T
2391-2014, GB/T 3920-2008, GB/T 3921-2008 and GB/T 3922-2013 method test its degree of fixation, resistance to
Friction, water-fastness and colour fastness to perspiration, test result are as shown in table 1：
Table 1
The coloration result of Black reactive dye composition according to obtained by above-described embodiment and comparative example can be seen that this
When the Black reactive dye composition that invention provides is applied to dyeing as black and active dye, degree of fixation is high, every color fastness
Excellent performance, thus there is more excellent combination property.
Claims (34)
1. a kind of Black reactive dye composition, it is characterised in that the Black reactive dye composition contains shown in formula (I)
The component C shown in component B, formula (III), the component D shown in formula (IV) and optional auxiliary agent shown in component A, formula (II)；
Wherein, M1、M2、M3It is each independently hydrogen, potassium, sodium, lithium or ammonium；R1For-CH=CH2Or-C2H4OSO3M1；R2、R3Each
It independently is-CH=CH2Or-C2H4OSO3M2；R4For-CH=CH2Or-C2H4OSO3M3；X1、X2It is each independently chlorine or fluorine.
2. Black reactive dye composition according to claim 1, it is characterised in that the component A be selected from formula (I-1)~
(I-8) one or more in compound；
。
3. Black reactive dye composition according to claim 1, it is characterised in that the component B is selected from formula (II -1)
One or more in the compound of~(II -6)；
4. Black reactive dye composition according to claim 1, it is characterised in that the component C is selected from formula (III -1)
One or more in the compound of~(III -12)；
5. Black reactive dye composition according to claim 1, it is characterised in that the component D is selected from formula (IV -1)
One or more in the compound of~(IV -7)；
6. according to the Black reactive dye composition described in claim any one of 1-5, it is characterised in that the auxiliary agent, which is selected from, to be divided
Powder, filler and other performance improvement auxiliary agents.
7. Black reactive dye composition according to claim 6, it is characterised in that the dispersant is selected from dispersant
One or more in MF, dispersant NNO, the filler are glauber salt, other described performance improvement auxiliary agents be selected from dust-proofing agent,
At least one of solubility improver.
8. Black reactive dye composition according to claim 7, it is characterised in that combined in the black and active dye
In thing, component A content is 30-83 parts by weight.
9. Black reactive dye composition according to claim 8, it is characterised in that combined in the black and active dye
In thing, component A content is 31-82 parts by weight.
10. Black reactive dye composition according to claim 9, it is characterised in that in the black and active dye group
In compound, component A content is 32-81 parts by weight.
11. Black reactive dye composition according to claim 10, it is characterised in that in the black and active dye group
In compound, component A content is 33-80 parts by weight.
12. Black reactive dye composition according to claim 7, it is characterised in that in the black and active dye group
In compound, component B content is 1-30 parts by weight.
13. Black reactive dye composition according to claim 12, it is characterised in that in the black and active dye group
In compound, component B content is 1-28 parts by weight.
14. Black reactive dye composition according to claim 13, it is characterised in that in the black and active dye group
In compound, component B content is 1-26 parts by weight.
15. Black reactive dye composition according to claim 14, it is characterised in that in the black and active dye group
In compound, component B content is 1-24 parts by weight.
16. Black reactive dye composition according to claim 7, it is characterised in that in the black and active dye group
In compound, component C content is 1-68 parts by weight.
17. Black reactive dye composition according to claim 16, it is characterised in that in the black and active dye group
In compound, component C content is 1-67 parts by weight.
18. Black reactive dye composition according to claim 17, it is characterised in that in the black and active dye group
In compound, component C content is 1-66 parts by weight.
19. Black reactive dye composition according to claim 18, it is characterised in that in the black and active dye group
In compound, component C content is 1-65 parts by weight.
20. the Black reactive dye composition according to right wants 7, it is characterised in that combined in the black and active dye
In thing, component D content is 1-20 parts by weight.
21. Black reactive dye composition according to claim 20, it is characterised in that in the black and active dye group
In compound, component D content is 1-18 parts by weight.
22. Black reactive dye composition according to claim 21, it is characterised in that in the black and active dye group
In compound, component D content is 1-16 parts by weight.
23. Black reactive dye composition according to claim 22, it is characterised in that in the black and active dye group
In compound, component D content is 1-14 parts by weight.
24. Black reactive dye composition according to claim 7, it is characterised in that in the black and active dye group
In compound, the content of auxiliary agent is 0-50 parts by weight.
25. Black reactive dye composition according to claim 24, it is characterised in that in the black and active dye group
In compound, the content of auxiliary agent is 0-45 parts by weight.
26. Black reactive dye composition according to claim 25, it is characterised in that in the black and active dye
In composition, the content of auxiliary agent is 0-40 parts by weight.
27. Black reactive dye composition according to claim 26, it is characterised in that in the black and active dye group
In compound, the content of auxiliary agent is 0-35 parts by weight.
28. a kind of preparation method of the Black reactive dye composition described in any one of claim 1-27, including：Take above-mentioned group
Divide A, component B, component C, component D dry powder and optional auxiliary agent, mixed in proportion, obtain solid black and active dye
Composition；
Or said components A, component B, component C, component D slurry and optional auxiliary agent are taken, mixing system material is carried out in proportion,
Liquid black reactive dye compound is obtained, or the black dye composition is done using optional drying process
It is dry, obtain solid Black reactive dye composition.
29. purposes of the Black reactive dye composition described in claim any one of 1-27 as black and active dye.
30. purposes according to claim 29, it is characterised in that the black and active dye is used for fiber or its yarn fabric
Dyeing or stamp.
31. purposes according to claim 30, it is characterised in that described black and active dye be used for Fypro,
The dyeing of cellulose fibre or their yarn fabric or stamp.
32. purposes according to claim 31, it is characterised in that the cellulose fibre includes cotton fiber and regeneration is fine
Dimension.
33. purposes according to claim 30, it is characterised in that the black and active dye be used for protein fibre or it
Yarn fabric dyeing or stamp.
34. purposes according to claim 33, it is characterised in that the protein fibre includes wool fiber.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610153288.5A CN105602286B (en) | 2016-03-17 | 2016-03-17 | A kind of Black reactive dye composition and its production and use |
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|---|---|---|---|
| CN201610153288.5A CN105602286B (en) | 2016-03-17 | 2016-03-17 | A kind of Black reactive dye composition and its production and use |
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| CN105602286A CN105602286A (en) | 2016-05-25 |
| CN105602286B true CN105602286B (en) | 2017-12-12 |
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Families Citing this family (2)
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| CN106752082B (en) * | 2016-12-30 | 2019-09-13 | 上海安诺其集团股份有限公司 | A kind of preparation method of gray dyes |
| CN106634044B (en) * | 2016-12-30 | 2019-09-27 | 上海安诺其集团股份有限公司 | A kind of gray dyes, dye composite and its application |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3501452A (en) * | 1966-08-29 | 1970-03-17 | Acna | Reactive monochlorotriazine azo dyestuffs containing a sodium salt of an aniline-n-omega-methane sulfonic acid group |
| CN101029184A (en) * | 2006-02-28 | 2007-09-05 | 浙江龙盛集团股份有限公司 | Disazo reactive dye, preparation method and composition thereof |
| CN101044211A (en) * | 2004-10-19 | 2007-09-26 | 亨斯迈先进材料（瑞士）有限公司 | Reactive dyers, their preparation and their use |
| CN102257074A (en) * | 2009-01-21 | 2011-11-23 | 亨斯迈先进材料（瑞士）有限公司 | Reactive dyes, their preparation and their use |
| CN102757667A (en) * | 2011-04-26 | 2012-10-31 | 上海雅运纺织化工股份有限公司 | Red reactive dye composition and dyeing application thereof on fiber |
-
2016
- 2016-03-17 CN CN201610153288.5A patent/CN105602286B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3501452A (en) * | 1966-08-29 | 1970-03-17 | Acna | Reactive monochlorotriazine azo dyestuffs containing a sodium salt of an aniline-n-omega-methane sulfonic acid group |
| CN101044211A (en) * | 2004-10-19 | 2007-09-26 | 亨斯迈先进材料（瑞士）有限公司 | Reactive dyers, their preparation and their use |
| CN101029184A (en) * | 2006-02-28 | 2007-09-05 | 浙江龙盛集团股份有限公司 | Disazo reactive dye, preparation method and composition thereof |
| CN102257074A (en) * | 2009-01-21 | 2011-11-23 | 亨斯迈先进材料（瑞士）有限公司 | Reactive dyes, their preparation and their use |
| CN102757667A (en) * | 2011-04-26 | 2012-10-31 | 上海雅运纺织化工股份有限公司 | Red reactive dye composition and dyeing application thereof on fiber |
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| CN105602286A (en) | 2016-05-25 |
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