CN104884539B - It is a kind of blue to black disperse dye compound and its application - Google Patents
It is a kind of blue to black disperse dye compound and its application Download PDFInfo
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- CN104884539B CN104884539B CN201280075941.0A CN201280075941A CN104884539B CN 104884539 B CN104884539 B CN 104884539B CN 201280075941 A CN201280075941 A CN 201280075941A CN 104884539 B CN104884539 B CN 104884539B
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- disperse
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- 239000000986 disperse dye Substances 0.000 title claims abstract description 41
- 150000001875 compounds Chemical class 0.000 title claims abstract description 18
- 239000000975 dye Substances 0.000 claims abstract description 184
- 239000002131 composite material Substances 0.000 claims abstract description 27
- 239000000178 monomer Substances 0.000 claims abstract description 12
- 238000004043 dyeing Methods 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 22
- 229920000728 polyester Polymers 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 17
- 239000012752 auxiliary agent Substances 0.000 claims description 15
- 239000004753 textile Substances 0.000 claims description 12
- 239000007859 condensation product Substances 0.000 claims description 9
- 230000002209 hydrophobic effect Effects 0.000 claims description 9
- -1 alkyl naphthalene sulfonic acid formaldehyde Chemical compound 0.000 claims description 5
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 claims description 5
- 229920001732 Lignosulfonate Polymers 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 2
- CBCZQJLYYRPMRI-UHFFFAOYSA-N 2-benzylnaphthalene-1-sulfonic acid Chemical class C1=CC2=CC=CC=C2C(S(=O)(=O)O)=C1CC1=CC=CC=C1 CBCZQJLYYRPMRI-UHFFFAOYSA-N 0.000 claims 3
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims 3
- 239000004744 fabric Substances 0.000 description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 239000000835 fiber Substances 0.000 description 13
- 238000002156 mixing Methods 0.000 description 12
- 239000002270 dispersing agent Substances 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 7
- 238000000227 grinding Methods 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 5
- 238000007639 printing Methods 0.000 description 5
- 229920005610 lignin Polymers 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- NMDKWAQVRNUKQH-UHFFFAOYSA-N 2-benzylnaphthalene-1-sulfonic acid formaldehyde Chemical compound C=O.C(C1=CC=CC=C1)C1=C(C2=CC=CC=C2C=C1)S(=O)(=O)O NMDKWAQVRNUKQH-UHFFFAOYSA-N 0.000 description 2
- 150000004982 aromatic amines Chemical class 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 238000000859 sublimation Methods 0.000 description 2
- 230000008022 sublimation Effects 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000012544 Viola sororia Nutrition 0.000 description 1
- 241001106476 Violaceae Species 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 238000010017 direct printing Methods 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000009980 pad dyeing Methods 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/19—Nitro dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
Abstract
The invention discloses a kind of blueness to black disperse dye compound, it includes dye component, is counted with the gross weight of dye component as 100 parts, and the dye component includes：Dye component E shown in the formula (IV) of the dye component B shown in dye component A, 1~40 weight portion formula (I 2), 1~25 weight portion dye component C, 10~45 weight portion dye component D and 1~55 weight portion shown in 10~65 weight portion formulas (I 1), the dye component C is selected from least one in the dye monomer compound shown in formula (II), and described dye component D is selected from least one in the dye monomer compound shown in formula (III).The features such as disperse dye composite of the invention has good depth, good color fastness, excellent lifting force in application, helps to save dyestuff use cost.
Description
(1) technical field
The present invention relates to a kind of blueness to black disperse dye compound and its application, particularly in hydrophobic fiber material
Such as the application in the dyeing and stamp of Polyester Fibers and its blend fabric.
(2) background technology
With the development of polyesters hydrophobic fiber material and its blend fabric and ecological to textile printing and dyeing product and safety
The raising of performance requirement, common disperse dyes can not meet its dyeing demand in printing and dyeing, and other fibers are stain when as above contaminating
Seriously, cause fabric entirety color fastness decreased, spot not easy-clear the problems such as.Further, since the exploitation of disperse dyes new construction
Speed ratio is slower, existing procucts is carried out with commercialized technology treatment and seems further important.In existing conventional disperse dyestuff, knot
The single black-and-blue disperse dyes kind of structure is little, and such dyestuff often has depth and lifting force deficiency, fastness ability
Poor shortcoming, therefore general without single black-and-blue disperse dyes during dyeing, generally using different types of structure, different colours
Dyestuff blending prepares black disperse dye.It is traditional by C.I. disperse blues 291:1st, C.I. disperse violets 93, C.I. disperse oranges 76 are mixed
Black, the blue series dyes spelled are most widely used, but C.I. disperse oranges 76 can split under given conditions in the blending component
Solve and produce harmful arylamine, forbidding azo dyes are classified as by European Union, and in the dispersion blue-black dyestuff of existing report,
When upper dye polyester and its blend fabric, its color fastness and depth aspect are remained to be further improved, in this regard, finding dyeability
Excellent and without carcinogenic aromatic amine dye product turns into currently to be badly in need of.
(3) content of the invention
It is an object of the invention to provide a kind of blueness to the disperse dye composite of black and its in hydrophobic textile material
Material application especially in the printing and dyeing of polyester material, the disperse dye composite have in application good depth, good color fastness,
The features such as lifting force is excellent, helps to save dyestuff use cost.
Technical scheme is illustrated below.
The invention provides a kind of disperse dye composite, it includes dye component, is 100 parts with the gross weight of dye component
Meter, the dye component includes：Shown in dye component A, 1~40 weight portion formula (I-2) shown in 10~65 weight portion formulas (I-1)
Dye component B, 1~25 weight portion dye component C, the formula of 10~45 weight portion dye component D and 1~55 weight portion
(IV) dye component E, the dye component C shown in are selected from least one in the dye monomer compound shown in formula (II),
Described dye component D is selected from least one in the dye monomer compound shown in formula (III)；
In above-mentioned formula (II), X1It is defined as Cl or Br；
In above-mentioned formula (III), X2It is defined as Cl or Br.
Further, the dye component of disperse dye composite of the present invention, can also include：
1~30 weight portion dye component F, the dye component F is selected from the dye monomer shown in formula (V)~formula (VII)
At least one in compound,
In above formula (V)~(VII), X3、X4、X5It is Cl or Br each to independently define.
Preferably, the dye component includes：15~60 weight portion dye component A, 5~30 weight portion dye component B,
1~20 weight portion dye component C, 15~45 weight portion dye component D and 1~50 weight portion dye component E.
Or preferably, the dye component includes：15~60 weight portion dye component A, 5~30 weight portion dye sets
Divide B, 1~20 weight portion dye component C, 15~45 weight portion dye component D, 1~50 weight portion dye component E and 1~30
Weight portion dye component F.
As further preferably, the dye component is composed of the following components：15~60 weight portion dye component A, 5~
30 weight portion dye component B, 1~20 weight portion dye component C, 15~45 weight portion dye component D and 1~50 weight portion
Dye component E.
Or as further preferably, the dye component is made up of following dye component：15~60 weight portion dyestuffs
Component A, 5~30 weight portion dye component B, 1~20 weight portion dye component C, 15~45 weight portion dye component D, 1~50 weight
Amount part dye component E and 1~30 weight portion dye component F.
The dye monomer compound of formula (I)~(VII) used in the present invention easily can be known by those skilled in the art
Mode synthesize, or with reference to patent CN1230575, JP10120932, the method described in US4405330 and CN1036974
Or similar method is prepared.In addition, in the preparation of above-mentioned composite dye, can be by changing dyestuff intermediate preparation process in
Raw material proportioning, the intermediate for being mixed closed in a conventional manner as coupling component raw material, then with diazo component
Into, mixed dye is obtained, also may be selected to be compounded again after each dye monomer is synthesized.
Disperse dye composite of the invention, generally needs to add auxiliary agent to be disperseed in commercialization.For example will
After dye monomer compound represented by component A~F is mixed by above-mentioned proportioning, in the presence of auxiliary agent, water or other wetting agents
It is lower to carry out corpusculed with pulverizers such as sand mill or grinders；In addition also can be by the dye monomer chemical combination represented by component A~F
After thing carries out corpusculed treatment in the presence of auxiliary agent, water or other wetting agents with pulverizers such as sand mill or grinders respectively
Mixed with above-mentioned ratio.Due to the particularity of dye industry, it is difficult to also there is no need to be made sterling, it will usually with one
Impurity in a little preparation process.Therefore, disperse dye composite of the invention, when being made finished product, mainly contain dye component and
Auxiliary agent, also allows to contain a small amount of moisture and micro physical impurity.In described disperse dye composite, auxiliary agent and dyestuff into
The weight ratio for dividing is 0.25~5：1, preferably 0.3-5:1.The present invention specifically recommend the disperse dye composite by dyestuff into
Divide and auxiliary agent composition, wherein auxiliary agent and the weight ratio of dye component is 0.25~5：1；The dye component is by following components group
Into：15~60 weight portion dye component A, 5~30 weight portion dye component B, 1~20 weight portion dye component C, 15~45 weight
Part dye component D and 1~50 weight portion dye component E, or the dye component is made up of following dye component：15~
60 weight portion dye component A, 5~30 weight portion dye component B, 1~20 weight portion dye component C, 15~45 weight portion dyestuffs
Component D, 1~50 weight portion dye component E and 1~30 weight portion dye component F.
Auxiliary agent dispersant conventional when being disperse dyes commercialization or post processing, diffusant and surfactant etc.,
It can be one of following or any several mixture：Naphthalene sulfonic acid-formaldehyde condensation product, lignosulfonates, the contracting of alkyl naphthalene sulfonic acid formaldehyde
Compound, benzyl naphthalene sulfonic acid-formaldehyde condensation product, specifically such as condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF), naphthalenesulfonateformaldehyde formaldehyde contracting
Compound (dispersing agent NNO), benzyl naphthalene sulfonic acid-formaldehyde condensation product (dispersing agent CNF), sodium lignin sulfonate (lignin 85A, lignin
83A) etc..
Especially gather in hydrophobic textile material present invention also offers described blueness to black disperse dye compound
Application in the printing and dyeing of ester material.
Disperse dye composite of the present invention, through commercial treatment after, can be with the liquid after corpusculed, emulsifiable paste state
Or powdery, graininess supply dyeing after being dried with spray drying process etc., prepared with foregoing specific mixed proportion,
Can obtain black or blue color.The disperse dye composite be applied to hydrophobic textile material printing and dyeing, including it is semi-synthetic or
The dyeing of the textile material of the hydrophobic fibre blending of synthesis and stamp, this kind of textile material can be contaminated in any one form
Color, including fiber, yarn or adhesive-bonded fabric or textile fabric or knitting fabric.The disperse dye composite is particularly well-suited to polyester
The dyeing of material such as Polyester Fibers and its blend fabric and stamp.
Disperse dye composite of the present invention, can be dyeed, it can also be used to straight using common dip method, pad-dyeing method
Connect stamp.Wherein, common dip method is such as pre-processed polyester textile, is put into dye vat and is contaminated, and dye finishes, cold water wash
To neutral, squeeze out, then carry out reduction cleaning, dry；Fabric is such as carried out dye pre-treatment by direct printing, drying, setting, in stamp
Disperse dyes mill base is printed on machine, then is evaporated, the dye fixing on fabric is made using decatize mode, finally washed, tentering is fixed
Type.
Compared with prior art, the beneficial effects of the present invention are：The blue disperse dyes to black of the invention are combined
Thing be applied to hydrophobic textile material especially the stamp of polyester material or dyeing when, with depth it is good, lifting force is excellent,
The features such as good color fastness, so as in dyeing, dye dosage is few, help to save dyestuff use cost.
(4) specific embodiment
With reference to specific embodiment, the invention will be further described, but protection scope of the present invention is not limited in
This.
" part " described in embodiment is if without specializing, all represent " weight portion ".The some dyes used in embodiment
Monomeric compound is as follows：
Embodiment 1
By 17 parts of dyestuff A of formula (I-1), the dyestuff B of 8 parts of formulas (I-2), 7.3 parts of formulas (II-1) and 2.7 parts of formulas (II-2)
Dyestuff C, the dyestuff D of 24 parts of formulas (III-1), the dyestuff E of 41 parts of formulas (IV), 125 parts of Dispersant MF, after the 600 parts of blendings that add water,
Grinding distribution, dries, and gets product, and the dyestuff is applicable the dyeing of polyester fiber and its blend fabric, and fabric can be supplied to uniform
And the good black of fastness ability.
Embodiment 2
By 26 parts of dyestuff A of formula (I-1), the dyestuff B of 11 parts of formulas (I-2), 10 parts of formulas (II-1) and 5 parts of formulas (II-2) dye
Material C, the dyestuff D of 36 parts of formulas (III-1), the dyestuff E of 12 parts of formulas (IV), 150 parts of Dispersant MF add water after 600 parts of blendings, grind
Mill dispersion, dry, get product, the dyestuff is applicable the dyeing of polyester fiber and its blend fabric, can be supplied to fabric uniformly and
The good navy blue of fastness ability.
Embodiment 3
By 17 parts of dyestuff A of formula (I-1), the dyestuff B of 8 parts of formulas (I-2), 7.3 parts of formulas (II-1) and 2.7 parts of formulas (II-2)
Dyestuff C, the dyestuff D of 24 parts of formulas (III-2), the dyestuff E of 41 parts of formulas (IV), 125 parts of Dispersant MF, after the 600 parts of blendings that add water,
Grinding distribution, dries, and gets product, and the dyestuff is applicable the dyeing of polyester fiber and its blend fabric, and fabric can be supplied to uniform
And the good black of fastness ability.
Embodiment 4
By 26 parts of dyestuff A of formula (I-1), the dyestuff B of 11 parts of formulas (I-2), 10 parts of formulas (II-1) and 5 parts of formulas (II-2) dye
Material C, 24 parts of formulas (III-1) and 12 parts of dyestuff D of formula (III-2), the dyestuff E of 12 parts of formulas (IV), 150 parts of Dispersant MF, plus
After 600 parts of blendings of water, grinding distribution is dried, and is got product, and the dyestuff is applicable the dyeing of polyester fiber and its blend fabric, energy
It is supplied to fabric uniform and the good navy blue of fastness ability.
Embodiment 5
By 17 parts of dyestuff A of formula (I-1), the dyestuff B of 8 parts of formulas (I-2), 7.3 parts of formulas (II-1) and 2.7 parts of formulas (II-2)
Dyestuff C, 18 parts of formulas (III-1) and 6 parts of dyestuff D of formula (III-2), the dyestuff E of 41 parts of formulas (IV), 125 parts of Dispersant MF, plus
After 600 parts of blendings of water, grinding distribution is dried, and is got product, and the dyestuff is applicable the dyeing of polyester fiber and its blend fabric, energy
It is supplied to fabric uniform and the good black of fastness ability.
Embodiment 6
By 17 parts of dyestuff A of formula (I-1), the dyestuff B of 8 parts of formulas (I-2), 10 parts of formulas (II-1) dyestuff C, 18 parts of formulas
(III-1) and 6 parts of dyestuff D of formula (III-2), the dyestuff E of 41 parts of formulas (IV), 125 parts of Dispersant MF, add water 600 parts of blendings
Afterwards, grinding distribution, dries, and gets product, and the dyestuff is applicable the dyeing of polyester fiber and its blend fabric, and fabric can be supplied to equal
The even and good black of fastness ability.
Embodiment 7~36
According to the preparation method described in above-described embodiment 1, unlike using dyestuff A~F in table 1 weight ratio and help
Agent, slurries are made after the blending that adds water, and control the solid content of slurries for 35~45% are advisable, and grinding distribution obtains liquid finished product, or
It is further dried, solid articles is obtained, the dyestuff is applicable the dyeing of polyester fiber and its blend fabric, fabric can be supplied to uniform
And fastness ability good blueness or black tone.85A, 83A in table 1 are respectively lignin 85A, lignin 83A, A in table 1
The unit of each component is weight portion in~F.
Embodiment 37~40
According to the preparation method described in above-described embodiment 1, the difference is that using dye component and auxiliary agent in table 2, plus
Slurries are made after water blending, control the solid content of slurries for 35~45% are advisable, grinding distribution obtains liquid finished product, or further
Dry, solid articles are obtained, the dyestuff is applicable the dyeing of polyester fiber and its blend fabric, fabric can be supplied to uniform and fastness
Blue or black tone of good performance.
Table 2
In upper table, described formula (Ⅹ -1), the compound structure of (Ⅹ -2) are as follows：
Comparative example 1~5
Immediate prior art, referring to patent CN102344694, using dye component and weight shown in table 3 below
Number, auxiliary agent, the blending that adds water are uniform, and mill-drying obtains composite disperse dye.
Table 3
In upper table, the dye composition structure of described formula (Ⅸ) is as follows：
Dyeing Example：
Disperse dyes, disperse dyes obtained in comparative example 1~5 obtained in 2 grams of embodiments 1~40 are weighed, is individually dispersed in
In 500 milliliters of water, add 1 gram of dispersing agent NNO to stir, draw the water after 20 milliliters with 100 milliliters and mix, with acetic acid/vinegar
Sour sodium buffer solution adjusts pH to 4.0~5.0, polyester textile is put into, respectively in dye level 1.5% (C), 3% (2C), 6% (4C)
Under conditions of be warming up to 70 DEG C, continue with about 2 DEG C/min gradient increased temperatures to 130 DEG C, insulation dyeing 45 minutes.Then 80 are cooled to
DEG C or so use hot water wash 10min, dry.Using GB GB/T3920, GB/T3921, GB/T5718 test respectively its rub resistance,
It is resistance to soap, color fastness to sublimation result such as table 4 below：
Table 4
Its lifting force performance is tested using GB GB/T2397, as a result such as table 5 below：
Table 5
| Embodiment | Lifting force |
| Embodiment 1~40 | A |
| Comparative example 1 | A-B |
| Comparative example 2 | A-B |
| Comparative example 3 | A-B |
| Comparative example 4 | A-B |
| Comparative example 5 | B-C |
To sum up, from above-mentioned table 4, table 5, compared to the dyestuff that prior art is provided, it is with dye for dyestuff of the invention
The increase of color depth, fastness to rubbing, fastness to soaping and fastness to sublimation change is smaller, and dyeability is more stable, lifting force
More preferably.
Claims (12)
1. a kind of disperse dye composite, it includes dye component, is counted with the gross weight of dye component as 100 parts, the dyestuff into
Dividing includes the dye component A shown in 10~65 weight portion formulas (I-1), dye component B, 1 shown in 1~40 weight portion formula (I-2)
Dye set shown in the formula (IV) of~25 weight portion dye component C, 10~45 weight portion dye component D and 1~55 weight portion
E, the dye component C is divided to be selected from least one in the dye monomer compound shown in formula (II), described dye component D choosings
At least one from the dye monomer compound shown in formula (III)；
In above-mentioned formula (II), X1It is defined as Cl or Br；
In above-mentioned formula (III), X2It is defined as Cl or Br.
2. disperse dye composite as claimed in claim 1, it is characterised in that the dye component also includes：
1~30 weight portion dye component F, the dye component F is selected from the dye monomer chemical combination shown in formula (V)~formula (VII)
At least one in thing,
In above formula (V)~(VII), X3、X4、X5It is Cl or Br each to independently define.
3. disperse dye composite as claimed in claim 1, it is characterised in that the dye component includes：15~60 weight portions
Dye component A, 5~30 weight portion dye component B, 1~20 weight portion dye component C, 15~45 weight portion dye component D, with
And 1~50 weight portion dye component E.
4. disperse dye composite as claimed in claim 2, it is characterised in that the dye component includes：15~60 weight portions
Dye component A, 5~30 weight portion dye component B, 1~20 weight portion dye component C, 15~45 weight portion dye component D, 1~
50 weight portion dye component E and 1~30 weight portion dye component F.
5. the disperse dye composite as described in one of Claims 1 to 4, it is characterised in that the disperse dye composite is by contaminating
Material composition and auxiliary agent composition, the dye component is 1 with auxiliary agent weight ratio：0.25~5.
6. disperse dye composite as claimed in claim 5, it is characterised in that：Described dye component is by 15~60 weight portions
Dye component A, 5~30 weight portion dye component B, 1~20 weight portion dye component C, 15~45 weight portion dye component D, with
And 1~50 weight portion dye component E composition.
7. disperse dye composite as claimed in claim 5, it is characterised in that described dye component is by 15~60 weight portions
Dye component A, 5~30 weight portion dye component B, 1~20 weight portion dye component C, 15~45 weight portion dye component D, 1~
50 weight portion dye component E and 1~30 weight portion dye component F are constituted.
8. disperse dye composite as claimed in claim 5, it is characterised in that described auxiliary agent is selected from following a kind of or any
Several mixtures：Naphthalene sulfonic acid-formaldehyde condensation product, lignosulfonates, alkyl naphthalene sulfonic acid formaldehyde condensation products, benzyl naphthalene sulfonic acids first
Aldehyde condensate.
9. disperse dye composite as claimed in claim 6, it is characterised in that described auxiliary agent is selected from following a kind of or any
Several mixtures：Naphthalene sulfonic acid-formaldehyde condensation product, lignosulfonates, alkyl naphthalene sulfonic acid formaldehyde condensation products, benzyl naphthalene sulfonic acids first
Aldehyde condensate.
10. disperse dye composite as claimed in claim 7, it is characterised in that described auxiliary agent is selected from following a kind of or any
Several mixtures：Naphthalene sulfonic acid-formaldehyde condensation product, lignosulfonates, alkyl naphthalene sulfonic acid formaldehyde condensation products, benzyl naphthalene sulfonic acids first
Aldehyde condensate.
Disperse dye composite as described in one of 11. such as claim 8~10 is in the stamp of hydrophobic textile material or dyeing
Application.
12. applications as claimed in claim 11, it is characterised in that：Described hydrophobic textile material is polyester material.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2012/086970 WO2014094261A1 (en) | 2012-12-19 | 2012-12-19 | Blue-to-black disperse dye compound substance and use thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104884539A CN104884539A (en) | 2015-09-02 |
| CN104884539B true CN104884539B (en) | 2017-06-13 |
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| CN201280075941.0A Active CN104884539B (en) | 2012-12-19 | 2012-12-19 | It is a kind of blue to black disperse dye compound and its application |
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| Country | Link |
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| CN (1) | CN104884539B (en) |
| WO (1) | WO2014094261A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105131648A (en) * | 2015-07-03 | 2015-12-09 | 浙江亿得化工有限公司 | Novel composite black disperse dye |
| CN106833020B (en) * | 2017-01-23 | 2022-06-28 | 浙江博澳新材料股份有限公司 | Disperse dye composition and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1121465A (en) * | 1997-05-07 | 1999-01-26 | Sumitomo Chem Co Ltd | Disperse dye composition |
| CN1230575A (en) * | 1998-03-23 | 1999-10-06 | 戴斯塔纺织纤维股份有限公司德国两和公司 | Disperse azo dye mixtures |
| CN1696205A (en) * | 2005-05-20 | 2005-11-16 | 浙江闰土股份有限公司 | Composite environmental protection type disperse dyes |
| CN101328320A (en) * | 2008-07-18 | 2008-12-24 | 浙江龙盛染料化工有限公司 | Black disperse dye composition |
| CN102516812A (en) * | 2011-11-14 | 2012-06-27 | 浙江闰土股份有限公司 | Complex blue dye composition, complex dispersion blue dye and preparation method thereof |
-
2012
- 2012-12-19 CN CN201280075941.0A patent/CN104884539B/en active Active
- 2012-12-19 WO PCT/CN2012/086970 patent/WO2014094261A1/en active Application Filing
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1121465A (en) * | 1997-05-07 | 1999-01-26 | Sumitomo Chem Co Ltd | Disperse dye composition |
| CN1230575A (en) * | 1998-03-23 | 1999-10-06 | 戴斯塔纺织纤维股份有限公司德国两和公司 | Disperse azo dye mixtures |
| CN1696205A (en) * | 2005-05-20 | 2005-11-16 | 浙江闰土股份有限公司 | Composite environmental protection type disperse dyes |
| CN101328320A (en) * | 2008-07-18 | 2008-12-24 | 浙江龙盛染料化工有限公司 | Black disperse dye composition |
| CN102516812A (en) * | 2011-11-14 | 2012-06-27 | 浙江闰土股份有限公司 | Complex blue dye composition, complex dispersion blue dye and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2014094261A1 (en) | 2014-06-26 |
| CN104884539A (en) | 2015-09-02 |
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