CN101945847B - 生产6-羟基己酸酯的方法 - Google Patents

生产6-羟基己酸酯的方法 Download PDF

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Publication number
CN101945847B
CN101945847B CN2009801053107A CN200980105310A CN101945847B CN 101945847 B CN101945847 B CN 101945847B CN 2009801053107 A CN2009801053107 A CN 2009801053107A CN 200980105310 A CN200980105310 A CN 200980105310A CN 101945847 B CN101945847 B CN 101945847B
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acid
process according
hydrogenation
aqueous phase
carbon atoms
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CN2009801053107A
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Chinese (zh)
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CN101945847A (zh
Inventor
R·平科斯
T·西尔希
G-D·特贝恩
R-H·菲舍尔
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BASF SE
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BASF SE
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/367—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by introduction of functional groups containing oxygen only in singly bound form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/01—Saturated compounds having only one carboxyl group and containing hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
    • C07C69/675—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids of saturated hydroxy-carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN2009801053107A 2008-02-15 2009-01-29 生产6-羟基己酸酯的方法 Expired - Fee Related CN101945847B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP08101692 2008-02-15
EP08101692.5 2008-02-15
PCT/EP2009/051000 WO2009100989A2 (de) 2008-02-15 2009-01-29 Verfahren zur herstellung von 6-hydroxycapronsäureestern

Publications (2)

Publication Number Publication Date
CN101945847A CN101945847A (zh) 2011-01-12
CN101945847B true CN101945847B (zh) 2013-07-10

Family

ID=40674192

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CN2009801053107A Expired - Fee Related CN101945847B (zh) 2008-02-15 2009-01-29 生产6-羟基己酸酯的方法

Country Status (9)

Country Link
US (1) US8183411B2 (enExample)
EP (1) EP2244996B2 (enExample)
JP (1) JP2011512339A (enExample)
KR (1) KR20100127782A (enExample)
CN (1) CN101945847B (enExample)
CA (1) CA2714574A1 (enExample)
ES (1) ES2393838T5 (enExample)
MY (1) MY148679A (enExample)
WO (1) WO2009100989A2 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8884076B2 (en) 2008-12-09 2014-11-11 Basf Se Method for preparing polymethylols
WO2010066673A2 (de) 2008-12-09 2010-06-17 Basf Se Verfahren zur herstellung von polymethylolen
MY155607A (en) 2009-01-12 2015-11-13 Basf Se Method for producing polymethylols
JP5586686B2 (ja) 2009-04-07 2014-09-10 ビーエーエスエフ ソシエタス・ヨーロピア １，６−ヘキサンジオールの製造方法
ES2421150T3 (es) 2009-04-07 2013-08-29 Basf Se Método para la preparación de 1,6-hexanodiol y caprolactona
CN102452919B (zh) * 2010-10-27 2014-10-01 中国石油化工股份有限公司 一种内酯催化氧化制备相应羟基酸的方法
PL227792B1 (pl) 2012-03-23 2018-01-31 Korzeniowski Waclaw Chemenergia Sposób otrzymywania estrów syntetycznych
JP6274573B2 (ja) * 2014-06-04 2018-02-07 宇部興産株式会社 カルボン酸並びにケトン及び／又はアルコールの製造方法
KR20220116501A (ko) * 2019-12-18 2022-08-23 바스프 에스이 시클로헥산올 및 시클로헥사논의 제조 방법
CN111892501A (zh) * 2020-07-15 2020-11-06 江西盛伟科技股份有限公司 一种6-羟基己酸甲酯的制备方法
CN112010753A (zh) * 2020-08-18 2020-12-01 青岛科技大学 一种6-羟基己酸酯的制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3772375A (en) * 1968-10-11 1973-11-13 Rhone Poulenc Sa Process for producing epsilon-hydroxycaproic acid
US6063958A (en) * 1998-12-22 2000-05-16 China Petrochemical Development Corporation Method of recovering adipic acid and 6-hydroxycaproic acid from waste solution of alkali metal salts of organic acids coming from the process of cyclohexane oxidation
CN1257470A (zh) * 1997-11-14 2000-06-21 巴斯福股份公司 制备1,6－己二醇和6－羟基己酸及其酯的方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1210785B (de) * 1963-11-27 1966-02-17 Basf Ag Verfahren zur Gewinnung von epsilon-Hydroxycapron-saeure
FR1505363A (fr) 1966-04-20 1967-12-15 Rhone Poulenc Sa Perfectionnement à la préparation des cycloalcanols et des mélanges cycloalcanols/cycloalcanones
FR1585375A (enExample) 1968-10-11 1970-01-16
JPS4815314B1 (enExample) * 1969-08-18 1973-05-14
US3848003A (en) * 1970-06-26 1974-11-12 Celanese Corp Hydrogenolysis of carboxylic acids with cobalt catalysts
US3752861A (en) * 1970-08-17 1973-08-14 Celanese Corp Production of hydroxy compounds by hydrogenolysis of buffered carboxylate salts
CA1049041A (en) 1972-11-23 1979-02-20 Stamicarbon B.V. Process for the preparation of cycloalkanones and/or cycloalkanols
US3933930A (en) * 1975-03-06 1976-01-20 Celanese Corporation Hexanediol from cyclohexane
DE3823695A1 (de) 1988-07-13 1990-01-18 Basf Ag Verfahren zur herstellung von 6-hydroxycapronsaeureestern
MY118128A (en) 1996-03-01 2004-09-30 Basf Ag The preparation of 1, 6-hexanediol and caprolactone
FR2757154B1 (fr) * 1996-12-12 2000-01-14 Rhone Poulenc Fibres Procede de preparation de diacides a partir des eaux de lavage des produits d'oxydation du cyclohexane
DE19738464A1 (de) 1997-09-03 1999-03-04 Basf Ag Verwendung von Formkörpern als Katalysator zur Herstellung von Caprolactam
FR2846652B1 (fr) 2002-10-30 2006-09-22 Rhodia Polyamide Intermediates Procede de fabrication d'acides carboxyliques
DE102009047193A1 (de) * 2009-11-26 2011-06-01 Basf Se Verfahren zur Herstellung von Diolen durch Hydrierung eines Carbonsäure enthaltenden Gemisches mittels Kobalt enthaltenden Katalysatoren

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3772375A (en) * 1968-10-11 1973-11-13 Rhone Poulenc Sa Process for producing epsilon-hydroxycaproic acid
CN1257470A (zh) * 1997-11-14 2000-06-21 巴斯福股份公司 制备1,6－己二醇和6－羟基己酸及其酯的方法
US6063958A (en) * 1998-12-22 2000-05-16 China Petrochemical Development Corporation Method of recovering adipic acid and 6-hydroxycaproic acid from waste solution of alkali metal salts of organic acids coming from the process of cyclohexane oxidation

Also Published As

Publication number Publication date
EP2244996B2 (de) 2015-11-11
EP2244996B1 (de) 2012-10-31
WO2009100989A2 (de) 2009-08-20
MY148679A (en) 2013-05-31
US20110015429A1 (en) 2011-01-20
CA2714574A1 (en) 2009-08-20
ES2393838T5 (es) 2016-03-02
KR20100127782A (ko) 2010-12-06
US8183411B2 (en) 2012-05-22
EP2244996A2 (de) 2010-11-03
JP2011512339A (ja) 2011-04-21
CN101945847A (zh) 2011-01-12
ES2393838T3 (es) 2012-12-28
WO2009100989A3 (de) 2009-11-19

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