CN101773129A - Compound insecticidal main agent of destruxins and matrine and compound insecticide - Google Patents
Compound insecticidal main agent of destruxins and matrine and compound insecticide Download PDFInfo
- Publication number
- CN101773129A CN101773129A CN201019050022A CN201019050022A CN101773129A CN 101773129 A CN101773129 A CN 101773129A CN 201019050022 A CN201019050022 A CN 201019050022A CN 201019050022 A CN201019050022 A CN 201019050022A CN 101773129 A CN101773129 A CN 101773129A
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- China
- Prior art keywords
- destruxins
- matrine
- weight
- agent
- compound
- Prior art date
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- ZSBXGIUJOOQZMP-UHFFFAOYSA-N Isomatrine Natural products C1CCC2CN3C(=O)CCCC3C3C2N1CCC3 ZSBXGIUJOOQZMP-UHFFFAOYSA-N 0.000 title claims abstract description 68
- 229930014456 matrine Natural products 0.000 title claims abstract description 68
- ZSBXGIUJOOQZMP-JLNYLFASSA-N Matrine Chemical compound C1CC[C@H]2CN3C(=O)CCC[C@@H]3[C@@H]3[C@H]2N1CCC3 ZSBXGIUJOOQZMP-JLNYLFASSA-N 0.000 title claims abstract description 66
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 54
- 239000002917 insecticide Substances 0.000 title claims abstract description 23
- 150000001875 compounds Chemical class 0.000 title claims abstract description 17
- 230000000749 insecticidal effect Effects 0.000 title claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 64
- 239000000839 emulsion Substances 0.000 claims abstract description 13
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 9
- 239000000126 substance Substances 0.000 claims abstract description 9
- 235000013311 vegetables Nutrition 0.000 claims abstract description 6
- 239000000575 pesticide Substances 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 9
- 239000000375 suspending agent Substances 0.000 claims description 7
- 241000238631 Hexapoda Species 0.000 claims description 5
- 238000009736 wetting Methods 0.000 claims description 5
- 239000010231 banlangen Substances 0.000 claims description 4
- 241001124076 Aphididae Species 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 6
- 241001600408 Aphis gossypii Species 0.000 abstract description 4
- 241000607479 Yersinia pestis Species 0.000 abstract description 4
- 239000012752 auxiliary agent Substances 0.000 abstract description 3
- 239000000243 solution Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 239000004563 wettable powder Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 49
- 238000009472 formulation Methods 0.000 description 39
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 27
- 239000002904 solvent Substances 0.000 description 21
- 239000003381 stabilizer Substances 0.000 description 18
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 16
- -1 matrine compound Chemical class 0.000 description 16
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 15
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 14
- 150000004996 alkyl benzenes Chemical class 0.000 description 14
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
- 230000003750 conditioning effect Effects 0.000 description 11
- 239000006184 cosolvent Substances 0.000 description 11
- 238000006303 photolysis reaction Methods 0.000 description 11
- 239000004094 surface-active agent Substances 0.000 description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- 239000011734 sodium Substances 0.000 description 10
- 229910052708 sodium Inorganic materials 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 239000002562 thickening agent Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 239000003995 emulsifying agent Substances 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
- 235000019198 oils Nutrition 0.000 description 8
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 6
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 6
- 150000002170 ethers Chemical class 0.000 description 6
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 6
- 229960005235 piperonyl butoxide Drugs 0.000 description 6
- 239000003549 soybean oil Substances 0.000 description 6
- 235000012424 soybean oil Nutrition 0.000 description 6
- 239000000080 wetting agent Substances 0.000 description 6
- 125000000129 anionic group Chemical group 0.000 description 5
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 5
- 229940077388 benzenesulfonate Drugs 0.000 description 5
- 239000004359 castor oil Substances 0.000 description 5
- 235000019438 castor oil Nutrition 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 5
- 150000002576 ketones Chemical class 0.000 description 5
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- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 4
- 240000002045 Guettarda speciosa Species 0.000 description 4
- 235000001287 Guettarda speciosa Nutrition 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000000908 ammonium hydroxide Substances 0.000 description 4
- 239000000440 bentonite Substances 0.000 description 4
- 229910000278 bentonite Inorganic materials 0.000 description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 4
- 210000000481 breast Anatomy 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 238000009313 farming Methods 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 240000006240 Linum usitatissimum Species 0.000 description 3
- 235000004431 Linum usitatissimum Nutrition 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- 239000004283 Sodium sorbate Substances 0.000 description 3
- 239000003905 agrochemical Substances 0.000 description 3
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 3
- 125000005910 alkyl carbonate group Chemical group 0.000 description 3
- 229960004050 aminobenzoic acid Drugs 0.000 description 3
- 238000005660 chlorination reaction Methods 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 3
- 235000004426 flaxseed Nutrition 0.000 description 3
- 239000003502 gasoline Substances 0.000 description 3
- 239000003350 kerosene Substances 0.000 description 3
- 239000010721 machine oil Substances 0.000 description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 3
- 230000000149 penetrating effect Effects 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- LROWVYNUWKVTCU-STWYSWDKSA-M sodium sorbate Chemical compound [Na+].C\C=C\C=C\C([O-])=O LROWVYNUWKVTCU-STWYSWDKSA-M 0.000 description 3
- 235000019250 sodium sorbate Nutrition 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- 150000003462 sulfoxides Chemical class 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical compound CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 description 2
- YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical compound CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 description 2
- CUFXMPWHOWYNSO-UHFFFAOYSA-N 2-[(4-methylphenoxy)methyl]oxirane Chemical compound C1=CC(C)=CC=C1OCC1OC1 CUFXMPWHOWYNSO-UHFFFAOYSA-N 0.000 description 2
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 2
- YPDQOJJHZWMGKY-UHFFFAOYSA-N C1(=CC=CC=C1)O.C(C1=CC=CC=C1)C1=C(C=CC=C1)C1=CC=CC=C1 Chemical compound C1(=CC=CC=C1)O.C(C1=CC=CC=C1)C1=C(C=CC=C1)C1=CC=CC=C1 YPDQOJJHZWMGKY-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 159000000013 aluminium salts Chemical class 0.000 description 2
- 229910000329 aluminium sulfate Inorganic materials 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229960003639 laurocapram Drugs 0.000 description 2
- 229920005610 lignin Polymers 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- AOBIOSPNXBMOAT-UHFFFAOYSA-N 2-[2-(oxiran-2-ylmethoxy)ethoxymethyl]oxirane Chemical compound C1OC1COCCOCC1CO1 AOBIOSPNXBMOAT-UHFFFAOYSA-N 0.000 description 1
- XVPBINOPNYFXID-JARXUMMXSA-N 85u4c366qs Chemical compound C([C@@H]1CCC[N@+]2(CCC[C@H]3[C@@H]21)[O-])N1[C@@H]3CCCC1=O XVPBINOPNYFXID-JARXUMMXSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 241000255789 Bombyx mori Species 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 241000258937 Hemiptera Species 0.000 description 1
- 241000256602 Isoptera Species 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 241000223250 Metarhizium anisopliae Species 0.000 description 1
- 241000238814 Orthoptera Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 240000003377 Shepherdia canadensis Species 0.000 description 1
- 235000018324 Shepherdia canadensis Nutrition 0.000 description 1
- 241000246044 Sophora flavescens Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229940095054 ammoniac Drugs 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000975 bioactive effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000000035 biogenic effect Effects 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
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- 230000002538 fungal effect Effects 0.000 description 1
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- 210000000087 hemolymph Anatomy 0.000 description 1
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a compound insecticidal main agent of destruxins and matrine and a compound insecticide. The compound insecticide comprises a main agent and an auxiliary agent, wherein the weight percentage content of the main agent is 1 to 30 percent and the weight percentage content of the auxiliary agent is 70 to 99 percent. The compound insecticidal main agent is a mixture prepared from the destruxins and the matrine in a weight ratio of 1:0.25-50. The destruxins is a pure substance or a mixture containing destruxins A, B, C, D and E, and the matrine is a pure substance or a mixture containing total matrines. The compound insecticide can be processed into emulsifiable solution, wettable powder, micro-emulsions, suspension emulsions or aqueous emulsions and the like. The compound insecticide is used for controlling vegetable foliar pests, in particular for controlling cotton aphids, and the effect is very remarkable.
Description
Technical field
The invention belongs to the insecticide technical field, relate to a kind of new and effective biological insecticides, relate in particular to the compound insecticidal host and the insecticide of a kind of destruxins and matrine.
Background technology
The crop diseases and pest disaster is grave danger of agricultural production, and applying pesticides is the major measure of prevention and elimination of disease and pests, yet long-term single dependence chemical pesticide has caused pesticide resistance, wildness and residual toxicity etc. " 3R " side effect again.Development of new biogenic pesticide and reasonable mixed insecticide are the Critical policies that overcomes " 3R " side effect.
Destruxins (destruxins, dtx) fungal source antibiotic, mainly produce by entomogenous fungi-Metarhizium anisopliae Metarhizium anisopliae, belong to and encircle the carboxylic peptides that contracts, mainly act on the hemolymph immune system of insect, 20 various pests of Lepidoptera, Homoptera, diptera, Isoptera, orthoptera and coleoptera are had effects such as poisoning, food refusal, repellent and growth inhibition.Since bioactive diversity and the uniqueness of mechanism of action, destruxins more and more demonstrates the potentiality as the new bio insecticide.Destruxins is still unregistered at present is agricultural chemicals.
Matrine is a kind of agricultural chemical of natural plant, and its effective ingredient is a Banlangen, based on matrine, oxymatrine, can extract from root, cauline leaf or the fruit of kuh-seng (Sophora flavescens Ait.).Matrine can with insecticide mixtures such as pyrethroid, organic phosphates, be mainly used in control vegetables blade face insect.Do not see at present the correlation technique report of destruxins and matrine mixture preparation.
Summary of the invention
An object of the present invention is to remedy the deficiency of existing plant pesticide, a kind of new and effective biological insecticides are provided, promptly destruxins and matrine compound desinsection host and insecticide reduce " 3R " side effect of agricultural chemicals.
Goal of the invention of the present invention is achieved by following technical proposals:
Provide the compound insecticidal host of a kind of destruxins and matrine, for destruxins and matrine mix the mixture that obtains according to 1: 0.25～50 part by weight.
The present invention provides the compounded pesticides of destruxins and matrine simultaneously, comprises host and assistant agent, is host with above-mentioned destruxins and matrine mixture, and the weight percentage of host and assistant agent is respectively 1～30% and 70～99%.
Preferably, the host part by weight that is mixed is a destruxins: matrine=(1～8): (9～2); More preferred ratio is a destruxins: matrine=5: 5 or 3: 7 or 2: 8.
Described destruxins is pure substance or the mixture that contains destruxins A, B, C, D, E, and described matrine is pure substance or the mixture that contains Banlangen.
Described assistant agent changes because of the processing formulation is different, and this compounded pesticides (being called for short preparation down) can be processed into preparations such as missible oil, wetting powder, microemulsion, suspending agent, suspended emulsion or aqueous emulsion.
When being processed into missible oil, use assistant agent to be:
(1) the surfactant comprise preparation by weight 5～70%, surfactant is the sodium alkyl sulfate or in the alkyl benzene sulfonate one or more of polyethenoxy ether class, the anionic of nonionic, use when multiple, total usage amount can not be greater than the maximum of surfactant comprise weight of formulation part;
(2) solvent accounts for preparation by weight 25～80%, solvent is various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers, in available benzene,toluene,xylene, naphthalane, gasoline, kerosene, machine oil, MEK, propylene glycol, butyl glycol ether, carrene or the benzinum one or more, use when multiple, total usage amount can not account for the maximum of weight of formulation part greater than solvent;
(3) cosolvent accounts for preparation by weight 5～20%, and cosolvent is one or more in methyl alcohol, isoamyl alcohol, phenol, ethyl acetate or the dimethyl sulfoxide (DMSO), uses when multiple, and total usage amount can not account for the maximum of weight of formulation part greater than cosolvent;
(4) pH value conditioning agent accounts for preparation by weight 0.5～1%, and pH value conditioning agent is one or more in sodium hydroxide, ammonium hydroxide, acetic acid, the hydrochloric acid, uses when multiple, and total usage amount can not account for the maximum of weight of formulation part greater than pH value conditioning agent;
(5) synergist accounts for preparation by weight 0.5～25%, and synergist is one or more in Butacide, sulfoxide, alkyl carbonate, chlorination fat or the formaldehyde, uses when multiple, and total usage amount can not account for the maximum of weight of formulation part greater than synergist;
(6) anti-photodissociation agent accounts for preparation by weight 0.5～15%, and anti-photodissociation agent is one or more in p-aminobenzoic acid, castor oil or the Angelica oil, uses when multiple, and total usage amount can not account for the maximum of weight of formulation part greater than anti-photodissociation agent;
(7) the stabilizer comprises preparation by weight 0.5～15%, stabilizing agent is one or more in citric acid, boric acid, phosphoric acid, sal-ammoniac and sulfate of ammoniac, epoxidized soybean oil or the epoxidized linseed, use when multiple, total usage amount can not be greater than the maximum of stabilizer comprises weight of formulation part;
(8) penetrating agent accounts for preparation by weight 0.5～2%, and penetrating agent is one or more in Laurocapram, JFC-2 or the maleic acid di-sec-octyl sodium sulfonate, uses when multiple, and total usage amount can not account for the maximum of weight of formulation part greater than penetrating agent.
Or when being processed into wetting powder, its assistant agent is:
(1) wetting agent accounts for preparation by weight 5～35%, wetting agent is natural products wetting agent and anionic wetting agent, available tea is withered, spaonin powder, soapberry powder, silkworm excrement, bay alcohol radical sodium sulphate, neopelex, washing powder or draw back in the powder one or more, use when multiple, total usage amount can not account for the maximum of weight of formulation part greater than wetting agent;
(2) dispersant accounts for preparation by weight 5～30%, dispersant is industrial by-products and anionic dispersing agent, in available lignosulfite, lignin and derivative sulfonate, naphthalene and alkylbenzene formaldehyde condensation products sulfonate or the alkylsulfonate one or more, use when multiple, total usage amount can not account for the maximum of weight of formulation part greater than dispersant;
(3) filler accounts for preparation by weight 20～90%, filler is mineral type carrier or synthetic vectors, in available kaolin, diatomite, bentonite, attapulgite, calcium carbonate, sodium bicarbonate or the white carbon one or more, use when multiple, total usage amount can not account for the maximum of weight of formulation part greater than filler.
Or when being processed into microemulsion, its assistant agent is:
(1) solvent accounts for preparation by weight 10～90%, and solvent is one or more in alcohols, ketone, ester class or the aromatic hydrocarbon, uses when multiple, and total usage amount can not account for the maximum of weight of formulation part greater than solvent;
(2) emulsifier accounts for preparation by weight 10～40%, emulsifier is an alkyl benzene sulfonate calcium salt, the alkyl benzene sulphonate magnesium salts, alkyl benzene sulphonate aluminium salt, the alkyl benzene sulphonate sodium salt, the alkyl benzene sulphonate barium salt, C8～C20 alkylsurfuric acid sodium salt, styrene polyoxyethylene ether ammonium sulfate salt, the benzylbiphenyl phenol polyethenoxy ether, phenethyl phenol polyethenoxy (N=15～30) ether, phenethyl phenol polyethenoxy polyoxypropylene, polyoxyethylene nonylphenol ether, alkylphenol polyoxyethylene first condensation product, the xenol APEO, in No. 300, homemade Nongru-700 number or the homemade farming breast one or more, use when multiple, total usage amount can not account for the maximum of weight of formulation part greater than emulsifier;
(3) the stabilizer comprises preparation by weight 0.5～15%, stabilizing agent is a 3-chloro-1, in 2-expoxy propane, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyvinyl-glycol diglycidyl ether, the sodium sorbate one or more, use when multiple, total usage amount can not be greater than the maximum of stabilizer comprises weight of formulation part;
(4) antifreezing agent accounts for preparation by weight 0.5～10%, and antifreezing agent is one or more in ethylene glycol, glycerine, propane diols, polyethylene glycol or the sorb sodium alkoxide, uses when multiple, and total usage amount can not account for the maximum of weight of formulation part greater than antifreezing agent; Water with surplus.
Or when being processed into suspending agent, its assistant agent is:
(1) the surfactant comprise preparation by weight 5～70%, surfactant is the polyethenoxy ether class of nonionic, or the sodium alkyl sulfate of anionic or in the alkyl benzene sulfonate one or more, use when multiple, total usage amount can not be greater than the maximum of surfactant comprise weight of formulation part; With
(2) solvent accounts for preparation by weight 25～80%, solvent is various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers, in available benzene,toluene,xylene, naphthalane, gasoline, kerosene, machine oil, MEK, propylene glycol, butyl glycol ether or the benzinum one or more, use when multiple, total usage amount can not account for the maximum of weight of formulation part greater than solvent;
(3) cosolvent accounts for preparation by weight 5～20%, and cosolvent is one or more in methyl alcohol, isoamyl alcohol, phenol, ethyl acetate or the dimethyl sulfoxide (DMSO), uses when multiple, and total usage amount can not account for the maximum of weight of formulation part greater than cosolvent;
(4) pH value conditioning agent accounts for preparation by weight 0.5～1%, and pH value conditioning agent is one or more in sodium hydroxide, ammonium hydroxide, acetic acid or the hydrochloric acid, uses when multiple, and total usage amount can not account for the maximum of weight of formulation part greater than pH value conditioning agent;
(5) synergist accounts for preparation by weight 0.5～25%, and synergist is one or more in Butacide, sulfoxide, alkyl carbonate, chlorination fat or the formaldehyde, uses when multiple, and total usage amount can not account for the maximum of weight of formulation part greater than synergist;
(6) anti-photodissociation agent accounts for preparation by weight 0.5～15%, and anti-photodissociation agent is one or more in p-aminobenzoic acid, castor oil or the Angelica oil, uses when multiple, and total usage amount can not account for the maximum of weight of formulation part greater than anti-photodissociation agent;
(7) the stabilizer comprises preparation by weight 0.5～15%, and stabilizing agent is one or more in epoxidized soybean oil or the epoxidized linseed, uses when multiple, and total usage amount can not be greater than the maximum of stabilizer comprises weight of formulation part;
(8) thickener accounts for preparation by weight 0.1～10%, and thickener is one or more in silica or the bentonite, uses when multiple, and total usage amount can not account for the maximum of weight of formulation part greater than thickener.
Or when being processed into suspended emulsion, its auxiliary agent is:
(1) the surfactant comprise preparation by weight 5～70%, surfactant is the sodium alkyl sulfate or in the alkyl benzene sulfonate one or more of polyethenoxy ether class, the anionic of nonionic, use when multiple, total usage amount can not be greater than the maximum of surfactant comprise weight of formulation part;
(2) solvent accounts for preparation by weight 25～80%, solvent is various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers, in available benzene,toluene,xylene, naphthalane, gasoline, kerosene, machine oil, MEK, propylene glycol, butyl glycol ether or the benzinum one or more, use when multiple, total usage amount can not account for the maximum of weight of formulation part greater than solvent;
(3) cosolvent accounts for preparation by weight 5～20%, and cosolvent is one or more in methyl alcohol, isoamyl alcohol, phenol, ethyl acetate or the dimethyl sulfoxide (DMSO), uses when multiple, and total usage amount can not account for the maximum of weight of formulation part greater than cosolvent;
(4) pH value conditioning agent accounts for preparation by weight 0.5～1%, and pH value conditioning agent is one or more in sodium hydroxide, ammonium hydroxide, acetic acid or the hydrochloric acid, uses when multiple, and total usage amount can not account for the maximum of weight of formulation part greater than pH value conditioning agent;
(5) synergist accounts for preparation by weight 0.5～25%, and synergist is one or more in Butacide, sulfoxide, alkyl carbonate, chlorination fat or the formaldehyde, uses when multiple, and total usage amount can not account for the maximum of weight of formulation part greater than synergist;
(6) anti-photodissociation agent accounts for preparation by weight 0.5～15%, and anti-photodissociation agent is one or more in p-aminobenzoic acid, castor oil or the Angelica oil, uses when multiple, and total usage amount can not account for the maximum of weight of formulation part greater than anti-photodissociation agent;
(7) the stabilizer comprises preparation by weight 0.5～15%, and stabilizing agent is one or more in epoxidized soybean oil or the epoxidized linseed, uses when multiple, and total usage amount can not be greater than the maximum of stabilizer comprises weight of formulation part;
(8) thickener accounts for preparation by weight 0.1～10%, and thickener is one or more in silica or the bentonite, uses when multiple, and total usage amount can not account for the maximum of weight of formulation part greater than thickener; Water with surplus.
Or when being processed into aqueous emulsion, its assistant agent is:
(1) solvent accounts for preparation by weight 10～90%, and solvent is one or more in alcohols, ketone, ester class or the aromatic hydrocarbon, uses when multiple, and total usage amount can not account for the maximum of weight of formulation part greater than solvent;
(2) emulsifier accounts for preparation by weight 10～30%, emulsifier is an alkyl benzene sulfonate calcium salt, the alkyl benzene sulphonate magnesium salts, alkyl benzene sulphonate aluminium salt, the alkyl benzene sulphonate sodium salt, the alkyl benzene sulphonate barium salt, C8～C20 alkylsurfuric acid sodium salt, styrene polyoxyethylene ether ammonium sulfate salt, the benzylbiphenyl phenol polyethenoxy ether, phenethyl phenol polyethenoxy (N=15～30) ether, phenethyl phenol polyethenoxy polyoxypropylene, polyoxyethylene nonylphenol ether, alkylphenol polyoxyethylene first condensation product, the xenol APEO, in No. 300, homemade Nongru-700 number or the homemade farming breast one or more, use when multiple, total usage amount can not account for the maximum of weight of formulation part greater than emulsifier;
(3) the stabilizer comprises preparation by weight 0.5～15%, stabilizing agent is a 3-chloro-1, in 2-expoxy propane, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyvinyl one glycol diglycidyl ether or the sodium sorbate one or more, use when multiple, total usage amount can not be greater than the maximum of stabilizer comprises weight of formulation part;
(4) antifreezing agent accounts for preparation by weight 0.5～10%, and antifreezing agent is one or more in ethylene glycol, glycerine, propane diols, polyethylene glycol or the sorb sodium alkoxide, uses when multiple, and total usage amount can not account for the maximum of weight of formulation part greater than antifreezing agent; Water with surplus.
The preparation method of the various formulations of compounded pesticides of the present invention is with reference to conventional preparation method of described formulation and equipment.Perhaps with reference to following preparation method:
The described mixed insecticide preparation that contains destruxins and matrine, the method that each component is mixed with into missible oil is: by proportioning destruxins and the former medicine of matrine are dissolved in the solvent, other assistant agent is joined in destruxins and the matrine solution, stir, put into and mix also homogenize in the homogenizer strongly promptly.
The described mixed insecticide preparation that contains destruxins and matrine, the method that each component is mixed with into wetting powder is: by proportioning destruxins and the former medicine of matrine are carried out joining in the blender behind the comminution by gas stream, in blender, add assistant agent respectively by proportioning, stir promptly.
The described mixed insecticide preparation that contains destruxins and matrine, the method that each component is mixed with into microemulsion is: matrine and destruxins are dissolved in the solvent, add emulsifier and stir, add other assistant agents then, put into and mix also homogenize in the homogenizer strongly promptly.
The method that the described mixed insecticide preparation that contains destruxins and matrine, each component are mixed with into suspending agent is: add assistant agent one in destruxins and the matrine by proportioning and arise from the ball mill ball milling and make suspending agent promptly.
The described mixed insecticide preparation that contains destruxins and matrine, the method that each component is mixed with into suspended emulsion is: by proportioning adding assistant agent except that thickener in destruxins and the former medicine of matrine, insert in the high-shear emulsion machine and mix, adding thickener further mixes, grind through sand mill, after microscopy is qualified promptly.
The described mixed insecticide preparation that contains destruxins and matrine, the method that each component is mixed with into aqueous emulsion is: by ratio requirement destruxins and the former medicine of matrine are dissolved in the solvent, other assistant agents beyond the water are joined in destruxins and the matrine solution, stir, slowly add then in the entry, fully stir promptly.
This complex preparation can be applicable to the control of insect of vegetables blade face, is preferred for preventing and treating the cotten aphid (Aphis gossypii Glover) of vegetables of causing harm.
The invention has the beneficial effects as follows:
The present invention successfully searches out two kinds of biologic products and is mixed, and has kept the plurality of advantages of biological insecticides, reduces dosage, and drug effect increases substantially to the resistance management of insect and makes the important techniques contribution.
The significant synergistic effect that has been mixed of destruxins and matrine, and can prepare different formulations, easy to use, efficacy stability, little to the pollution of ecotope, help protecting the person poultry safety.
Embodiment
Below in conjunction with specific embodiment compound insecticidal preparation of the present invention is described in further detail.
Embodiment 1 10% destruxins microemulsion containing matrine agent
Destruxins: the weight percentage ratio of matrine is 3: 7.Described destruxins is pure substance or the mixture that contains destruxins A, B, C, D or E, and described matrine is pure substance or the mixture that contains Banlangen, all is existing product.
According to the weight meter, destruxins 3%; Farming breast 500 8%; Matrine 7%; 6,501 4%; Acetone 3.2%; Glycerine 2%; Ethanol 5.6%; Ethyl acetate 12.6%; Water surplus.By proportioning destruxins, matrine are dissolved in ethyl acetate, ethanol, the acetone, mix other composition of back adding and promptly get microemulsion according to existing routine techniques modulation.
Embodiment 2 10% destruxins microemulsion containing matrine agent
According to the weight meter, destruxins 2.5%; Matrine 2.5%; Farming breast 500 4%; 6,501 2%; Ethanol 2.8%; Glycerine 1%; Ethyl acetate 6.3%; Acetone 1.6%; Water surplus.By proportioning destruxins, matrine are dissolved in ethyl acetate, ethanol, the acetone, mix other composition modulation of back adding and promptly get microemulsion.
Embodiment 3 20% destruxins matrine missible oil
According to the weight meter, destruxins 4%; Matrine 16%; Sodium alkyl sulfate 30%; Acetic acid 0.5%; Butacide 0.5%; Ethyl acetate 10%; Castor oil 1%; Benzinum 25%; Epoxidized soybean oil 11%; Laurocapram 2%.Each component is put into modulation kettle mixes well promptly.
Embodiment 4 12.5% destruxins matrine suspending agent wetting powders
According to the weight meter, destruxins 10%; Matrine 2.5%; : wetting agent bay alcohol radical sodium sulphate 32%; Dispersant lignin 25%; Filler diatomite 30.5%.Make according to conventional method.
Embodiment 5 25.5% destruxins matrine suspending agents
The weight proportion of each component is: destruxins 0.5%; Matrine 25%; Surfactant sodium alkyl sulfate 17.4%; Solvent propylene glycol 40%; Cosolvent dimethyl sulfoxide (DMSO) 15%; PH value conditioning agent acetic acid 0.5%; Synergist Butacide 0.5%; Anti-photodissociation agent castor oil 0.5%; Stabilizing agent epoxidized soybean oil 0.5%; Thickener-silica 0.1%; Make according to conventional method.
Embodiment 6 30% destruxins matrine suspended emulsions
The weight proportion of each component is: destruxins 0.5%; Matrine 25%; Surfactant sodium alkyl sulfate 20%; Solvent benzinum 25%; Cosolvent ethyl acetate 5%; PH value conditioning agent ammonium hydroxide 0.6%; Butacide 0.5%; Anti-photodissociation agent Angelica oil 5%; Stabilizing agent epoxidized soybean oil 5%; The water of thickener bentonite 1% and surplus.Make according to conventional method.
Embodiment 7 10% destruxins matrine water emulsions
The weight proportion of each component is: destruxins 1%; Matrine 9%; Solvent 60%, the homemade Nongru-700 of emulsifier number 10%; Stabilizing agent sodium sorbate 1%; The water of antifreezing agent glycerine 1% and surplus.Prepare according to conventional method.
Embodiment 8 destruxinses, matrine and mixture thereof are to the action of contace poison activity experiment of cotten aphid Aphis gossypii Glover
Insecticide indoor virulence experimental technique according to the FAO recommendation, measured destruxins, matrine and mixture thereof to the action of contace poison of melon aphid active as following table: when destruxins and matrine weight ratio are (1～8): when (9～2), its co-toxicity coefficient CTC is greater than 120, illustrate that both have synergistic effect when using with in this ratio, especially when destruxins: matrine=5: 5, destruxins: matrine=2: 8, destruxins: during matrine=3: 7, its CTC reaches 2699.76,1144.18,7051.82 respectively, its synergistic effect highly significant.
Claims (9)
1. the compound insecticidal host of destruxins and matrine is characterized in that being mixed with according to 1: 0.25～50 part by weight by destruxins and matrine and obtains.
2. the compound insecticidal host of destruxins according to claim 1 and matrine, it is characterized in that by destruxins and matrine according to 1～8: 9～2 part by weight is mixed with and obtains
3. the compound insecticidal host of destruxins according to claim 1 and matrine is characterized in that being mixed with according to the part by weight of 5: 5,3: 7 or 2: 8 by destruxins and matrine and obtains.
4. according to the compound insecticidal host of claim 1,2 or 3 described destruxinses and matrine, it is characterized in that described destruxins is pure substance or the mixture that contains destruxins A, B, C, D, E.
5. according to the compound insecticidal host of claim 1,2 or 3 described destruxinses and matrine, it is characterized in that described matrine is pure substance or the mixture that contains Banlangen.
6. the compounded pesticides of destruxins and matrine is characterized in that each composition weight percentage composition is:
The compound insecticidal host 1～30% of destruxins and matrine;
Assistant agent 70～99%.
7. compounded pesticides according to claim 6 is characterized in that described insecticide is missible oil, wetting powder, microemulsion, suspending agent, suspended emulsion or aqueous emulsion.
8. the application of the described compounded pesticides of claim 6 is characterized in that being applied to prevent and treat vegetables blade face insect.
9. the application of described compounded pesticides according to Claim 8 is characterized in that being used to prevent and treat the cotten aphid of vegetables of causing harm.
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| CN103271103A (en) * | 2013-07-02 | 2013-09-04 | 宁夏农林科学院 | Botanical complex insecticide containing matrine and aconitum flavum hand alkaloid and preparation method of botanical complex insecticide |
| CN103444759A (en) * | 2012-06-01 | 2013-12-18 | 武汉乐立基生物科技有限责任公司 | Isorhodanate and matrine mixture and its application |
| CN104604945A (en) * | 2015-01-08 | 2015-05-13 | 馥稷生物科技发展（上海）有限公司 | Insecticidal composition containing metarrhizium anisopliae and veratrine and application of insecticidal composition in rice disease prevention and control |
| CN105432669A (en) * | 2014-08-22 | 2016-03-30 | 付顺林 | Method for controlling Lepidoptera larvae with combination of Metarhizium and alkaloids |
| CN106070338A (en) * | 2016-06-22 | 2016-11-09 | 北京联合大学 | A kind of compounding agricultural insecticidal bactericidal composition and application thereof |
| CN106719849A (en) * | 2017-01-20 | 2017-05-31 | 华南农业大学 | Insecticide associated with a kind of matrine and Verticillium lecanii |
| CN107114392A (en) * | 2017-05-09 | 2017-09-01 | 佛山市瑞生通科技有限公司 | Bio-insecticidal composition comprising destruxins |
| CN107821422A (en) * | 2017-11-09 | 2018-03-23 | 山西大学 | A kind of Pesticidal combination containing destruxins and Acetamiprid and its application |
| CN108041049A (en) * | 2017-12-13 | 2018-05-18 | 广东省林业科学研究院 | A kind of compounded pesticides and its preparation method and application |
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| CN115644187A (en) * | 2022-10-09 | 2023-01-31 | 宁夏农林科学院植物保护研究所（宁夏植物病虫害防治重点实验室） | Butterflybush and metarhizium anisopliae composite microbial inoculum and application thereof |
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| CN103444759A (en) * | 2012-06-01 | 2013-12-18 | 武汉乐立基生物科技有限责任公司 | Isorhodanate and matrine mixture and its application |
| CN103444759B (en) * | 2012-06-01 | 2015-02-25 | 武汉乐立基生物科技有限责任公司 | Isorhodanate and matrine mixture and its application |
| CN103271103A (en) * | 2013-07-02 | 2013-09-04 | 宁夏农林科学院 | Botanical complex insecticide containing matrine and aconitum flavum hand alkaloid and preparation method of botanical complex insecticide |
| CN105432669B (en) * | 2014-08-22 | 2018-11-13 | 徽县绿源科技开发有限责任公司 | A kind of method that green muscardine fungus is combined prevention lepidopterous larvae with alkaloid |
| CN105432669A (en) * | 2014-08-22 | 2016-03-30 | 付顺林 | Method for controlling Lepidoptera larvae with combination of Metarhizium and alkaloids |
| CN104604945B (en) * | 2015-01-08 | 2019-05-28 | 杨凌馥稷生物科技有限公司 | A kind of Pesticidal combination containing green muscardine fungus and jervine and its application in prevention and treatment rice disease |
| CN104604945A (en) * | 2015-01-08 | 2015-05-13 | 馥稷生物科技发展（上海）有限公司 | Insecticidal composition containing metarrhizium anisopliae and veratrine and application of insecticidal composition in rice disease prevention and control |
| CN106070338B (en) * | 2016-06-22 | 2018-10-23 | 北京联合大学 | A kind of compounding agricultural insecticidal bactericidal composition and its application |
| CN106070338A (en) * | 2016-06-22 | 2016-11-09 | 北京联合大学 | A kind of compounding agricultural insecticidal bactericidal composition and application thereof |
| CN106719849A (en) * | 2017-01-20 | 2017-05-31 | 华南农业大学 | Insecticide associated with a kind of matrine and Verticillium lecanii |
| CN106719849B (en) * | 2017-01-20 | 2019-03-26 | 华南农业大学 | Insecticide associated with a kind of matrine and Verticillium lecanii |
| CN107114392A (en) * | 2017-05-09 | 2017-09-01 | 佛山市瑞生通科技有限公司 | Bio-insecticidal composition comprising destruxins |
| CN107821422A (en) * | 2017-11-09 | 2018-03-23 | 山西大学 | A kind of Pesticidal combination containing destruxins and Acetamiprid and its application |
| CN108041049A (en) * | 2017-12-13 | 2018-05-18 | 广东省林业科学研究院 | A kind of compounded pesticides and its preparation method and application |
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