CN102061066A - 稀土掺杂铁氧体-二氧化钛/聚噻吩微波吸收剂的制备方法 - Google Patents
稀土掺杂铁氧体-二氧化钛/聚噻吩微波吸收剂的制备方法 Download PDFInfo
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- CN102061066A CN102061066A CN 201010568793 CN201010568793A CN102061066A CN 102061066 A CN102061066 A CN 102061066A CN 201010568793 CN201010568793 CN 201010568793 CN 201010568793 A CN201010568793 A CN 201010568793A CN 102061066 A CN102061066 A CN 102061066A
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- Prior art keywords
- ferrite
- titanium dioxide
- nitrate
- solution
- doped
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 47
- 239000004408 titanium dioxide Substances 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 229920000123 polythiophene Polymers 0.000 title claims abstract description 13
- 229910052761 rare earth metal Inorganic materials 0.000 title abstract description 5
- 150000002910 rare earth metals Chemical class 0.000 title abstract 3
- 230000002745 absorbent Effects 0.000 title abstract 2
- 239000002250 absorbent Substances 0.000 title abstract 2
- 229910000859 α-Fe Inorganic materials 0.000 claims abstract description 36
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 33
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 238000006243 chemical reaction Methods 0.000 claims abstract description 11
- 239000000178 monomer Substances 0.000 claims abstract description 11
- 229930192474 thiophene Natural products 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- FYDKNKUEBJQCCN-UHFFFAOYSA-N lanthanum(3+);trinitrate Chemical compound [La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FYDKNKUEBJQCCN-UHFFFAOYSA-N 0.000 claims abstract description 7
- CFYGEIAZMVFFDE-UHFFFAOYSA-N neodymium(3+);trinitrate Chemical compound [Nd+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O CFYGEIAZMVFFDE-UHFFFAOYSA-N 0.000 claims abstract description 7
- -1 titanium dioxide compound Chemical class 0.000 claims abstract description 7
- 238000002485 combustion reaction Methods 0.000 claims abstract description 5
- 239000012153 distilled water Substances 0.000 claims abstract description 3
- 238000010521 absorption reaction Methods 0.000 claims description 18
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 14
- 229960001701 chloroform Drugs 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- 229910002651 NO3 Inorganic materials 0.000 claims description 6
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 6
- 229910001864 baryta Inorganic materials 0.000 claims description 6
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 4
- 229910052779 Neodymium Inorganic materials 0.000 claims description 4
- 229910052788 barium Inorganic materials 0.000 claims description 4
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 4
- 238000001354 calcination Methods 0.000 claims description 4
- 239000000706 filtrate Substances 0.000 claims description 4
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 4
- 229910052746 lanthanum Inorganic materials 0.000 claims description 4
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate group Chemical group [N+](=O)([O-])[O-] NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 4
- 239000002243 precursor Substances 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 238000000967 suction filtration Methods 0.000 claims description 4
- 238000001291 vacuum drying Methods 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 2
- 238000005352 clarification Methods 0.000 claims description 2
- 238000011065 in-situ storage Methods 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- YPJKMVATUPSWOH-UHFFFAOYSA-N nitrooxidanyl Chemical compound [O][N+]([O-])=O YPJKMVATUPSWOH-UHFFFAOYSA-N 0.000 claims description 2
- 230000010355 oscillation Effects 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 abstract description 6
- 239000013078 crystal Substances 0.000 abstract description 5
- 230000008901 benefit Effects 0.000 abstract description 4
- 230000005672 electromagnetic field Effects 0.000 abstract description 2
- IWOUKMZUPDVPGQ-UHFFFAOYSA-N barium nitrate Chemical compound [Ba+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O IWOUKMZUPDVPGQ-UHFFFAOYSA-N 0.000 abstract 2
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 abstract 2
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 239000011358 absorbing material Substances 0.000 description 12
- 239000000499 gel Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- AJCDFVKYMIUXCR-UHFFFAOYSA-N oxobarium;oxo(oxoferriooxy)iron Chemical compound [Ba]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O AJCDFVKYMIUXCR-UHFFFAOYSA-N 0.000 description 4
- 239000011240 wet gel Substances 0.000 description 4
- 230000035699 permeability Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000005415 magnetization Effects 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 238000001132 ultrasonic dispersion Methods 0.000 description 2
- 206010007247 Carbuncle Diseases 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- WMMAJCFFFQQZGX-UHFFFAOYSA-N calcium;oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ca+2].[Ti+4] WMMAJCFFFQQZGX-UHFFFAOYSA-N 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000000593 microemulsion method Methods 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000001902 propagating effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Hard Magnetic Materials (AREA)
- Compounds Of Iron (AREA)
Abstract
Description
Claims (2)
Priority Applications (1)
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CN2010105687939A CN102061066B (zh) | 2010-12-02 | 2010-12-02 | 稀土掺杂铁氧体-二氧化钛/聚噻吩微波吸收剂的制备方法 |
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CN2010105687939A CN102061066B (zh) | 2010-12-02 | 2010-12-02 | 稀土掺杂铁氧体-二氧化钛/聚噻吩微波吸收剂的制备方法 |
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CN102061066A true CN102061066A (zh) | 2011-05-18 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102634013A (zh) * | 2012-04-05 | 2012-08-15 | 南昌航空大学 | 一种镧钐掺杂锶铁氧体-聚间甲苯胺复合微波吸收剂的制备方法 |
CN102634016A (zh) * | 2012-04-05 | 2012-08-15 | 南昌航空大学 | 一种镧钕掺杂钡铁氧体-聚吡咯复合微波吸收剂的制备方法 |
CN109233237A (zh) * | 2018-08-13 | 2019-01-18 | 深圳市京信通科技有限公司 | 高强吸波复合材料及其制备方法 |
CN111360056A (zh) * | 2020-02-25 | 2020-07-03 | 华北电力大学(保定) | 一种土壤微波修复装置及修复方法 |
CN113856690A (zh) * | 2021-09-09 | 2021-12-31 | 福州大学 | 一种用于低浓甲烷催化燃烧的钴基催化剂 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101035630A (zh) * | 2004-08-03 | 2007-09-12 | 坎梅陶尔股份有限公司 | 用防腐涂层涂覆金属表面的方法 |
-
2010
- 2010-12-02 CN CN2010105687939A patent/CN102061066B/zh not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101035630A (zh) * | 2004-08-03 | 2007-09-12 | 坎梅陶尔股份有限公司 | 用防腐涂层涂覆金属表面的方法 |
Non-Patent Citations (1)
Title |
---|
《胶体与聚合物》 20081215 辛麟等 聚噻吩类化合物在染料敏化太阳能电池中的应用研究进展 , 第04期 2 * |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102634013A (zh) * | 2012-04-05 | 2012-08-15 | 南昌航空大学 | 一种镧钐掺杂锶铁氧体-聚间甲苯胺复合微波吸收剂的制备方法 |
CN102634016A (zh) * | 2012-04-05 | 2012-08-15 | 南昌航空大学 | 一种镧钕掺杂钡铁氧体-聚吡咯复合微波吸收剂的制备方法 |
CN102634013B (zh) * | 2012-04-05 | 2014-08-20 | 南昌航空大学 | 一种镧钐掺杂锶铁氧体-聚间甲苯胺复合微波吸收剂的制备方法 |
CN109233237A (zh) * | 2018-08-13 | 2019-01-18 | 深圳市京信通科技有限公司 | 高强吸波复合材料及其制备方法 |
CN111360056A (zh) * | 2020-02-25 | 2020-07-03 | 华北电力大学(保定) | 一种土壤微波修复装置及修复方法 |
CN113856690A (zh) * | 2021-09-09 | 2021-12-31 | 福州大学 | 一种用于低浓甲烷催化燃烧的钴基催化剂 |
CN113856690B (zh) * | 2021-09-09 | 2023-08-18 | 福州大学 | 一种用于低浓甲烷催化燃烧的钴基催化剂 |
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CN102061066B (zh) | 2012-06-27 |
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Effective date of registration: 20140326 Address after: 100031 West Chang'an Avenue, Beijing, No. 86 Patentee after: State Grid Corporation of China Patentee after: Jiangxi Electric Power Science Academy Patentee after: Nanchang Univ. of Aviation Address before: 696 No. 330000 Jiangxi province Nanchang Honggutan Feng and South Avenue Patentee before: Nanchang Univ. of Aviation |
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