CN101952036B - 用于制造碳纳米结构材料的方法 - Google Patents
用于制造碳纳米结构材料的方法 Download PDFInfo
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- CN101952036B CN101952036B CN200780045156XA CN200780045156A CN101952036B CN 101952036 B CN101952036 B CN 101952036B CN 200780045156X A CN200780045156X A CN 200780045156XA CN 200780045156 A CN200780045156 A CN 200780045156A CN 101952036 B CN101952036 B CN 101952036B
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- catalyst layer
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- carbon nanotubes
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/16—Preparation
- C01B32/162—Preparation characterised by catalysts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
- B01J21/185—Carbon nanotubes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/63—Platinum group metals with rare earths or actinides
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0217—Pretreatment of the substrate before coating
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- B01J37/0221—Coating of particles
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- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0225—Coating of metal substrates
- B01J37/0226—Oxidation of the substrate, e.g. anodisation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0238—Impregnation, coating or precipitation via the gaseous phase-sublimation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0244—Coatings comprising several layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
- B01J37/088—Decomposition of a metal salt
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
- B01J37/348—Electrochemical processes, e.g. electrochemical deposition or anodisation
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- B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
- B01J37/349—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of flames, plasmas or lasers
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- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- B82—NANOTECHNOLOGY
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- B82Y40/00—Manufacture or treatment of nanostructures
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- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
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- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
- D01F9/1273—Alkenes, alkynes
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/06—Multi-walled nanotubes
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
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- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/08—Aligned nanotubes
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- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/20—Nanotubes characterized by their properties
- C01B2202/34—Length
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/70—Nanostructure
- Y10S977/734—Fullerenes, i.e. graphene-based structures, such as nanohorns, nanococoons, nanoscrolls or fullerene-like structures, e.g. WS2 or MoS2 chalcogenide nanotubes, planar C3N4, etc.
- Y10S977/742—Carbon nanotubes, CNTs
- Y10S977/752—Multi-walled
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- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Nanotechnology (AREA)
- Thermal Sciences (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Toxicology (AREA)
- General Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Plasma & Fusion (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Composite Materials (AREA)
- Optics & Photonics (AREA)
- Manufacturing & Machinery (AREA)
- Electrochemistry (AREA)
- Inorganic Chemistry (AREA)
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Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US86212306P | 2006-10-19 | 2006-10-19 | |
| US60/862,123 | 2006-10-19 | ||
| US11/734,143 US8753602B2 (en) | 2006-10-19 | 2007-04-11 | Composite catalyst and method for manufacturing carbon nanostructured materials |
| US11/734,143 | 2007-04-11 | ||
| PCT/US2007/079528 WO2008105936A2 (en) | 2006-10-19 | 2007-09-26 | Composite catalyst and method for manufacturing carbon nanostructured materials |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101952036A CN101952036A (zh) | 2011-01-19 |
| CN101952036B true CN101952036B (zh) | 2013-11-27 |
Family
ID=39318123
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200780045156XA Expired - Fee Related CN101952036B (zh) | 2006-10-19 | 2007-09-26 | 用于制造碳纳米结构材料的方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US8753602B2 (enExample) |
| EP (1) | EP2155384A2 (enExample) |
| JP (1) | JP5345061B2 (enExample) |
| CN (1) | CN101952036B (enExample) |
| WO (1) | WO2008105936A2 (enExample) |
Families Citing this family (74)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2195392A2 (en) * | 2007-10-03 | 2010-06-16 | Raytheon Company | Nanocomposite coating for reflection reduction |
| CN101597049B (zh) * | 2008-06-04 | 2011-11-09 | 清华大学 | 碳纳米管薄膜的制备方法 |
| FR2933237B1 (fr) * | 2008-06-25 | 2010-10-29 | Commissariat Energie Atomique | Architecture d'interconnexions horizontales a base de nanotubes de carbone. |
| RU2389550C1 (ru) * | 2008-09-22 | 2010-05-20 | Учреждение Российской академии наук Институт неорганической химии им. А.В. Николаева Сибирского отделения РАН | Способ получения нанесенного катализатора и способ получения углеродных нанотруб |
| WO2010043401A2 (en) | 2008-10-15 | 2010-04-22 | Martin Vorbach | Data processing device |
| CN101811658B (zh) * | 2009-02-20 | 2012-09-19 | 清华大学 | 碳纳米管阵列传感器及其制备方法 |
| EA028873B1 (ru) | 2009-04-17 | 2018-01-31 | СИРСТОУН ЭлЭлСи | Способ производства твердого углерода путем восстановления оксидов углерода |
| JP5783669B2 (ja) * | 2009-07-23 | 2015-09-24 | ニッタ株式会社 | 触媒金属微粒子形成方法 |
| CN101786617A (zh) * | 2010-03-18 | 2010-07-28 | 北京富纳特创新科技有限公司 | 碳纳米管阵列结构及其制备方法 |
| TWI469919B (zh) * | 2010-03-26 | 2015-01-21 | Beijing Funate Innovation Tech | 奈米碳管陣列結構及其製備方法 |
| JP5660804B2 (ja) * | 2010-04-30 | 2015-01-28 | 東京エレクトロン株式会社 | カーボンナノチューブの形成方法及びカーボンナノチューブ成膜装置 |
| CA2712051A1 (en) * | 2010-08-12 | 2012-02-12 | The Governors Of The University Of Alberta | Method of fabricating a carbon nanotube array |
| JP5649901B2 (ja) * | 2010-10-06 | 2015-01-07 | 川研ファインケミカル株式会社 | 多層カーボンナノチューブ集合体及びその製造方法 |
| CN102005302A (zh) * | 2010-10-19 | 2011-04-06 | 吉首大学 | 染料敏化外负载TiO2/(PPA-Pt)surf.薄膜电极及其制备工艺 |
| JP5775705B2 (ja) * | 2011-02-25 | 2015-09-09 | 東京エレクトロン株式会社 | カーボンナノチューブの形成方法及び前処理方法 |
| JP5622278B2 (ja) * | 2011-03-31 | 2014-11-12 | 日本ゼオン株式会社 | カーボンナノチューブ配向集合体製造用基材、カーボンナノチューブ配向集合体の製造方法、及びカーボンナノチューブ配向集合体製造用基材の製造方法 |
| JP5779439B2 (ja) | 2011-07-29 | 2015-09-16 | 東京エレクトロン株式会社 | 前処理方法及びカーボンナノチューブの形成方法 |
| MX354526B (es) | 2012-04-16 | 2018-03-07 | Seerstone Llc | Metodos y sistemas para capturar y secuestrar carbono y para reducir la masa de oxidos de carbono en una corriente de gas de desechos. |
| US9090472B2 (en) | 2012-04-16 | 2015-07-28 | Seerstone Llc | Methods for producing solid carbon by reducing carbon dioxide |
| JP2015520717A (ja) * | 2012-04-16 | 2015-07-23 | シーアストーン リミテッド ライアビリティ カンパニー | 炭素酸化物触媒変換器中で金属触媒を使用するための方法 |
| JP6379085B2 (ja) | 2012-04-16 | 2018-08-22 | シーアストーン リミテッド ライアビリティ カンパニー | 炭素酸化物を含有するオフガスを処理するための方法 |
| NO2749379T3 (enExample) | 2012-04-16 | 2018-07-28 | ||
| MX2014012548A (es) | 2012-04-16 | 2015-04-10 | Seerstone Llc | Metodos y estructuras para reducir oxidos de carbono con catalizadores no ferrosos. |
| US9896341B2 (en) | 2012-04-23 | 2018-02-20 | Seerstone Llc | Methods of forming carbon nanotubes having a bimodal size distribution |
| WO2013163493A1 (en) * | 2012-04-26 | 2013-10-31 | University Of Cincinnati | Catalyst composition and method for growing spinable carbon nanotube arrays |
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| MX2015000515A (es) | 2012-07-12 | 2015-10-12 | Seerstone Llc | Productos de carbono solido que comprenden nanotubos de carbono y metodos para su formación. |
| US10815124B2 (en) | 2012-07-12 | 2020-10-27 | Seerstone Llc | Solid carbon products comprising carbon nanotubes and methods of forming same |
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| WO2014071693A1 (zh) * | 2012-11-08 | 2014-05-15 | 北京大学 | 单壁碳纳米管的定位生长方法 |
| CN103803522B (zh) * | 2012-11-08 | 2015-06-17 | 北京大学 | 半导体性单壁碳纳米管的制备方法 |
| JP6389824B2 (ja) | 2012-11-29 | 2018-09-12 | シーアストーン リミテッド ライアビリティ カンパニー | 固体炭素材料を製造するための反応器および方法 |
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| WO2014151144A1 (en) | 2013-03-15 | 2014-09-25 | Seerstone Llc | Carbon oxide reduction with intermetallic and carbide catalysts |
| EP3114077A4 (en) | 2013-03-15 | 2017-12-27 | Seerstone LLC | Methods of producing hydrogen and solid carbon |
| US10086349B2 (en) | 2013-03-15 | 2018-10-02 | Seerstone Llc | Reactors, systems, and methods for forming solid products |
| ES3003919T3 (en) | 2013-03-15 | 2025-03-11 | Seerstone Llc | Systems for producing solid carbon by reducing carbon oxides |
| US10115844B2 (en) | 2013-03-15 | 2018-10-30 | Seerstone Llc | Electrodes comprising nanostructured carbon |
| JP5764236B2 (ja) * | 2014-05-01 | 2015-08-19 | 日東電工株式会社 | カーボンナノチューブ集合体の製造方法 |
| WO2015191897A1 (en) | 2014-06-11 | 2015-12-17 | Georgia Tech Research Corporation | Polymer-based nanostructured materials with tunable properties and methods of making thereof |
| WO2016004191A1 (en) | 2014-07-02 | 2016-01-07 | General Nano Llc | Method for making a catalyst metal substrate for growth of carbon nanotubes |
| WO2016019143A1 (en) | 2014-07-30 | 2016-02-04 | General Nano Llc | Carbon nanotube sheet structure and method for its making |
| CN105361977B (zh) * | 2014-08-26 | 2018-08-10 | 中国科学院苏州纳米技术与纳米仿生研究所 | 电阻式柔性透明关节部位电子皮肤及其制备方法和应用 |
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- 2007-09-26 WO PCT/US2007/079528 patent/WO2008105936A2/en not_active Ceased
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| WO2008105936A2 (en) | 2008-09-04 |
| WO2008105936A3 (en) | 2010-01-14 |
| US8753602B2 (en) | 2014-06-17 |
| US20140295098A1 (en) | 2014-10-02 |
| JP5345061B2 (ja) | 2013-11-20 |
| CN101952036A (zh) | 2011-01-19 |
| US9845243B2 (en) | 2017-12-19 |
| EP2155384A2 (en) | 2010-02-24 |
| US20080095695A1 (en) | 2008-04-24 |
| JP2010511580A (ja) | 2010-04-15 |
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