CN107699403A - A kind of preparation method of solid granite surface derusting cleaning agent - Google Patents

A kind of preparation method of solid granite surface derusting cleaning agent Download PDF

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Publication number
CN107699403A
CN107699403A CN201710811250.7A CN201710811250A CN107699403A CN 107699403 A CN107699403 A CN 107699403A CN 201710811250 A CN201710811250 A CN 201710811250A CN 107699403 A CN107699403 A CN 107699403A
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CN
China
Prior art keywords
cleaning agent
granite
surface derusting
solid
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710811250.7A
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Chinese (zh)
Inventor
李慧芝
赵淑英
翟殿棠
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University of Jinan
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University of Jinan
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Publication date
Application filed by University of Jinan filed Critical University of Jinan
Priority to CN201710811250.7A priority Critical patent/CN107699403A/en
Publication of CN107699403A publication Critical patent/CN107699403A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/06—Phosphates, including polyphosphates
    • C11D3/075—Phosphates, including polyphosphates in admixture with ethers of polyoxyalkylenes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2082—Polycarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a kind of preparation method of solid granite surface derusting cleaning agent, it is characterised in that is mixed by mass percentage by following components：Oxalic acid：38 ~ 42%, lemon acid amide：10 ~ 15%, Brij 35 sodium sulphate：2 ~ 5%, ammonium fluozirconate：16 ~ 20%, sodium tripolyphosphate：10 ~ 15%, sodium borohydride：10 ~ 15%, each component sum is a hundred per cent, is well mixed, produces solid granite surface derusting cleaning agent, pack.Produce granite face derusting and cleaning agent.The dispersibility and permeability of cleaning agent cleaning are strong, and cleaning performance is notable, can improve the brightness of granite, reduce the possibility of granite yellowing again.

Description

A kind of preparation method of solid granite surface derusting cleaning agent
Technical field
The present invention relates to the cleaning field of silicate product, more particularly to a kind of solid granite surface derusting cleaning agent Preparation method.
Background technology
Granite is formed by igneous rock, is a kind of hard crystalline lens stone material of steel, is initially formed and be mingled with by feldspar, quartz One or more dark minerals matter, are all stay aligned in structure.Granite using quartz, feldspar and mica as mainly into Point.Wherein feldspar content is 40%-60%, quartz content 20%-40%, and its color is decided by the type and quantity of ingredient. Granite is the rock of holocrystalline structure, and high-quality granite crystal grain is thin and uniform, construction is close, quartz content is more, feldspar gloss It is bright.Granitic dioxide-containing silica is higher, belongs to acid rock.Some granites contain trace-level activity element, this kind of Granite should avoid being used for interior.Granite compact structure, quality are hard, acid and alkali-resistance, against weather are good, can be outdoor long-term Use.
Granite can produce in use rust staining, macula lutea and influence the attractive in appearance and life-span of granite.Formed rust staining or Macula lutea mainly has three kinds of reasons：First, it is oxidized because granite itself contains some chemical substances such as iron mineral, or flower hilllock Rock is adhered to and is embedded in the metallic iron on granite top layer in saw, mill, transportation by extraneous iron rust such as stone material, certain Under environmental condition iron oxide is generated with oxygen effect in air（Iron rust）, cause granite face to turn yellow, rust staining occur, seriously very Cavity is formed to corrosion；Second, it is the intrusion of adjacent objects, the water pipe corrosion that the metal of such as cladding installation can be neighbouring, corrosion Thing rainwater etc. rushes band throughout the year and attachment and infiltration stone surface form sheet macula lutea；3rd, it is that contact is other containing organic pigment Material, such as straw rope, carton, excrement, food tea, coffee, the pollutant of fruit juice, surface can also glow macula lutea, so The attractive in appearance of building is not only influenceed, changes the original appearance of stone matter, can also influence the life-span of granite.Many removes macula lutea both at home and abroad at present Cleaning agent is mostly in acid or alkalescence.It is averaged according to different chemical composition ratio in 2485 parts of granite all over the world, according to shared Percentage by weight is by again to being gently：SiO2- 72.04%, Al2O3- 14.42%, K2O -4.12%, Na2O -3.69%, CaO -1.82%, FeO -1.68%, Fe2O3- 1.22%, MgO -0.71%, TiO2- 0.30%, P2O5- 0.12%, MnO -0.05%, from the point of view of its chemical composition, granite mainly contains silicon and aluminium component, and therefore, it has acid resistance, clear Fluorochemical additive is added during Chu's granite face rust staining, derusting effect can be greatly improved.Rust remover is prepared into solid, it is used Amount is few, greatly reduces cost of transportation, while also help storage.
The content of the invention
It is an object of the invention to provide a kind of preparation method of solid granite surface derusting cleaning agent, can not only remove The greasy dirt and rust staining of granite face, recover primary colors, while the cleaning agent of granite glossiness can be improved, pass through following technology Scheme is realized.
A kind of preparation method of solid granite surface derusting cleaning agent, it is characterised in that quality hundred is pressed by following components Ratio is divided to mix：
Oxalic acid：38 ~ 42%,
Lemon acid amide：10 ~ 15%,
Brij 35 sodium sulphate：2 ~ 5%,
Ammonium fluozirconate：16 ~ 20%,
Sodium tripolyphosphate：10 ~ 15%,
Sodium borohydride：10 ~ 15%, each component sum produces the cleaning of solid granite surface derusting absolutely, to be well mixed Agent, pack.
The active ingredient of described sodium borohydride is more than 95%.
Solid granite surface derusting cleaning agent application method obtained by the present invention：By granite face derusting and cleaning agent It is dissolved in water by 10% ~ 15% quality concentration expressed in percentage by volume, it is laggard is then coated in 10 ~ 20min of reaction on granite rust staining point Row is cleaned, then clear water is rinsed well, you can.
Advantages of the present invention and effect are：
（1）The obtained solid granite surface derusting cleaning agent of the present invention, using acid gentle oxalic acid and lemon acid amide, will not be produced Raw acid mist, will not corrode the structure of granite, and also with cushioning effect, while oxalic acid can also improve the brightness of granite, With the addition of sodium borohydride has strong reducing property, and addition sodium tripolyphosphate with iron there is strong complexing to promote granite face rust staining Quick bottom of surveying removes, and cleaning performance is obvious, reduces the possibility of granite yellowing again.
（2）The present invention obtains solid granite surface derusting cleaning agent, and preparation technology is simple, and condition is easily controllable, production Cost is low, is easy to industrialized production.
（3）The present invention obtains solid granite surface derusting cleaning agent, with the addition of ammonium fluozirconate and contains fluorine ion and improves Qu Rust abilities；It with the addition of dispersibility and infiltration that Brij 35 sulfuric acid natrium surfactant improves cleaning Property, improve cleaning performance.
Embodiment
Embodiment 1
It is separately added into the following order：
Oxalic acid：40g,
Lemon acid amide：12g,
Brij 35 sodium sulphate：3g,
Ammonium fluozirconate：18g,
Sodium tripolyphosphate：13g,
Sodium borohydride：14g, it is well mixed, produces solid granite surface derusting cleaning agent, pack.
Embodiment 2
It is separately added into the following order：
Oxalic acid：420g,
Lemon acid amide：100g,
Brij 35 sodium sulphate：40g,
Ammonium fluozirconate：200g,
Sodium tripolyphosphate：140g,
Sodium borohydride：100g, it is well mixed, produces solid granite surface derusting cleaning agent, pack
Embodiment 3
It is separately added into the following order：
Oxalic acid：380g,
Lemon acid amide：140g,
Brij 35 sodium sulphate：20g,
Ammonium fluozirconate：160g,
Sodium tripolyphosphate：150g,
Sodium borohydride：150g, it is well mixed, produces solid granite surface derusting cleaning agent, pack
Embodiment 4
It is separately added into the following order：
Oxalic acid：39g,
Lemon acid amide：15g,
Brij 35 sodium sulphate：5g,
Ammonium fluozirconate：19g,
Sodium tripolyphosphate：10g,
Sodium borohydride：12g, it is well mixed, produces solid granite surface derusting cleaning agent, pack
Embodiment 5
It is separately added into the following order：
Oxalic acid：200g,
Lemon acid amide：60g,
Brij 35 sodium sulphate：15g,
Ammonium fluozirconate：90g,
Sodium tripolyphosphate：65g,
Sodium borohydride：70g, it is well mixed, produces solid granite surface derusting cleaning agent, pack
Embodiment 6
It is separately added into the following order：
Oxalic acid：4100g,
Lemon acid amide：1400g,
Brij 35 sodium sulphate：300g,
Ammonium fluozirconate：1700g,
Sodium tripolyphosphate：1200g,
Sodium borohydride：1300g, it is well mixed, produces solid granite surface derusting cleaning agent, pack
Solid granite surface derusting cleaning agent application method obtained by the present invention：Granite face derusting and cleaning agent is pressed 10% ~ 15% quality concentration expressed in percentage by volume is dissolved in water, and is then coated in after reacting 10 ~ 20min on granite rust staining point and is carried out Clean, then clear water is rinsed well, you can, cleaning performance is excellent, rustless spot mark, improves brightness.

Claims (3)

1. a kind of preparation method of solid granite surface derusting cleaning agent, it is characterised in that quality percentage is pressed by following components Than mixing：
Oxalic acid：38 ~ 42%,
Lemon acid amide：10 ~ 15%,
Brij 35 sodium sulphate：2 ~ 5%,
Ammonium fluozirconate：16 ~ 20%,
Sodium tripolyphosphate：10 ~ 15%,
Sodium borohydride：10 ~ 15%, each component sum produces the cleaning of solid granite surface derusting absolutely, to be well mixed Agent, pack.
A kind of 2. preparation method of solid granite surface derusting cleaning agent according to claim 1, it is characterised in that institute The active ingredient for the sodium borohydride stated is more than 95%.
3. the solid flower prepared by a kind of preparation method of solid granite surface derusting cleaning agent according to claim 1 Hilllock rock surface derusting cleaning agent.
CN201710811250.7A 2017-09-11 2017-09-11 A kind of preparation method of solid granite surface derusting cleaning agent Pending CN107699403A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710811250.7A CN107699403A (en) 2017-09-11 2017-09-11 A kind of preparation method of solid granite surface derusting cleaning agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710811250.7A CN107699403A (en) 2017-09-11 2017-09-11 A kind of preparation method of solid granite surface derusting cleaning agent

Publications (1)

Publication Number Publication Date
CN107699403A true CN107699403A (en) 2018-02-16

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111717981A (en) * 2020-06-23 2020-09-29 哈尔滨工业大学 NaBH based on oxalic acid reinforcement4Method for rapidly reducing hexavalent chromium ions

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5274604A (en) * 1975-12-18 1977-06-22 Nishitani Eigo Detergent
CN1532271A (en) * 2003-03-25 2004-09-29 福建省漳平市振福化工有限公司 Rust removing agent, for stone material and its proparing method
CN103388151A (en) * 2013-07-05 2013-11-13 天津市化学试剂研究所 Marble rust remover and preparation method thereof
CN103525591A (en) * 2013-10-21 2014-01-22 柳州鑫磊科技有限公司 Environment-friendly cleaning agent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5274604A (en) * 1975-12-18 1977-06-22 Nishitani Eigo Detergent
CN1532271A (en) * 2003-03-25 2004-09-29 福建省漳平市振福化工有限公司 Rust removing agent, for stone material and its proparing method
CN103388151A (en) * 2013-07-05 2013-11-13 天津市化学试剂研究所 Marble rust remover and preparation method thereof
CN103525591A (en) * 2013-10-21 2014-01-22 柳州鑫磊科技有限公司 Environment-friendly cleaning agent

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
化学工业部天津化工研究院等: "《化工产品手册 无机化工产品》", 31 August 1983 *
张树仁: "《建筑工程质量事故及施工质量通病实用防治技术》", 30 June 2011 *
李东光: "《实用化工产品配方与制备》", 30 June 2013 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111717981A (en) * 2020-06-23 2020-09-29 哈尔滨工业大学 NaBH based on oxalic acid reinforcement4Method for rapidly reducing hexavalent chromium ions
CN111717981B (en) * 2020-06-23 2022-05-24 哈尔滨工业大学 NaBH based on oxalic acid strengthening4Method for rapidly reducing hexavalent chromium ions

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Application publication date: 20180216