CN107502472A - A kind of preparation method for granite face derusting and cleaning agent - Google Patents
A kind of preparation method for granite face derusting and cleaning agent Download PDFInfo
- Publication number
- CN107502472A CN107502472A CN201710810827.2A CN201710810827A CN107502472A CN 107502472 A CN107502472 A CN 107502472A CN 201710810827 A CN201710810827 A CN 201710810827A CN 107502472 A CN107502472 A CN 107502472A
- Authority
- CN
- China
- Prior art keywords
- liquid
- cleaning agent
- granite
- preparation
- derusting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of preparation method for granite face derusting and cleaning agent, it is characterised in that（1）16 ~ 20% concentrated sulfuric acid is slowly added in 58 ~ 64% water：Stir and evenly mix, after being cooled to room temperature, add 10 ~ 15% phosphoric acid, stir and evenly mix, add 6 ~ 10% stannous chloride heating for dissolving, be cooled to room temperature, it is body A liquid to obtain transparent liquid；（2）Added by following composition, water：76 ~ 80%, N alkyl dimethyl betaine：2 ~ 5%, triisopropanolamine：16 ~ 20%, each component sum is well mixed, that is, it is B liquid to obtain transparency liquid absolutely, dissolving to be stirred at room temperature；（3）Preparation for granite face derusting and cleaning agent：It is 1 by volume by A liquid and B liquid in reactor：1 mixing, produces granite face derusting and cleaning agent.The cleaning agent cleaning performance is notable, can improve the brightness of granite, reduces the possibility of granite yellowing again.
Description
Technical field
It is more particularly to a kind of for granite face derusting and cleaning agent the present invention relates to the cleaning field of silicate product
Preparation method.
Background technology
Granite is formed by igneous rock, is a kind of hard crystalline lens stone material of steel, is initially formed and be mingled with by feldspar, quartz
One or more dark minerals matter, are all stay aligned in structure.Granite using quartz, feldspar and mica as mainly into
Point.Wherein feldspar content is 40%-60%, quartz content 20%-40%, and its color is decided by the type and quantity of ingredient.
Granite is the rock of holocrystalline structure, and high-quality granite crystal grain is thin and uniform, construction is close, quartz content is more, feldspar gloss
It is bright.Granitic dioxide-containing silica is higher, belongs to acid rock.Some granites contain trace-level activity element, this kind of
Granite should avoid being used for interior.Granite compact structure, quality are hard, acid and alkali-resistance, against weather are good, can be outdoor long-term
Use.
Granite can produce in use rust staining, macula lutea and influence the attractive in appearance and life-span of granite.Formed rust staining or
Macula lutea mainly has three kinds of reasons：First, it is oxidized because granite itself contains some chemical substances such as iron mineral, or flower hilllock
Rock is adhered to and is embedded in the metallic iron on granite top layer in saw, mill, transportation by extraneous iron rust such as stone material, certain
Under environmental condition iron oxide is generated with oxygen effect in air（Iron rust）, cause granite face to turn yellow, rust staining occur, seriously very
Cavity is formed to corrosion；Second, it is the intrusion of adjacent objects, the water pipe corrosion that the metal of such as cladding installation can be neighbouring, corrosion
Thing rainwater etc. rushes band throughout the year and attachment and infiltration stone surface form sheet macula lutea；3rd, it is that contact is other containing organic pigment
Material, such as straw rope, carton, excrement, food tea, coffee, the pollutant of fruit juice, surface can also glow macula lutea, so
The attractive in appearance of building is not only influenceed, changes the original appearance of stone matter, can also influence the life-span of granite.Many removes macula lutea both at home and abroad at present
Cleaning agent is mostly in acid or alkalescence.It is averaged according to different chemical composition ratio in 2485 parts of granite all over the world, according to shared
Percentage by weight is by again to being gently：SiO2- 72.04%, Al2O3- 14.42%, K2O -4.12%, Na2O -3.69%,
CaO -1.82%, FeO -1.68%, Fe2O3- 1.22%, MgO -0.71%, TiO2- 0.30%, P2O5- 0.12%,
MnO -0.05%, from the point of view of its chemical composition, granite has acid resistance, thus be accordingly used in the cleaning of granite and can make acidity
's.
The content of the invention
It is an object of the invention to provide a kind of preparation method for granite face derusting and cleaning agent, can not only remove
The greasy dirt and rust staining of granite face, recover primary colors, while the cleaning agent of granite glossiness can be improved, pass through following technology
Scheme is realized.
A kind of preparation method for granite face derusting and cleaning agent, it is characterised in that this method has following technique
Step：
（1）A liquid is prepared：In reactor, added by following composition mass percentage concentration, 16 ~ 20% concentrated sulfuric acid is slowly added to 58
In ~ 64% water：Stir and evenly mix, after being cooled to room temperature, add 10 ~ 15% phosphoric acid, stir and evenly mix, add 6 ~ 10% dichlorides
Tin, each component sum are a hundred per cent, dissolve by heating, are cooled to room temperature, it is body A liquid to obtain transparent liquid；
（2）B liquid is prepared：In reactor, added by following composition mass percentage concentration, water：76 ~ 80%, N- alkyl dimethyl beet
Alkali：2 ~ 5%, triisopropanolamine：16 ~ 20%, each component sum is well mixed absolutely, dissolving to be stirred at room temperature, that is, obtained
Prescribed liquid is B liquid；
（3）Preparation for granite face derusting and cleaning agent：It is 1 by volume by A liquid and B liquid in reactor：1 mixing, i.e.,
Obtain granite face derusting and cleaning agent.
Step（1）Described in phosphoric acid and sulfuric acid volume ratio 1：1.6 between ~ 1.8.
Step（1）Described in stannous chloride active ingredient more than 95%.
It is used for granite face derusting and cleaning agent application method obtained by the present invention：By granite face derusting and cleaning agent
It is coated in after reacting 5 ~ 00min on granite rust staining point and is cleaned, then clear water is rinsed well, you can.
Advantages of the present invention and effect are：
（1）The present invention is made for granite face derusting and cleaning agent, is mixed using inorganic acid, and cleaning speed is fast, will not be corroded
The structure of granite, with the addition of stannous chloride has strong reducing property, and addition triisopropanolamine with iron there is strong complexing to promote
Granite face rust staining quickly surveys bottom removing, and cleaning performance is obvious, reduces the possibility of granite yellowing again.
（2）The present invention is obtained for granite face derusting and cleaning agent, and preparation technology is simple, and condition is easily controllable, production
Cost is low, is easy to industrialized production.
（3）The present invention, which obtains, is used for granite face derusting and cleaning agent, with the addition of N- alkyl dimethyl betaines two
Property surfactant improve the dispersibility and permeability of cleaning, improve cleaning performance.
Embodiment
Embodiment 1
（1）A liquid is prepared：In reactor, the 10 mL concentrated sulfuric acid is slowly added in 60 mL water：Stir and evenly mix, be cooled to room temperature
Afterwards, 7 mL phosphoric acid is added, is stirred and evenly mixed, adds 7g stannous chloride, dissolves by heating, is cooled to room temperature, obtaining transparent liquid is
Body A liquid；
（2）B liquid is prepared：In reactor, it is separately added into, water：78mL, N- alkyl dimethyl betaine：3g, triisopropanolamine：
19g, dissolving is stirred at room temperature, is well mixed, that is, it is B liquid to obtain transparency liquid；
（3）Preparation for granite face derusting and cleaning agent：It is 1 by volume by A liquid and B liquid in reactor：1 mixing, i.e.,
Obtain granite face derusting and cleaning agent.
Embodiment 2
（1）A liquid is prepared：In reactor, the 80mL concentrated sulfuric acid is slowly added in 640mL water：Stir and evenly mix, be cooled to room temperature
Afterwards, 80 mL phosphoric acid is added, is stirred and evenly mixed, adds 60g stannous chloride, is dissolved by heating, is cooled to room temperature, obtains transparent liquid
For body A liquid；
（2）B liquid is prepared：In reactor, it is separately added into, water：800mL, N- alkyl dimethyl betaine：20g, triisopropanolamine：
180g, dissolving is stirred at room temperature, is well mixed, that is, it is B liquid to obtain transparency liquid；
（3）Preparation for granite face derusting and cleaning agent：It is 1 by volume by A liquid and B liquid in reactor：1 mixing, i.e.,
Obtain granite face derusting and cleaning agent.
Embodiment 3
（1）A liquid is prepared：In reactor, the 12 mL concentrated sulfuric acid is slowly added in 62 mL water：Stir and evenly mix, be cooled to room temperature
Afterwards, 6 mL phosphoric acid is added, is stirred and evenly mixed, adds 8g stannous chloride, dissolves by heating, is cooled to room temperature, obtaining transparent liquid is
Body A liquid；
（2）B liquid is prepared：In reactor, it is separately added into, water：76mL, N- alkyl dimethyl betaine：4g, triisopropanolamine：
20g, dissolving is stirred at room temperature, is well mixed, that is, it is B liquid to obtain transparency liquid；
（3）Preparation for granite face derusting and cleaning agent：It is 1 by volume by A liquid and B liquid in reactor：1 mixing, i.e.,
Obtain granite face derusting and cleaning agent.
Embodiment 4
（1）A liquid is prepared：In reactor, the 100 mL concentrated sulfuric acid is slowly added in 600 mL water：Stir and evenly mix, be cooled to room
Wen Hou, 70 mL phosphoric acid is added, is stirred and evenly mixed, add 70g stannous chloride, dissolved by heating, be cooled to room temperature, obtain transparent
Liquid is body A liquid；
（2）B liquid is prepared：In reactor, it is separately added into, water：780mL, N- alkyl dimethyl betaine：30g, triisopropanolamine：
190g, dissolving is stirred at room temperature, is well mixed, that is, it is B liquid to obtain transparency liquid；
（3）Preparation for granite face derusting and cleaning agent：It is 1 by volume by A liquid and B liquid in reactor：1 mixing, i.e.,
Obtain granite face derusting and cleaning agent.
Embodiment 5
（1）A liquid is prepared：In reactor, the 110 mL concentrated sulfuric acid is slowly added in 580 mL water：Stir and evenly mix, be cooled to room
Wen Hou, 90mL phosphoric acid is added, is stirred and evenly mixed, add 80g stannous chloride, dissolved by heating, be cooled to room temperature, obtain transparent liquid
For body A liquid；
（2）B liquid is prepared：In reactor, it is separately added into, water：790mL, N- alkyl dimethyl betaine：50g, triisopropanolamine：
160g, dissolving is stirred at room temperature, is well mixed, that is, it is B liquid to obtain transparency liquid；
（3）Preparation for granite face derusting and cleaning agent：It is 1 by volume by A liquid and B liquid in reactor：1 mixing, i.e.,
Obtain granite face derusting and cleaning agent.
Embodiment 6
（1）A liquid is prepared：In reactor, the 9 mL concentrated sulfuric acid is slowly added in 63 mL water：Stir and evenly mix, be cooled to room temperature
Afterwards, 7 mL phosphoric acid is added, is stirred and evenly mixed, adds 9g stannous chloride, dissolves by heating, is cooled to room temperature, obtaining transparent liquid is
Body A liquid；
（2）B liquid is prepared：In reactor, it is separately added into, water：78mL, N- alkyl dimethyl betaine：5g, triisopropanolamine：
17g, dissolving is stirred at room temperature, is well mixed, that is, it is B liquid to obtain transparency liquid；
（3）Preparation for granite face derusting and cleaning agent：It is 1 by volume by A liquid and B liquid in reactor：1 mixing, i.e.,
Obtain granite face derusting and cleaning agent.
Granite face derusting and cleaning agent application method obtained by the present invention：Granite face derusting and cleaning agent is coated in
Cleaned after reacting 5 ~ 10min on granite rust staining point, then clear water is rinsed well, you can, cleaning performance is excellent, rustless spot
Mark, improve brightness.
Claims (4)
1. a kind of preparation method for granite face derusting and cleaning agent, it is characterised in that there is this method following technique to walk
Suddenly：
（1）A liquid is prepared：In reactor, added by following composition mass percentage concentration, 16 ~ 20% concentrated sulfuric acid is slowly added to 58
In ~ 64% water：Stir and evenly mix, after being cooled to room temperature, add 10 ~ 15% phosphoric acid, stir and evenly mix, add 6 ~ 10% dichlorides
Tin, each component sum are a hundred per cent, dissolve by heating, are cooled to room temperature, it is body A liquid to obtain transparent liquid；
（2）B liquid is prepared：In reactor, added by following composition mass percentage concentration, water：76 ~ 80%, N- alkyl dimethyl beet
Alkali：2 ~ 5%, triisopropanolamine：16 ~ 20%, each component sum is well mixed absolutely, dissolving to be stirred at room temperature, that is, obtained
Prescribed liquid is B liquid；
（3）Preparation for granite face derusting and cleaning agent：It is 1 by volume by A liquid and B liquid in reactor：1 mixing, i.e.,
Obtain granite face derusting and cleaning agent.
A kind of 2. preparation method for granite face derusting and cleaning agent according to claim 1, it is characterised in that step
Suddenly（1）Described in phosphoric acid and sulfuric acid volume ratio 1：Between 1.6 ~ 1.8.
A kind of 3. preparation method for granite face derusting and cleaning agent according to claim 1, it is characterised in that step
Suddenly（1）Described in stannous chloride active ingredient more than 95%.
4. the granite prepared by a kind of preparation method for granite face derusting and cleaning agent according to claim 1
Surface derusting cleaning agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710810827.2A CN107502472A (en) | 2017-09-11 | 2017-09-11 | A kind of preparation method for granite face derusting and cleaning agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710810827.2A CN107502472A (en) | 2017-09-11 | 2017-09-11 | A kind of preparation method for granite face derusting and cleaning agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107502472A true CN107502472A (en) | 2017-12-22 |
Family
ID=60696229
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710810827.2A Pending CN107502472A (en) | 2017-09-11 | 2017-09-11 | A kind of preparation method for granite face derusting and cleaning agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107502472A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102191142A (en) * | 2011-04-13 | 2011-09-21 | 浙江大学 | Surface yellow spot cleaning agent for neutral stones and stone cultural relics and preparation method thereof |
| CN103525591A (en) * | 2013-10-21 | 2014-01-22 | 柳州鑫磊科技有限公司 | Environment-friendly cleaning agent |
| CN103525583A (en) * | 2013-10-21 | 2014-01-22 | 柳州鑫磊科技有限公司 | Oil stain cleaning agent |
| WO2017099933A1 (en) * | 2015-12-07 | 2017-06-15 | S.C. Johnson & Son, Inc. | Acidic hard surface cleaner with glycine betaine ester |
-
2017
- 2017-09-11 CN CN201710810827.2A patent/CN107502472A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102191142A (en) * | 2011-04-13 | 2011-09-21 | 浙江大学 | Surface yellow spot cleaning agent for neutral stones and stone cultural relics and preparation method thereof |
| CN103525591A (en) * | 2013-10-21 | 2014-01-22 | 柳州鑫磊科技有限公司 | Environment-friendly cleaning agent |
| CN103525583A (en) * | 2013-10-21 | 2014-01-22 | 柳州鑫磊科技有限公司 | Oil stain cleaning agent |
| WO2017099933A1 (en) * | 2015-12-07 | 2017-06-15 | S.C. Johnson & Son, Inc. | Acidic hard surface cleaner with glycine betaine ester |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101913841B (en) | Sulfate corrosion-resistance preservative for concrete | |
| CN104445937A (en) | Formula of colored glaze | |
| CN105294039B (en) | A kind of steel slag plant-growing concrete | |
| CN104403401B (en) | A kind of Surface coating SiO2Modified coal ash and its production and use | |
| CN109437753B (en) | Inorganic stone and production process thereof | |
| CN105271974A (en) | New soil stabilizer and preparation method | |
| CN109250912A (en) | A kind of automatically cleaning cosmetics vial and its production technology | |
| CN106833368A (en) | A kind of preparation method of waterborne organic silicon stone protectant | |
| CN103483944A (en) | Light-reflection, heat-insulation and anticorrosion paint and preparation method thereof | |
| CN105174872A (en) | High-strength soil stabilizer and preparing method thereof | |
| CN105271739A (en) | High-quality colored glaze | |
| CN107502472A (en) | A kind of preparation method for granite face derusting and cleaning agent | |
| CN107266024A (en) | A kind of antibacterial wearable environment protection ceramic tile and preparation method thereof | |
| CN105271740A (en) | Colored glaze formula | |
| CN107699403A (en) | A kind of preparation method of solid granite surface derusting cleaning agent | |
| CN102372437B (en) | Method for producing self-cleaning glass-ceramic by using waste glass | |
| CN105152529A (en) | Colored glaze | |
| CN109554111A (en) | Nano-thermal-insulating coating for building and preparation method thereof | |
| CN105271737A (en) | Novel colored glaze | |
| CN105271738A (en) | Colored glaze with high clarity | |
| CN103482895B (en) | The preparation method of modification rice husk | |
| CN107056065A (en) | A kind of devitrified glass and preparation method thereof | |
| CN105254175A (en) | Colored glaze formula for producing colored glaze pendant | |
| CN102951893A (en) | Light and color glazed tile for building | |
| CN107460063A (en) | A kind of preparation method for marble surface derusting and cleaning agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171222 |