CN113373008A - M20 top-speed rust remover - Google Patents
M20 top-speed rust remover Download PDFInfo
- Publication number
- CN113373008A CN113373008A CN202110616037.7A CN202110616037A CN113373008A CN 113373008 A CN113373008 A CN 113373008A CN 202110616037 A CN202110616037 A CN 202110616037A CN 113373008 A CN113373008 A CN 113373008A
- Authority
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- Prior art keywords
- rust
- rust remover
- speed
- acid
- sodium hydroxide
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title claims abstract description 67
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 66
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 54
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229920002125 Sokalan® Polymers 0.000 claims abstract description 17
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000004584 polyacrylic acid Substances 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 238000003756 stirring Methods 0.000 claims description 23
- 238000001816 cooling Methods 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000004575 stone Substances 0.000 abstract description 16
- 239000000463 material Substances 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 4
- 238000004140 cleaning Methods 0.000 abstract description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052742 iron Inorganic materials 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 abstract description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 3
- BAERPNBPLZWCES-UHFFFAOYSA-N (2-hydroxy-1-phosphonoethyl)phosphonic acid Chemical compound OCC(P(O)(O)=O)P(O)(O)=O BAERPNBPLZWCES-UHFFFAOYSA-N 0.000 description 2
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 2
- 229940120146 EDTMP Drugs 0.000 description 2
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 2
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 description 2
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- DYWWGOMIADYEET-UHFFFAOYSA-N copper urea Chemical compound [Cu++].NC(N)=O DYWWGOMIADYEET-UHFFFAOYSA-N 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 229940043237 diethanolamine Drugs 0.000 description 2
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000004220 glutamic acid Substances 0.000 description 2
- 229960002989 glutamic acid Drugs 0.000 description 2
- 235000013922 glutamic acid Nutrition 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229940068041 phytic acid Drugs 0.000 description 2
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 2
- 239000000176 sodium gluconate Substances 0.000 description 2
- 229940005574 sodium gluconate Drugs 0.000 description 2
- 235000012207 sodium gluconate Nutrition 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- -1 iron ions Chemical class 0.000 description 1
- 229940033355 lauric acid Drugs 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/34—Organic compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/53—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone involving the removal of at least part of the materials of the treated article, e.g. etching, drying of hardened concrete
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/06—Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3218—Alkanolamines or alkanolimines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/24—Mineral surfaces, e.g. stones, frescoes, plasters, walls or concretes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Ceramic Engineering (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses an M20 top-speed rust remover, which comprises the following raw material components: 50-60% of pure water, 8-10% of sodium hydroxide, 4-6% of monoethanolamine, 3.5-3.7% of polyacrylic acid, 1-1.2% of acetic acid and 24-26% of sulfamic acid. This M20 top-speed rust remover PH value is between 8-9, can not corrode the stone material, lead to the stone material to lose light, can have faster recognition speed and get rid of the efficiency to the rust, this rust remover once meets the rust stain, will become purple liquid within 2 minutes, can distinguish whether for the rust, 15 minutes can accomplish the reaction, clear away the iron ion on the stone material, thereby play the effect of rust cleaning, through this reaction, operating personnel can discern the rust fast, thereby the scheme of selecting different rust removals solutions, the time and the material cost of having saved the trial-and-error, operating personnel's work efficiency and economic benefits have been improved.
Description
Technical Field
The invention relates to the technical field of stone rust removal, and relates to an M20 top-speed rust remover.
Background
The stone rust removal is to clean natural rust spots and acquired rust spots on the surface layer and the shallow surface layer of the stone by adopting a professional stone chemical cleaning product so as to recover the texture, the appearance and the decorative effect of the stone.
Chinese patents CN03112059.8 and CN201410341314.8 both disclose a rust remover for stone materials, which contains acetic acid, tartaric acid and other organic acids, and although it can achieve a certain rust removing effect, the rust remover can cause corrosion of stone surfaces, and is especially not suitable for non-silicate stone materials. Chinese patent CN 110204360A discloses a preparation method of an environment-friendly rust remover, which comprises the following steps of placing 100 parts of deionized water in a stirrer 1, heating to the temperature A1, and adding lauric acid, sodium gluconate, glutamic acid, inositol hexaphosphate and diethanol amine in the component A according to the mass proportion; then naturally cooling the deionized water to the temperature A2, and adding the emulsifier in the component A; the component A comprises, by mass, 30-60 parts of lauric acid, 5-18 parts of an emulsifier, 3-9 parts of sodium gluconate, 8-14 parts of glutamic acid, 2-9 parts of inositol hexaphosphate and 5-20 parts of diethanolamine;
putting 100 parts of hydrogen peroxide into a stirrer 2, heating to the temperature of B1, and adding the potassium hydroxide, the hydroxyethylidene diphosphonic acid, the propylene-maleic copolymer, the ethylenediamine tetramethylene phosphonic acid and the copper urea complex in the component B according to the mass proportion; then the hydrogen peroxide is naturally cooled to the temperature B2, and the film forming agent in the component B is added; the component B comprises, by mass, 20-50 parts of potassium hydroxide, 2-7 parts of hydroxyethylidene diphosphonic acid, 12-38 parts of a film-forming agent, 6-22 parts of a propylene-maleic copolymer, 1-8 parts of ethylene diamine tetramethylene phosphonic acid and 8-12 parts of a copper-urea complex;
mixing the component A and the component B, placing the mixture in a stirrer, and stirring the mixture for 1 hour at 50 ℃ to obtain the environment-friendly stone rust remover; wherein the rotating speed of a stirrer for mixing the component A and the component B is 600-800 r/min.
The preparation method of the environment-friendly rust remover has more component types, needs heating during preparation, is responsible for the process and has higher production cost.
Most of the existing stone rust removers in the market are acid rust removers, so that marble is corroded by the acid rust removers, and whether rust exists cannot be identified.
Disclosure of Invention
The invention aims to provide an M20 top-speed rust remover to solve the problems in the background art.
In order to achieve the purpose, the invention provides the following technical scheme: an M20 top-speed rust remover, which consists of the following raw material components: 50-60% of pure water, 8-10% of sodium hydroxide, 4-6% of monoethanolamine, 3.5-3.7% of polyacrylic acid, 1-1.2% of acetic acid and 24-26% of sulfamic acid.
Preferably, the rust remover consists of the following raw material components: 50% of pure water, 8% of sodium hydroxide, 4% of monoethanolamine, 3.5% of polyacrylic acid, 1-1.2% of acetic acid and 24% of sulfamic acid.
Preferably, the rust remover consists of the following raw material components: 60% of pure water, 10% of sodium hydroxide, 6% of monoethanolamine, 3.7% of polyacrylic acid, 1.2% of acetic acid and 26% of sulfamic acid.
Preferably, the rust remover consists of the following raw material components: 55% of pure water, 9% of sodium hydroxide, 5% of monoethanolamine, 3.6% of polyacrylic acid, 1.1% of acetic acid and 25% of sulfamic acid.
The production process of the M20 top-speed rust remover comprises the following steps:
according to the components, sodium hydroxide and pure water are placed in a stirrer and stirred at normal temperature, so that the sodium hydroxide is dissolved in the pure water;
standing and cooling to room temperature, sequentially adding monoethanolamine, polyacrylic acid and acetic acid, and stirring for 30 minutes at a stirring speed of
And finally, adding sulfamic acid, stirring for 15 minutes, and cooling to room temperature to obtain the M20 top-speed rust remover.
Compared with the prior art, the invention has the beneficial effects that: the M20 top-speed rust remover:
the M20 high-speed rust remover is an alkaline rust remover, has a pH value of 8-9, cannot corrode stone materials, causes stone material to lose light, and can quickly recognize rust and remove the rust, once the rust remover meets the rust, the rust remover can be changed into purple liquid within 2 minutes, whether the rust is the rust can be identified, the reaction can be completed within 15 minutes, iron ions on the stone materials are removed, and the rust removing effect is achieved.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The first embodiment is as follows:
an M20 top-speed rust remover, which consists of the following raw material components: 50% of pure water, 8% of sodium hydroxide, 4% of monoethanolamine, 3.5% of polyacrylic acid, 1-1.2% of acetic acid and 24% of sulfamic acid;
the production process of the M20 top-speed rust remover comprises the following steps:
according to the components, sodium hydroxide and pure water are placed in a stirrer and stirred at normal temperature, so that the sodium hydroxide is dissolved in the pure water;
standing and cooling to room temperature, sequentially adding monoethanolamine, polyacrylic acid and acetic acid, and stirring for 30 minutes at a stirring speed of
And finally, adding sulfamic acid, stirring for 15 minutes, and cooling to room temperature to obtain the M20 top-speed rust remover.
Example two
An M20 top-speed rust remover, which consists of the following raw material components: the rust remover consists of the following raw material components: 60% of pure water, 10% of sodium hydroxide, 6% of monoethanolamine, 3.7% of polyacrylic acid, 1.2% of acetic acid and 26% of sulfamic acid;
the production process of the M20 top-speed rust remover comprises the following steps:
according to the components, sodium hydroxide and pure water are placed in a stirrer and stirred at normal temperature, so that the sodium hydroxide is dissolved in the pure water;
standing and cooling to room temperature, sequentially adding monoethanolamine, polyacrylic acid and acetic acid, and stirring for 30 minutes at a stirring speed of
And finally, adding sulfamic acid, stirring for 15 minutes, and cooling to room temperature to obtain the M20 top-speed rust remover.
EXAMPLE III
An M20 top-speed rust remover, which consists of the following raw material components: the rust remover consists of the following raw material components: 55% of pure water, 9% of sodium hydroxide, 5% of monoethanolamine, 3.6% of polyacrylic acid, 1.1% of acetic acid and 25% of sulfamic acid;
the production process of the M20 top-speed rust remover comprises the following steps:
according to the components, sodium hydroxide and pure water are placed in a stirrer and stirred at normal temperature, so that the sodium hydroxide is dissolved in the pure water;
standing and cooling to room temperature, sequentially adding monoethanolamine, polyacrylic acid and acetic acid, and stirring for 30 minutes at a stirring speed of
Finally, sulfamic acid is added, stirred for 15 minutes and cooled to room temperature to obtain the M20 top-speed rust remover
Although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that various changes in the embodiments and/or modifications of the invention can be made, and equivalents and modifications of some features of the invention can be made without departing from the spirit and scope of the invention.
Claims (6)
1. An M20 top-speed rust remover, which is characterized in that: the rust remover consists of the following raw material components: 50-60% of pure water, 8-10% of sodium hydroxide, 4-6% of monoethanolamine, 3.5-3.7% of polyacrylic acid, 1-1.2% of acetic acid and 24-26% of sulfamic acid.
2. The M20 top-speed rust remover as claimed in claim 1, wherein: the rust remover consists of the following raw material components: 50% of pure water, 8% of sodium hydroxide, 4% of monoethanolamine, 3.5% of polyacrylic acid, 1-1.2% of acetic acid and 24% of sulfamic acid.
3. The M20 top-speed rust remover as claimed in claim 1, wherein: the rust remover consists of the following raw material components: 60% of pure water, 10% of sodium hydroxide, 6% of monoethanolamine, 3.7% of polyacrylic acid, 1.2% of acetic acid and 26% of sulfamic acid.
4. The M20 top-speed rust remover as claimed in claim 1, wherein: the rust remover consists of the following raw material components: 55% of pure water, 9% of sodium hydroxide, 5% of monoethanolamine, 3.6% of polyacrylic acid, 1.1% of acetic acid and 25% of sulfamic acid.
5. The M20 top-speed rust remover according to any one of claims 1-4, wherein: the preparation method of the rust remover comprises the following steps:
s1: according to the components, sodium hydroxide and pure water are placed in a stirrer and stirred at normal temperature, so that the sodium hydroxide is dissolved in the pure water;
s2: standing and cooling to room temperature, sequentially adding monoethanolamine, polyacrylic acid and acetic acid, and stirring;
s3: and finally, adding sulfamic acid, stirring for 15 minutes, and cooling to room temperature to obtain the M20 top-speed rust remover.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN202110616037.7A CN113373008A (en) | 2021-06-02 | 2021-06-02 | M20 top-speed rust remover |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN202110616037.7A CN113373008A (en) | 2021-06-02 | 2021-06-02 | M20 top-speed rust remover |
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CN113373008A true CN113373008A (en) | 2021-09-10 |
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CN202110616037.7A Pending CN113373008A (en) | 2021-06-02 | 2021-06-02 | M20 top-speed rust remover |
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Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4749508A (en) * | 1985-02-05 | 1988-06-07 | Kay Chemical Company | Floor cleaning compositions and their use |
EP1721961A1 (en) * | 2005-05-12 | 2006-11-15 | The Procter and Gamble Company | Liquid acidic hard surface cleaning composition |
CN102191142A (en) * | 2011-04-13 | 2011-09-21 | 浙江大学 | Surface yellow spot cleaning agent for neutral stones and stone cultural relics and preparation method thereof |
CN105671563A (en) * | 2016-03-18 | 2016-06-15 | 中山市华光化工有限公司 | Rust remover and preparation method thereof |
CN106566704A (en) * | 2016-09-30 | 2017-04-19 | 格林润滑科技(惠州)有限公司 | Environment-friendly outer wall strong cleaning agent |
CN107777788A (en) * | 2016-08-24 | 2018-03-09 | 天长市地震办公室 | Non-corrosiveness scale remover |
CN111662785A (en) * | 2020-06-15 | 2020-09-15 | 厦门诺恩斯科技有限公司 | Mild stone rust remover and preparation method thereof |
CN111793802A (en) * | 2020-06-24 | 2020-10-20 | 厦门中思诺新材料有限公司 | Alkaline rust remover for rapidly removing rust and preparation method thereof |
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-
2021
- 2021-06-02 CN CN202110616037.7A patent/CN113373008A/en active Pending
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