CN102617123B - Formula and method for manufacturing ceramic tile blank bodies and glazed tiles by utilizing polished waste residues - Google Patents
Formula and method for manufacturing ceramic tile blank bodies and glazed tiles by utilizing polished waste residues Download PDFInfo
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- CN102617123B CN102617123B CN201210050321.3A CN201210050321A CN102617123B CN 102617123 B CN102617123 B CN 102617123B CN 201210050321 A CN201210050321 A CN 201210050321A CN 102617123 B CN102617123 B CN 102617123B
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Abstract
The invention discloses a formula and a method for manufacturing ceramic tile blank bodies by utilizing polished waste residues. The formula adopts ingredients by weight portions: porcelain clays account for 18 to 40 parts, clays account for 20 to 30 parts, limestone grains account for 1 to 10 parts, wollastonite grains account for 3 to 15 parts, glazed tile sludge residues account for 3 to 10 parts, ceramic polished waste residues account for 15 to 45 parts, soluble glass accounts for 1 to 2 parts, thinners account for 0.15 to 0.4 parts, sodium tripolyphosphate accounts for 0.05 to 0.2 parts, and a proper amount of water is adopted. A manufacturing method of the ceramic tile blank bodies comprises the steps as follows: a. raw materials are put in a ball grinder for ball milling after being blended so as to form sizing agents with proper fineness and screen tailings through milling, and the sizing agents are processed through deferrization, sieving and spray drying so as to form powders; and b. the powders are put in a die cavity of a press forming machine to form waterish blanks through pressing, the waterish blanks are dried in a drying kiln, the dried waterish blanks are applied with base pulp and then enter a biscuit firing kiln, biscuit firing is carried out under the temperature ranging from 1080 to 1160 DEG C, heat preservation is carried out in an area with the temperature ranging from 1040 to 1060 DEG C, the sintering time of the area is prolonged, and the sintering process for oxidizing atmosphere can be enhanced at the same time so as to obtain the ceramic tile blank bodies.
Description
Technical field:
The present invention relates to a kind of formula and method of utilizing polishing slag to manufacture ceramic tile blank and ornamental brick.
Background technology:
Chinese architecture snitaryware output is positioned at the whole world the first for continuous 18 years, and still, along with ceramic industry develops rapidly, ceramic industry waste residue is increasing, especially ceramic polished waste residue.According to incompletely statistics, only Foshan Ceramic producing region, the amount that produces every year ceramic polished waste residue has exceeded 3,000,000 tons, and the generation of national ceramic polished waste residue is estimated more than 1,000 ten thousand tons every year.So a large amount of ceramic polished waste residues has not been with soluble problem with simple land-fill method; and along with expanding economy and social progress; protection of the environment has become the focus that people pay close attention to; the accumulation of ceramic polished waste residue ties up soil; affect the dust content of local air; and the cleaning of ceramic polished waste residue, landfill expend a large amount of manpower and materials, groundwater quality are had a certain impact simultaneously.How to make these polishing slags turn waste into wealth, change resource circulation utilization, become the task of top priority of Ceramics Enterprises.
Owing to containing the material such as magnesium oxide, silicon carbide in ceramic polished waste residue, impurity is many, and plasticity-is low, burns till activity not high, in the time burning till, can emit the obnoxious flavoures such as chlorine, and the ceramic product that contains these waste residues can foam at high temperature production gas due to raw material.Aspect ceramic waste residue recycle, the enterprise of the outer Wall brick of domestic some production utilizes more than 40% waste residue to produce outer Wall brick, but the specification of outer Wall brick is little, and technical difficulty is low comparatively speaking, and because outer Wall brick consumption is less, the ceramic waste residue of its consumption is limited.Some enterprise utilizes ceramic polished waste residue to produce light-weight ceramic tile in addition, but output is limited, ceramic polished waste residue remains taking landfill as main, and the new technology that exploitation is produced for the large ceramic polished waste residue of glaze for glazed tile recycle of output becomes the task of top priority.
Summary of the invention:
The object of the invention is to overcome above-mentioned shortcoming, solve ceramic polished waste residue in glaze for glazed tile application because the gas of producing too much foams, affect product endoplasm and visual appearance, and too much can produce glaze pin hole because of gas, the defects such as bubble, a kind of formula and method of utilizing ceramic polished waste residue production adobe and ornamental brick is provided, the existing twice firing ornamental brick technological process of production is not being made on the basis of great change, the base substrate that emphasis is good to high temperature bond performance, the ground-coat enamel that high temperature venting performance is good, begin to melt temperature high, high temperature viscosity is large, the composition of the cover-coat enamel that ductility is good, firing process etc. are adjusted and are optimized, make this technology there is stronger universality, be easy in industry promote.
Of the present inventionly utilize ceramic polished waste residue to produce ceramic adobe and ornamental brick, comprising following steps:
A. the good body preparation of high temperature bond performance.
A. the preparation of powder:
Take by weight ratio 18～40 parts, porcelain sand, 20～30 parts of clays, 1～10 part of limestone particle, 3～15 parts of wollastonite grains, 3～10 parts of ornamental brick sludge silts, 15～45 parts, ceramic polished waste residue.
By above-mentioned raw materials prepare burden by weight, 0.05～0.2 part, 1～2 part, external adding water glass, 0.15～0.4 part of thinner, tripoly phosphate sodium STPP enters ball mill ball milling with together with appropriate water, the slurry that obtain fineness, tail over, water ratio meets following table 1 parameter, sieve through deironing, be spray dried to powder, its powder water ratio (according to product specification size, the dry wet water ratio that regulates of weather), grain composition are the requirement of following table 1.
Table 1 slurry and powder processing parameter require table
B. the preparation of adobe and biscuiting firing process
By the powder preparing in above-mentioned steps a, put into the die cavity of press-forming machine, be pressed into and there is certain thickness wet base, enter in dry kiln and be dried, dried wet base was executed prime cement, then entered biscuit kiln, at the temperature of 1080 DEG C～1160 DEG C, carry out biscuiting, and take to be incubated in 1040 DEG C～1060 DEG C temperature provinces, extend the firing time in this region, simultaneously the sintering technology of oxidation reinforced atmosphere and obtain adobe.
The preparation of the ground-coat enamel that B. high temperature venting performance is good.
A. the preparation of ground-coat enamel frit:
Take by weight ratio 20～30 parts of feldspars in powder, 10～18 parts of light calcium carbonates, 6～12 parts, glass powder, 0.5～3 part of boric acid, 0.5～3 part, saltpetre, 3～8 parts, zirconium English powder, 15～25 parts, lithium porcelain stone powder, 1～5 part of talcum powder, 15～25 parts of silica powders.
Above-mentioned raw materials is prepared burden by weight, mix, in Cinker clew furnace, at the temperature of 1480 DEG C～1540 DEG C, found, shrend becomes transparent vitreum frit for subsequent use.
B. the preparation of ground-coat enamel:
3～8 parts of 3～8 parts of 1～26 part of 5～25 parts of 25～60 parts of frit siccatives, feldspars in powder, silica powder, aluminum oxide powders, zirconium silicates that step a is made, burn 0.2～0.6 part, 1～28 part, talcum, 3～8 parts of calcined kaolins, 7～15 parts of kaolin, 0.05～0.15 part of outer methylate, tripoly phosphate sodium STPP and enter ball mill ball milling with together with the water of 37～45 parts, wearing into fineness is that tailing over of 325 mesh sieves is 0.1%～0.5% glaze slip, and deironing is sieved and made ground-coat enamel.
C. begin to melt the cover-coat enamel preparation that temperature is high, high temperature viscosity large, high temperature ductility is good.
A. the preparation of clear frit:
Take by weight ratio 25～40 parts of feldspars in powder, 13～22 parts of light calcium carbonates, 1～6 part of boric acid, 0.2～2 part, saltpetre, 25～38 parts of silica powders, 0.5～2 part of Strontium carbonate powder, 3～10 parts, zinc oxide, 1～5 part, lithium porcelain stone powder, 0.2～2 part of aluminum oxide powder.
Above-mentioned raw materials is prepared burden by weight, mix, in Cinker clew furnace, at the temperature of 1480 DEG C～1540 DEG C, found, shrend becomes transparent vitreum frit for subsequent use.
B. the preparation of milkiness frit:
Take by weight ratio 12～20 parts of feldspars in powder, 10～20 parts of light calcium carbonates, 5～10 parts, zinc oxide, 5～9 parts of boric acid, 2～6 parts of talcum powder, 6～12 parts, zirconium English powder, 1～5 part, saltpetre, 3～8 parts, lithium porcelain stone powder, 0.5～3 part of Strontium carbonate powder, 0.2～2 part of titanium dioxide, 25～38 parts of silica powders.
Above-mentioned raw materials is prepared burden by weight, mix, in Cinker clew furnace, at the temperature of 1480 DEG C～1540 DEG C, found, shrend becomes transparent vitreum milkiness frit for subsequent use.
C. the preparation of matt fused block:
Take by weight ratio 7～12 parts of feldspars in powder, 23～30 parts of light calcium carbonates, 5～10 parts, zinc oxide, 6～10 parts, zirconium English powder, 1～5 part, saltpetre, 0.5～2 part of Strontium carbonate powder, 0.2～2 part of Fluorspar Powder, 7～12 parts of talcum powder, 0.5～3 part of titanium dioxide, 35～42 parts of silica powders.
Above-mentioned raw materials is prepared burden by weight, mix, in Cinker clew furnace, at the temperature of 1480 DEG C～1540 DEG C, found, shrend becomes transparent vitreum matt fused block for subsequent use.
D. the preparation of transparent cover-coat enamel:
15～40 parts of milkiness frits preparing in 60～85 parts of clear frit siccatives that step a is made, step b, again 0.15～0.45 part of 1～5 part of additional kaolin, 0.05～0.15 part of outer methylate, tripoly phosphate sodium STPP to enter ball mill ball milling with together with the water of 37～45 parts, wear into fineness be that tailing over of 325 mesh sieves is that 0.1%～0.5% glaze slip, deironing are sieved and made transparent cover-coat enamel.
E. the preparation of milkiness cover-coat enamel:
15～30 parts of clear frits preparing in 70～85 parts of milkiness frit siccatives that step b is made, step a, 0.15～0.45 part of 1～5 part of additional kaolin, 0.05～0.15 part of outer methylate, tripoly phosphate sodium STPP enter ball mill ball milling with together with the water of 37～45 parts again, wearing into fineness is that tailing over of 325 mesh sieves is 0.1%～0.5% glaze slip, and deironing is sieved and made milkiness cover-coat enamel.
F. the preparation of dull surface glaze:
5～10 parts of milkiness frits preparing in 5～10 parts of clear frits preparing in 80～90 parts of matt fused block siccatives that step c is made, step a, step b, 0.15～0.45 part of 1～5 part of additional kaolin, 0.05～0.15 part of outer methylate, tripoly phosphate sodium STPP enter ball mill ball milling with together with the water of 37～45 parts again, wearing into fineness is that tailing over of 325 mesh sieves is 0.1%～0.5% glaze slip, and deironing is sieved and made dull surface glaze.
D. the preparation of product and glaze firing firing process
The adobe that steps A is obtained, first execute the ground-coat enamel that step B obtains, in the time that ground-coat enamel is just dry, execute respectively more transparent cover-coat enamel or milkiness cover-coat enamel or the dull surface glaze that step C obtains, then pass through side washing, stamp, enter glost kiln, in the temperature of 1080 DEG C～1140 DEG C, fire, be incubated in the temperature province of 1050 DEG C and 1090 DEG C simultaneously, extend the firing time of these two temperature provinces, and oxidation reinforced atmosphere.
The present invention utilizes ceramic polished waste residue to produce ornamental brick, by optimizing the good base substrate of high temperature bond performance, the ground-coat enamel that high temperature venting performance is good, begin to melt the composition of the cover-coat enamel that temperature is high, high temperature viscosity is large, ductility is good, firing process etc., overcome ceramic polished waste residue in ornamental brick is produced because the gas producing too much foams, affect product endoplasm and visual appearance, and too much can produce the shortcomings such as glaze pin hole, bubble because of gas.The optimization research of the base substrate composition that high temperature bond performance is good, make base substrate 1050 DEG C of left and right temperature provinces, when a large amount of gas of ceramic polished waste sludge discharge, part material is as the meetings such as ornamental brick sludge silt, Wingdale, wollastonite acting in conjunction generation flux at this temperature, these flux have become stronger binding agent in high temperature, thereby ensure that base substrate can be because of a large amount of gases of ceramic polished waste sludge discharge, cause the particle bonding splitting of chain in base substrate, thereby make loosely organized, density is poor, and causes foamed phenomenon; Because common glaze adobe formula sintering temperature is high, in the time of 1050 DEG C of a large amount of gas of the ceramic polished waste sludge discharge in left and right, do not have flux to occur, make the particle in base substrate not have at this moment enough binding agents bonding, thereby make interparticle bonding splitting of chain, and cause the foamed phenomenon loosely organized, density is poor.The optimization research of the ground-coat enamel composition that high temperature venting performance is good, make product in the time of glaze firing for the second time, there will be a large amount of open pores in the temperature province of 1050 DEG C and 1090 DEG C left and right, thereby the gas that ensures ceramic polished waste sludge discharge has passage to discharge smoothly, and can not accumulate in base substrate inside and then destroy blank structure, and break through glaze and form pin hole, the glaze plane defects such as glaze bubble, simultaneously these open pore passages can ensure again segment glass body in cover-coat enamel in high temperature along with these passages enter into billet surface, make ground-coat enamel form a good middle layer, thereby improve the anti-glaze fragility energy of product.Common ornamental brick ground-coat enamel does not reach the needs of ceramic polished waste residue exhaust in the performance of 1050 DEG C and 1090 DEG C these two temperature provinces, and can cause product to foam, occur the defects such as glaze pin hole, bubble.Begin to melt temperature high, high temperature viscosity is large, the optimization of the cover-coat enamel composition that ductility is good, make cover-coat enamel in the time of 1050 DEG C of a large amount of exhausts of the ceramic polished waste residue in left and right, also there is no melting, open pore is many, thereby ensure gas purging, simultaneously in the time there is liquid phase in 1090 DEG C of ceramic polished waste residues in left and right, can produce a large amount of liquid phases moment, these liquid phases have higher viscosity simultaneously, can moment sealed porosity, thereby the residual gas in guarantee base substrate is no longer discharged by glaze, now the ductility of liquid phase should be got well, can be at short notice stay little small rut molten flat when flowing to billet surface because of gas purging and Partial Liquid Phase vitreum by ground-coat enamel, thereby guarantee glaze quality, therefore in various cover-coat enamel compositions of the present invention, all adopt the frit of multiple different compositions to mix formation, can ensure that like this cover-coat enamel is never with guarantee to possess above-described multiple performance in the frit performance forming simultaneously, thereby ensure the glaze quality of product.And the cover-coat enamel of common ornamental brick is because its composition is single, can not possess above-described multiple performance simultaneously.The optimization of firing process, when product is burnt till, can be according to the characteristic of ceramic polished waste residue, adopt at specific temperature by being incubated, extending firing time, increasing oxidizing atmosphere to ensure the gaseous emission of ceramic polished waste residue.And then overcome because ceramic polished waste residue is at high temperature because the gas of discharge too much makes product foaming, affects product endoplasm and outward appearance and make product occur the shortcomings such as glaze pin hole, bubble.
Brief description of the drawings:
Fig. 1 is that the present invention utilizes ceramic polished waste residue to produce the production technological process of ornamental brick;
Embodiment:
Below in conjunction with embodiment, the present invention is described in further detail.
The present invention relates to a kind of preparation method who utilizes ceramic polished waste residue to produce ornamental brick, comprising following steps:
The preparation of the base substrate that A. high temperature bond performance is good
The component of base substrate sees the following form 2:
The component composition (weight part) of table 2 base substrate
Above-mentioned raw materials is prepared burden by weight, additional appropriate water enters ball mill ball milling together, the slurry that wear into fineness, tail over, water ratio meets following table 1 parameter, sieve through deironing, be spray dried to powder, its powder water ratio (according to product specification size, the dry wet water ratio that regulates of weather), powder grain composition are the requirement of following table 1.And repressed forming machine is pressed into certain thickness wet base, enter in dry kiln and be dried, dried wet base was executed prime cement, then enter biscuit kiln, carry out biscuiting by the temperature in upper table 2, and take to be incubated in 1040 DEG C～1060 DEG C temperature provinces, extend the firing time in this region, and the firing process of oxidation reinforced atmosphere, obtain the adobe that high temperature bond performance is good.Because the sintering temperature of common ornamental brick base substrate is high, in the time of 1050 DEG C of a large amount of gas of the ceramic polished waste sludge discharge in left and right, do not have flux to occur, make particle in base substrate there is no at this moment enough binding agent bondings and cause loosely organized, density is poor, and causes foamed phenomenon.Pass through test of many times, produce ornamental brick in order to use in a large number ceramic polished waste residue, reach energy-conservation, lower consumption, subtract the object of dirt, synergy, mix in the time of 1050 DEG C of a large amount of exhausts of the ceramic polished waste residue in left and right, the part material containing in base substrate can acting in conjunction produce flux at this moment, and these flux can form stronger binding agent in high temperature, thereby the particle that ensures base substrate is closely bonded together, the particle chain fracture that can not cause because of the gas of polishing slag discharge, loosely organized and cause product foaming.
Table 1 slurry and the requirement of powder processing parameter
The preparation of the ground-coat enamel that B. high temperature venting performance is good
A. the preparation of ground-coat enamel frit, its component sees the following form 3:
Table 3 ground-coat enamel frit component composition (weight part)
Above-mentioned raw materials is prepared burden by weight, mix, in Cinker clew furnace, found, shrend becomes transparent vitreum frit for subsequent use.
The preparation of the ground-coat enamel that b. high temperature venting performance is good, its component sees the following form 4:
Table 4 ground-coat enamel component composition (weight part)
Carry out proportioning according to the weight part in table 4, the frit that step a is made enters ball mill ball milling with potassium felspar sand, silica powder, aluminum oxide powder, zirconium silicate, burning talcum, calcined kaolin, kaolin, methyl, tripoly phosphate sodium STPP together with water, wearing into fineness is that tailing over of 325 mesh sieves is 0.1%～0.5% glaze slip, deironing is sieved, and obtains the ground-coat enamel that high temperature venting performance is good.Can not meet ceramic polished waste residue discharge a large amount of gas in specific temperature province due to common ornamental brick ground-coat enamel time, there are enough passages by discharge favourable these gases, these gases are overstock in a large number at interiors of products, thereby destroy the structure of product, cause the defects such as foaming and glaze pin hole, bubble.Pass through test of many times, according to the characteristic of ceramic polished waste residue, mix the ground-coat enamel that high temperature venting performance is good, this ground-coat enamel is in the time of product glaze firing for the second time, there will be a large amount of open pores in the temperature province of 1050 DEG C, 1090 DEG C left and right, thereby the gas that ensures polishing slag discharge has passage to discharge smoothly, and can not accumulate in base substrate and then destroy blank structure; And break through glaze and form the glaze plane defect such as pin hole, glaze bubble, simultaneously these open pore passages can ensure again segment glass body in cover-coat enamel in high temperature along with these passages enter into billet surface, make ground-coat enamel form a good middle layer, thereby improve the anti-glaze fragility energy of product.
C. begin to melt the cover-coat enamel preparation that temperature is high, high temperature viscosity large, high temperature ductility is good
A. begin to melt the cover-coat enamel praducing frits that temperature is high, high temperature viscosity large, high temperature ductility is good, its component sees the following form 5:
Table 5 cover-coat enamel frit component composition (weight part)
Above-mentioned raw materials is prepared burden by weight, mix, in Cinker clew furnace, found, shrend becomes transparent vitreum frit for subsequent use.
B. begin to melt the cover-coat enamel preparation that temperature is high, high temperature viscosity large, high temperature ductility is good, its component sees the following form 6:
Table 6 cover-coat enamel component composition (weight part)
Carry out proportioning according to the weight part of table 6, the frit that step a is made enters ball mill ball milling with kaolin, methyl, tripoly phosphate sodium STPP together with water, wearing into fineness is that tailing over of 325 mesh sieves is 0.1%～0.5% glaze slip, deironing is sieved, and obtains beginning to melt the cover-coat enamel that temperature is high, high temperature viscosity large, high temperature ductility is good.Because body recipe of the present invention has added a large amount of ceramic polished waste residues, and according to the specificity analysis to ceramic polished waste residue, known its has a large amount of gas to discharge in the time of 1050 DEG C of left and right temperature provinces, there is liquid phase to occur 1090 DEG C of left and right temperature provinces, by test of many times, adjust and begin to melt the cover-coat enamel that temperature is high, high temperature viscosity large, high temperature ductility is good.This cover-coat enamel, in the time of 1050 DEG C of a large amount of exhausts of the ceramic polished waste residue of left and right temperature province, does not also have melting, and open pore is many, thereby has ensured gas purging, is unlikely to that these gases accumulate in interiors of products and the structure of destroying product; Simultaneously in the time there is liquid phase in 1090 DEG C of ceramic polished waste residues of left and right temperature province, can produce a large amount of liquid phases moment, these liquid phases have higher viscosity simultaneously, can moment sealed porosity, thereby the residual gas in guarantee base substrate is no longer discharged by glaze, otherwise can form pin hole, glaze bubble defect because gas breaks through glaze, now the ductility of liquid phase is good again, the small rut can be at short notice staying when flowing to billet surface because of gas purging and Partial Liquid Phase vitreum by ground-coat enamel is molten flat, thereby ensures glaze quality.And the cover-coat enamel of common ornamental brick because of its composition single, can not possess above-described multiple performance simultaneously, therefore the present invention is in the composition of cover-coat enamel, all adopt the frit of multiple different compositions to mix formation, can ensure that like this cover-coat enamel is never with guarantee to possess above-described multiple performance in the frit performance forming simultaneously, to overcome the unfavorable factor of having brought because having added a large amount of ceramic polished waste residues in product, ensure quality product.
D. the preparation of product and glaze firing firing process
The adobe that steps A is obtained, first execute the ground-coat enamel that step B obtains, in the time that ground-coat enamel is just dry, execute respectively again transparent cover-coat enamel or milkiness cover-coat enamel or dull surface glaze that step C obtains, simultaneously in order to ensure the degree of deformation of product, the ground-coat enamel kind can flexible step B obtaining and suitable cover-coat enamel kind are arranged in pairs or groups, then pass through side washing, after stamp, carry out glaze firing, in the temperature province of 1080 DEG C～1140 DEG C, fire, be incubated in the temperature province of 1050 DEG C and 1090 DEG C simultaneously, extend the firing time of these two temperature provinces, and oxidation reinforced atmosphere, can discharge smoothly to guarantee a large amount of gases that ceramic polished waste residue produces, be unlikely to accumulate in interiors of products and destroy the structure of product and affect product appearance quality, or because these gases break through the pin hole that glaze forms, the cover-coat enamel defects such as bubble, thereby affect quality product.
The ornamental brick product that the present invention prepares by the above-mentioned preparation method who utilizes ceramic polished waste residue to produce ornamental brick, product indices meets GB/T4100-2006, GB6566-2001, HJ/T297-2006 standard-required after testing.
The present invention is not making on the basis of great change the existing twice firing ornamental brick technological process of production, the base substrate that emphasis is good to high temperature bond performance, the ground-coat enamel that high temperature venting performance is good, begin to melt the composition of the cover-coat enamel that temperature is high, high temperature viscosity is large, ductility is good, firing process etc. are optimized, make this technology possess stronger universality, be easy in industry promote.
In sum, it is only preferred embodiment of the present invention, not the present invention is done to any pro forma restriction, the those of ordinary skill of all industry, all can implement swimmingly by the above the present invention, but all those skilled in the art are not departing within the scope of technical solution of the present invention, can utilize disclosed above technology contents and a little change, the modification of making and the equivalent variations developing, be equivalent embodiment of the present invention; Meanwhile, the change of any equivalent variations that all essence technology according to the present invention are done above embodiment, modification and differentiation, within all still belonging to the protection domain of technical scheme of the present invention.
Claims (1)
1. utilize polishing slag to manufacture the method for ceramic tile blank, its raw material is prepared burden by weight: 18～40 parts, porcelain sand, 20～30 parts of clays, 1～10 part of limestone particle, 3～15 parts of wollastonite grains, 3～10 parts of ornamental brick sludge silts, 15～45 parts, ceramic polished waste residue, 1～2 part of water glass, 0.15～0.4 part of thinner, 0.05～0.2 part of tripoly phosphate sodium STPP, appropriate water, and production stage is:
A. raw material is entered to ball mill ball milling together, wears into fineness, tails over suitable slurry, sieve through deironing, be spray dried to powder,
B. the powder preparing in above-mentioned steps a is put into the die cavity of press-forming machine, be pressed into and there is certain thickness wet base, enter in dry kiln and be dried, dried wet base was executed prime cement, then enter biscuit kiln, at the temperature of 1080 DEG C～1160 DEG C, carry out biscuiting, and take to be incubated in 1040 DEG C～1060 DEG C temperature provinces, extend the firing time in this region, simultaneously the sintering technology of oxidation reinforced atmosphere and obtain ceramic tile blank.
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