CN101817916B - 抗疲劳聚氨酯泡沫及其制备方法 - Google Patents
抗疲劳聚氨酯泡沫及其制备方法 Download PDFInfo
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- CN101817916B CN101817916B CN2010101477452A CN201010147745A CN101817916B CN 101817916 B CN101817916 B CN 101817916B CN 2010101477452 A CN2010101477452 A CN 2010101477452A CN 201010147745 A CN201010147745 A CN 201010147745A CN 101817916 B CN101817916 B CN 101817916B
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- 230000002929 anti-fatigue Effects 0.000 title claims abstract description 19
- 239000006260 foam Substances 0.000 title abstract description 12
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 title abstract description 9
- 238000002360 preparation method Methods 0.000 title description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 45
- 229920000570 polyether Polymers 0.000 claims abstract description 45
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 239000003054 catalyst Substances 0.000 claims abstract description 10
- 239000006261 foam material Substances 0.000 claims abstract description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 64
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 32
- 239000000463 material Substances 0.000 claims description 22
- 229920002635 polyurethane Polymers 0.000 claims description 18
- 239000004814 polyurethane Substances 0.000 claims description 16
- 150000002334 glycols Chemical class 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000004902 Softening Agent Substances 0.000 claims description 10
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 9
- 229920002545 silicone oil Polymers 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000012986 modification Methods 0.000 claims description 5
- 230000004048 modification Effects 0.000 claims description 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 4
- 238000007334 copolymerization reaction Methods 0.000 claims description 3
- 150000002009 diols Chemical class 0.000 claims description 3
- 229920001519 homopolymer Polymers 0.000 claims description 3
- 239000002075 main ingredient Substances 0.000 claims description 3
- 229920001451 polypropylene glycol Polymers 0.000 claims description 3
- 229920000909 polytetrahydrofuran Polymers 0.000 claims description 3
- 238000009661 fatigue test Methods 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 4
- 229920005862 polyol Polymers 0.000 abstract description 3
- 150000003077 polyols Chemical class 0.000 abstract description 3
- 150000001412 amines Chemical class 0.000 abstract description 2
- 125000005442 diisocyanate group Chemical group 0.000 abstract description 2
- 238000013012 foaming technology Methods 0.000 abstract description 2
- 239000002131 composite material Substances 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 7
- 208000037656 Respiratory Sounds Diseases 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- 239000012774 insulation material Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 1
- 125000006736 (C6-C20) aryl group Chemical group 0.000 description 1
- 125000000041 C6-C10 aryl group Chemical group 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical group NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 210000003195 fascia Anatomy 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical group NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
GEP 330NY,重量份 | 50 | 60 | 70 |
NC 701,重量份 | 50 | 40 | 30 |
二乙醇胺,重量份 | 1.0 | 1.1 | 1.2 |
防冻剂,重量份 | 0.8 | 1.0 | 1.0 |
拉力剂,重量份 | 0.8 | 1.1 | 1.2 |
柔软剂,重量份 | 0.6 | 0.6 | 0.7 |
复合胺催化剂,重量份 | 0.8 | 0.85 | 0.9 |
硅油3415,重量份 | 1.0 | 1.1 | 1.2 |
水,重量份 | 1.9 | 2.0 | 2.2 |
序号 | 测试项目 | 技术标准 |
1 | 性能疲劳实验(水平方向 30000次) | -30℃低温下30000次后 不允许出现明显裂纹、断 裂、褶皱和变形 |
1.1 | 性能疲劳实验(左倾方向 30000次) | -30℃低温下30000次后 不允许出现明显裂纹、断 裂、褶皱和变形 |
1.2 | 性能疲劳实验(右倾方向 30000次) | -30℃低温下30000次后 不允许出现明显裂纹、断 裂、褶皱和变形 |
Claims (19)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN2010101477452A CN101817916B (zh) | 2010-04-15 | 2010-04-15 | 抗疲劳聚氨酯泡沫及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN2010101477452A CN101817916B (zh) | 2010-04-15 | 2010-04-15 | 抗疲劳聚氨酯泡沫及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN101817916A CN101817916A (zh) | 2010-09-01 |
CN101817916B true CN101817916B (zh) | 2012-07-04 |
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CN2010101477452A Expired - Fee Related CN101817916B (zh) | 2010-04-15 | 2010-04-15 | 抗疲劳聚氨酯泡沫及其制备方法 |
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CN (1) | CN101817916B (zh) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102794849B (zh) * | 2012-08-28 | 2015-07-01 | 北京汽车研究总院有限公司 | 用于安全气囊标定的快速成型仪表台样件制作方法 |
CN105566600A (zh) * | 2015-12-16 | 2016-05-11 | 芜湖馨源海绵有限公司 | 具有极好的抗疲劳性的海绵及其制备工艺 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3741917A (en) * | 1970-10-26 | 1973-06-26 | Union Carbide Corp | Cold cure high resilience foam |
JPS6236420A (ja) * | 1985-08-09 | 1987-02-17 | Human Ind Corp | ウレタンフオ−ムの製造方法 |
US5510054A (en) * | 1995-06-29 | 1996-04-23 | Dow Italia S.P.A. | Polyurethane elastomer and foam exhibiting improved abrasion resistance |
EP1178061A1 (en) * | 2000-08-01 | 2002-02-06 | Huntsman International Llc | Process for preparing a polyurethane material |
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2010
- 2010-04-15 CN CN2010101477452A patent/CN101817916B/zh not_active Expired - Fee Related
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Publication number | Publication date |
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CN101817916A (zh) | 2010-09-01 |
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Owner name: SHANGHAI HUATE AUTOMOBILE FITTINGS CO., LTD. Free format text: FORMER OWNER: SHANGHAI ZIYUAN AUTOMOBILE COMPONENTS AND PARTS CO., LTD. Effective date: 20131031 |
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C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20131031 Address after: Jiading District Anting Town, Shanghai City, 201805 Road No. 3555 Patentee after: SHANGHAI HUATE AUTOMOTIVE PARTS Co.,Ltd. Address before: 201805 Shanghai Jiading District city Anting Town Park Road No. 1388 Patentee before: SHANGHAI ZIYUAN AUTOMOBILE PARTS Co.,Ltd. |
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CP01 | Change in the name or title of a patent holder |
Address after: 201805 3555 Jia An Road, Anting Town, Jiading District, Shanghai Patentee after: SHANGHAI HUATE ENTERPRISE GROUP CO.,LTD. Address before: 201805 3555 Jia An Road, Anting Town, Jiading District, Shanghai Patentee before: SHANGHAI HUATE AUTOMOTIVE PARTS Co.,Ltd. |
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CP01 | Change in the name or title of a patent holder | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120704 |
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CF01 | Termination of patent right due to non-payment of annual fee |