CN101896267A - 混合型铁酸锰催化剂、其制备方法、以及使用该催化剂制备1,3-丁二烯的方法 - Google Patents
混合型铁酸锰催化剂、其制备方法、以及使用该催化剂制备1,3-丁二烯的方法 Download PDFInfo
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- CN101896267A CN101896267A CN2008801203190A CN200880120319A CN101896267A CN 101896267 A CN101896267 A CN 101896267A CN 2008801203190 A CN2008801203190 A CN 2008801203190A CN 200880120319 A CN200880120319 A CN 200880120319A CN 101896267 A CN101896267 A CN 101896267A
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- Prior art keywords
- catalyst
- butadiene
- manganese
- precursor
- preparing
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- 239000003054 catalyst Substances 0.000 title claims abstract description 122
- 239000011572 manganese Substances 0.000 title claims abstract description 106
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 title claims abstract description 92
- 229910052748 manganese Inorganic materials 0.000 title claims abstract description 88
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title claims abstract description 87
- 229910000859 α-Fe Inorganic materials 0.000 title claims abstract description 66
- 238000000034 method Methods 0.000 title claims abstract description 49
- 239000000203 mixture Substances 0.000 claims abstract description 60
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims abstract description 54
- 238000005839 oxidative dehydrogenation reaction Methods 0.000 claims abstract description 45
- 239000000376 reactant Substances 0.000 claims abstract description 38
- 238000000975 co-precipitation Methods 0.000 claims abstract description 22
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims abstract description 20
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 38
- 239000002243 precursor Substances 0.000 claims description 34
- 238000002360 preparation method Methods 0.000 claims description 31
- 239000002253 acid Substances 0.000 claims description 30
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 20
- 239000012692 Fe precursor Substances 0.000 claims description 19
- 238000006243 chemical reaction Methods 0.000 claims description 18
- 229910052742 iron Inorganic materials 0.000 claims description 17
- 239000007864 aqueous solution Substances 0.000 claims description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 238000002441 X-ray diffraction Methods 0.000 claims description 11
- 239000011949 solid catalyst Substances 0.000 claims description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000003595 mist Substances 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 229940044631 ferric chloride hexahydrate Drugs 0.000 claims description 4
- NQXWGWZJXJUMQB-UHFFFAOYSA-K iron trichloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].Cl[Fe+]Cl NQXWGWZJXJUMQB-UHFFFAOYSA-K 0.000 claims description 4
- CNFDGXZLMLFIJV-UHFFFAOYSA-L manganese(II) chloride tetrahydrate Chemical compound O.O.O.O.[Cl-].[Cl-].[Mn+2] CNFDGXZLMLFIJV-UHFFFAOYSA-L 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
- 229910000616 Ferromanganese Inorganic materials 0.000 claims description 3
- 229910002651 NO3 Inorganic materials 0.000 claims description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 3
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 claims description 3
- 229910021380 Manganese Chloride Inorganic materials 0.000 claims description 2
- GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 claims description 2
- NJQIFQZKRYNHTE-UHFFFAOYSA-L [Mn](=O)(=O)(Cl)Cl Chemical compound [Mn](=O)(=O)(Cl)Cl NJQIFQZKRYNHTE-UHFFFAOYSA-L 0.000 claims description 2
- 229940068911 chloride hexahydrate Drugs 0.000 claims description 2
- NSNHWTBQMQIDCF-UHFFFAOYSA-N dihydrate;hydrochloride Chemical compound O.O.Cl NSNHWTBQMQIDCF-UHFFFAOYSA-N 0.000 claims description 2
- VOAPTKOANCCNFV-UHFFFAOYSA-N hexahydrate;hydrochloride Chemical compound O.O.O.O.O.O.Cl VOAPTKOANCCNFV-UHFFFAOYSA-N 0.000 claims description 2
- SUOTZEJYYPISIE-UHFFFAOYSA-N iron(2+);dinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O SUOTZEJYYPISIE-UHFFFAOYSA-N 0.000 claims description 2
- HVENHVMWDAPFTH-UHFFFAOYSA-N iron(3+) trinitrate hexahydrate Chemical compound O.O.O.O.O.O.[Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HVENHVMWDAPFTH-UHFFFAOYSA-N 0.000 claims description 2
- SZQUEWJRBJDHSM-UHFFFAOYSA-N iron(3+);trinitrate;nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O SZQUEWJRBJDHSM-UHFFFAOYSA-N 0.000 claims description 2
- 235000002867 manganese chloride Nutrition 0.000 claims description 2
- 239000011565 manganese chloride Substances 0.000 claims description 2
- YMKHJSXMVZVZNU-UHFFFAOYSA-N manganese(2+);dinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YMKHJSXMVZVZNU-UHFFFAOYSA-N 0.000 claims description 2
- HBTFASPVVFSRRI-UHFFFAOYSA-N manganese(2+);dinitrate;hydrate Chemical compound O.[Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O HBTFASPVVFSRRI-UHFFFAOYSA-N 0.000 claims description 2
- ALIMWUQMDCBYFM-UHFFFAOYSA-N manganese(2+);dinitrate;tetrahydrate Chemical compound O.O.O.O.[Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ALIMWUQMDCBYFM-UHFFFAOYSA-N 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- MAJZZCVHPGUSPM-UHFFFAOYSA-N nitric acid nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.O[N+]([O-])=O MAJZZCVHPGUSPM-UHFFFAOYSA-N 0.000 claims description 2
- OYFUIMQYZOLBMZ-UHFFFAOYSA-J tetrachloromanganese Chemical compound Cl[Mn](Cl)(Cl)Cl OYFUIMQYZOLBMZ-UHFFFAOYSA-J 0.000 claims description 2
- ZUUZGQPEQORUEV-UHFFFAOYSA-N tetrahydrate;hydrochloride Chemical compound O.O.O.O.Cl ZUUZGQPEQORUEV-UHFFFAOYSA-N 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 7
- 239000012535 impurity Substances 0.000 abstract description 4
- 238000000605 extraction Methods 0.000 abstract description 2
- 238000000926 separation method Methods 0.000 abstract 2
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 229910052725 zinc Inorganic materials 0.000 description 15
- 239000011701 zinc Substances 0.000 description 15
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 14
- 239000012071 phase Substances 0.000 description 14
- 230000003197 catalytic effect Effects 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000012153 distilled water Substances 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 229910052596 spinel Inorganic materials 0.000 description 6
- 239000011029 spinel Substances 0.000 description 6
- 238000000197 pyrolysis Methods 0.000 description 5
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 5
- WGEATSXPYVGFCC-UHFFFAOYSA-N zinc ferrite Chemical compound O=[Zn].O=[Fe]O[Fe]=O WGEATSXPYVGFCC-UHFFFAOYSA-N 0.000 description 5
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 4
- 229910001308 Zinc ferrite Inorganic materials 0.000 description 4
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000012805 post-processing Methods 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000006356 dehydrogenation reaction Methods 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 238000002309 gasification Methods 0.000 description 3
- 239000011259 mixed solution Substances 0.000 description 3
- 239000013049 sediment Substances 0.000 description 3
- 238000007086 side reaction Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- IAQRGUVFOMOMEM-ARJAWSKDSA-N cis-but-2-ene Chemical compound C\C=C/C IAQRGUVFOMOMEM-ARJAWSKDSA-N 0.000 description 2
- 238000010960 commercial process Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000002779 inactivation Effects 0.000 description 2
- -1 iron ion Chemical class 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- BDJAEZRIGNCQBZ-UHFFFAOYSA-N methylcyclobutane Chemical compound CC1CCC1 BDJAEZRIGNCQBZ-UHFFFAOYSA-N 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229910017488 Cu K Inorganic materials 0.000 description 1
- 229910017541 Cu-K Inorganic materials 0.000 description 1
- PMPVIKIVABFJJI-UHFFFAOYSA-N Cyclobutane Chemical compound C1CCC1 PMPVIKIVABFJJI-UHFFFAOYSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 230000005260 alpha ray Effects 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- 235000013844 butane Nutrition 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- DKUYEPUUXLQPPX-UHFFFAOYSA-N dibismuth;molybdenum;oxygen(2-) Chemical class [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Mo].[Mo].[Bi+3].[Bi+3] DKUYEPUUXLQPPX-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
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- 239000007789 gas Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
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- 238000007210 heterogeneous catalysis Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 235000013847 iso-butane Nutrition 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 150000002696 manganese Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
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- 229910021645 metal ion Inorganic materials 0.000 description 1
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- 150000004706 metal oxides Chemical class 0.000 description 1
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- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/889—Manganese, technetium or rhenium
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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KR1020070129115A KR100888143B1 (ko) | 2007-12-12 | 2007-12-12 | 혼성 망간 페라이트 촉매, 이의 제조방법 및 이를 이용한1,3-부타디엔의 제조방법 |
KR10-2007-0129115 | 2007-12-12 | ||
PCT/KR2008/006568 WO2009075478A2 (en) | 2007-12-12 | 2008-11-07 | Mixed manganese ferrite catalysts, method of preparing thereof and method of preparing 1,3-butadiene using thereof |
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CN101896267A true CN101896267A (zh) | 2010-11-24 |
CN101896267B CN101896267B (zh) | 2014-03-12 |
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CN200880120319.0A Active CN101896267B (zh) | 2007-12-12 | 2008-11-07 | 混合型铁酸锰催化剂、其制备方法、以及使用该催化剂制备1,3-丁二烯的方法 |
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US (1) | US8674156B2 (zh) |
EP (1) | EP2219782B1 (zh) |
JP (1) | JP5467444B2 (zh) |
KR (1) | KR100888143B1 (zh) |
CN (1) | CN101896267B (zh) |
ES (1) | ES2519471T3 (zh) |
WO (1) | WO2009075478A2 (zh) |
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CN103831114A (zh) * | 2012-11-21 | 2014-06-04 | 上海华谊丙烯酸有限公司 | 铁酸盐催化剂、其制备方法和用途 |
CN104968434A (zh) * | 2012-12-06 | 2015-10-07 | 巴斯夫欧洲公司 | 用于将正丁烯氧化脱氢成丁二烯的催化剂和方法 |
CN105582954A (zh) * | 2014-10-24 | 2016-05-18 | 上海碧科清洁能源技术有限公司 | 一种固体氧化物催化剂及其制备方法和应用 |
CN108649239A (zh) * | 2018-05-14 | 2018-10-12 | 陕西科技大学 | 一种调控氧化物型电催化剂晶格应力的方法 |
CN112337490A (zh) * | 2020-11-10 | 2021-02-09 | 安徽舜禹水务股份有限公司 | 一种Mn-FeOCl材料制备及其催化降解水中孔雀石绿使用方法 |
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KR101713328B1 (ko) * | 2010-07-20 | 2017-03-08 | 에스케이이노베이션 주식회사 | 혼성 망간 페라이트가 코팅된 촉매, 이의 제조방법 및 이를 이용한 1,3-부타디엔의 제조방법 |
US20130217568A1 (en) * | 2012-02-20 | 2013-08-22 | Saudi Basic Industries Corporation | Oxidative dehydrogenation of olefins catalyst and methods of making and using the same |
CN102716754B (zh) * | 2012-07-12 | 2014-06-18 | 上海碧科清洁能源技术有限公司 | 一种用于流化床反应器的丁烯氧化脱氢制丁二烯催化剂及其制备方法和用途 |
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KR101953919B1 (ko) * | 2012-12-18 | 2019-03-04 | 에스케이이노베이션 주식회사 | 혼성 망간 페라이트 허니컴형 촉매, 이의 제조방법 및 이를 이용한 1,3-부타디엔의 제조방법 |
WO2014118194A2 (fr) | 2013-01-29 | 2014-08-07 | IFP Energies Nouvelles | Catalyseur comprenant des oxydes mixtes des éléments aluminium, zinc et manganèse et son utilisation en déshydrogenation |
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KR101933480B1 (ko) * | 2016-03-25 | 2018-12-31 | 주식회사 엘지화학 | 산화적 탈수소화 반응용 촉매 및 제조방법 |
WO2017171441A2 (ko) * | 2016-03-30 | 2017-10-05 | 주식회사 엘지화학 | 페라이트계 촉매, 이의 제조방법 및 이를 이용한 부타디엔의 제조방법 |
KR102115299B1 (ko) | 2016-06-07 | 2020-05-26 | 주식회사 엘지화학 | 산화적 탈수소화 반응 촉매 및 이의 제조방법 |
EP3957396A4 (en) | 2019-12-31 | 2022-09-14 | Lg Chem, Ltd. | METHOD FOR PRODUCING A CATALYST FOR OXIDIZING DEHYDROGENATION REACTION, CATALYST FOR OXIDIZING DEHYDROGENATION REACTION AND METHOD FOR PRODUCTION OF BUTADIENE USING THE SAME |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1972A (en) | 1841-02-10 | Joseph martin | ||
US4658074A (en) * | 1965-05-28 | 1987-04-14 | Petro-Tex Chemical Corporation | Catalytic oxidative dehydrogenation process |
US3420911A (en) * | 1967-01-27 | 1969-01-07 | Petro Tex Chem Corp | Oxidative dehydrogenation using zinc or cadmium ferrite |
US3567793A (en) * | 1967-09-28 | 1971-03-02 | Petro Tex Chem Corp | Oxidative dehydrogenation of organic compounds |
NL137292C (zh) * | 1968-05-21 | |||
US3671606A (en) * | 1969-10-02 | 1972-06-20 | Petro Tex Chem Corp | Oxidative dehydrogenation utilizing manganese ferrite |
US3743683A (en) * | 1970-06-11 | 1973-07-03 | Petro Tex Chem Corp | Oxidative dehydrogenation process |
US3900525A (en) * | 1972-05-16 | 1975-08-19 | Petro Tex Chem Corp | Manganese ferrite catalyzed oxidative dehydrogenation |
US3951869A (en) * | 1974-09-03 | 1976-04-20 | Petro-Tex Chemical Corporation | Modified zinc ferrite oxidative dehydrogenation catalysts |
US4097392A (en) * | 1975-03-25 | 1978-06-27 | Spang Industries, Inc. | Coprecipitation methods and manufacture of soft ferrite materials and cores |
US4372865A (en) * | 1980-09-26 | 1983-02-08 | Spang Industries, Inc. | Carbonate/hydroxide coprecipitation process |
AU707906B2 (en) * | 1994-12-14 | 1999-07-22 | Shell Internationale Research Maatschappij B.V. | Restructured iron oxide |
EP0797560B1 (en) * | 1994-12-14 | 1999-03-10 | Shell Internationale Researchmaatschappij B.V. | Large particle dehydrogenation catalyst and process |
JP3389170B2 (ja) * | 1999-10-12 | 2003-03-24 | ティーディーケイ株式会社 | NiMnZn系フェライト |
JP3707781B2 (ja) * | 2001-08-20 | 2005-10-19 | Tdk株式会社 | フェライトコアの製造方法 |
-
2007
- 2007-12-12 KR KR1020070129115A patent/KR100888143B1/ko active IP Right Grant
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2008
- 2008-11-07 WO PCT/KR2008/006568 patent/WO2009075478A2/en active Application Filing
- 2008-11-07 ES ES08859263.9T patent/ES2519471T3/es active Active
- 2008-11-07 CN CN200880120319.0A patent/CN101896267B/zh active Active
- 2008-11-07 EP EP08859263.9A patent/EP2219782B1/en active Active
- 2008-11-07 US US12/746,558 patent/US8674156B2/en active Active
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Cited By (10)
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CN103831114B (zh) * | 2012-11-21 | 2016-08-24 | 上海华谊丙烯酸有限公司 | 铁酸盐催化剂、其制备方法和用途 |
US9731280B2 (en) | 2012-11-21 | 2017-08-15 | Shanghai Huayi Acrylic Acid Co. Ltd. | Ferrite catalyst and preparation method thereof |
CN104968434A (zh) * | 2012-12-06 | 2015-10-07 | 巴斯夫欧洲公司 | 用于将正丁烯氧化脱氢成丁二烯的催化剂和方法 |
CN105582954A (zh) * | 2014-10-24 | 2016-05-18 | 上海碧科清洁能源技术有限公司 | 一种固体氧化物催化剂及其制备方法和应用 |
CN105582954B (zh) * | 2014-10-24 | 2018-04-17 | 上海碧科清洁能源技术有限公司 | 一种固体氧化物催化剂及其制备方法和应用 |
CN108649239A (zh) * | 2018-05-14 | 2018-10-12 | 陕西科技大学 | 一种调控氧化物型电催化剂晶格应力的方法 |
CN108649239B (zh) * | 2018-05-14 | 2021-06-15 | 陕西科技大学 | 一种调控氧化物型电催化剂晶格应力的方法 |
CN112337490A (zh) * | 2020-11-10 | 2021-02-09 | 安徽舜禹水务股份有限公司 | 一种Mn-FeOCl材料制备及其催化降解水中孔雀石绿使用方法 |
CN112337490B (zh) * | 2020-11-10 | 2023-06-02 | 安徽舜禹水务股份有限公司 | 一种Mn-FeOCl材料制备及其催化降解水中孔雀石绿使用方法 |
Also Published As
Publication number | Publication date |
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JP5467444B2 (ja) | 2014-04-09 |
EP2219782A4 (en) | 2011-05-11 |
ES2519471T3 (es) | 2014-11-07 |
WO2009075478A2 (en) | 2009-06-18 |
EP2219782A2 (en) | 2010-08-25 |
CN101896267B (zh) | 2014-03-12 |
US8674156B2 (en) | 2014-03-18 |
KR100888143B1 (ko) | 2009-03-13 |
JP2011518649A (ja) | 2011-06-30 |
EP2219782B1 (en) | 2014-07-23 |
US20100280300A1 (en) | 2010-11-04 |
WO2009075478A3 (en) | 2009-08-13 |
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