CN1020417C - 单环芳烃部分加氢制备环烯烃用的钌/水滑石催化剂 - Google Patents

单环芳烃部分加氢制备环烯烃用的钌/水滑石催化剂 Download PDF

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Publication number
CN1020417C
CN1020417C CN88109260A CN88109260A CN1020417C CN 1020417 C CN1020417 C CN 1020417C CN 88109260 A CN88109260 A CN 88109260A CN 88109260 A CN88109260 A CN 88109260A CN 1020417 C CN1020417 C CN 1020417C
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CN
China
Prior art keywords
ruthenium
hydrotalcite
ion
catalyst
hydrogenation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN88109260A
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English (en)
Chinese (zh)
Other versions
CN1035255A (zh
Inventor
福原浩
松永藤尚
中岛靖
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemical Industry Co Ltd
Original Assignee
Mitsui Petrochemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Petrochemical Industries Ltd filed Critical Mitsui Petrochemical Industries Ltd
Publication of CN1035255A publication Critical patent/CN1035255A/zh
Application granted granted Critical
Publication of CN1020417C publication Critical patent/CN1020417C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • C07C5/11—Partial hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/44—Hydrogenation of the aromatic hydrocarbons
    • C10G45/46—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
    • C10G45/52—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CN88109260A 1987-12-29 1988-12-29 单环芳烃部分加氢制备环烯烃用的钌/水滑石催化剂 Expired - Fee Related CN1020417C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP62332527A JPH088985B2 (ja) 1987-12-29 1987-12-29 水添用触媒
JP332527/87 1987-12-29

Publications (2)

Publication Number Publication Date
CN1035255A CN1035255A (zh) 1989-09-06
CN1020417C true CN1020417C (zh) 1993-05-05

Family

ID=18255917

Family Applications (1)

Application Number Title Priority Date Filing Date
CN88109260A Expired - Fee Related CN1020417C (zh) 1987-12-29 1988-12-29 单环芳烃部分加氢制备环烯烃用的钌/水滑石催化剂

Country Status (10)

Country Link
US (1) US4923837A (el)
EP (1) EP0323192B1 (el)
JP (1) JPH088985B2 (el)
KR (1) KR960008613B1 (el)
CN (1) CN1020417C (el)
AT (1) ATE77571T1 (el)
CA (1) CA1326009C (el)
DE (1) DE3872368T2 (el)
ES (1) ES2041814T3 (el)
GR (1) GR3004972T3 (el)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5037787A (en) * 1989-07-13 1991-08-06 Quantum Chemical Corporation Nickel pillared interlayered clay
DK167146B1 (da) * 1990-09-11 1993-09-06 Topsoe Haldor As Fremgangsmaade og katalysator til fremstilling af aromatiske forbindelser
EP0562113B1 (en) * 1991-08-13 1998-10-21 Asahi Kasei Kogyo Kabushiki Kaisha Continuous partial hydrogenation of monocyclic aromatic hydrocarbon with pretreated catalyst slurry
US5334790A (en) * 1992-02-26 1994-08-02 Catalytica Process and catalyst for partially hydrogenating aromatics to produce cycloolefins
US5414171A (en) * 1992-02-26 1995-05-09 Catalytica, Inc. Process and washed catalyst for partially hydrogenating aromatics to produce cycloolefins
US5399537A (en) * 1992-12-21 1995-03-21 Amoco Corporation Method for preparing synthesis gas using nickel catalysts
IT1273491B (it) * 1995-02-03 1997-07-08 Snam Progetti Materiale avente struttura a strati tipo idrotalcite e relativi usi
JP2884050B2 (ja) * 1995-10-13 1999-04-19 工業技術院長 ルテニウム担持金属酸化物触媒による選択的核水素化反応
JP2884058B2 (ja) * 1996-01-19 1999-04-19 工業技術院長 ルテニウム担持金属酸化物触媒による効率的な石炭液化方法
JP2002274852A (ja) * 2001-03-14 2002-09-25 Asahi Kasei Corp 金属固定化ハイドロタルサイト、及びそれを用いるアルデヒド、ケトンまたはカルボン酸の製造方法
US7449425B2 (en) * 2005-06-29 2008-11-11 Exxonmobil Chemical Patents Inc. Production of alcohols from synthesis gas
JP5444327B2 (ja) 2008-04-25 2014-03-19 エクソンモービル・ケミカル・パテンツ・インク フェノール及び／又はシクロヘキサノンの製造方法
WO2011096995A1 (en) 2010-02-05 2011-08-11 Exxonmobil Chemical Patents Inc. Dehydrogenation process
KR101205897B1 (ko) 2010-04-19 2012-11-29 한국과학기술연구원 복합금속산화물 담체에 담지된 귀금속 촉매 및 이를 이용한 1,2-프로판디올의 제조방법
KR20130133008A (ko) 2011-03-28 2013-12-05 엑손모빌 케미칼 패턴츠 인코포레이티드 탈수소화 방법
CN112316960B (zh) * 2020-11-25 2021-08-20 华中科技大学 一种催化二氧化碳生成甲醛的方法
CN113231058A (zh) * 2021-04-23 2021-08-10 北京化工大学 一种锌修饰的亲水性Ru基催化剂的制备方法及其催化苯选择性加氢反应的应用

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3767720A (en) * 1972-02-25 1973-10-23 Du Pont Selective hydrogenation of aromatic hydrocarbons to cycloolefins
US3963789A (en) * 1974-12-12 1976-06-15 Kruse Walter M Polyhydric alcohol production using RU on clay supports
US3971354A (en) * 1975-06-23 1976-07-27 The Bendix Corporation Increasing warm up enrichment as a function of manifold absolute pressure
US4197415A (en) * 1976-10-08 1980-04-08 Toray Industries, Inc. Process for preparing cyclic olefins by selective partial hydrogenation of aromatic hydrocarbons
US4337177A (en) * 1979-08-23 1982-06-29 Phillips Petroleum Company Catalyst for hydrogenation of unsaturated dinitriles
JPS57130926A (en) * 1981-02-06 1982-08-13 Toray Ind Inc Partial hydrogenating method of aromatic hydrocarbon
JPS6059215B2 (ja) * 1983-02-24 1985-12-24 工業技術院長 ベンゼンからのシクロヘキセンの製法
JPS59184138A (ja) * 1983-04-04 1984-10-19 Asahi Chem Ind Co Ltd シクロオレフインの製造方法
WO1985005562A1 (en) * 1984-05-28 1985-12-19 Mitsui Petrochemical Industries, Ltd. Alkali metal-carrying substance, and its use as catalyst
JPS6245544A (ja) * 1985-08-22 1987-02-27 Asahi Chem Ind Co Ltd シクロオレフインの製造方法
JPH064545B2 (ja) * 1985-09-11 1994-01-19 住友化学工業株式会社 シクロオレフインの製造方法
US4774212A (en) * 1987-12-22 1988-09-27 Amoco Corporation Pillared hydrotalcites

Also Published As

Publication number Publication date
ATE77571T1 (de) 1992-07-15
EP0323192A1 (en) 1989-07-05
KR890009465A (ko) 1989-08-02
JPH088985B2 (ja) 1996-01-31
CA1326009C (en) 1994-01-11
ES2041814T3 (es) 1993-12-01
CN1035255A (zh) 1989-09-06
DE3872368D1 (de) 1992-07-30
EP0323192B1 (en) 1992-06-24
US4923837A (en) 1990-05-08
JPH01176451A (ja) 1989-07-12
DE3872368T2 (de) 1992-12-10
KR960008613B1 (ko) 1996-06-28
GR3004972T3 (el) 1993-04-28

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C06 Publication
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SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C53 Correction of patent of invention or patent application
COR Change of bibliographic data

Free format text: CORRECT: PATENTEE; FROM: MITSUI SEKIYU K.K.K. TO: MITSUI CHEMICALS, INC.

CP01 Change in the name or title of a patent holder

Patentee after: Mitsui Chemical Industry Co., Ltd.

Patentee before: Mitsui Petrochemical Industries, Ltd.

C15 Extension of patent right duration from 15 to 20 years for appl. with date before 31.12.1992 and still valid on 11.12.2001 (patent law change 1993)
OR01 Other related matters
C19 Lapse of patent right due to non-payment of the annual fee
CF01 Termination of patent right due to non-payment of annual fee