CN102015774B - 用于溴化丁二烯共聚物的两步法 - Google Patents
用于溴化丁二烯共聚物的两步法 Download PDFInfo
- Publication number
- CN102015774B CN102015774B CN2009801147833A CN200980114783A CN102015774B CN 102015774 B CN102015774 B CN 102015774B CN 2009801147833 A CN2009801147833 A CN 2009801147833A CN 200980114783 A CN200980114783 A CN 200980114783A CN 102015774 B CN102015774 B CN 102015774B
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- CN
- China
- Prior art keywords
- bromination
- tribromide
- butadiene
- solvent
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/12—Incorporating halogen atoms into the molecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/12—Incorporating halogen atoms into the molecule
- C08C19/14—Incorporating halogen atoms into the molecule by reaction with halogens
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
- C08F8/22—Halogenation by reaction with free halogens
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
反应时间(min) | 转化% |
0 | 0 |
10 | 77.0 |
15 | 83.4 |
20 | 87.6 |
25 | 89.3 |
30 | 91.4 |
45 | 93.5 |
60 | 93.7 |
Claims (11)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US4972108P | 2008-05-01 | 2008-05-01 | |
US61/049,721 | 2008-05-01 | ||
PCT/US2009/040915 WO2009134628A1 (en) | 2008-05-01 | 2009-04-17 | Two-step process for brominating butadiene copolymers |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102015774A CN102015774A (zh) | 2011-04-13 |
CN102015774B true CN102015774B (zh) | 2013-01-02 |
Family
ID=40843348
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2009801147833A Active CN102015774B (zh) | 2008-05-01 | 2009-04-17 | 用于溴化丁二烯共聚物的两步法 |
Country Status (6)
Country | Link |
---|---|
US (1) | US8410226B2 (zh) |
EP (1) | EP2274338B1 (zh) |
JP (1) | JP5508397B2 (zh) |
CN (1) | CN102015774B (zh) |
IL (1) | IL209038A (zh) |
WO (1) | WO2009134628A1 (zh) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2596030B1 (en) | 2010-09-30 | 2014-05-14 | Dow Global Technologies LLC | Process for brominating butadiene polymers using mixed solvents |
JP2014520929A (ja) | 2011-07-14 | 2014-08-25 | ダウ グローバル テクノロジーズ エルエルシー | 臭素化ビニル芳香族−ブタジエンコポリマーを含有する耐衝撃性改良スチレン系ポリマー |
CN103649191B (zh) | 2011-07-14 | 2016-05-18 | 陶氏环球技术有限责任公司 | 包含溴化苯乙烯-丁二烯共聚物的选择性气体运输薄膜 |
WO2016123263A1 (en) * | 2015-01-30 | 2016-08-04 | Dow Global Technologies Llc | Method for producing brominated and halohydrated polymers |
WO2017196512A1 (en) | 2016-05-11 | 2017-11-16 | Owens Corning Intellectual Capital, Llc | Polymeric foam comprising low levels of brominated flame retardant and method of making same |
WO2018165168A1 (en) * | 2017-03-06 | 2018-09-13 | Kemiraoyj | Polymer flooding produced water treatment |
WO2020139112A1 (en) * | 2018-12-27 | 2020-07-02 | Public Joint Stock Company "Sibur Holding" | Modified diene-containing (co)polymer, method for preparing thereof and use as a flame retardant |
JP7142786B2 (ja) * | 2018-12-27 | 2022-09-27 | パブリック・ジョイント・ストック・カンパニー・“シブール・ホールディング” | 変性(コ)ポリマー、それを調製する方法及びその使用 |
WO2020139113A1 (en) * | 2018-12-27 | 2020-07-02 | Public Joint Stock Company "Sibur Holding" | Modified diene-containing (co)polymer, method for preparing thereof and use of the same as flame retardant |
CN109762121B (zh) * | 2018-12-27 | 2021-07-30 | 山东旭锐新材有限公司 | 一种低分子量高热稳定性的溴化sbs产品及其制备方法 |
US20220298320A1 (en) | 2019-09-04 | 2022-09-22 | Totalenergies One Tech Belgium | Expandable Vinyl Aromatic Polymers with Improved Flame Retardancy |
US20220315749A1 (en) | 2019-09-04 | 2022-10-06 | Totalenergies One Tech Belgium | Process for Producing Vinyl Aromatic (Co)Polymer Incorporating Post-Consumer and/or Post-Industrial Recycled Polystyrene |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1165831A (zh) * | 1997-03-13 | 1997-11-26 | 华东理工大学 | 一种橡胶与乙烯基单体接枝物的制备方法 |
CN1421483A (zh) * | 2001-11-27 | 2003-06-04 | 拜尔公司 | 焦烧安全性改进的充填弹性体丁基混炼胶 |
CN1667000A (zh) * | 2005-02-24 | 2005-09-14 | 宜兴市昌吉利化工有限公司 | 改良的水相制备氯化橡胶的方法 |
WO2007058736A1 (en) * | 2005-11-12 | 2007-05-24 | Dow Global Technologies Inc. | Brominated butadiene/vinyl aromatic copolymers, blends of such copolymers with a vinyl aromatic polymer, and polymeric foams formed from such blends |
CN101100491A (zh) * | 2006-02-15 | 2008-01-09 | 兰科瑟斯有限公司 | 不用酸中和剂生产卤化丁基橡胶的方法 |
WO2008021417A2 (en) * | 2006-08-16 | 2008-02-21 | Dow Global Technologies, Inc. | Process for brominating butadiene/vinyl aromatic copolymers |
WO2008021418A1 (en) * | 2006-08-16 | 2008-02-21 | Dow Global Technologies, Inc. | Process for brominating butadiene/vinyl aromatic copolymers |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB383154A (en) | 1931-03-25 | 1932-11-10 | Ig Farbenindustrie Ag | Manufacture of stabilised halogen derivatives |
DE1301497B (de) * | 1966-01-05 | 1969-08-21 | Basf Ag | Verfahren zur Herstellung bromierter Polymerisate des Butadiens |
DD137308A3 (de) * | 1969-09-24 | 1979-08-29 | Paul Herte | Verfahren zur herstellung von bromierten ungesaettigten niedermolekularen polymeren |
US4925900A (en) | 1988-09-16 | 1990-05-15 | Polysar Limited | Halogenated-hydrogenated acrylonitrile-butadiene rubber |
DE4437931A1 (de) * | 1994-10-24 | 1996-04-25 | Bayer Ag | Verfahren zur Bromierung von Alkylkautschuken |
KR0137579B1 (ko) * | 1994-11-30 | 1998-06-01 | 김주용 | 반도체 소자의 플러그 형성방법 |
US6133381A (en) | 1996-09-26 | 2000-10-17 | Albelmarle Corporation | Brominated polystyrenic flame retardants |
US5767203A (en) * | 1996-09-26 | 1998-06-16 | Albemarle Corporation | Process for brominated styrenic polymers |
US6232408B1 (en) * | 1996-09-26 | 2001-05-15 | Albemarle Corporation | Brominated polstyrenic resins |
US6232393B1 (en) * | 1996-09-26 | 2001-05-15 | Albemarle Corporation | Polymers flame retarded with brominated polystyrenic resins |
US5677390A (en) * | 1996-09-26 | 1997-10-14 | Albemarle Corporation | Process for brominating polystyrenic resins |
US6235844B1 (en) * | 1996-09-26 | 2001-05-22 | Albemarle Corporation | Brominated polystyrenic resins |
US6235831B1 (en) * | 1996-09-26 | 2001-05-22 | Albemarle Corporation | Polymer compositions containing brominated polystyrenic resins |
-
2009
- 2009-04-17 WO PCT/US2009/040915 patent/WO2009134628A1/en active Application Filing
- 2009-04-17 JP JP2011507532A patent/JP5508397B2/ja active Active
- 2009-04-17 CN CN2009801147833A patent/CN102015774B/zh active Active
- 2009-04-17 EP EP09739430A patent/EP2274338B1/en active Active
- 2009-04-17 US US12/936,843 patent/US8410226B2/en not_active Expired - Fee Related
-
2010
- 2010-10-31 IL IL209038A patent/IL209038A/en active IP Right Grant
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1165831A (zh) * | 1997-03-13 | 1997-11-26 | 华东理工大学 | 一种橡胶与乙烯基单体接枝物的制备方法 |
CN1421483A (zh) * | 2001-11-27 | 2003-06-04 | 拜尔公司 | 焦烧安全性改进的充填弹性体丁基混炼胶 |
CN1667000A (zh) * | 2005-02-24 | 2005-09-14 | 宜兴市昌吉利化工有限公司 | 改良的水相制备氯化橡胶的方法 |
WO2007058736A1 (en) * | 2005-11-12 | 2007-05-24 | Dow Global Technologies Inc. | Brominated butadiene/vinyl aromatic copolymers, blends of such copolymers with a vinyl aromatic polymer, and polymeric foams formed from such blends |
CN101100491A (zh) * | 2006-02-15 | 2008-01-09 | 兰科瑟斯有限公司 | 不用酸中和剂生产卤化丁基橡胶的方法 |
WO2008021417A2 (en) * | 2006-08-16 | 2008-02-21 | Dow Global Technologies, Inc. | Process for brominating butadiene/vinyl aromatic copolymers |
WO2008021418A1 (en) * | 2006-08-16 | 2008-02-21 | Dow Global Technologies, Inc. | Process for brominating butadiene/vinyl aromatic copolymers |
Also Published As
Publication number | Publication date |
---|---|
WO2009134628A1 (en) | 2009-11-05 |
JP5508397B2 (ja) | 2014-05-28 |
JP2011519992A (ja) | 2011-07-14 |
IL209038A0 (en) | 2011-01-31 |
EP2274338A1 (en) | 2011-01-19 |
CN102015774A (zh) | 2011-04-13 |
US20110065868A1 (en) | 2011-03-17 |
US8410226B2 (en) | 2013-04-02 |
IL209038A (en) | 2014-01-30 |
EP2274338B1 (en) | 2012-12-12 |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CP01 | Change in the name or title of a patent holder |
Address after: American Michigan Patentee after: DOW GLOBAL TECHNOLOGIES LLC Address before: American Michigan Patentee before: DOW GLOBAL TECHNOLOGIES Inc. Address after: Pennsylvania, USA Patentee after: American special electronic materials Co.,Ltd. Address before: Pennsylvania, USA Patentee before: Special Electronic Materials Inc. |
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CP01 | Change in the name or title of a patent holder | ||
TR01 | Transfer of patent right |
Effective date of registration: 20210315 Address after: Pennsylvania, USA Patentee after: Special Electronic Materials Inc. Address before: American Delaware Patentee before: THE DOW CHEMICAL Co. Effective date of registration: 20210315 Address after: American Delaware Patentee after: THE DOW CHEMICAL Co. Address before: American Michigan Patentee before: DOW GLOBAL TECHNOLOGIES LLC |
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