EP1288285A1 - Aqueous cleaning composition based on a natural product - Google Patents

Aqueous cleaning composition based on a natural product Download PDF

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Publication number
EP1288285A1
EP1288285A1 EP02018631A EP02018631A EP1288285A1 EP 1288285 A1 EP1288285 A1 EP 1288285A1 EP 02018631 A EP02018631 A EP 02018631A EP 02018631 A EP02018631 A EP 02018631A EP 1288285 A1 EP1288285 A1 EP 1288285A1
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weight
aqueous detergent
detergent according
cleaning
natural product
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EP02018631A
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German (de)
French (fr)
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EP1288285B1 (en
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Ilona Parsch
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/38Products in which the composition is not well defined
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/26Organic compounds, e.g. vitamins containing oxygen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/44Perfumes; Colouring materials; Brightening agents ; Bleaching agents

Definitions

  • the invention relates to an aqueous acidic cleaning agent a natural product for metal surfaces, in particular in Sanitary and kitchen area, for surfaces made of ceramic, glass, Plastic and stones, as well as for cleaning carpets, fabrics and fibrous materials.
  • From DE 41 04 191 C1 is a method for producing a Cleaning agent based on nettles and from the DE 37 21 004 C1 a household detergent using known from stinging juice. This remedy is unsatisfactory Effect on. In addition, the extraction of nettle juice very expensive.
  • the object of the invention is to provide an aqueous cleaning agent to develop a natural product that is used to clean surfaces of metal, ceramics, glass, plastic and stones and of Carpets, fabrics and fibrous materials is suitable and a high Has dissolving power for calcification and rust surfaces can remove.
  • the cleaning agent according to the invention has the advantage that all Ingredients are pure natural substances. It turns in a natural color.
  • the detergent can both as a concentrate as well as in dilution with water, for example For cleaning surfaces with low water-soluble contamination be used.
  • the degree of dilution depends according to the type and extent of pollution.
  • the concentrate is directly on a sponge applied to the polluted areas. After a short exposure time the removal of the concentrate takes place with the detached Impurities by means of a damp sponge or a damp cloth. The sponge or the cloth are then in clear To flush water.
  • the cleaning effect is also more economical Dosage high, which in conjunction with the high environmental impact and the quick dismantling to no disposal problems leads.
  • the cleaning agent is also suitable for cleaning elastic Joints in the wet area as well as glass. It turned out that the concentrate is also used for cleaning wood can be. This in particular if the following Wood is pickled. For cleaning the surfaces of ink as well as of certain graffiti are also good detectable Results have been achieved.
  • Sorrel as a further additional component increases the cleaning power, especially in the removal of rust spots. It suffice about 0.5 wt .-%.
  • a added additional substance in the form of horsetail be whose share should be about 0.5 wt .-%.
  • the surfactants used for the substance under b) are 95% environmentally friendly biodegradable.
  • the preparation of the concentrate of the cleaning agent is like follows: In a first step, the harvested and cleaned red beet whole blanched. It is except the Fruit also the leaves processable. After cooling, the Beetroot stuffed in coarse pieces into a fruit juice centrifuge and there caught the red betesaft. The clear juice is by subsequent decanting and filtering by a fine Sieve won. In further process steps, the individual Substances added proportionally to the red betes juice and cold mixed together. The last ingredients are distilled Water and the essential oils added.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

Aqueous detergent of a natural product for cleaning metal, ceramic, glass, plastics, stone or tile surfaces consists of a mixture of 10.0-20.0 wt.% red beetroot juice, 3.0-15.0 wt.% soft soap, 6.0-8.0 wt.% citric acid (30%), 0.5-0.6 wt.% ascorbic acid, 0.1-0.2 wt.% ethereal orange oil, 0.1-0.2 wt.% ethereal tea tree oil and distilled water to 100.0 wt.%.

Description

Die Erfindung betrifft ein wäßriges saures Reinigungsmittel aus einem Naturprodukt für metallene Oberflächen, insbesondere im Sanitär- und Küchenbereich, für Oberflächen aus Keramik, Glas, Kunststoff und Steinen, sowie zum Reinigen von Teppichen, Gewebe und Faserstoffen.The invention relates to an aqueous acidic cleaning agent a natural product for metal surfaces, in particular in Sanitary and kitchen area, for surfaces made of ceramic, glass, Plastic and stones, as well as for cleaning carpets, fabrics and fibrous materials.

Reinigungsmittel aus Naturprodukten sind bekannt. So ist in der DE 43 11 409 A1 ein Reingungsmittel zur Oberflächenreinigung von Gegenständen beschrieben, dessen Hauptgemischbestandteil aus einem kaltgepreßten Orangenschalenöl besteht. Der Anwendungsbereich dieses Reinigungsmittels ist beschränkt, da im wesentlichen nur Fettlösungen entfernt werden können. Außerdem enthält das Reinigungsmittel einen Emulgator der industriell hergestellt wird.Detergents from natural products are known. So is in the DE 43 11 409 A1 a cleaning agent for surface cleaning of Items described, its main component of the mixture consists of a cold-pressed orange peel oil. The scope this cleaning agent is limited because essentially only fat solutions can be removed. It also contains the detergent is an emulsifier industrially produced becomes.

Aus der DE 41 04 191 C1 ist ein Verfahren zum Herstellen eines Reinigungsmittels auf der Grundlage von Brennesseln und aus der DE 37 21 004 C1 ein Haushaltsreinigungsmittel unter Verwendung von Brennesselsaft bekannt. Dieses Mittel weist eine nur unbefriedigende Wirkung auf. Außerdem ist die Gewinnung von Brennnesselsaft sehr aufwendig.From DE 41 04 191 C1 is a method for producing a Cleaning agent based on nettles and from the DE 37 21 004 C1 a household detergent using known from stinging juice. This remedy is unsatisfactory Effect on. In addition, the extraction of nettle juice very expensive.

Zum Reinigen von Sanitärkeramik und von harten Oberflächen sind in der DE 40 32 123 C2 und der DE 40 32 126 C2 Reinigungsmittel auf der Basis von Rhabarbersäften beschrieben. Sie üben zwar einen guten Reinigungseffekt aus, können aber nicht lange genug gelagert werden, da die Konservierung schwierig ist. Für die Gewinnung des Saftes wird eine große Menge Rohmaterial benötigt.For cleaning sanitary ware and hard surfaces in DE 40 32 123 C2 and DE 40 32 126 C2 detergent described on the basis of rhubarb juices. You practice though a good cleansing effect, but can not last long enough be stored as the preservation is difficult. For the Extraction of the juice requires a large amount of raw material.

Gemeinsam nachteilig bei den bekannten Reinigungsmitteln aus Naturprodukten ist die Verwendung von Wasser mit einem hohen Härtegrad.Together disadvantageous in the known cleaning agents Natural products is the use of high water Hardness.

Aus der DE 44 20 735 A1 ist ein Verfahren zur Herstellung mechanisch stabiler, sich mit hoher Auflösegeschwindigkeit auszeichnender Brausetabletten für pharmazeutische Brausetabletten, Diätbrausetablette sowie Brausetabletten in Form von Waschmittel-, Bade- und Entkalkungstabletten bekannt, wobei in einigen Gemischen geringe Anteile von Rote Bete-Saftpulver enthalten sind.From DE 44 20 735 A1 a method for the production of mechanical more stable, characterized by high dissolution speed Effervescent tablets for pharmaceutical effervescent tablets, Dietary spray tablet and effervescent tablets in the form of detergent, Bath and descaling tablets are known, in some Mixtures contain low levels of beetroot juice powder are.

Aufgabe der Erfindung ist es, ein wäßriges Reinigungsmittel aus einem Naturprodukt zu entwickeln, das zum Reinigen von Oberflächen aus Metall, Keramik, Glas, Kunststoff und Steinen sowie von Teppichen, Gewebe und Faserstoffen geeignet ist und ein hohes Lösevermögen für Kalkablagerungen besitzt sowie Rostflächen entfernen kann.The object of the invention is to provide an aqueous cleaning agent to develop a natural product that is used to clean surfaces of metal, ceramics, glass, plastic and stones and of Carpets, fabrics and fibrous materials is suitable and a high Has dissolving power for calcification and rust surfaces can remove.

Diese Aufgabe wird erfindungsgemäß durch ein Reinigungsmittel gelöst, das im wesentlichen den Saft der roten Bete (beta vulgaris) enthält, dessen Gemisch im kennzeichnenden Teil des Anspruches 1 dargestellt ist und einen pH-Wert zwischen 2 und 3 hat. Vorteilhafte Ausgestaltungen und Weiterbildungen des Gegenstandes der Erfindung sind in den Unteransprüchen 2 bis 7 angegeben.This object is achieved by a cleaning agent essentially dissolved the juice of the red beet (beta vulgaris) contains, the mixture in the characterizing part of claim 1 and has a pH between 2 and 3. Advantageous embodiments and further developments of the subject The invention are specified in the subclaims 2 to 7.

Das erfindungsgemäße Reinigungsmittel hat den Vorteil, daß alle Bestandteile reine natürliche Stoffe sind. Es stellt sich in einer natürlichen Farbe dar. Das Reinigungsmittel kann sowohl als Konzentrat als auch in Verdünnung mit Wasser, beispielsweise zum Reinigen von Flächen mit geringem wasserlösbaren Verschmutzungsgrad verwendet werden. Der Verdünnungsgrad richtet sich dabei nach der Art und dem Umfang der Verschmutzung. Bei der Anwendung wird das Konzentrat mittels eines Schwammes direkt auf die verschmutzten Stellen aufgetragen. Nach einer kurzen Einwirkzeit erfolgt das Entfernen des Konzentrat mit den abgelösten Verunreinigungen mittels eines feuchten Schwammes oder eines feuchten Tuches. Der Schwamm bzw. das Tuch sind danach in klarem Wasser zu spülen. Die Reinigungswirkung ist auch bei sparsamer Dosierung hoch, was in Verbindung mit der hohen Umweltverträglichkeit und dem schnellen Abbau zu keinen Entsorgungsproblemen führt.The cleaning agent according to the invention has the advantage that all Ingredients are pure natural substances. It turns in a natural color. The detergent can both as a concentrate as well as in dilution with water, for example For cleaning surfaces with low water-soluble contamination be used. The degree of dilution depends according to the type and extent of pollution. In the Application, the concentrate is directly on a sponge applied to the polluted areas. After a short exposure time the removal of the concentrate takes place with the detached Impurities by means of a damp sponge or a damp cloth. The sponge or the cloth are then in clear To flush water. The cleaning effect is also more economical Dosage high, which in conjunction with the high environmental impact and the quick dismantling to no disposal problems leads.

Bei starken Verkalkungen an Armaturen ist es bisher üblich Essigsäure zu verwenden. Die Essigsäure beseitigt zwar die Verkalkungen hat aber auch den Nachteil, daß Zerstörungen an den Armaturen auftreten können. Diese starken Verkalkungen werden durch das neue Reinigungsmittel ohne nachteilige Wirkungen gründlich beseitigt.With strong calcifications on fittings, it is usual practice acetic acid to use. The acetic acid eliminates the calcifications But also has the disadvantage that destruction to the Fittings can occur. These strong calcifications will be by the new detergent without adverse effects thoroughly eliminated.

Das Reinigungsmittel eignet sich auch zur Reinigung von elastischen Fugen im Naßbereich sowie von Glas. Es hat sich herausgestellt, daß das Konzentrat ebenfalls zum Reinigen von Holz verwendet werden kann. Dies insbesondere dann, wenn nachfolgend das Holz gebeizt wird. Für das Reinigen der Oberflächen von Tinte sowie von bestimmten Graffiti sind gleichfalls gute nachweisbare Ergebnisse erzielt worden.The cleaning agent is also suitable for cleaning elastic Joints in the wet area as well as glass. It turned out that the concentrate is also used for cleaning wood can be. This in particular if the following Wood is pickled. For cleaning the surfaces of ink as well as of certain graffiti are also good detectable Results have been achieved.

Zur Erhöhung der Haltbarkeit des Reinigungsmittels trägt Ascorbinsäure bei, deren Anteil zwischen 0,5 und 0,6 Gew.-% liegen sollte.To increase the shelf life of the detergent carries ascorbic acid at, whose proportion is between 0.5 and 0.6 wt .-% should.

Durch die Verwendung von destilliertem bzw. weichem Wasser mit einem Härtegrad von 1°d bis 7°d wird das Bilden eines Kalkfilmes beim Trocknen vermieden, so daß ein Nachpolieren entfällt. Insbesondere beim Reinigen von Armaturen und Nirosta sind diese Vorteile erkennbar.By using distilled or soft water with a degree of hardness of 1 ° d to 7 ° d, the formation of a lime film avoided during drying, so that repolishing omitted. In particular when cleaning faucets and Nirosta these are Advantages recognizable.

Es ist vorteilhaft ätherisches Orangenöl und ätherisches Teebaumöl als zusätzliche Substanzen dem Konzentrat beizugeben, da diese Öle keim- und geruchsabweisend wirken. Ihr Anteil sollte je 0,1 bis 0,2 Gew.-% betragen.It is beneficial to essential orange oil and tea tree essential oil as additional substances to add to the concentrate, since These oils have a germ and odor-repellent effect. Your share should be each 0.1 to 0.2 wt .-% amount.

Sauerampfer als weitere zusätzliche Komponente erhöht die Reinigungskraft, insbesondere bei der Beseitigung von Rostflecken. Dabei genügen ca. 0,5 Gew.-%.Sorrel as a further additional component increases the cleaning power, especially in the removal of rust spots. It suffice about 0.5 wt .-%.

Zur Beeinflussung der Farbgebung des Konzentrates kann eine weitere zusätzliche Substanz in Form von Zinnkraut beigegeben werden, dessen Anteil ca. 0,5 Gew.-% betragen sollte.To influence the coloring of the concentrate, a added additional substance in the form of horsetail be whose share should be about 0.5 wt .-%.

Zum Reinigen von Oberflächen mit geringem Verschmutzungsgrad, z.B. Keramik- bzw. Kunststoffböden, Glas sowie Fliesen und Sanitärkeramik, ist eine Verdünnung des Konzentrats mit weichem Wasser in einem Verhältnis von 1:100 bis 1:200 mit gutem Reinigungserfolg möglich.For cleaning surfaces with a low degree of contamination, e.g. Ceramic or plastic floors, glass as well as tiles and sanitary ceramics, is a dilution of the concentrate with soft Water in a ratio of 1: 100 to 1: 200 with good cleaning success possible.

Anstelle der 30 %-igen Zitronensäure ist die Verwendung reiner Zitronensäure mit einem Anteil von 1,8 bis 2,4 Gew.-% denkbar.The use is purer instead of the 30% citric acid Citric acid in a proportion of 1.8 to 2.4 wt .-% conceivable.

Die verwendeten Tenside für die Substanz unter b) sind zu 95 % umweltfreundlich biologisch abbaubar.The surfactants used for the substance under b) are 95% environmentally friendly biodegradable.

Eine bevorzugte Ausgestaltung wäre folgende Zusammensetzung des Konzentrates für das erfindungsgemäße Reinigungsmittel:

  • a) 12,5 Gew.-% rote Betesaft;
  • b) 4,2 Gew.-% Schmierseife;
  • c) 8,3 Gew.-% Zitronensäure (30 %-ig);
  • d) 0,5 Gew.-% Ascorbinsäure;
  • f) 0,1 Gew.-% äthetisches Orangenöl;
  • g) 0,1 Gew.-% äthetisches Teebaumöl;
  • e) ad. 100,0 Gew.-% destilliertes Wasser.
  • A preferred embodiment would be the following composition of the concentrate for the cleaning agent according to the invention:
  • a) 12.5% by weight of red beta-juice;
  • b) 4.2% by weight of soft soap;
  • c) 8.3% by weight of citric acid (30%);
  • d) 0.5% by weight of ascorbic acid;
  • f) 0.1% by weight of orange oil;
  • g) 0.1% by weight of tea-tea esthetic oil;
  • e) ad. 100.0% by weight of distilled water.
  • Anhand der folgenden Tabelle werden für einige Anwendungsfälle Mischungsverhältnisse des Konzentrats mit weichem Wasser genannt: Verwendungszweck Mischungsverhältnis Starke Verschmutzung von Teppichen, Polsterstoffen, Synthesefasern 1 : 10 Normale Verschmutzung von Teppichen, Polsterstoffen, Synthesefasern 1 : 100 Allgemeine Oberflächenreinigung für glatte Flächen 1 : 50 Backofen- und Grillreinigung 1 : 8 Fensterreinigung 1 : 200 Beseitigung von Kalkablagerungen 1 : 8 Beseitigung von Rostflecken 1 : 1 bis 1 : 5. The following table gives for some applications mixing ratios of the concentrate with soft water: Usage mixing ratio Heavy pollution of carpets, Upholstery fabrics, synthetic fibers 1:10 Normal pollution of carpets, Upholstery fabrics, synthetic fibers 1: 100 General surface cleaning for smooth surfaces 1:50 Oven and grill cleaning 1: 8 window cleaning 1: 200 Elimination of limescale 1: 8 Elimination of rust spots 1: 1 to 1: 5.

    Die Herstellung des Konzentrates des Reinigungsmittels ist wie folgt : In einem ersten Verfahrensschritt wird die geerntete und gesäuberte rote Bete im Ganzen blanchiert. Dabei sind außer der Frucht auch die Blätter verarbeitbar. Nach dem Erkalten wird die rote Bete in groben Stücken in eine Fruchtsaftzentrifuge gefüllt und dort der rote Betesaft aufgefangen. Der klare Saft wird durch anschließendes Dekantieren und Filtern durch ein feines Sieb gewonnen. In weiteren Verfahrensschritten werden die einzelnen Substanzen anteilsmäßig dem rote Betesaft zugegeben und miteinander kalt vermischt. Als letzte Bestandteile werden destilliertes Wasser sowie die ätherischen Öle hinzugefügt.The preparation of the concentrate of the cleaning agent is like follows: In a first step, the harvested and cleaned red beet whole blanched. It is except the Fruit also the leaves processable. After cooling, the Beetroot stuffed in coarse pieces into a fruit juice centrifuge and there caught the red betesaft. The clear juice is by subsequent decanting and filtering by a fine Sieve won. In further process steps, the individual Substances added proportionally to the red betes juice and cold mixed together. The last ingredients are distilled Water and the essential oils added.

    Claims (7)

    Wäßriges Reinigungsmittel aus einem Naturprodukt zur Reinigung von Oberflächen aus Metall, Keramik, Glas, Kunststoff, Steinen oder Fliesen, sowie zum Reinigen von Teppichen, Gewebe und Faserstoffen bestehend aus einem Gemisch folgender Substanzen: a) 10,0 bis 20,0 Gew.-% rote Betesaft; b) 3,0 bis 15,0 Gew.-% Schmierseife; c) 6,0 bis 8,0 Gew.-% Zitronensäure (30%-ig); d) 0,5 bis 0,6 Gew.-% Ascorbinsäure; e) 0,1 bis 0,2 Gew.-% ätherisches Orangenöl; f) 0,1 bis 0,2 Gew.-% ätherisches Teebaumöl und g) ad. 100,0 Gew.-% destilliertes Wasser. Aqueous detergent from a natural product for cleaning surfaces of metal, ceramic, glass, plastic, stones or tiles, and for cleaning carpets, fabrics and fibrous materials consisting of a mixture of the following substances: a) 10.0 to 20.0% by weight of beeswax; b) 3.0 to 15.0% by weight of soft soap; c) 6.0 to 8.0 wt% citric acid (30%); d) 0.5 to 0.6% by weight of ascorbic acid; e) 0.1 to 0.2% by weight of essential orange oil; f) 0.1 to 0.2 wt .-% tea tree essential oil and g) ad. 100.0% by weight of distilled water. Wäßriges Reinigungsmittel nach Anspruch 1, dadurch gekennzeichnet, daß die Substanz unter g) ein Wasser mit einem Härtegrad von 1°d bis 7°d enthält.Aqueous detergent according to claim 1, characterized in that the substance under g) contains a water with a degree of hardness of 1 ° d to 7 ° d. Wäßriges Reinigungsmittel nach einem der Ansprüche 1 bis 2, gekennzeichnet durch eine weitere Substanz h) 0,5 Gew.-% Sauerampfer. Aqueous detergent according to one of claims 1 to 2, characterized by a further substance h) 0.5% by weight sorrel. Wäßriges Reinigungsmittel nach einem der Ansprüche 1 bis 3, gekennzeichnet durch eine weitere zusätzliche Substanz i) 0,5 Gew.-% Zinnkraut. Aqueous detergent according to one of claims 1 to 3, characterized by a further additional substance i) 0.5% by weight of horsetail. Wäßriges Reinigungsmittel nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, daß das Konzentrat mit weichem Wasser im Verhältnis 1:100 bis 1:200 mischbar ist.An aqueous detergent according to any one of claims 1 to 4, characterized in that the concentrate is miscible with soft water in a ratio of 1: 100 to 1: 200. Wäßriges Reinigungsmittel nach Anspruch 1, dadurch gekennzeichnet, daß die Substanz unter c) reine Zitronensäure mit einem Anteil von 1,8 bis 2,4 Gew.-% enthält.An aqueous detergent according to claim 1, characterized in that the substance under c) contains pure citric acid in a proportion of 1.8 to 2.4 wt .-%. Wäßriges Reinigungsmittel nach Anspruch 1, dadurch gekennzeichnet, daß die Substanz unter b) Tenside enthält, die zu 95 % umweltfreundlich biologisch abbaubar sind.Aqueous detergent according to claim 1, characterized in that the substance under b) contains surfactants which are biodegradable to 95% environmentally friendly.
    EP02018631A 2001-08-24 2002-08-20 Aqueous cleaning composition based on a natural product Expired - Lifetime EP1288285B1 (en)

    Applications Claiming Priority (2)

    Application Number Priority Date Filing Date Title
    DE10141648A DE10141648C1 (en) 2001-08-24 2001-08-24 Aqueous detergent for cleaning metal, ceramic, glass, plastics, stone or tile surfaces is mixture of red beetroot juice, soft soap, citric acid, ascorbic acid, ethereal orange oil, ethereal tea tree oil and distilled water
    DE10141648 2001-08-24

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    Publication Number Publication Date
    EP1288285A1 true EP1288285A1 (en) 2003-03-05
    EP1288285B1 EP1288285B1 (en) 2005-10-05

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    EP (1) EP1288285B1 (en)
    AT (1) ATE305959T1 (en)
    DE (2) DE10141648C1 (en)
    DK (1) DK1288285T3 (en)
    NO (1) NO329115B1 (en)

    Cited By (10)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    WO2006133897A2 (en) * 2005-06-13 2006-12-21 Gerd-Rudolf Meilke Surface treatment agent and method for the production thereof
    EP2207539A1 (en) * 2007-06-20 2010-07-21 The Trustees of Columbia University in The City of New York Skin and surface disinfectant compositions containing botanicals
    CN102191142A (en) * 2011-04-13 2011-09-21 浙江大学 Surface yellow spot cleaning agent for neutral stones and stone cultural relics and preparation method thereof
    ITMI20120997A1 (en) * 2012-06-08 2013-12-09 Ernesto Attilio Bozzi BIODEGRADABLE AND NATURAL CLEANING SOLUTION.
    US9687429B2 (en) 2007-06-20 2017-06-27 The Trustees Of Columbia University In The City Of New York Antimicrobial compositions containing low concentrations of botanicals
    US9968101B2 (en) 2011-11-03 2018-05-15 The Trustees Of Columbia University In The City Of New York Botanical antimicrobial compositions
    US9981069B2 (en) 2007-06-20 2018-05-29 The Trustees Of Columbia University In The City Of New York Bio-film resistant surfaces
    US10542760B2 (en) 2007-06-20 2020-01-28 The Trustees Of Columbia University In The City Of New York Skin and surface disinfectant compositions containing botanicals
    US10806144B2 (en) 2011-11-03 2020-10-20 The Trustees Of Columbia University In The City Of New York Composition with sustained antimicrobial activity
    US11535764B2 (en) 2016-11-14 2022-12-27 Kao Corporation Aqueous gravure ink

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    * Cited by examiner, † Cited by third party
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    DE10315304B4 (en) * 2002-09-11 2014-03-13 Karsten Püschner Method for decontaminating an object contaminated with organochlorine biocides
    EP2166840B1 (en) 2007-06-20 2017-01-11 The Trustees of Columbia University in the City of New York Bio-film resistant surfaces
    WO2013086094A1 (en) 2011-12-06 2013-06-13 The Trustees Of Columbia University In The City Of New York Broad spectrum natural preservative composition

    Citations (5)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    JPS5947300A (en) * 1982-09-13 1984-03-16 芦川 啓太郎 Detergent
    JPH07171426A (en) * 1993-11-05 1995-07-11 Nippon Saafuakutanto Kogyo Kk Rice washing agent composition and rice washing agent
    DE4420735A1 (en) * 1994-06-15 1995-12-21 Allphamed Arzneimittel Gmbh Process for the production of mechanically stable, high-speed effervescent tablets
    JPH10324893A (en) * 1997-05-27 1998-12-08 Teshima Kaken:Kk Kitchen detergent for tableware
    DE19737072A1 (en) * 1997-08-26 1999-03-04 Romaine Niesner Monika Cleaning mixture useful e.g. for laundry, surface disinfection, body cleanser or liquid detergent

    Patent Citations (5)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    JPS5947300A (en) * 1982-09-13 1984-03-16 芦川 啓太郎 Detergent
    JPH07171426A (en) * 1993-11-05 1995-07-11 Nippon Saafuakutanto Kogyo Kk Rice washing agent composition and rice washing agent
    DE4420735A1 (en) * 1994-06-15 1995-12-21 Allphamed Arzneimittel Gmbh Process for the production of mechanically stable, high-speed effervescent tablets
    JPH10324893A (en) * 1997-05-27 1998-12-08 Teshima Kaken:Kk Kitchen detergent for tableware
    DE19737072A1 (en) * 1997-08-26 1999-03-04 Romaine Niesner Monika Cleaning mixture useful e.g. for laundry, surface disinfection, body cleanser or liquid detergent

    Non-Patent Citations (3)

    * Cited by examiner, † Cited by third party
    Title
    DATABASE WPI Section Ch Week 198417, Derwent World Patents Index; Class D13, AN 1984-104341, XP002223752 *
    DATABASE WPI Section Ch Week 199536, Derwent World Patents Index; Class D13, AN 1995-271610, XP002223753 *
    PATENT ABSTRACTS OF JAPAN vol. 1999, no. 03 31 March 1999 (1999-03-31) *

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    WO2006133897A3 (en) * 2005-06-13 2007-05-18 Gerd-Rudolf Meilke Surface treatment agent and method for the production thereof
    WO2006133897A2 (en) * 2005-06-13 2006-12-21 Gerd-Rudolf Meilke Surface treatment agent and method for the production thereof
    US9687429B2 (en) 2007-06-20 2017-06-27 The Trustees Of Columbia University In The City Of New York Antimicrobial compositions containing low concentrations of botanicals
    EP2207539A1 (en) * 2007-06-20 2010-07-21 The Trustees of Columbia University in The City of New York Skin and surface disinfectant compositions containing botanicals
    US10542760B2 (en) 2007-06-20 2020-01-28 The Trustees Of Columbia University In The City Of New York Skin and surface disinfectant compositions containing botanicals
    EP2207539A4 (en) * 2007-06-20 2013-03-27 Univ Columbia Skin and surface disinfectant compositions containing botanicals
    US9981069B2 (en) 2007-06-20 2018-05-29 The Trustees Of Columbia University In The City Of New York Bio-film resistant surfaces
    CN102191142A (en) * 2011-04-13 2011-09-21 浙江大学 Surface yellow spot cleaning agent for neutral stones and stone cultural relics and preparation method thereof
    CN102191142B (en) * 2011-04-13 2012-09-19 浙江大学 Surface yellow spot cleaning agent for neutral stones and stone cultural relics and preparation method thereof
    US9968101B2 (en) 2011-11-03 2018-05-15 The Trustees Of Columbia University In The City Of New York Botanical antimicrobial compositions
    US10806144B2 (en) 2011-11-03 2020-10-20 The Trustees Of Columbia University In The City Of New York Composition with sustained antimicrobial activity
    ITMI20120997A1 (en) * 2012-06-08 2013-12-09 Ernesto Attilio Bozzi BIODEGRADABLE AND NATURAL CLEANING SOLUTION.
    US11535764B2 (en) 2016-11-14 2022-12-27 Kao Corporation Aqueous gravure ink

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    ATE305959T1 (en) 2005-10-15
    DE50204448D1 (en) 2006-02-16
    NO20024008D0 (en) 2002-08-22
    NO329115B1 (en) 2010-08-30
    DE10141648C1 (en) 2003-01-16
    EP1288285B1 (en) 2005-10-05
    DK1288285T3 (en) 2005-11-07

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