CN101953012B - 具有组合添加剂的耐久性燃料电池膜电极组件 - Google Patents

具有组合添加剂的耐久性燃料电池膜电极组件 Download PDF

Info

Publication number
CN101953012B
CN101953012B CN200880127293.2A CN200880127293A CN101953012B CN 101953012 B CN101953012 B CN 101953012B CN 200880127293 A CN200880127293 A CN 200880127293A CN 101953012 B CN101953012 B CN 101953012B
Authority
CN
China
Prior art keywords
polymer electrolyte
electrode assembly
membrane electrode
fuel cell
cell membrane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN200880127293.2A
Other languages
English (en)
Chinese (zh)
Other versions
CN101953012A (zh
Inventor
丹尼尔·M·皮尔庞特
史蒂文·J·哈姆罗克
马修·H·弗雷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of CN101953012A publication Critical patent/CN101953012A/zh
Application granted granted Critical
Publication of CN101953012B publication Critical patent/CN101953012B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1025—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon and oxygen, e.g. polyethers, sulfonated polyetheretherketones [S-PEEK], sulfonated polysaccharides, sulfonated celluloses or sulfonated polyesters
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1046—Mixtures of at least one polymer and at least one additive
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1046—Mixtures of at least one polymer and at least one additive
    • H01M8/1051—Non-ion-conducting additives, e.g. stabilisers, SiO2 or ZrO2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M2008/1095—Fuel cells with polymeric electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0082—Organic polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0088—Composites
    • H01M2300/0091—Composites in the form of mixtures
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Composite Materials (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inert Electrodes (AREA)
  • Fuel Cell (AREA)
CN200880127293.2A 2007-12-27 2008-12-23 具有组合添加剂的耐久性燃料电池膜电极组件 Active CN101953012B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US1702707P 2007-12-27 2007-12-27
US61/017,027 2007-12-27
PCT/US2008/088126 WO2009086354A1 (en) 2007-12-27 2008-12-23 Durable fuel cell membrane electrode assembly with combined additives

Publications (2)

Publication Number Publication Date
CN101953012A CN101953012A (zh) 2011-01-19
CN101953012B true CN101953012B (zh) 2014-05-07

Family

ID=40418933

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200880127293.2A Active CN101953012B (zh) 2007-12-27 2008-12-23 具有组合添加剂的耐久性燃料电池膜电极组件

Country Status (5)

Country Link
US (4) US8137828B2 (enExample)
EP (1) EP2243183B1 (enExample)
JP (1) JP5291121B2 (enExample)
CN (1) CN101953012B (enExample)
WO (1) WO2009086354A1 (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8628871B2 (en) * 2005-10-28 2014-01-14 3M Innovative Properties Company High durability fuel cell components with cerium salt additives
JP5291121B2 (ja) * 2007-12-27 2013-09-18 スリーエム イノベイティブ プロパティズ カンパニー 組み合わせ添加物を含む耐久性を備えた燃料電池の膜電極組立体
JP2011523398A (ja) 2008-04-24 2011-08-11 スリーエム イノベイティブ プロパティズ カンパニー プロトン伝導性材料
CN104016891B (zh) 2010-04-16 2016-08-17 3M创新有限公司 质子传导材料
US20110287338A1 (en) * 2010-05-21 2011-11-24 Gm Global Technology Operations, Inc. Low level cerium mitigation with electrode edge protection
CN103004001B (zh) * 2010-05-25 2016-02-17 3M创新有限公司 强化的电解质膜
JP6382105B2 (ja) * 2011-08-04 2018-08-29 スリーエム イノベイティブ プロパティズ カンパニー 低当量重量ポリマー
JP6289454B2 (ja) 2012-06-25 2018-03-07 スリーエム イノベイティブ プロパティズ カンパニー センサー素子、その製造方法、及びその使用方法
WO2016178848A1 (en) 2015-05-01 2016-11-10 Ballard Power Systems Inc. Method of making a membrane electrode assembly
WO2018026682A1 (en) 2016-08-02 2018-02-08 Ballard Power Systems Inc. Membrane electrode assembly with improved electrode
WO2019160985A1 (en) 2018-02-14 2019-08-22 Ballard Power Systems Inc. Membrane electrode assembly with supported metal oxide
WO2021205406A1 (en) * 2020-04-09 2021-10-14 3M Innovative Properties Company Composite including fluorinated polymer and salt nanoparticles and articles including the same
KR20220086949A (ko) 2020-12-17 2022-06-24 현대자동차주식회사 산화방지제 위치를 제어하는 연료전지의 제조방법
US12341227B2 (en) 2021-06-04 2025-06-24 3M Innovative Properties Company Perfluorosulfonyl monomers suitable for fluoropolymers and fuel cell membrane articles

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060099475A1 (en) * 2004-11-11 2006-05-11 Mitsubishi Heavy Industries, Ltd. Solid polymer electrolyte membrane electrode assembly and solid polymer electrolyte fuel cell using same
CN1969418A (zh) * 2004-06-22 2007-05-23 旭硝子株式会社 液状组合物、其制造方法及固体高分子型燃料电池用膜电极接合体的制造方法

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4417969A (en) * 1980-06-11 1983-11-29 The Dow Chemical Co. Sulfonic acid electrolytic cell membranes
US4358545A (en) * 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
ES2134792T3 (es) 1991-12-13 1999-10-16 Ici Plc Catodo para cuba electrolitica.
US6790554B2 (en) * 1998-10-08 2004-09-14 Imperial Chemical Industries Plc Fuel cells and fuel cell plates
KR20030072391A (ko) 2001-01-29 2003-09-13 쓰리엠 이노베이티브 프로퍼티즈 컴파니 연료 전지용 멤브레인 전극 조립체의 전사 제조 방법
JP2004018573A (ja) * 2002-06-13 2004-01-22 Kanegafuchi Chem Ind Co Ltd プロトン伝導性高分子膜
JP3861146B2 (ja) 2002-10-25 2006-12-20 独立行政法人産業技術総合研究所 燃料電池用負極触媒
JP2004197130A (ja) 2002-12-17 2004-07-15 Asahi Kasei Corp 酸素還元用電極触媒
US20040116742A1 (en) * 2002-12-17 2004-06-17 3M Innovative Properties Company Selective reaction of hexafluoropropylene oxide with perfluoroacyl fluorides
US6624328B1 (en) * 2002-12-17 2003-09-23 3M Innovative Properties Company Preparation of perfluorinated vinyl ethers having a sulfonyl fluoride end-group
US7348088B2 (en) * 2002-12-19 2008-03-25 3M Innovative Properties Company Polymer electrolyte membrane
JP4278133B2 (ja) 2003-04-21 2009-06-10 株式会社豊田中央研究所 固体高分子型燃料電池用電解質膜電極接合体および固体高分子型燃料電池
JP4451154B2 (ja) * 2004-02-17 2010-04-14 株式会社豊田中央研究所 固体高分子型燃料電池用電解質膜電極接合体および固体高分子型燃料電池
ATE491237T1 (de) * 2004-06-22 2010-12-15 Asahi Glass Co Ltd Flüssige zusammensetzung, verfahren zu deren herstellung und verfahren zur herstellung einer membranelektrodenbaugruppe für polymerelektrolyt- brennstoffzelle
US8101317B2 (en) * 2004-09-20 2012-01-24 3M Innovative Properties Company Durable fuel cell having polymer electrolyte membrane comprising manganese oxide
US7572534B2 (en) * 2004-09-20 2009-08-11 3M Innovative Properties Company Fuel cell membrane electrode assembly
JP4972867B2 (ja) * 2005-03-15 2012-07-11 旭硝子株式会社 固体高分子形燃料電池用電解質膜、その製造方法及び固体高分子形燃料電池用膜電極接合体
EP1912272A4 (en) 2005-07-12 2009-12-02 Asahi Glass Co Ltd ELECTROLYTE MEMBRANE FOR USE IN A FESTPOLYMER FUEL CELL, PROCESS FOR PRODUCING THE MEMBRANE AND MEMBRANE ELECTRODE ASSEMBLY FOR USE IN A FESTPOLYMER FUEL CELL
US7838138B2 (en) * 2005-09-19 2010-11-23 3M Innovative Properties Company Fuel cell electrolyte membrane with basic polymer
US8367267B2 (en) * 2005-10-28 2013-02-05 3M Innovative Properties Company High durability fuel cell components with cerium oxide additives
US8628871B2 (en) * 2005-10-28 2014-01-14 3M Innovative Properties Company High durability fuel cell components with cerium salt additives
US8110320B2 (en) * 2006-12-29 2012-02-07 3M Innovative Properties Company Method of making durable polymer electrolyte membranes
US7989115B2 (en) * 2007-12-14 2011-08-02 Gore Enterprise Holdings, Inc. Highly stable fuel cell membranes and methods of making them
JP5291121B2 (ja) * 2007-12-27 2013-09-18 スリーエム イノベイティブ プロパティズ カンパニー 組み合わせ添加物を含む耐久性を備えた燃料電池の膜電極組立体

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1969418A (zh) * 2004-06-22 2007-05-23 旭硝子株式会社 液状组合物、其制造方法及固体高分子型燃料电池用膜电极接合体的制造方法
US20060099475A1 (en) * 2004-11-11 2006-05-11 Mitsubishi Heavy Industries, Ltd. Solid polymer electrolyte membrane electrode assembly and solid polymer electrolyte fuel cell using same

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
JP特开2007-31718A 2007.02.08

Also Published As

Publication number Publication date
US20170317368A1 (en) 2017-11-02
EP2243183B1 (en) 2012-09-05
JP5291121B2 (ja) 2013-09-18
CN101953012A (zh) 2011-01-19
US20150221968A1 (en) 2015-08-06
WO2009086354A1 (en) 2009-07-09
US20120148937A1 (en) 2012-06-14
US9728801B2 (en) 2017-08-08
US20090169959A1 (en) 2009-07-02
US9023496B2 (en) 2015-05-05
US8137828B2 (en) 2012-03-20
EP2243183A1 (en) 2010-10-27
JP2011508953A (ja) 2011-03-17

Similar Documents

Publication Publication Date Title
EP2243183B1 (en) Durable fuel cell membrane electrode assembly with combined additives
CN102318121B (zh) 具有多层阴极的燃料电池膜电极组件
JP6231588B2 (ja) 酸化セリウム添加物を有する高い耐久性の燃料電池構成要素
CN101297430B (zh) 具有铈盐添加剂的高耐久性燃料电池元件
US8092954B2 (en) Method of making a fuel cell polymer electrolyte membrane comprising manganese oxide
JP5676696B2 (ja) 耐久性のあるポリマー電解質薄膜を製造する方法
CN101023550A (zh) 燃料电池耐久性
US20110151353A1 (en) Fuel cell electrode with nanostructured catalyst and dispersed catalyst sublayer
WO2014105407A1 (en) Electrode and method of making the same

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant