CN111154561A - Alkali-efflorescence cleaning and alkali-inhibiting agent for brick wall and stone surface - Google Patents
Alkali-efflorescence cleaning and alkali-inhibiting agent for brick wall and stone surface Download PDFInfo
- Publication number
- CN111154561A CN111154561A CN202010024317.4A CN202010024317A CN111154561A CN 111154561 A CN111154561 A CN 111154561A CN 202010024317 A CN202010024317 A CN 202010024317A CN 111154561 A CN111154561 A CN 111154561A
- Authority
- CN
- China
- Prior art keywords
- parts
- alkali
- cleaning
- inhibiting agent
- efflorescence
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 55
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 50
- 230000002401 inhibitory effect Effects 0.000 title claims abstract description 49
- 239000003513 alkali Substances 0.000 title claims abstract description 45
- 239000004575 stone Substances 0.000 title claims abstract description 36
- 239000011449 brick Substances 0.000 title claims abstract description 32
- 238000006253 efflorescence Methods 0.000 title claims description 26
- 206010037844 rash Diseases 0.000 title claims description 26
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 72
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000008367 deionised water Substances 0.000 claims abstract description 42
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 42
- -1 alkylbenzene sulfonate Chemical class 0.000 claims abstract description 29
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 24
- 235000006408 oxalic acid Nutrition 0.000 claims abstract description 24
- 239000003054 catalyst Substances 0.000 claims abstract description 21
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 19
- 150000008051 alkyl sulfates Chemical class 0.000 claims abstract description 15
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 claims abstract description 14
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical compound CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 claims abstract description 12
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims abstract description 12
- RKWGIWYCVPQPMF-UHFFFAOYSA-N Chloropropamide Chemical compound CCCNC(=O)NS(=O)(=O)C1=CC=C(Cl)C=C1 RKWGIWYCVPQPMF-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 12
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 12
- 150000003973 alkyl amines Chemical class 0.000 claims abstract description 12
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 12
- 150000001412 amines Chemical class 0.000 claims abstract description 12
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 12
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229930195729 fatty acid Natural products 0.000 claims abstract description 12
- 239000000194 fatty acid Substances 0.000 claims abstract description 12
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 12
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229960005323 phenoxyethanol Drugs 0.000 claims abstract description 12
- 229960003080 taurine Drugs 0.000 claims abstract description 5
- 239000002904 solvent Substances 0.000 claims description 24
- 238000005507 spraying Methods 0.000 claims description 17
- 238000003756 stirring Methods 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 229940104261 taurate Drugs 0.000 claims description 9
- 230000001680 brushing effect Effects 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 239000000428 dust Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 239000012459 cleaning agent Substances 0.000 abstract description 2
- 150000003839 salts Chemical class 0.000 description 4
- 239000000126 substance Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 2
- 239000003566 sealing material Substances 0.000 description 2
- KIWBPDUYBMNFTB-UHFFFAOYSA-N Ethyl hydrogen sulfate Chemical compound CCOS(O)(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-N 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
- C04B41/61—Coating or impregnation
- C04B41/62—Coating or impregnation with organic materials
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2082—Polycarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/24—Mineral surfaces, e.g. stones, frescoes, plasters, walls or concretes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Emergency Medicine (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Detergent Compositions (AREA)
Abstract
The invention belongs to the technical field of wall surface cleaning agents, and particularly discloses a whiskering cleaning and alkali inhibiting agent for brick walls and stone surfaces, which is prepared from the following raw materials in parts by weight: 1-2 parts of oxalic acid; 2.5-6 parts of alkyl polyglucoside, fatty acid glucamide, alkylphenol ethoxylate, alkylamine oxide or ethoxylated amine; 1-3 parts of alkylbenzene sulfonate, taurine, alkyl sulfate, isethionate or alkyl ether sulfate; 0.5-2 parts of water-miscible glycol, soluble alkali metal, phenoxyethanol, glycol ether or dipropylene glycol n-propyl ether; 1-1.5 parts of catalyst and 18-30 parts of deionized water.
Description
Technical Field
The invention relates to the field related to wall surface cleaning agents, in particular to a saltpetering cleaning and alkali inhibiting agent for brick walls and stone surfaces.
Background
At present, in more and more cultural relics and buildings, the phenomena of efflorescence after the surfaces of brick walls and stones are cleaned are serious in the repairing process. The main reason is that natural stone and brick crystals are relatively thick, many capillaries cannot be seen by naked eyes exist, and water is transmitted to the other side through the capillary immersed surface in the stone. The characteristics and capillary pores of the natural stone provide channels for the permeation and precipitation of substances such as water, alkali, salt and the like in the bonding material and the formation of whiskering. The generation of alkali, salt and other component substances in the bonding material is a direct substance source for generating saltpetering by permeating pores of the stone and the brick. When the building is built, moisture-proof treatment is not carried out, so that water vapor permeates upwards along the wall body and is also the main reason for generating saltpetering.
The invention provides a whiskering cleaning and alkali inhibiting agent for brick wall and stone surface, which uses oxalic acid, alkyl polyglucoside, fatty acid glucamide, alkylphenol ethoxylate, alkyl amine oxide or ethoxylated amine, alkyl benzene sulfonate, taurine salt, alkyl sulfate, ethoxyl sulfonate or alkyl ether sulfate, water-miscible glycol, soluble alkali metal, phenoxyethanol, glycol ether or dipropylene glycol n-propyl ether, catalyst and deionized water to continuously mix and match and adjust the best cleaning time, removes the soluble alkali or salt, ensures no damage to the material surface, and simultaneously uses high permeability, fast curing and other sealing materials to brush to reduce whiskering phenomenon after repairing, thereby achieving the purpose of protecting the antique building wall surface and the stone surface.
Disclosure of Invention
The invention aims to provide a saltpetering cleaning and alkali inhibiting agent for brick walls and stone surfaces, which solves the problems in the prior art.
In order to achieve the purpose, the invention provides the following technical scheme:
a saltpetering cleaning and alkali inhibiting agent for brick walls and stone surfaces is composed of the following raw materials in parts by weight: 1-2 parts of oxalic acid, 2.5-6 parts of alkyl polyglucoside, 1-3 parts of alkylbenzene sulfonate, 0.5-2 parts of water-miscible glycol, 1-1.5 parts of catalyst and 18-30 parts of deionized water.
As a preferable technical scheme, the whiskering cleaning and alkali inhibiting agent is composed of the following raw materials in parts by weight: 1-2 parts of oxalic acid, 2.5-6 parts of fatty acid glucamide, 1-3 parts of taurate, 0.5-2 parts of soluble alkali metal and 18-30 parts of deionized water.
As a preferable technical scheme, the whiskering cleaning and alkali inhibiting agent is composed of the following raw materials in parts by weight: 1-2 parts of oxalic acid, 2.5-6 parts of alkylphenol ethoxylate, 1-3 parts of alkyl sulfate, 0.5-2 parts of phenoxyethanol, 1-1.5 parts of catalyst and 18-30 parts of deionized water.
As a preferable technical scheme, the whiskering cleaning and alkali inhibiting agent is composed of the following raw materials in parts by weight: 1-2 parts of oxalic acid, 2.5-6 parts of alkyl amine oxide, 1-3 parts of isethionate, 0.5-2 parts of glycol ether, 1-1.5 parts of catalyst and 18-30 parts of deionized water.
As a preferable technical scheme, the whiskering cleaning and alkali inhibiting agent is composed of the following raw materials in parts by weight: 1-2 parts of oxalic acid, 2.5-6 parts of ethoxylated amine, 1-3 parts of alkyl ether sulfate, 0.5-2 parts of dipropylene glycol n-propyl ether, 1-1.5 parts of a catalyst and 18-30 parts of deionized water.
A method for preparing a saltpetering cleaning and alkali inhibiting agent for brick walls and stone surfaces comprises the following steps:
s1, preparing raw materials:
1 part of oxalic acid;
4 parts of alkyl polyglucoside, fatty acid glucamide, alkylphenol ethoxylate, alkylamine oxide or ethoxylated amine;
2 parts of alkylbenzene sulfonate, taurine, alkyl sulfate, hydroxyethyl sulfonate or alkyl ether sulfate;
1 part of water-miscible glycol, soluble alkali metal, phenoxyethanol, glycol ether or dipropylene glycol n-propyl ether;
1 part of a catalyst;
19 parts of deionized water;
s2, taking oxalic acid and deionized water according to the ratio of 1:10, and uniformly stirring to obtain a solvent I;
s3, dividing the rest deionized water into 3 parts, respectively placing the 3 parts into A, B, C three containers, and then heating the two containers A and B to ensure that the deionized water in the container A is heated to 45-50 ℃, the deionized water in the container B is heated to 60-80 ℃, and keeping the temperature;
s4, taking the alkyl polyglucoside, the fatty acid glucamide, the alkylphenol ethoxylate, the alkylamine oxide or ethoxylated amine in parts by weight, putting the mixture into a container A, and mixing and stirring the mixture with deionized water for 10-15 minutes to obtain a solvent II;
s5, putting the alkylbenzene sulfonate, the taurate, the alkyl sulfate, the hydroxyethyl sulfonate or the alkyl ether sulfate in parts by weight into a container B, and mixing and stirring the alkylbenzene sulfonate, the taurate, the alkyl sulfate, the hydroxyethyl sulfonate or the alkyl ether sulfate with deionized water for 10-35 minutes to obtain a solvent III;
s6, taking the water-miscible glycol, soluble alkali metal, phenoxyethanol, glycol ether or dipropylene glycol n-propyl ether in parts by weight, putting the mixture into a container C, and mixing and stirring the mixture with deionized water for 2-3 minutes to obtain a solvent IV;
and S7, mixing the solvent II, the solvent III and the solvent IV with the solvent I at room temperature, adding the catalyst in parts by weight, and stirring uniformly to obtain the whiskering cleaning and alkali inhibiting agent.
A method for using a saltpetering cleaning and alkali inhibiting agent for brick walls and stone surfaces comprises the following steps:
s1, cleaning dust and sundries on the surfaces of the brick wall and the stone;
s2, spraying the alkali-efflorescence cleaning and alkali-inhibiting agent on the surfaces of the brick walls and the stones by adopting a high-pressure spray gun;
s3, after the first-time spraying alkali-efflorescence cleaning and alkali-inhibiting agent is initially dried, spraying a second-time alkali-efflorescence cleaning and alkali-inhibiting agent, wherein the spraying process is uniform and free of exposed bottom;
and S4, naturally drying, and brushing the surfaces of the brick walls and the stone for multiple times by using the high-permeability and fast-curing coating, wherein the thickness of each brushing is 1.4-1.6 mm.
As a preferable technical scheme of the invention, the first time of the alkali-efflorescence cleaning and alkali-inhibiting agent is 30-60s, and the second time of the alkali-efflorescence cleaning and alkali-inhibiting agent is 20-40 s.
In a preferred embodiment of the present invention, the whiskering cleaning and alkali suppressing agent is sprayed in a non-rainy environment.
Compared with the prior art, the invention has the beneficial effects that: the invention relates to a whiskering cleaning and alkali inhibiting agent for brick walls and stone surfaces, which utilizes oxalic acid, alkyl polyglucoside, fatty acid glucamide, alkylphenol ethoxylate, alkylamine oxide or ethoxylated amine, alkylbenzene sulfonate, taurine, alkyl sulfate, isethionate or alkyl ether sulfate, water-miscible glycol, soluble alkali metal, phenoxyethanol, glycol ether or dipropylene glycol n-propyl ether, catalyst and deionized water to continuously adjust the proportion and debug the best cleaning time, removes the soluble alkali or salt, ensures no damage to the material surface, and simultaneously adopts high-permeability and fast-curing sealing materials to brush, reduces the whiskering phenomenon after the repair is finished, thereby achieving the purpose of protecting the antique building wall surfaces and the stone surfaces.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1: the invention provides a technical scheme that: a saltpetering cleaning and alkali inhibiting agent for brick walls and stone surfaces is composed of the following raw materials in parts by weight: 1-2 parts of oxalic acid, 2.5-6 parts of alkyl polyglucoside, 1-3 parts of alkylbenzene sulfonate, 0.5-2 parts of water-miscible glycol, 1-1.5 parts of catalyst and 18-30 parts of deionized water.
Further, the whiskering cleaning and alkali inhibiting agent is composed of the following raw materials in parts by weight: 1-2 parts of oxalic acid, 2.5-6 parts of fatty acid glucamide, 1-3 parts of taurate, 0.5-2 parts of soluble alkali metal and 18-30 parts of deionized water.
Further, the whiskering cleaning and alkali inhibiting agent is composed of the following raw materials in parts by weight: 1-2 parts of oxalic acid, 2.5-6 parts of alkylphenol ethoxylate, 1-3 parts of alkyl sulfate, 0.5-2 parts of phenoxyethanol, 1-1.5 parts of catalyst and 18-30 parts of deionized water.
Further, the whiskering cleaning and alkali inhibiting agent is composed of the following raw materials in parts by weight: 1-2 parts of oxalic acid, 2.5-6 parts of alkyl amine oxide, 1-3 parts of isethionate, 0.5-2 parts of glycol ether, 1-1.5 parts of catalyst and 18-30 parts of deionized water.
Further, the whiskering cleaning and alkali inhibiting agent is composed of the following raw materials in parts by weight: 1-2 parts of oxalic acid, 2.5-6 parts of ethoxylated amine, 1-3 parts of alkyl ether sulfate, 0.5-2 parts of dipropylene glycol n-propyl ether, 1-1.5 parts of a catalyst and 18-30 parts of deionized water.
A method for preparing a saltpetering cleaning and alkali inhibiting agent for brick walls and stone surfaces comprises the following steps:
s1, preparing raw materials:
1 part of oxalic acid;
4 parts of alkyl polyglucoside, fatty acid glucamide, alkylphenol ethoxylate, alkylamine oxide or ethoxylated amine;
2 parts of alkylbenzene sulfonate, taurine, alkyl sulfate, hydroxyethyl sulfonate or alkyl ether sulfate;
1 part of water-miscible glycol, soluble alkali metal, phenoxyethanol, glycol ether or dipropylene glycol n-propyl ether;
1 part of a catalyst;
19 parts of deionized water;
s2, taking oxalic acid and deionized water according to the ratio of 1:10, and uniformly stirring to obtain a solvent I;
s3, dividing the rest deionized water into 3 parts, respectively placing the 3 parts into A, B, C three containers, and then heating the two containers A and B to ensure that the deionized water in the container A is heated to 45-50 ℃, the deionized water in the container B is heated to 60-80 ℃, and keeping the temperature;
s4, taking the alkyl polyglucoside, the fatty acid glucamide, the alkylphenol ethoxylate, the alkylamine oxide or ethoxylated amine in parts by weight, putting the mixture into a container A, and mixing and stirring the mixture with deionized water for 10-15 minutes to obtain a solvent II;
s5, putting the alkylbenzene sulfonate, the taurate, the alkyl sulfate, the hydroxyethyl sulfonate or the alkyl ether sulfate in parts by weight into a container B, and mixing and stirring the alkylbenzene sulfonate, the taurate, the alkyl sulfate, the hydroxyethyl sulfonate or the alkyl ether sulfate with deionized water for 10-35 minutes to obtain a solvent III;
s6, taking the water-miscible glycol, soluble alkali metal, phenoxyethanol, glycol ether or dipropylene glycol n-propyl ether in parts by weight, putting the mixture into a container C, and mixing and stirring the mixture with deionized water for 2-3 minutes to obtain a solvent IV;
and S7, mixing the solvent II, the solvent III and the solvent IV with the solvent I at room temperature, adding the catalyst in parts by weight, and stirring uniformly to obtain the whiskering cleaning and alkali inhibiting agent.
A method for using a saltpetering cleaning and alkali inhibiting agent for brick walls and stone surfaces comprises the following steps:
s1, cleaning dust and sundries on the surfaces of the brick wall and the stone;
s2, spraying the alkali-efflorescence cleaning and alkali-inhibiting agent on the surfaces of the brick walls and the stones by adopting a high-pressure spray gun;
s3, after the first-time spraying alkali-efflorescence cleaning and alkali-inhibiting agent is initially dried, spraying a second-time alkali-efflorescence cleaning and alkali-inhibiting agent, wherein the spraying process is uniform and free of exposed bottom;
and S4, naturally drying, and brushing the surfaces of the brick walls and the stone for multiple times by using the high-permeability and fast-curing coating, wherein the thickness of each brushing is 1.4-1.6 mm.
Furthermore, the first time of spraying the alkali-efflorescence cleaning and alkali-inhibiting agent is 30-60s, and the second time of spraying is 20-40 s.
Further, the whiskering cleaning and alkali-inhibiting agent is sprayed in the non-rainy environment.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (9)
1. The efflorescence cleaning and alkali inhibiting agent for the surfaces of brick walls and stone materials is characterized by comprising the following raw materials in parts by weight: 1-2 parts of oxalic acid, 2.5-6 parts of alkyl polyglucoside, 1-3 parts of alkylbenzene sulfonate, 0.5-2 parts of water-miscible glycol, 1-1.5 parts of catalyst and 18-30 parts of deionized water.
2. The alkali-efflorescence cleaning and inhibiting agent for brick walls and stone surfaces as claimed in claim 1, wherein the alkali-efflorescence cleaning and inhibiting agent is composed of the following raw materials in parts by weight: 1-2 parts of oxalic acid, 2.5-6 parts of fatty acid glucamide, 1-3 parts of taurate, 0.5-2 parts of soluble alkali metal and 18-30 parts of deionized water.
3. The alkali-efflorescence cleaning and inhibiting agent for brick walls and stone surfaces as claimed in claim 1, wherein the alkali-efflorescence cleaning and inhibiting agent is composed of the following raw materials in parts by weight: 1-2 parts of oxalic acid, 2.5-6 parts of alkylphenol ethoxylate, 1-3 parts of alkyl sulfate, 0.5-2 parts of phenoxyethanol, 1-1.5 parts of catalyst and 18-30 parts of deionized water.
4. The alkali-efflorescence cleaning and inhibiting agent for brick walls and stone surfaces as claimed in claim 1, wherein the alkali-efflorescence cleaning and inhibiting agent is composed of the following raw materials in parts by weight: 1-2 parts of oxalic acid, 2.5-6 parts of alkyl amine oxide, 1-3 parts of isethionate, 0.5-2 parts of glycol ether, 1-1.5 parts of catalyst and 18-30 parts of deionized water.
5. The alkali-efflorescence cleaning and inhibiting agent for brick walls and stone surfaces as claimed in claim 1, wherein the alkali-efflorescence cleaning and inhibiting agent is composed of the following raw materials in parts by weight: 1-2 parts of oxalic acid, 2.5-6 parts of ethoxylated amine, 1-3 parts of alkyl ether sulfate, 0.5-2 parts of dipropylene glycol n-propyl ether, 1-1.5 parts of a catalyst and 18-30 parts of deionized water.
6. The method for preparing the efflorescence cleaning and alkali inhibiting agent for brick walls and stone surfaces according to any one of claims 1 to 5, characterized by comprising the following steps:
s1, preparing raw materials:
1 part of oxalic acid;
4 parts of alkyl polyglucoside, fatty acid glucamide, alkylphenol ethoxylate, alkylamine oxide or ethoxylated amine;
2 parts of alkylbenzene sulfonate, taurine, alkyl sulfate, hydroxyethyl sulfonate or alkyl ether sulfate;
1 part of water-miscible glycol, soluble alkali metal, phenoxyethanol, glycol ether or dipropylene glycol n-propyl ether;
1 part of a catalyst;
19 parts of deionized water;
s2, taking oxalic acid and deionized water according to the ratio of 1:10, and uniformly stirring to obtain a solvent I;
s3, dividing the rest deionized water into 3 parts, respectively placing the 3 parts into A, B, C three containers, and then heating the two containers A and B to ensure that the deionized water in the container A is heated to 45-50 ℃, the deionized water in the container B is heated to 60-80 ℃, and keeping the temperature;
s4, taking the alkyl polyglucoside, the fatty acid glucamide, the alkylphenol ethoxylate, the alkylamine oxide or ethoxylated amine in parts by weight, putting the mixture into a container A, and mixing and stirring the mixture with deionized water for 10-15 minutes to obtain a solvent II;
s5, putting the alkylbenzene sulfonate, the taurate, the alkyl sulfate, the hydroxyethyl sulfonate or the alkyl ether sulfate in parts by weight into a container B, and mixing and stirring the alkylbenzene sulfonate, the taurate, the alkyl sulfate, the hydroxyethyl sulfonate or the alkyl ether sulfate with deionized water for 10-35 minutes to obtain a solvent III;
s6, taking the water-miscible glycol, soluble alkali metal, phenoxyethanol, glycol ether or dipropylene glycol n-propyl ether in parts by weight, putting the mixture into a container C, and mixing and stirring the mixture with deionized water for 2-3 minutes to obtain a solvent IV;
and S7, mixing the solvent II, the solvent III and the solvent IV with the solvent I at room temperature, adding the catalyst in parts by weight, and stirring uniformly to obtain the whiskering cleaning and alkali inhibiting agent.
7. The use method of the efflorescence cleaning and alkali inhibiting agent for brick walls and stone surfaces according to any one of claims 1 to 6, characterized by comprising the following steps:
s1, cleaning dust and sundries on the surfaces of the brick wall and the stone;
s2, spraying the alkali-efflorescence cleaning and alkali-inhibiting agent on the surfaces of the brick walls and the stones by adopting a high-pressure spray gun;
s3, after the first-time spraying alkali-efflorescence cleaning and alkali-inhibiting agent is initially dried, spraying a second-time alkali-efflorescence cleaning and alkali-inhibiting agent, wherein the spraying process is uniform and free of exposed bottom;
and S4, naturally drying, and brushing the surfaces of the brick walls and the stone for multiple times by using the high-permeability and fast-curing coating, wherein the thickness of each brushing is 1.4-1.6 mm.
8. The method as claimed in claim 7, wherein the time for the first spraying is 30-60s, and the time for the second spraying is 20-40 s.
9. The method of claim 7, wherein the cleaning and inhibiting agent is applied by spraying in a non-rainy environment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010024317.4A CN111154561A (en) | 2020-01-10 | 2020-01-10 | Alkali-efflorescence cleaning and alkali-inhibiting agent for brick wall and stone surface |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010024317.4A CN111154561A (en) | 2020-01-10 | 2020-01-10 | Alkali-efflorescence cleaning and alkali-inhibiting agent for brick wall and stone surface |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111154561A true CN111154561A (en) | 2020-05-15 |
Family
ID=70562230
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010024317.4A Pending CN111154561A (en) | 2020-01-10 | 2020-01-10 | Alkali-efflorescence cleaning and alkali-inhibiting agent for brick wall and stone surface |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111154561A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111304012A (en) * | 2020-04-16 | 2020-06-19 | 武汉东方聚仁防水保温有限公司 | Concrete base surface cleaning alkali-resistant material and preparation method thereof |
| CN115125068A (en) * | 2022-06-23 | 2022-09-30 | 广东翔顺建设集团有限公司 | Biogel type structure surface alkali return crystal clearing material and application |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1045417A (en) * | 1989-03-10 | 1990-09-19 | 秦宝平 | Silicate building material and building surface clean-out system |
| CN1532271A (en) * | 2003-03-25 | 2004-09-29 | 福建省漳平市振福化工有限公司 | Rust removing agent, for stone material and its proparing method |
| CN102080024A (en) * | 2009-11-30 | 2011-06-01 | 杭州正博新型建筑材料有限公司 | High-performance mild cleanser for cleansing wall face brick |
| CN102159692A (en) * | 2008-08-14 | 2011-08-17 | 麦莱琉卡有限公司 | Ultra concentrated liquid laundry detergent |
| CN102191142A (en) * | 2011-04-13 | 2011-09-21 | 浙江大学 | Surface yellow spot cleaning agent for neutral stones and stone cultural relics and preparation method thereof |
| CN102533469A (en) * | 2010-12-10 | 2012-07-04 | 苏州蜘蛛人外墙粉涂工程有限公司 | Cleaning agent and cleaning method for building outer walls |
| CN103492546A (en) * | 2011-04-18 | 2014-01-01 | 罗狄亚聚酰胺特殊品有限公司 | Preparations for all-purpose cleaning compositions |
| CN105670819A (en) * | 2014-11-17 | 2016-06-15 | 天津橙垄达环保科技开发有限公司 | Cleaning agent for building exterior walls and preparation method therefor |
| CN107057875A (en) * | 2017-04-12 | 2017-08-18 | 佛山市德可为装饰材料有限公司 | Cleaning agent for cleaning ceramic tile back side attachment |
-
2020
- 2020-01-10 CN CN202010024317.4A patent/CN111154561A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1045417A (en) * | 1989-03-10 | 1990-09-19 | 秦宝平 | Silicate building material and building surface clean-out system |
| CN1532271A (en) * | 2003-03-25 | 2004-09-29 | 福建省漳平市振福化工有限公司 | Rust removing agent, for stone material and its proparing method |
| CN102159692A (en) * | 2008-08-14 | 2011-08-17 | 麦莱琉卡有限公司 | Ultra concentrated liquid laundry detergent |
| CN102080024A (en) * | 2009-11-30 | 2011-06-01 | 杭州正博新型建筑材料有限公司 | High-performance mild cleanser for cleansing wall face brick |
| CN102533469A (en) * | 2010-12-10 | 2012-07-04 | 苏州蜘蛛人外墙粉涂工程有限公司 | Cleaning agent and cleaning method for building outer walls |
| CN102191142A (en) * | 2011-04-13 | 2011-09-21 | 浙江大学 | Surface yellow spot cleaning agent for neutral stones and stone cultural relics and preparation method thereof |
| CN103492546A (en) * | 2011-04-18 | 2014-01-01 | 罗狄亚聚酰胺特殊品有限公司 | Preparations for all-purpose cleaning compositions |
| CN105670819A (en) * | 2014-11-17 | 2016-06-15 | 天津橙垄达环保科技开发有限公司 | Cleaning agent for building exterior walls and preparation method therefor |
| CN107057875A (en) * | 2017-04-12 | 2017-08-18 | 佛山市德可为装饰材料有限公司 | Cleaning agent for cleaning ceramic tile back side attachment |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111304012A (en) * | 2020-04-16 | 2020-06-19 | 武汉东方聚仁防水保温有限公司 | Concrete base surface cleaning alkali-resistant material and preparation method thereof |
| CN115125068A (en) * | 2022-06-23 | 2022-09-30 | 广东翔顺建设集团有限公司 | Biogel type structure surface alkali return crystal clearing material and application |
| CN115125068B (en) * | 2022-06-23 | 2023-07-07 | 广东翔顺建设集团有限公司 | Biological gel type structure surface alkali return crystallization removal material and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102249708B (en) | Preparation method for anti-corrosion and flameproof integrated coating for thick-type steel structure | |
| CN111154561A (en) | Alkali-efflorescence cleaning and alkali-inhibiting agent for brick wall and stone surface | |
| CN106082893A (en) | Seepage selfreparing waterproof mortar and preparation method thereof | |
| CN106278058A (en) | A kind of preparation method of moistureproof Salt And Alkali Tolerance building mortar | |
| CN106867345A (en) | A kind of gypsum slag cement base thicker steel structure fireproofing, anti-corrosion, the preparation method of heat insulation integrated coating | |
| CN105777053A (en) | Single-component quick-drying and quick-hardening type polymer cement waterproof coating and use method thereof | |
| CN104829161A (en) | Novel waterproof agent for building gypsum, and preparation method thereof | |
| CN109133841A (en) | A kind of novel magnesium oxysulfide cement-based fireproofing coating, preparation and construction method | |
| CN103131229B (en) | Sealant used for aqueous acrylic acid ester emulsion coating and application method | |
| JPS61287477A (en) | Formation of inorganic coating film | |
| CN108698928A (en) | Multifunctional composite construction material and its construction method | |
| KR101791420B1 (en) | Organic-inorganic eco-friendly surface coating material composition for protecting surface of structure and method for protecting surface of structure therewith | |
| CN105086821B (en) | A kind of wall hydrophober and preparation method thereof | |
| SK8892000A3 (en) | Method of producing a water-repellent product, and product and method for waterproofing a surface of a building material | |
| CN102976706B (en) | Composite mortar | |
| CN105236822B (en) | A kind of cement-based material surface waterproofing method and the preparation method of Special waterproof material and the waterproof material | |
| CN116332580A (en) | Preparation method for preparing simulated stone by using chrome-containing leather ash | |
| CN108580239A (en) | Water-fast granite coating and its construction technology | |
| CN108929069A (en) | A kind of self-cleaning lacquer and preparation method thereof | |
| CN105176147B (en) | A kind of coating modelled after an antique and preparation method thereof | |
| CN101239842B (en) | Concrete rough surface processing agent and its preparation method and application | |
| CN105018935A (en) | Metalware buffing compound and preparing method thereof | |
| CN104211440A (en) | Preparation method of exposed aggregate concrete and exposed aggregate water-washing agent used by same | |
| US1541606A (en) | Composition of matter for facing concrete blocks | |
| CN115260873B (en) | Waterproof coating for hydraulic engineering |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200515 |
|
| RJ01 | Rejection of invention patent application after publication |