CN105778562A - Black active dye composition and preparation method and use thereof - Google Patents
Black active dye composition and preparation method and use thereof Download PDFInfo
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- CN105778562A CN105778562A CN201610153721.5A CN201610153721A CN105778562A CN 105778562 A CN105778562 A CN 105778562A CN 201610153721 A CN201610153721 A CN 201610153721A CN 105778562 A CN105778562 A CN 105778562A
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- Prior art keywords
- component
- black
- reactive dye
- dye composition
- weight portion
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/004—Mixtures of two or more reactive dyes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0055—Mixtures of two or more disazo dyes
- C09B67/0057—Mixtures of two or more reactive disazo dyes
- C09B67/0059—Mixtures of two or more reactive disazo dyes all the reactive groups are not directly attached to a heterocyclic system
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
- D06P1/384—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes reactive group not directly attached to heterocyclic group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/14—Wool
- D06P3/148—Wool using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/24—Polyamides; Polyurethanes
- D06P3/248—Polyamides; Polyurethanes using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
- D06P3/666—Natural or regenerated cellulose using reactive dyes reactive group not directly attached to heterocyclic group
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
A black active dye composition and a preparation method and use thereof are provided. The black dye composition comprises component A shown in formula (I), component B shown in formula (II), component C shown in formula (III) and an optional aid. The black active dye composition is suitable for dyeing various fiber materials, is high in color fixing rate and excellent in color fastness and thereby has excellent comprehensive performances.
Description
Technical field
The present invention relates to reactive dyestuff field, in particular it relates to a kind of Black reactive dye composition and its production and use.
Background technology
Along with the development of staining technique, the dyeability of reactive dye is required also more and more higher by Dyestuff Market, and this also promotes reactive dye to improving the development of application performance aspect.Currently, the yield of black and active dye accounts for more than half of whole reactive dye yield, and therefore black and active dye exploitation is always up the focus of dye industry.Existing Black reactive dye composition is difficult to have concurrently the combination properties such as strong degree of fixation, good rub resistance, water-fastness and colour fastness to perspiration, extremely lack the black and active dye of high comprehensive performance, therefore, it is badly in need of developing a kind of performance and better can meet the black and active dye kind of above-mentioned characteristic requirements simultaneously.
Summary of the invention
Various performance indications after fiber printing and dyeing are difficult to reach the defect that people require by the present invention in order to overcome existing black and active dye to exist, there is provided a kind of degree of fixation high, the Black reactive dye composition that every color fastness such as rub resistance, water-fastness and perspiration resistance are excellent, and the preparation method of said composition and purposes.
A first aspect of the present invention, a kind of Black reactive dye composition is provided, wherein, described Black reactive dye composition contains the component C shown in the component B shown in the component A shown in formula (I), formula (II), formula (III) and optional auxiliary agent；
Wherein, M1、M2、M3It is each independently hydrogen, potassium, sodium, lithium or ammonium；R1、R2It is each independently-CH=CH2Or-C2H4OSO3M1；R3For-CH=CH2Or-C2H4OSO3M2, R4For (C1～C4)-alkyl or (C1～C4)-alkoxyl；R5、R6It is each independently-CH=CH2Or-C2H4OSO3M3, R7、R8It is each independently hydrogen, (C1～C4)-alkyl or (C1～C4)-alkoxyl；X1For-NH-X ', X ' for hydrogen, (C1～C4)-alkyl or R ' SO3M2, R ' is each independently (C1～C4)-alkylidene.
Preferably, described component A is selected from one or more in formula (I-1)～(I-10) compound；
Preferably, in described Black reactive dye composition, component B is selected from one or more in formula (II-1)～(II-7) compound；
Preferably, in described black and active dye, component C is selected from one or more in formula (III-1)～(III-13) compound；
In the present invention, to the selection of described auxiliary agent, there is no particular limitation, it is possible to for conven-tional adjuvants, including dispersant, filler and other performance improvement auxiliary agents.Described dispersant is preferably selected from one or more in Dispersant MF, dispersant NNO, and described filler is Matrii Sulfas Exsiccatus, it is preferable that other performance improvement auxiliary agents described at least one in dust-proofing agent, dissolubility improving agent.
In described Black reactive dye composition, the content of component A is preferably 20～90 weight portions, more preferably 25～85 weight portions, more preferably 30～80 weight portions, more preferably 35～75 weight portion；The content of component B is preferably 1～30 weight portion, more preferably 2～30 weight portions, more preferably 3～30 weight portions, more preferably 4～30 weight portion；The content of component C is preferably 1～30 weight portion, more preferably 1～25 weight portion, more preferably 1～20 weight portion, more preferably 1～15 weight portion；The content of auxiliary agent is preferably 0～50 weight portion, more preferably 0～45 weight portion, more preferably 0～40 weight portion, more preferably 0～35 weight portion.
A second aspect of the present invention, it is provided that the preparation method of above-mentioned Black reactive dye composition, including: take said components A, component B, the dry powder of component C and optional auxiliary agent, carry out mixing system material in proportion, obtain solid Black reactive dye composition；Or take said components A, component B, the slurry of component C and optional auxiliary agent, carry out mixing system material in proportion, obtain liquid black reactive dye compound, or adopt optional dry run to be dried described liquid black reactive dye compound, obtain solid Black reactive dye composition.
In the present invention, there is no particular limitation for the equipment described dry powder mixed, it is preferable that adopting the blender of taper, drum-type or pears blade to mix, after mix homogeneously, test analysis is qualified packs again.It addition, to the mixed method of described slurry, there is no particular limitation, it is preferable that is stirred mixing in a reservoir.It addition, the present invention is to carrying out described dry equipment also without special restriction, it is preferred to use spray tower, drying room or flash dryer are dried and obtain granular or powdery Black reactive dye composition.
A third aspect of the present invention, it is provided that above-mentioned Black reactive dye composition is as the purposes of black and active dye.
Preferably, described black and active dye is for fiber or the dyeing or the stamp that are used for fiber or its yarn fabric；It is highly preferred that described black and active dye is used for dyeing or the stamp of cotton fiber, wool fiber, regeneration fibre, Fypro, cellulose fibre, protein fibre or their yarn fabric.
The Black reactive dye composition of the present invention, has the advantage that degree of fixation is high, dye stability is good, and every color fastness such as rub resistance, water-fastness and perspiration resistance is excellent.The Black reactive dye composition of the present invention is applicable to the dyeing of cellulosic fibre material, such as the printing and dyeing of cotton, fiber crops, regenerated fiber and yarn fabric thereof, is also applied for the dyeing of Fypro, protein fibre and yarn fabric thereof in addition.
The present invention is described in detail by the following examples.It should be appreciated that being merely cited for property of embodiments herein the present invention will be described, be not used to limit the invention.
Detailed description of the invention
Component A, component B and the component C used in Black reactive dye composition of the present invention, can synthesize by mode well known to those skilled in the art easily, as prepared by diazotising conventionally, couling process, it is possible to adopt commercially available prod.
Embodiment 1
The component A of 70 weight portion formulas (I-1), the component B of 15 weight portion formulas (II-1) and the component C of 15 weight portion formulas (III-1) are carried out dry powder blend by cone blender, obtain compositions J1, using described compositions as black and active dye, cotton dyeing can be become black.
Embodiment 2
By the slurry of the component A given money as a gift containing 75 weight portion formulas (I-1), the slurry of component B given money as a gift containing 15 weight portion formulas (II-6) and the slurry agitation of component C given money as a gift containing 10 weight portion formulas (III-1) uniformly after, dry in drying room, obtain compositions J2, using described compositions as black and active dye, cotton dyeing can be become black.
Embodiment 3
The component A of 70 weight portion formulas (I-1), the component B of 20 weight portion formulas (II-1) and the component C of 10 weight portion formulas (III-9) are carried out dry powder blend by cone blender, obtain compositions J3, using described compositions as black and active dye, cotton dyeing can be become black.
Embodiment 4
The component A of 65 weight portion formulas (I-1), the component B of 15 weight portion formulas (II-6), the component C of 10 weight portion formulas (III-9) and the Matrii Sulfas Exsiccatus of 10 weight portions are carried out dry powder blend by cone blender, obtain compositions J4, using described compositions as black and active dye, cotton dyeing can be become black.
Comparative example 1
The dry powder of component A of 75 weight portion formulas (I-1) and the Matrii Sulfas Exsiccatus of 25 weight portions are carried out dry powder blend by blender, obtains compositions D1, using described compositions as black and active dye, cotton dyeing can be become black.
Comparative example 2
The dry powder of component A of 65 weight portion formulas (I-1), the dry powder of the component B of 25 weight portion Formulas I V and the component C of 10 weight portion formulas (III-1) are carried out dry powder blend by blender, obtain compositions D2, using described compositions as black and active dye, cotton dyeing can be become black.
Comparative example 3
The dry powder of component A of 65 weight portion formulas (I-1), the dry powder of the component B of 25 weight portion Formula V and the component C of 10 weight portion formulas (III-1) are carried out dry powder blend by blender, obtain compositions D3, using described compositions as black and active dye, cotton dyeing can be become black.
Dyeing Example
The each 2g of Black reactive dye composition D1-D3 obtained to the Black reactive dye composition J1-J4 obtained by embodiment 1-4 and comparative example 1 respectively with in each 1000g of the dye liquor that 45g sodium chloride is made, it is separately added into 100g bafta, after being warmed up to 60 DEG C with 1 DEG C/minute, adding 100g concentration again in each dye liquor is the sodium carbonate liquor of 20g/L, after being warmed up to 60 DEG C with 1 DEG C/minute, the sodium carbonate liquor of 100g20g/L is added again in each dye liquor, and dye 1 hour at this temperature, then dyeing and weaving thing is rinsed, post rinse drying after soaping 15 minutes with nonionic detergent.Respectively according to GB/T2391-2014, GB/T3920-2008, GB/T3921-2008 and GB/T3922-2013 method test its degree of fixation, rub resistance, water-fastness and colour fastness to perspiration, test result is as shown in table 1:
Table 1
The coloration result of the Black reactive dye composition obtained by above-described embodiment and comparative example can be seen that, Black reactive dye composition provided by the invention as black and active dye purposes in dyeing time, degree of fixation is high, every fastness properties is excellent, thus has comparatively excellent combination property.
Claims (10)
1. a Black reactive dye composition, it is characterised in that described Black reactive dye composition contains the component C shown in the component B shown in the component A shown in formula (I), formula (II), formula (III) and optional auxiliary agent；
Wherein, M1、M2、M3It is each independently hydrogen, potassium, sodium, lithium or ammonium；R1、R2It is each independently-CH=CH2Or-C2H4OSO3M1；R3For-CH=CH2Or-C2H4OSO3M2, R4For (C1～C4)-alkyl or (C1～C4)-alkoxyl；R5、R6It is each independently-CH=CH2Or-C2H4OSO3M3, R7、R8It is each independently hydrogen, (C1～C4)-alkyl or (C1～C4)-alkoxyl；X1For-NH-X ', X ' for hydrogen, (C1～C4)-alkyl or R ' SO3M2, R ' is each independently (C1～C4)-alkylidene.
2. Black reactive dye composition according to claim 1, it is characterised in that described component A is selected from one or more in formula (I-1)～(I-10) compound；
3. Black reactive dye composition according to claim 1 and 2, it is characterised in that described component B is selected from one or more in formula (II-1)～(II-7) compound；
4. the Black reactive dye composition according to any one of claim 1-3, it is characterised in that described component C is selected from one or more in formula (III-1)～(III-13) compound；
5. the Black reactive dye composition according to any one of claim 1-4, it is characterised in that described auxiliary agent is selected from dispersant, filler and other performance improvement auxiliary agents；
Preferably, described dispersant is selected from one or more in Dispersant MF, dispersant NNO, and described filler is Matrii Sulfas Exsiccatus, other performance improvement auxiliary agents described at least one in dust-proofing agent, dissolubility improving agent.
6. the Black reactive dye composition according to any one of claim 1-5, it is characterized in that, in described Black reactive dye composition, the content of described component A is 20～90 weight portions, it is preferably 25～85 weight portions, it is more preferably 30～80 weight portions, more preferably 35～75 weight portion；The content of component B is 1～30 weight portion, it is preferred to 2～30 weight portions, more preferably 3～30 weight portions, more preferably 4～30 weight portion；The content of component C is 1～30 weight portion, it is preferred to 1～25 weight portion, more preferably 1～20 weight portion, more preferably 1～15 weight portion；The content of auxiliary agent is 0～50 weight portion, it is preferred to 0～45 weight portion, more preferably 0～40 weight portion, more preferably 0～35 weight portion.
7. a preparation method for the Black reactive dye composition described in any one of claim 1-6, including: take said components A, component B, the dry powder of component C and optional auxiliary agent, carry out mixing system material in proportion, obtain solid Black reactive dye composition；
Or take said components A, component B, the slurry of component C and optional auxiliary agent, carry out mixing system material in proportion, obtain liquid black reactive dye compound, or adopt optional dry run to be dried described liquid black reactive dye compound, obtain solid Black reactive dye composition.
8. the Black reactive dye composition described in any one of claim 1-6 is as the purposes of black and active dye.
9. purposes according to claim 8, it is characterised in that described black and active dye is used for dyeing or the stamp of fiber or its yarn fabric.
10. purposes according to claim 9, it is characterised in that described black and active dye is used for dyeing or the stamp of cotton fiber, wool fiber, regeneration fibre, Fypro, cellulose fibre, protein fibre or their yarn fabric.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610153721.5A CN105778562A (en) | 2016-03-17 | 2016-03-17 | Black active dye composition and preparation method and use thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610153721.5A CN105778562A (en) | 2016-03-17 | 2016-03-17 | Black active dye composition and preparation method and use thereof |
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| Publication Number | Publication Date |
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| CN105778562A true CN105778562A (en) | 2016-07-20 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610153721.5A Pending CN105778562A (en) | 2016-03-17 | 2016-03-17 | Black active dye composition and preparation method and use thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108148449A (en) * | 2017-12-31 | 2018-06-12 | 浙江龙盛化工研究有限公司 | A kind of active black dye composition and its application |
| CN108410210A (en) * | 2018-02-27 | 2018-08-17 | 绍兴永通印花有限公司 | Blending black and active dye suitable for people's cotton stamp |
| CN108486921A (en) * | 2018-02-27 | 2018-09-04 | 绍兴永通印花有限公司 | People's cotton-padded clothes printing technology and people's cotton-spinning fabric |
| CN114149694A (en) * | 2021-12-10 | 2022-03-08 | 上海雅运新材料有限公司 | Black dye composition and application and dyeing method thereof |
-
2016
- 2016-03-17 CN CN201610153721.5A patent/CN105778562A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108148449A (en) * | 2017-12-31 | 2018-06-12 | 浙江龙盛化工研究有限公司 | A kind of active black dye composition and its application |
| CN108410210A (en) * | 2018-02-27 | 2018-08-17 | 绍兴永通印花有限公司 | Blending black and active dye suitable for people's cotton stamp |
| CN108486921A (en) * | 2018-02-27 | 2018-09-04 | 绍兴永通印花有限公司 | People's cotton-padded clothes printing technology and people's cotton-spinning fabric |
| CN114149694A (en) * | 2021-12-10 | 2022-03-08 | 上海雅运新材料有限公司 | Black dye composition and application and dyeing method thereof |
| CN114149694B (en) * | 2021-12-10 | 2023-10-20 | 上海雅运新材料有限公司 | Black dye composition and application and dyeing method thereof |
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