CN101501076B - 溴化丁二烯/乙烯基芳族共聚物的方法 - Google Patents
溴化丁二烯/乙烯基芳族共聚物的方法 Download PDFInfo
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- CN101501076B CN101501076B CN2007800302090A CN200780030209A CN101501076B CN 101501076 B CN101501076 B CN 101501076B CN 2007800302090 A CN2007800302090 A CN 2007800302090A CN 200780030209 A CN200780030209 A CN 200780030209A CN 101501076 B CN101501076 B CN 101501076B
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- Prior art keywords
- brominated
- described method
- multipolymer
- bromination
- bromine
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/12—Incorporating halogen atoms into the molecule
- C08C19/14—Incorporating halogen atoms into the molecule by reaction with halogens
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
- C08F8/22—Halogenation by reaction with free halogens
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
实施例或比较样品号 | 碱金属碱 | g碱 | g起始共聚物 | 5%WLT |
B* | 无 | 无 | 16.73 | 221.6 |
18A | 甲醇钠1 | 0.24 | 16.71 | 230.7 |
19A | 乙醇钠2 | 0.32 | 16.73 | 230.1 |
20A | 乙醇锂3 | 0.91 | 16.87 | 232.7 |
21A | 氢氧化钠4 | 0.20 | 16.82 | 225.3 |
22A | 碳酸钠5 | 0.11 | 17.52 | 226.8 |
C* | 无 | 无 | 16.73 | 235.4 |
18B | 甲醇钠1 | 0.24 | 16.71 | 240.8 |
19B | 乙醇钠2 | 0.32 | 16.73 | 242.9 |
20B | 乙醇锂3 | 0.91 | 16.87 | 238.1 |
21B | 氢氧化钠4 | 0.20 | 16.82 | 234.9 |
22B | 碳酸钠5 | 0.11 | 17.52 | 238.6 |
Claims (14)
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US83808606P | 2006-08-16 | 2006-08-16 | |
US60/838,086 | 2006-08-16 | ||
US90231707P | 2007-02-20 | 2007-02-20 | |
US60/902,317 | 2007-02-20 | ||
PCT/US2007/018111 WO2008021418A1 (en) | 2006-08-16 | 2007-08-14 | Process for brominating butadiene/vinyl aromatic copolymers |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101501076A CN101501076A (zh) | 2009-08-05 |
CN101501076B true CN101501076B (zh) | 2011-07-13 |
Family
ID=38863053
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2007800302090A Active CN101501076B (zh) | 2006-08-16 | 2007-08-14 | 溴化丁二烯/乙烯基芳族共聚物的方法 |
Country Status (7)
Country | Link |
---|---|
US (1) | US8114943B2 (zh) |
EP (1) | EP2054446B1 (zh) |
JP (1) | JP5536452B2 (zh) |
CN (1) | CN101501076B (zh) |
ES (1) | ES2751021T3 (zh) |
IL (1) | IL197019A (zh) |
WO (1) | WO2008021418A1 (zh) |
Families Citing this family (36)
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CN101754983B (zh) | 2007-07-03 | 2012-05-23 | 陶氏环球技术公司 | 用于从溶液回收溴化丁二烯聚合物的方法 |
ATE524514T1 (de) | 2007-11-02 | 2011-09-15 | Dow Global Technologies Llc | Extrudierte polymerschaumstoffe mit bromierten flammenresistenten zusätzen auf fettsäurebasis |
EP2207812B1 (en) | 2007-11-07 | 2011-11-23 | Dow Global Technologies LLC | Partial solvent stripping process for recovering brominated butadiene polymers from solution |
CN102015774B (zh) * | 2008-05-01 | 2013-01-02 | 陶氏环球技术公司 | 用于溴化丁二烯共聚物的两步法 |
US9732178B1 (en) | 2008-07-24 | 2017-08-15 | Bridgestone Corporation | Block copolymers including high vinyl segments |
WO2010021906A1 (en) * | 2008-08-22 | 2010-02-25 | Dow Global Technologies Inc. | Process for brominating unsaturated organic compounds using a quaternary phosphonium tribromide as the brominating agent |
CA2742264C (en) | 2008-10-31 | 2016-09-27 | Dow Global Technologies Llc | Extruded polymer foams containing esters of a sugar and a brominated fatty acid as a flame retardant additive |
JP5462278B2 (ja) | 2008-12-18 | 2014-04-02 | ダウ グローバル テクノロジーズ エルエルシー | 脂肪族結合した臭素を含有するポリマーのための安定剤 |
CN102257016B (zh) * | 2008-12-19 | 2014-04-09 | 陶氏环球技术有限责任公司 | 使用酯溶剂混合物溴化丁二烯聚合物的方法 |
CN102378769B (zh) | 2009-03-31 | 2013-06-12 | 陶氏环球技术有限责任公司 | 用于溴化不饱和有机化合物并去除单氯化季铵或季*的方法 |
CN102471397B (zh) | 2009-06-30 | 2013-11-06 | 陶氏环球技术有限责任公司 | 溴化并环氧化的阻燃剂 |
WO2012044483A1 (en) | 2010-09-30 | 2012-04-05 | Dow Global Technologies Llc | Process for recovering brominated styrene-butadiene copolymers from a bromination reaction solution |
EP2608945B1 (en) | 2010-10-29 | 2016-01-13 | Dow Global Technologies LLC | Melt devolatilization extrusion process |
RU2593628C2 (ru) | 2010-12-17 | 2016-08-10 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Способ экструдирования полистирола из расплава |
CN102174149B (zh) * | 2011-02-25 | 2013-04-10 | 山东润科化工股份有限公司 | 一种生产溴化丁二烯共聚物的方法 |
JP2014520929A (ja) * | 2011-07-14 | 2014-08-25 | ダウ グローバル テクノロジーズ エルエルシー | 臭素化ビニル芳香族−ブタジエンコポリマーを含有する耐衝撃性改良スチレン系ポリマー |
EP2731983B1 (en) | 2011-07-14 | 2019-10-02 | Dow Global Technologies LLC | Selective gas transport films that contain brominated styrene-butadiene copolymers |
IN2014CN02210A (zh) | 2011-09-27 | 2015-06-12 | Dow Global Technologies Llc | |
CN105722901B (zh) * | 2013-11-14 | 2019-03-29 | 株式会社钟化 | 苯乙烯系树脂挤出发泡体及其制造方法 |
ES2743445T3 (es) | 2015-01-30 | 2020-02-19 | Dow Global Technologies Llc | Método de producción de polímeros bromados y halohidratados |
CN106146767B (zh) * | 2015-04-02 | 2018-09-04 | 中国石油化工股份有限公司 | 作为阻燃剂的溴化的嵌段共聚物及其制备方法 |
CN106146768B (zh) * | 2015-04-02 | 2018-09-04 | 中国石油化工股份有限公司 | 作为阻燃剂的溴化的嵌段共聚物及其制备方法 |
CN106146769B (zh) * | 2015-04-24 | 2018-09-04 | 中国石油化工股份有限公司 | 作为阻燃剂的溴化的嵌段共聚物及其制备方法 |
CN106065038B (zh) * | 2015-04-24 | 2018-05-18 | 中国石油化工股份有限公司 | 作为阻燃剂的溴化的嵌段共聚物及其制备方法 |
CN106146766B (zh) * | 2015-04-24 | 2018-09-14 | 中国石油化工股份有限公司 | 作为阻燃剂的溴化的嵌段共聚物及其制备方法 |
CN106065054B (zh) * | 2015-04-24 | 2018-05-18 | 中国石油化工股份有限公司 | 作为阻燃剂的溴化的嵌段共聚物及其制备方法 |
US20200123364A1 (en) | 2016-08-02 | 2020-04-23 | Bromine Compounds Ltd. | Stabilizers for brominated polymeric flame retardants |
CN106947007A (zh) * | 2017-04-21 | 2017-07-14 | 天津天盈新型建材有限公司 | 一种溴化高分子阻燃剂及其制备方法 |
WO2019030756A1 (en) | 2017-08-09 | 2019-02-14 | Bromine Compounds Ltd. | STABILIZATION OF FLAME RETARDANT POLYMERS |
WO2020139113A1 (en) * | 2018-12-27 | 2020-07-02 | Public Joint Stock Company "Sibur Holding" | Modified diene-containing (co)polymer, method for preparing thereof and use of the same as flame retardant |
CA3124792C (en) * | 2018-12-27 | 2024-05-21 | Public Joint Stock Company "Sibur Holding" | Modified (co)polymer, method for preparing thereof and use of the same |
CN113260637B (zh) * | 2018-12-27 | 2023-06-16 | 公共型股份公司希布尔控股 | 经改性的含二烯(共聚)聚合物,用于制备其的方法和作为阻燃剂的用途 |
EP4025615A1 (en) | 2019-09-04 | 2022-07-13 | TotalEnergies One Tech Belgium | Process for producing vinyl aromatic (co)polymer incorporating post-consumer and/or post-industrial recycled polystyrene |
CN114341256A (zh) | 2019-09-04 | 2022-04-12 | 道达尔能源一技术比利时公司 | 具有改进的阻燃性的可膨胀乙烯基芳族聚合物 |
WO2022251027A1 (en) | 2021-05-24 | 2022-12-01 | DDP Specialty Electronic Materials US, Inc. | Process for recovering quaternary salt bromination catalyst |
Citations (2)
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GB383154A (en) * | 1931-03-25 | 1932-11-10 | Ig Farbenindustrie Ag | Manufacture of stabilised halogen derivatives |
DD137308A3 (de) * | 1969-09-24 | 1979-08-29 | Paul Herte | Verfahren zur herstellung von bromierten ungesaettigten niedermolekularen polymeren |
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US4925900A (en) * | 1988-09-16 | 1990-05-15 | Polysar Limited | Halogenated-hydrogenated acrylonitrile-butadiene rubber |
KR0137579B1 (ko) * | 1994-11-30 | 1998-06-01 | 김주용 | 반도체 소자의 플러그 형성방법 |
US5767203A (en) * | 1996-09-26 | 1998-06-16 | Albemarle Corporation | Process for brominated styrenic polymers |
US6235844B1 (en) * | 1996-09-26 | 2001-05-22 | Albemarle Corporation | Brominated polystyrenic resins |
US6235831B1 (en) * | 1996-09-26 | 2001-05-22 | Albemarle Corporation | Polymer compositions containing brominated polystyrenic resins |
US6232393B1 (en) * | 1996-09-26 | 2001-05-15 | Albemarle Corporation | Polymers flame retarded with brominated polystyrenic resins |
US6232408B1 (en) * | 1996-09-26 | 2001-05-15 | Albemarle Corporation | Brominated polstyrenic resins |
US5677390A (en) * | 1996-09-26 | 1997-10-14 | Albemarle Corporation | Process for brominating polystyrenic resins |
US6133381A (en) | 1996-09-26 | 2000-10-17 | Albelmarle Corporation | Brominated polystyrenic flame retardants |
US7851558B2 (en) * | 2005-11-12 | 2010-12-14 | Dow Global Technologies Inc. | Brominated butadiene/vinyl aromatic copolymers, blends of such copolymers with a vinyl aromatic polymer and polymeric foams formed from such blends |
EP2207812B1 (en) * | 2007-11-07 | 2011-11-23 | Dow Global Technologies LLC | Partial solvent stripping process for recovering brominated butadiene polymers from solution |
-
2007
- 2007-08-14 ES ES07836890T patent/ES2751021T3/es active Active
- 2007-08-14 US US12/375,656 patent/US8114943B2/en active Active
- 2007-08-14 EP EP07836890.9A patent/EP2054446B1/en active Active
- 2007-08-14 JP JP2009524677A patent/JP5536452B2/ja active Active
- 2007-08-14 CN CN2007800302090A patent/CN101501076B/zh active Active
- 2007-08-14 WO PCT/US2007/018111 patent/WO2008021418A1/en active Application Filing
-
2009
- 2009-02-12 IL IL197019A patent/IL197019A/en active IP Right Grant
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB383154A (en) * | 1931-03-25 | 1932-11-10 | Ig Farbenindustrie Ag | Manufacture of stabilised halogen derivatives |
DD137308A3 (de) * | 1969-09-24 | 1979-08-29 | Paul Herte | Verfahren zur herstellung von bromierten ungesaettigten niedermolekularen polymeren |
Also Published As
Publication number | Publication date |
---|---|
EP2054446A1 (en) | 2009-05-06 |
WO2008021418A1 (en) | 2008-02-21 |
JP5536452B2 (ja) | 2014-07-02 |
US20090292079A1 (en) | 2009-11-26 |
US8114943B2 (en) | 2012-02-14 |
CN101501076A (zh) | 2009-08-05 |
EP2054446B1 (en) | 2019-07-24 |
JP2010514843A (ja) | 2010-05-06 |
ES2751021T3 (es) | 2020-03-30 |
IL197019A (en) | 2013-10-31 |
IL197019A0 (en) | 2009-11-18 |
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Address after: Pennsylvania, USA Patentee after: American special electronic materials Co.,Ltd. Address before: Pennsylvania, USA Patentee before: Special Electronic Materials Inc. Address after: American Michigan Patentee after: DOW GLOBAL TECHNOLOGIES LLC Address before: American Michigan Patentee before: DOW GLOBAL TECHNOLOGIES Inc. |
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Effective date of registration: 20210315 Address after: Pennsylvania, USA Patentee after: Special Electronic Materials Inc. Address before: American Delaware Patentee before: THE DOW CHEMICAL Co. Effective date of registration: 20210315 Address after: American Delaware Patentee after: THE DOW CHEMICAL Co. Address before: American Michigan Patentee before: DOW GLOBAL TECHNOLOGIES LLC |
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