CN102191142A - Surface yellow spot cleaning agent for neutral stones and stone cultural relics and preparation method thereof - Google Patents
Surface yellow spot cleaning agent for neutral stones and stone cultural relics and preparation method thereof Download PDFInfo
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- CN102191142A CN102191142A CN 201110091776 CN201110091776A CN102191142A CN 102191142 A CN102191142 A CN 102191142A CN 201110091776 CN201110091776 CN 201110091776 CN 201110091776 A CN201110091776 A CN 201110091776A CN 102191142 A CN102191142 A CN 102191142A
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Abstract
The invention discloses a cleaning agent for stones and stone cultural relics and a preparation method thereof. The cleaning agent can remove yellow spots from the surfaces of the stones and the stone cultural relics, wherein the yellow spots comprise rust yellow spots and organic yellow spots. The cleaning agent comprises organic acid, a reducing agent and water, wherein the organic acid mainly comprises monocarboxylic, dicarboxylic and polycarboxylic low-carbon acid (--COOH), sulfonic acid (--SO3H) and the like; and the reducing agent mainly comprises amine compounds. Cleaning liquid and waste liquid are neutral, do not have corrosion effect on the stones, and do not damage the environment. The cleaning agent has oxidation resistance, low cost, extremely low concentration and a simple operating method, is convenient to carry, can be prepared in advance, and can also be prepared on site.
Description
Technical field
The present invention relates to a kind of chemicals of removing stone material and stone cultural artifact surface rust macula lutea and organic macula lutea, particularly a kind of preparation method of neutral stain remover.
Background technology
Many building decoration stone materials or large-scale stone cultural artifact, because stone material self iron-bearing mineral is oxidized, perhaps stone material is subjected to the pollution of extraneous iron rust or coloring matter (as straw rope, packing case carton, ight soil, food, tea, coffee, fruit juice etc.), the surface can glow the xanchromatic spot, this not only influences the outward appearance of buildings, change the original appearance of stone cultural artifact, but also can influence the life-span of stone material.There is following problem in many macula lutea clean-out systems that go both at home and abroad at present: 1, be acid or alkaline, can cause corrosion to stone material; 2, concentration higher, and more or less contain tensio-active agent etc., enter and be difficult to remove behind the stone material micropore clean, can stay hidden danger or contaminate environment.
Summary of the invention
The object of the present invention is to provide a kind of clean-out system of removing stone material and stone cultural artifact surface macula lutea, it is neutral that this clean-out system and waste liquid thereof all are, and stone material is not had corrosive nature, and environment is not had destruction.Itself has antioxygenation clean-out system, and is with low cost, and concentration is extremely low, and is easy to carry, can prepare in advance, also can now join first usefulness, and working method is simple.
Concrete technical scheme of the present invention is as follows:
The present invention is a kind of neutral stone material and stone cultural artifact surface macula lutea clean-out system, prepares raw material according to the following portions by weight ratio: organic acid, 1.7 ~ 2.0 %; Reductive agent, 2.0 ~ 4.0 %; Water, 94.0 ~ 96.0 %; All percentage ratios are mass percent.
Organic acid of the present invention is monobasic, binary, low-carbon (LC) carboxylic acid cpd solid such as polynary, and the low-carbon (LC) carboxylic acid cpd is any of formic acid, acetate, oxalic acid, phenylformic acid, Whitfield's ointment, citric acid.
Reductive agent of the present invention is an aminated compounds matter, and aminated compounds is any of trolamine, azanol, aniline, hydrazine hydrate.
Clean-out system of the present invention, its pH value is 6.5 ~ 8.0.
The preparation method of neutral stone material of the present invention and stone cultural artifact surface macula lutea clean-out system comprises the steps:
(1), under the room temperature normal pressure, get the organic acid and the water of corresponding ratio of weight and number, organic acid is dissolved in the water, stirs, dissolve naturally;
(2), under the room temperature normal pressure, get the reductive agent of corresponding ratio of weight and number, be added drop-wise in the solution that step (1) obtained, mix and to obtain neutral stone material and stone cultural artifact surface macula lutea clean-out system.
The operating procedure of clean-out system of the present invention preferably adopts application method construction, and is promptly with clean-out system that materials such as facial tissue, paper pulp or rubber powder is wetting, sticks on the macula lutea place of stone material, above covered with plastic film, treat to remove behind the substantially dry and stick thing, stick to doing with clear water again.
Compared with prior art, the present invention has following advantage:
1, the present invention adopts gentle organic monoacid, is difficult for producing acid mist; And with aminated compounds as neutralizing agent, make clean-out system and waste liquid all be neutral, can not corrode stone material and destroy environment;
2, the reductibility of amine substance has strengthened the clenaing effect of clean-out system among the present invention, and its antioxidant property has also reduced the possibility of yellowing of cleaning the back stone material because self iron compound is oxidized once more simultaneously;
3, clean-out system of the present invention does not contain strong acid, heavy metal ion and tensio-active agent etc., and waste liquid is easy to handle.
Embodiment
Below in conjunction with specific examples content of the present invention is described in detail, but is to be understood that content of the present invention is not subjected to the specifically described restriction of the following example.
Example one
Under the room temperature normal pressure, get ratio of weight and number and be respectively 2.0% organic acid and 96% deionized water, the organic acid of this umber is dissolved in the water of this umber, and at the uniform velocity stirs dissolving naturally under the room temperature, cooling with glass stick; The adding ratio of weight and number is 2.0% amine reductive agent in above-mentioned solution, at the uniform velocity mixes to get final product.This solution is water white transparency, pH=6.5 ~ 7.0.Draw the wetting facial tissue of the above-mentioned solution of two droppers (about 2.5ml) with glue head dropper, stick stone surface rust staining Polluted area with facial tissue again, stone surface cleans up after 6 hours.
Example two
Under the room temperature normal pressure, get ratio of weight and number and be respectively 1.7% organic acid and 94.0% deionized water, the organic acid of this umber is dissolved in the water of this umber, and at the uniform velocity stirs dissolving naturally under the room temperature, cooling with glass stick; The adding ratio of weight and number is 94% amine reductive agent in above-mentioned solution, at the uniform velocity mixes to get final product.This solution is water white transparency, pH=7.5 ~ 8.0.Draw the wetting facial tissue of the above-mentioned solution of two droppers (about 2.5ml) with glue head dropper, stick stone surface coffee, soy sauce stain zone with facial tissue again, stone surface cleans up after 6 hours.
Example three
Under the room temperature normal pressure, get ratio of weight and number and be respectively 2.0% organic acid and 96% deionized water, the organic acid of this umber is dissolved in the water of this umber, and at the uniform velocity stirs dissolving naturally under the room temperature, cooling with glass stick; The adding ratio of weight and number is 2.0% amine reductive agent in above-mentioned solution, at the uniform velocity mixes to get final product.This solution is water white transparency, pH=6.5 ~ 7.0.Draw the wetting facial tissue of the above-mentioned solution of two droppers (about 2.5ml) with glue head dropper, stick stone surface soy sauce stain zone with facial tissue again, stone surface cleans up after 6 hours.
Above ratio all adopts ratio of weight and number.
Claims (7)
1. neutral stone material and stone cultural artifact surface macula lutea clean-out system is characterized in that, according to following portions by weight than the preparation raw material: organic acid, 1.7 ~ 2.0 %; Reductive agent, 2.0 ~ 4.0 %; Water, 94.0 ~ 96.0 %; All percentage ratios are mass percent.
2. neutral stone material according to claim 1 and stone cultural artifact surface macula lutea clean-out system is characterized in that, described organic acid is monobasic, binary, low-carbon (LC) carboxylic acid cpd solid such as polynary.
3. neutral stone material and the stone cultural artifact surface macula lutea clean-out system removed as claimed in claim 2 is characterized in that, described low-carbon (LC) carboxylic acid cpd is any of formic acid, acetate, oxalic acid, phenylformic acid, Whitfield's ointment, citric acid.
4. neutral stone material as claimed in claim 1 and stone cultural artifact surface macula lutea clean-out system is characterized in that described reductive agent is an aminated compounds matter.
5. neutral stone material as claimed in claim 4 and stone cultural artifact surface macula lutea clean-out system is characterized in that, described aminated compounds is any of trolamine, azanol, aniline, hydrazine hydrate.
6. as claim 1 or 2 or 3 or 4 or 5 described neutral stone materials and stone cultural artifact surface macula lutea clean-out system, it is characterized in that its pH value is 6.5 ~ 8.0.
7. the preparation method of neutral stone material according to claim 6 and stone cultural artifact surface macula lutea clean-out system is characterized in that described preparation method comprises the steps:
(1), under the room temperature normal pressure, get the organic acid and the water of corresponding ratio of weight and number, organic acid is dissolved in the water, stirs, dissolve naturally;
(2), under the room temperature normal pressure, get the reductive agent of corresponding ratio of weight and number, be added drop-wise in the solution that step (1) obtained, mix and to obtain neutral stone material and stone cultural artifact surface macula lutea clean-out system.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110091776A CN102191142B (en) | 2011-04-13 | 2011-04-13 | Surface yellow spot cleaning agent for neutral stones and stone cultural relics and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110091776A CN102191142B (en) | 2011-04-13 | 2011-04-13 | Surface yellow spot cleaning agent for neutral stones and stone cultural relics and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102191142A true CN102191142A (en) | 2011-09-21 |
| CN102191142B CN102191142B (en) | 2012-09-19 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201110091776A Expired - Fee Related CN102191142B (en) | 2011-04-13 | 2011-04-13 | Surface yellow spot cleaning agent for neutral stones and stone cultural relics and preparation method thereof |
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Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103525591A (en) * | 2013-10-21 | 2014-01-22 | 柳州鑫磊科技有限公司 | Environment-friendly cleaning agent |
| CN104419544A (en) * | 2013-08-22 | 2015-03-18 | 南通丝乡丝绸有限公司 | Scrubbing agent used for silk summer sleeping mat |
| CN104531404A (en) * | 2014-12-30 | 2015-04-22 | 陕西师范大学 | Gel cleaning agent for lampblack on surface of polychrome cultural relic |
| CN105111472A (en) * | 2015-08-13 | 2015-12-02 | 陕西师范大学 | Gel film for cleaning mildew and dust on surface of cultural relic |
| CN106995656A (en) * | 2017-04-28 | 2017-08-01 | 上海古猿人石材有限公司 | A kind of method for handling soft stone face tiles pollution |
| CN107034038A (en) * | 2017-04-28 | 2017-08-11 | 中昊(大连)化工研究设计院有限公司 | A kind of cleaning agent for being used to clean quartz ore |
| CN107335654A (en) * | 2017-05-18 | 2017-11-10 | 天赐瑰宝（北京）古建工程技术研究院有限公司 | A kind of cleaning reagent and cleaning method of stone cultural artifact sepia crust |
| CN107460063A (en) * | 2017-09-11 | 2017-12-12 | 济南大学 | A kind of preparation method for marble surface derusting and cleaning agent |
| CN107502472A (en) * | 2017-09-11 | 2017-12-22 | 济南大学 | A kind of preparation method for granite face derusting and cleaning agent |
| CN111154561A (en) * | 2020-01-10 | 2020-05-15 | 上海建为历保科技股份有限公司 | Alkali-efflorescence cleaning and alkali-inhibiting agent for brick wall and stone surface |
| CN111304021A (en) * | 2020-04-12 | 2020-06-19 | 长沙汇泉环境科技有限公司 | Neutral detergent and preparation method thereof |
| CN113182261A (en) * | 2021-05-19 | 2021-07-30 | 湖北高芯光电科技有限公司 | Novel technology for cleaning stone |
| CN113373008A (en) * | 2021-06-02 | 2021-09-10 | 佛山市雅伦高科石业有限公司 | M20 top-speed rust remover |
| CN113546907A (en) * | 2021-07-28 | 2021-10-26 | 韩忠君 | Non-acidic pollution-free stone cleaning method |
| CN113563806A (en) * | 2021-08-09 | 2021-10-29 | 浙江大学 | Inorganic magnesium-based adhesive for bonding and grouting fractured stone cultural relics and preparation method thereof |
| CN113860914A (en) * | 2021-09-16 | 2021-12-31 | 湖北文理学院 | Soak solution for removing white cobblestone rust yellow spots, preparation method of soak solution and method for removing white cobblestone rust yellow spots |
| CN115178509A (en) * | 2022-07-11 | 2022-10-14 | 南京博物院 | Sizing material colored drawing cultural relic reinforcement and surface clay cleaning method considering archaeological unearthing |
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Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104419544A (en) * | 2013-08-22 | 2015-03-18 | 南通丝乡丝绸有限公司 | Scrubbing agent used for silk summer sleeping mat |
| CN103525591A (en) * | 2013-10-21 | 2014-01-22 | 柳州鑫磊科技有限公司 | Environment-friendly cleaning agent |
| CN103525591B (en) * | 2013-10-21 | 2015-11-04 | 柳州鑫磊科技有限公司 | A kind of environment-friendly cleaning agent |
| CN104531404A (en) * | 2014-12-30 | 2015-04-22 | 陕西师范大学 | Gel cleaning agent for lampblack on surface of polychrome cultural relic |
| CN104531404B (en) * | 2014-12-30 | 2017-07-11 | 陕西师范大学 | A kind of colored drawing class cultural artifact surface oil smoke gel cleaning agent |
| CN105111472A (en) * | 2015-08-13 | 2015-12-02 | 陕西师范大学 | Gel film for cleaning mildew and dust on surface of cultural relic |
| CN105111472B (en) * | 2015-08-13 | 2018-01-12 | 陕西师范大学 | A kind of cultural artifact surface mildew and dust cleaning gel mould |
| CN106995656A (en) * | 2017-04-28 | 2017-08-01 | 上海古猿人石材有限公司 | A kind of method for handling soft stone face tiles pollution |
| CN107034038A (en) * | 2017-04-28 | 2017-08-11 | 中昊(大连)化工研究设计院有限公司 | A kind of cleaning agent for being used to clean quartz ore |
| CN107335654A (en) * | 2017-05-18 | 2017-11-10 | 天赐瑰宝（北京）古建工程技术研究院有限公司 | A kind of cleaning reagent and cleaning method of stone cultural artifact sepia crust |
| CN107502472A (en) * | 2017-09-11 | 2017-12-22 | 济南大学 | A kind of preparation method for granite face derusting and cleaning agent |
| CN107460063A (en) * | 2017-09-11 | 2017-12-12 | 济南大学 | A kind of preparation method for marble surface derusting and cleaning agent |
| CN111154561A (en) * | 2020-01-10 | 2020-05-15 | 上海建为历保科技股份有限公司 | Alkali-efflorescence cleaning and alkali-inhibiting agent for brick wall and stone surface |
| CN111304021A (en) * | 2020-04-12 | 2020-06-19 | 长沙汇泉环境科技有限公司 | Neutral detergent and preparation method thereof |
| CN113182261A (en) * | 2021-05-19 | 2021-07-30 | 湖北高芯光电科技有限公司 | Novel technology for cleaning stone |
| CN113373008A (en) * | 2021-06-02 | 2021-09-10 | 佛山市雅伦高科石业有限公司 | M20 top-speed rust remover |
| CN113546907A (en) * | 2021-07-28 | 2021-10-26 | 韩忠君 | Non-acidic pollution-free stone cleaning method |
| CN113563806A (en) * | 2021-08-09 | 2021-10-29 | 浙江大学 | Inorganic magnesium-based adhesive for bonding and grouting fractured stone cultural relics and preparation method thereof |
| CN113563806B (en) * | 2021-08-09 | 2022-04-12 | 浙江大学 | Inorganic magnesium-based adhesive for bonding and grouting fractured stone cultural relics and preparation method thereof |
| CN113860914A (en) * | 2021-09-16 | 2021-12-31 | 湖北文理学院 | Soak solution for removing white cobblestone rust yellow spots, preparation method of soak solution and method for removing white cobblestone rust yellow spots |
| CN113860914B (en) * | 2021-09-16 | 2023-06-27 | 湖北文理学院 | Soaking liquid for removing white cobblestone yellow spots, preparation method thereof and method for removing white cobblestone yellow spots |
| CN115178509A (en) * | 2022-07-11 | 2022-10-14 | 南京博物院 | Sizing material colored drawing cultural relic reinforcement and surface clay cleaning method considering archaeological unearthing |
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