CN101970531B - 具有改进的可再循环性的共聚酯和共混物,它们的制造方法和由其制成的制品 - Google Patents

具有改进的可再循环性的共聚酯和共混物,它们的制造方法和由其制成的制品 Download PDF

Info

Publication number
CN101970531B
CN101970531B CN2009801090125A CN200980109012A CN101970531B CN 101970531 B CN101970531 B CN 101970531B CN 2009801090125 A CN2009801090125 A CN 2009801090125A CN 200980109012 A CN200980109012 A CN 200980109012A CN 101970531 B CN101970531 B CN 101970531B
Authority
CN
China
Prior art keywords
moles
mole
polyester
weight
dicarboxylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN2009801090125A
Other languages
English (en)
Chinese (zh)
Other versions
CN101970531A (zh
Inventor
T·J·佩科里尼
S·A·吉利亚姆
I·加西亚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Chemical Co
Original Assignee
Eastman Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Chemical Co filed Critical Eastman Chemical Co
Publication of CN101970531A publication Critical patent/CN101970531A/zh
Application granted granted Critical
Publication of CN101970531B publication Critical patent/CN101970531B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/199—Acids or hydroxy compounds containing cycloaliphatic rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/02—Combined blow-moulding and manufacture of the preform or the parison
    • B29C49/04—Extrusion blow-moulding
    • B29C49/04102—Extrusion blow-moulding extruding the material continuously
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/02—Combined blow-moulding and manufacture of the preform or the parison
    • B29C49/06905—Using combined techniques for making the preform
    • B29C49/0691—Using combined techniques for making the preform using sheet like material, e.g. sheet blow-moulding from joined sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article
    • Y10T428/1393—Multilayer [continuous layer]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1397—Single layer [continuous layer]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Containers Having Bodies Formed In One Piece (AREA)
CN2009801090125A 2008-01-14 2009-01-09 具有改进的可再循环性的共聚酯和共混物,它们的制造方法和由其制成的制品 Active CN101970531B (zh)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
US2085908P 2008-01-14 2008-01-14
US61/020,859 2008-01-14
US12/255,237 US8980389B2 (en) 2008-01-14 2008-10-21 Copolyesters and blends with improved recyclability, processes for their manufacture, and articles prepared therefrom
US12/255,243 2008-10-21
US12/255,243 US8604138B2 (en) 2008-01-14 2008-10-21 Extrusion blow molded articles
US12/255,245 US8604139B2 (en) 2008-01-14 2008-10-21 Extrusion profile articles
US12/255,245 2008-10-21
US12/255,237 2008-10-21
PCT/US2009/000152 WO2009091517A1 (en) 2008-01-14 2009-01-09 Copolyesters and blends with improved recyclability, processes for their manufacture, and articles prepared therefrom

Publications (2)

Publication Number Publication Date
CN101970531A CN101970531A (zh) 2011-02-09
CN101970531B true CN101970531B (zh) 2012-11-28

Family

ID=40850877

Family Applications (3)

Application Number Title Priority Date Filing Date
CN2009801090125A Active CN101970531B (zh) 2008-01-14 2009-01-09 具有改进的可再循环性的共聚酯和共混物,它们的制造方法和由其制成的制品
CN2009801021873A Active CN101910242B (zh) 2008-01-14 2009-01-09 挤出吹塑制品
CN2009801021892A Active CN101910243B (zh) 2008-01-14 2009-01-09 挤出型材制品

Family Applications After (2)

Application Number Title Priority Date Filing Date
CN2009801021873A Active CN101910242B (zh) 2008-01-14 2009-01-09 挤出吹塑制品
CN2009801021892A Active CN101910243B (zh) 2008-01-14 2009-01-09 挤出型材制品

Country Status (5)

Country Link
US (3) US8604138B2 (enExample)
EP (3) EP2231745B1 (enExample)
JP (4) JP2011510117A (enExample)
CN (3) CN101970531B (enExample)
WO (3) WO2009091519A1 (enExample)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8604138B2 (en) * 2008-01-14 2013-12-10 Eastman Chemical Company Extrusion blow molded articles
US8556621B2 (en) 2011-02-09 2013-10-15 Pepsico, Inc. Extrusion blow molding apparatus for preparing polyester articles
US20130029068A1 (en) * 2011-07-28 2013-01-31 Eastman Chemical Company Extrusion blow molded articles
US8722163B2 (en) 2011-09-16 2014-05-13 Pepsico, Inc. Recyclable colorants in plastic beverage containers
US9273206B2 (en) * 2012-07-09 2016-03-01 Eastman Chemical Company Ternary blends of terephthalate or isophthalate polyesters containing EG, CHDM and TMCD
WO2015009666A1 (en) * 2013-07-15 2015-01-22 E. I. Du Pont De Nemours And Company Suppression of silencing by gwar proteins
US20150298852A1 (en) 2014-04-17 2015-10-22 S.C. Johnson & Son, Inc. Molded article formed from post consumer recycled material
EP3548523B1 (de) * 2016-12-05 2022-08-03 Covestro Deutschland AG Verfahren und system zur herstellung eines gegenstandes durch schichtweisen aufbau im stempelverfahren
EP3891205B1 (en) 2018-12-06 2024-08-28 Eastman Chemical (China) Co., Ltd. Polyesters comprising 2, 2, 4, 4-tetraalkyl-1, 3-cyclobutanediol
EP3898763A1 (en) * 2018-12-17 2021-10-27 Eastman Chemical Company Copolyester from terephthalic acid containing low diethylene glycol
KR102576713B1 (ko) * 2019-02-11 2023-09-07 에스케이케미칼 주식회사 압출 성형이 가능한 폴리에스테르 공중합체
KR20220007670A (ko) * 2019-05-10 2022-01-18 이스트만 케미칼 컴파니 재활용된 함량 및 높은 내열성을 갖는 코폴리에스테르의 블렌드
WO2020231781A1 (en) * 2019-05-10 2020-11-19 Eastman Chemical Company Recyclable extrusion blow molded articles from blends of copolyesters and recycled pet
KR20220041177A (ko) * 2019-07-29 2022-03-31 이스트만 케미칼 컴파니 열분해 및 가메탄올분해로부터의 재활용된 단량체를 갖는 폴리에스테르의 제조 방법
US12264244B2 (en) 2019-08-27 2025-04-01 Sk Chemicals Co., Ltd. Polyester resin blend
KR102772762B1 (ko) 2019-10-01 2025-02-24 에스케이케미칼 주식회사 폴리에스테르 수지 혼합물 및 이로부터 형성된 성형품
US11325774B2 (en) * 2019-11-25 2022-05-10 The Procter & Gamble Company Recyclable aerosol dispensers
GB2616768B (en) * 2020-12-22 2025-03-12 Auriga Polymers Inc Improved polyester composition for extrusion blow molded containers
US20250034392A1 (en) * 2021-11-12 2025-01-30 Polymetrix Ag Method and apparatus for production and processing of a mixture of recycled polyester material and a polyester prepolymer from a polyester production process
EP4180199B1 (de) * 2021-11-12 2025-04-16 Polymetrix AG Verfahren und vorrichtung zur herstellung und verarbeitung eines gemisches aus rezykliertem polyestermaterial und einem polyester-prepolymer aus einem polyester-herstellprozess
EP4450546A3 (de) * 2021-11-12 2024-12-18 Polymetrix AG Verfahren und vorrichtung zur herstellung und verarbeitung eines gemisches aus rezykliertem polyestermaterial und einem polyester-prepolymer aus einem polyester-herstellprozess
WO2025136741A1 (en) * 2023-12-18 2025-06-26 Eastman Chemical Company Films for use in dental appliances

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4983711A (en) * 1989-12-04 1991-01-08 Eastman Kodak Company Copolyesters and articles extrusion blow-molded therefrom
WO1997022474A1 (en) * 1995-12-20 1997-06-26 Eastman Chemical Company Synthetic laminate structure and method for making same
CN1189176A (zh) * 1995-04-28 1998-07-29 伊斯曼化学公司 紫外线吸收剂和聚酯的共混物
CN1347430A (zh) * 1999-03-24 2002-05-01 伊斯曼化学公司 制造具有降低的熔体破裂的热塑性型材的方法
CN1399656A (zh) * 1999-08-17 2003-02-26 伊斯曼化学公司 用于收缩薄膜的反应器级共聚聚酯

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE794938A (fr) 1972-02-02 1973-08-02 Eastman Kodak Co Nouveau procede de preparation de copolyesters et applications
US4161579A (en) * 1978-04-10 1979-07-17 Celanese Corporation Extrusion grade polyethylene terephthalate
US4219527A (en) 1978-10-31 1980-08-26 Celanese Corporation Extrusion grade polyethylene terephthalate
US4234708A (en) * 1979-04-23 1980-11-18 Celanese Corporation Extrusion grade polyethylene iso/terephthalate copolymer
US4554328A (en) * 1985-01-30 1985-11-19 Celanese Corporation Modified PET polymers and copolymers suitable for extrusion blow molding
US4554329A (en) 1985-01-30 1985-11-19 Celanese Corporation Modified PET polymers and copolymers suitable for extrusion blow molding
US4609721A (en) 1985-06-21 1986-09-02 Celanese Corporation Process for making molding grade polyethylene terephthalate
JP3467044B2 (ja) * 1991-04-04 2003-11-17 三井化学株式会社 ポリエステル樹脂およびその製造方法
DE4125167A1 (de) * 1991-07-30 1993-02-04 Zimmer Ag Modifiziertes co-polyethylenterephthalat
US5372864A (en) * 1993-09-03 1994-12-13 Eastman Chemical Company Toners for polyesters
IL110514A0 (en) * 1993-10-04 1994-10-21 Eastman Chem Co Concentrates for improving polyester compositions and a method for preparing such compositions
JP3173753B2 (ja) 1993-12-24 2001-06-04 株式会社クラレ 共重合ポリエステル、それからなる中空容器およびその製造法
US5442036A (en) 1994-09-06 1995-08-15 Eastman Chemical Company Branched copolyesters especially suitable for extrusion blow molding
US5696176A (en) * 1995-09-22 1997-12-09 Eastman Chemical Company Foamable polyester compositions having a low level of unreacted branching agent
JP3460907B2 (ja) 1996-05-09 2003-10-27 株式会社クラレ ポリエステルフイルム
US6632390B1 (en) * 1999-06-15 2003-10-14 Eastman Chemical Company Process for profile extrusion of a polyester
JP2002060472A (ja) * 2000-08-16 2002-02-26 Nippon Ester Co Ltd 共重合ポリエステル及び成形品
EP1188540B1 (en) 2000-09-19 2005-03-23 Fuji Photo Film Co., Ltd. Method for recycling plastic products and process with apparatus for washing crushed plastic
US20030060596A1 (en) * 2001-07-18 2003-03-27 Turner Sam Richard Amorphous copolyesters
JP2003119260A (ja) 2001-10-12 2003-04-23 Nippon Ester Co Ltd 共重合ポリエステル及び成形品
JP2003252969A (ja) 2002-03-05 2003-09-10 Nippon Ester Co Ltd 共重合ポリエステル及び成形品
US6924349B2 (en) * 2003-06-23 2005-08-02 Sk Chemicals Co., Ltd. Copolyester resin and articles using the same
JP4744822B2 (ja) 2003-10-29 2011-08-10 大和製罐株式会社 ポリエステル樹脂異形押出成形体
US7959998B2 (en) * 2005-03-02 2011-06-14 Eastman Chemical Company Transparent, oxygen-scavenging compositions containing polyesters comprising a cyclobutanediol and articles prepared therefrom
JP4525447B2 (ja) * 2005-04-25 2010-08-18 東洋製罐株式会社 耐熱性ポリエステル延伸成形容器及びその製造方法
KR101204136B1 (ko) 2005-08-30 2012-11-22 에스케이케미칼주식회사 공중합 폴리에스테르 수지 조성물을 이용하여 프로파일 압출 성형제품을 제조하는 방법
US8080191B2 (en) 2006-10-20 2011-12-20 Pepsico, Inc. Extrudable polyethylene terephthalate blend
EP1918327B1 (en) 2006-10-20 2016-07-27 PepsiCo, Inc. Extrudable polyethylene terephthalate blend
US8604138B2 (en) 2008-01-14 2013-12-10 Eastman Chemical Company Extrusion blow molded articles

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4983711A (en) * 1989-12-04 1991-01-08 Eastman Kodak Company Copolyesters and articles extrusion blow-molded therefrom
CN1189176A (zh) * 1995-04-28 1998-07-29 伊斯曼化学公司 紫外线吸收剂和聚酯的共混物
WO1997022474A1 (en) * 1995-12-20 1997-06-26 Eastman Chemical Company Synthetic laminate structure and method for making same
CN1347430A (zh) * 1999-03-24 2002-05-01 伊斯曼化学公司 制造具有降低的熔体破裂的热塑性型材的方法
CN1399656A (zh) * 1999-08-17 2003-02-26 伊斯曼化学公司 用于收缩薄膜的反应器级共聚聚酯

Also Published As

Publication number Publication date
JP2011510117A (ja) 2011-03-31
US8604138B2 (en) 2013-12-10
CN101910242A (zh) 2010-12-08
EP2231744B1 (en) 2016-05-04
JP2013249481A (ja) 2013-12-12
US20090181196A1 (en) 2009-07-16
CN101910242B (zh) 2013-09-11
US20090181202A1 (en) 2009-07-16
JP5801856B2 (ja) 2015-10-28
EP2240532B1 (en) 2017-09-06
JP2011511102A (ja) 2011-04-07
CN101910243B (zh) 2013-09-18
WO2009091512A1 (en) 2009-07-23
EP2231745B1 (en) 2016-09-21
US20090181201A1 (en) 2009-07-16
JP2011510116A (ja) 2011-03-31
CN101970531A (zh) 2011-02-09
CN101910243A (zh) 2010-12-08
WO2009091519A1 (en) 2009-07-23
US8604139B2 (en) 2013-12-10
US8980389B2 (en) 2015-03-17
EP2240532A1 (en) 2010-10-20
WO2009091517A1 (en) 2009-07-23
EP2231744A1 (en) 2010-09-29
EP2231745A1 (en) 2010-09-29

Similar Documents

Publication Publication Date Title
CN101970531B (zh) 具有改进的可再循环性的共聚酯和共混物,它们的制造方法和由其制成的制品
US20220213263A1 (en) Recyclable molded articles from blends of copolyesters and recycled pet
KR20140063636A (ko) 압출 취입 성형된 물품
TWI884959B (zh) 聚酯樹脂共混物
EP2127850A1 (en) Biaxially stretched blow-molded container and process for producing the same
JP2024501278A (ja) 押出ブロー成形容器のための改良されたポリエステル組成物
US20220227993A1 (en) Recyclable extrusion blow molded articles from blends of copolyesters and recycled pet
JP6985698B2 (ja) ポリエステル樹脂及びブロー成形品
MXPA03003875A (es) Paliculas y articulos formados de mezclas de policarbonato y poliester.
JP2002220442A (ja) 共重合ポリエステル及び成形品
TWI828914B (zh) 聚酯樹脂共混物及由其形成的製品
JPH10204162A (ja) ポリエステル粒状体及びこれを用いた容器の製造方法
JP2007138156A (ja) ポリエステル組成物、それからなるポリエステル成形体およびポリエステル中空成形体の製造方法
JP2020050851A (ja) ポリエステル樹脂及び成形品
JPH06172549A (ja) 熱可塑性ポリエステル樹脂配合物及び紫外線バリヤー性容器の製造方法
JPH05155992A (ja) 共重合ポリエステルならびにそれより成る中空容器および延伸フィルム
JP2006188676A (ja) ポリエステル組成物およびそれからなるポリエステル成形体
JP2007138158A (ja) ポリエステル組成物、それからなるポリエステル成形体およびその製造方法
JP2002060472A (ja) 共重合ポリエステル及び成形品
JP2006192890A (ja) ポリエステル予備成形体およびポリエステル延伸成形体の製造方法、並びにそれらの製造方法により得られるポリエステル成形体

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant