CN113373008A - M20 top-speed rust remover - Google Patents

M20 top-speed rust remover Download PDF

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Publication number
CN113373008A
CN113373008A CN202110616037.7A CN202110616037A CN113373008A CN 113373008 A CN113373008 A CN 113373008A CN 202110616037 A CN202110616037 A CN 202110616037A CN 113373008 A CN113373008 A CN 113373008A
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China
Prior art keywords
rust
rust remover
speed
acid
sodium hydroxide
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CN202110616037.7A
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Chinese (zh)
Inventor
黄家朗
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Foshan Yalun Stone Tech Industry Ltd
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Foshan Yalun Stone Tech Industry Ltd
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Priority to CN202110616037.7A priority Critical patent/CN113373008A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/34Organic compounds containing sulfur
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/53After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone involving the removal of at least part of the materials of the treated article, e.g. etching, drying of hardened concrete
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/06Hydroxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/265Carboxylic acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/32Organic compounds containing nitrogen
    • C11D7/3218Alkanolamines or alkanolimines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • C11D2111/24Mineral surfaces, e.g. stones, frescoes, plasters, walls or concretes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Ceramic Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses an M20 top-speed rust remover, which comprises the following raw material components: 50-60% of pure water, 8-10% of sodium hydroxide, 4-6% of monoethanolamine, 3.5-3.7% of polyacrylic acid, 1-1.2% of acetic acid and 24-26% of sulfamic acid. This M20 top-speed rust remover PH value is between 8-9, can not corrode the stone material, lead to the stone material to lose light, can have faster recognition speed and get rid of the efficiency to the rust, this rust remover once meets the rust stain, will become purple liquid within 2 minutes, can distinguish whether for the rust, 15 minutes can accomplish the reaction, clear away the iron ion on the stone material, thereby play the effect of rust cleaning, through this reaction, operating personnel can discern the rust fast, thereby the scheme of selecting different rust removals solutions, the time and the material cost of having saved the trial-and-error, operating personnel's work efficiency and economic benefits have been improved.

Description

M20 top-speed rust remover
Technical Field
The invention relates to the technical field of stone rust removal, and relates to an M20 top-speed rust remover.
Background
The stone rust removal is to clean natural rust spots and acquired rust spots on the surface layer and the shallow surface layer of the stone by adopting a professional stone chemical cleaning product so as to recover the texture, the appearance and the decorative effect of the stone.
Chinese patents CN03112059.8 and CN201410341314.8 both disclose a rust remover for stone materials, which contains acetic acid, tartaric acid and other organic acids, and although it can achieve a certain rust removing effect, the rust remover can cause corrosion of stone surfaces, and is especially not suitable for non-silicate stone materials. Chinese patent CN 110204360A discloses a preparation method of an environment-friendly rust remover, which comprises the following steps of placing 100 parts of deionized water in a stirrer 1, heating to the temperature A1, and adding lauric acid, sodium gluconate, glutamic acid, inositol hexaphosphate and diethanol amine in the component A according to the mass proportion; then naturally cooling the deionized water to the temperature A2, and adding the emulsifier in the component A; the component A comprises, by mass, 30-60 parts of lauric acid, 5-18 parts of an emulsifier, 3-9 parts of sodium gluconate, 8-14 parts of glutamic acid, 2-9 parts of inositol hexaphosphate and 5-20 parts of diethanolamine;
putting 100 parts of hydrogen peroxide into a stirrer 2, heating to the temperature of B1, and adding the potassium hydroxide, the hydroxyethylidene diphosphonic acid, the propylene-maleic copolymer, the ethylenediamine tetramethylene phosphonic acid and the copper urea complex in the component B according to the mass proportion; then the hydrogen peroxide is naturally cooled to the temperature B2, and the film forming agent in the component B is added; the component B comprises, by mass, 20-50 parts of potassium hydroxide, 2-7 parts of hydroxyethylidene diphosphonic acid, 12-38 parts of a film-forming agent, 6-22 parts of a propylene-maleic copolymer, 1-8 parts of ethylene diamine tetramethylene phosphonic acid and 8-12 parts of a copper-urea complex;
mixing the component A and the component B, placing the mixture in a stirrer, and stirring the mixture for 1 hour at 50 ℃ to obtain the environment-friendly stone rust remover; wherein the rotating speed of a stirrer for mixing the component A and the component B is 600-800 r/min.
The preparation method of the environment-friendly rust remover has more component types, needs heating during preparation, is responsible for the process and has higher production cost.
Most of the existing stone rust removers in the market are acid rust removers, so that marble is corroded by the acid rust removers, and whether rust exists cannot be identified.
Disclosure of Invention
The invention aims to provide an M20 top-speed rust remover to solve the problems in the background art.
In order to achieve the purpose, the invention provides the following technical scheme: an M20 top-speed rust remover, which consists of the following raw material components: 50-60% of pure water, 8-10% of sodium hydroxide, 4-6% of monoethanolamine, 3.5-3.7% of polyacrylic acid, 1-1.2% of acetic acid and 24-26% of sulfamic acid.
Preferably, the rust remover consists of the following raw material components: 50% of pure water, 8% of sodium hydroxide, 4% of monoethanolamine, 3.5% of polyacrylic acid, 1-1.2% of acetic acid and 24% of sulfamic acid.
Preferably, the rust remover consists of the following raw material components: 60% of pure water, 10% of sodium hydroxide, 6% of monoethanolamine, 3.7% of polyacrylic acid, 1.2% of acetic acid and 26% of sulfamic acid.
Preferably, the rust remover consists of the following raw material components: 55% of pure water, 9% of sodium hydroxide, 5% of monoethanolamine, 3.6% of polyacrylic acid, 1.1% of acetic acid and 25% of sulfamic acid.
The production process of the M20 top-speed rust remover comprises the following steps:
according to the components, sodium hydroxide and pure water are placed in a stirrer and stirred at normal temperature, so that the sodium hydroxide is dissolved in the pure water;
the stirring rate is
Figure BDA0003097552120000021
Stirring for 30 minutes;
standing and cooling to room temperature, sequentially adding monoethanolamine, polyacrylic acid and acetic acid, and stirring for 30 minutes at a stirring speed of
Figure BDA0003097552120000022
And finally, adding sulfamic acid, stirring for 15 minutes, and cooling to room temperature to obtain the M20 top-speed rust remover.
Compared with the prior art, the invention has the beneficial effects that: the M20 top-speed rust remover:
the M20 high-speed rust remover is an alkaline rust remover, has a pH value of 8-9, cannot corrode stone materials, causes stone material to lose light, and can quickly recognize rust and remove the rust, once the rust remover meets the rust, the rust remover can be changed into purple liquid within 2 minutes, whether the rust is the rust can be identified, the reaction can be completed within 15 minutes, iron ions on the stone materials are removed, and the rust removing effect is achieved.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The first embodiment is as follows:
an M20 top-speed rust remover, which consists of the following raw material components: 50% of pure water, 8% of sodium hydroxide, 4% of monoethanolamine, 3.5% of polyacrylic acid, 1-1.2% of acetic acid and 24% of sulfamic acid;
the production process of the M20 top-speed rust remover comprises the following steps:
according to the components, sodium hydroxide and pure water are placed in a stirrer and stirred at normal temperature, so that the sodium hydroxide is dissolved in the pure water;
the stirring rate is
Figure BDA0003097552120000031
Stirring for 30 minutes;
standing and cooling to room temperature, sequentially adding monoethanolamine, polyacrylic acid and acetic acid, and stirring for 30 minutes at a stirring speed of
Figure BDA0003097552120000032
And finally, adding sulfamic acid, stirring for 15 minutes, and cooling to room temperature to obtain the M20 top-speed rust remover.
Example two
An M20 top-speed rust remover, which consists of the following raw material components: the rust remover consists of the following raw material components: 60% of pure water, 10% of sodium hydroxide, 6% of monoethanolamine, 3.7% of polyacrylic acid, 1.2% of acetic acid and 26% of sulfamic acid;
the production process of the M20 top-speed rust remover comprises the following steps:
according to the components, sodium hydroxide and pure water are placed in a stirrer and stirred at normal temperature, so that the sodium hydroxide is dissolved in the pure water;
the stirring rate is
Figure BDA0003097552120000041
Stirring for 30 minutes;
standing and cooling to room temperature, sequentially adding monoethanolamine, polyacrylic acid and acetic acid, and stirring for 30 minutes at a stirring speed of
Figure BDA0003097552120000042
And finally, adding sulfamic acid, stirring for 15 minutes, and cooling to room temperature to obtain the M20 top-speed rust remover.
EXAMPLE III
An M20 top-speed rust remover, which consists of the following raw material components: the rust remover consists of the following raw material components: 55% of pure water, 9% of sodium hydroxide, 5% of monoethanolamine, 3.6% of polyacrylic acid, 1.1% of acetic acid and 25% of sulfamic acid;
the production process of the M20 top-speed rust remover comprises the following steps:
according to the components, sodium hydroxide and pure water are placed in a stirrer and stirred at normal temperature, so that the sodium hydroxide is dissolved in the pure water;
the stirring rate is
Figure BDA0003097552120000043
Stirring for 30 minutes;
standing and cooling to room temperature, sequentially adding monoethanolamine, polyacrylic acid and acetic acid, and stirring for 30 minutes at a stirring speed of
Figure BDA0003097552120000044
Finally, sulfamic acid is added, stirred for 15 minutes and cooled to room temperature to obtain the M20 top-speed rust remover
Although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that various changes in the embodiments and/or modifications of the invention can be made, and equivalents and modifications of some features of the invention can be made without departing from the spirit and scope of the invention.

Claims (6)

1. An M20 top-speed rust remover, which is characterized in that: the rust remover consists of the following raw material components: 50-60% of pure water, 8-10% of sodium hydroxide, 4-6% of monoethanolamine, 3.5-3.7% of polyacrylic acid, 1-1.2% of acetic acid and 24-26% of sulfamic acid.
2. The M20 top-speed rust remover as claimed in claim 1, wherein: the rust remover consists of the following raw material components: 50% of pure water, 8% of sodium hydroxide, 4% of monoethanolamine, 3.5% of polyacrylic acid, 1-1.2% of acetic acid and 24% of sulfamic acid.
3. The M20 top-speed rust remover as claimed in claim 1, wherein: the rust remover consists of the following raw material components: 60% of pure water, 10% of sodium hydroxide, 6% of monoethanolamine, 3.7% of polyacrylic acid, 1.2% of acetic acid and 26% of sulfamic acid.
4. The M20 top-speed rust remover as claimed in claim 1, wherein: the rust remover consists of the following raw material components: 55% of pure water, 9% of sodium hydroxide, 5% of monoethanolamine, 3.6% of polyacrylic acid, 1.1% of acetic acid and 25% of sulfamic acid.
5. The M20 top-speed rust remover according to any one of claims 1-4, wherein: the preparation method of the rust remover comprises the following steps:
s1: according to the components, sodium hydroxide and pure water are placed in a stirrer and stirred at normal temperature, so that the sodium hydroxide is dissolved in the pure water;
s2: standing and cooling to room temperature, sequentially adding monoethanolamine, polyacrylic acid and acetic acid, and stirring;
s3: and finally, adding sulfamic acid, stirring for 15 minutes, and cooling to room temperature to obtain the M20 top-speed rust remover.
6. The M20 top-speed rust remover according to any one of claims 5, wherein: the stirring rate in steps S1 and S2 is 100
Figure FDA0003097552110000011
Stirred for 30 minutes.
CN202110616037.7A 2021-06-02 2021-06-02 M20 top-speed rust remover Pending CN113373008A (en)

Priority Applications (1)

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4749508A (en) * 1985-02-05 1988-06-07 Kay Chemical Company Floor cleaning compositions and their use
EP1721961A1 (en) * 2005-05-12 2006-11-15 The Procter and Gamble Company Liquid acidic hard surface cleaning composition
CN102191142A (en) * 2011-04-13 2011-09-21 浙江大学 Surface yellow spot cleaning agent for neutral stones and stone cultural relics and preparation method thereof
CN105671563A (en) * 2016-03-18 2016-06-15 中山市华光化工有限公司 Rust remover and preparation method thereof
CN106566704A (en) * 2016-09-30 2017-04-19 格林润滑科技(惠州)有限公司 Environment-friendly outer wall strong cleaning agent
CN107777788A (en) * 2016-08-24 2018-03-09 天长市地震办公室 Non-corrosiveness scale remover
CN111662785A (en) * 2020-06-15 2020-09-15 厦门诺恩斯科技有限公司 Mild stone rust remover and preparation method thereof
CN111793802A (en) * 2020-06-24 2020-10-20 厦门中思诺新材料有限公司 Alkaline rust remover for rapidly removing rust and preparation method thereof
CN113045338A (en) * 2019-12-28 2021-06-29 江苏苏博特新材料股份有限公司 Environment-friendly rust remover for stone containing iron impurities and preparation method thereof

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4749508A (en) * 1985-02-05 1988-06-07 Kay Chemical Company Floor cleaning compositions and their use
EP1721961A1 (en) * 2005-05-12 2006-11-15 The Procter and Gamble Company Liquid acidic hard surface cleaning composition
CN102191142A (en) * 2011-04-13 2011-09-21 浙江大学 Surface yellow spot cleaning agent for neutral stones and stone cultural relics and preparation method thereof
CN105671563A (en) * 2016-03-18 2016-06-15 中山市华光化工有限公司 Rust remover and preparation method thereof
CN107777788A (en) * 2016-08-24 2018-03-09 天长市地震办公室 Non-corrosiveness scale remover
CN106566704A (en) * 2016-09-30 2017-04-19 格林润滑科技(惠州)有限公司 Environment-friendly outer wall strong cleaning agent
CN113045338A (en) * 2019-12-28 2021-06-29 江苏苏博特新材料股份有限公司 Environment-friendly rust remover for stone containing iron impurities and preparation method thereof
CN111662785A (en) * 2020-06-15 2020-09-15 厦门诺恩斯科技有限公司 Mild stone rust remover and preparation method thereof
CN111793802A (en) * 2020-06-24 2020-10-20 厦门中思诺新材料有限公司 Alkaline rust remover for rapidly removing rust and preparation method thereof

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北京土木建筑学会: "<<建筑工程质量常见问题防治手册.装饰装修工程>>", 31 January 2016 *
实用技工技术教材编写组: "<<实用清洗技术>>", 31 December 2007 *
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