CN101688124B - 催化剂 - Google Patents

催化剂 Download PDF

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Publication number
CN101688124B
CN101688124B CN200880014754.5A CN200880014754A CN101688124B CN 101688124 B CN101688124 B CN 101688124B CN 200880014754 A CN200880014754 A CN 200880014754A CN 101688124 B CN101688124 B CN 101688124B
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CN
China
Prior art keywords
catalyst
precursor
activation stage
activation
hours
Prior art date
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Application number
CN200880014754.5A
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English (en)
Chinese (zh)
Other versions
CN101688124A (zh
Inventor
J·L·维萨吉
J·M·波塔
J·G·科尔特增
M·S·达塔
A·博默
J·范德洛斯德雷茨
A·M·赛义卜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sasol Technology Pty Ltd
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Sasol Technology Pty Ltd
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Publication date
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Publication of CN101688124A publication Critical patent/CN101688124A/zh
Application granted granted Critical
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/703—Activation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Thermal Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CN200880014754.5A 2007-05-04 2008-05-05 催化剂 Active CN101688124B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ZA200703621 2007-05-04
ZA2007/03621 2007-05-04
PCT/IB2008/051723 WO2008135939A2 (en) 2007-05-04 2008-05-05 Catalysts

Publications (2)

Publication Number Publication Date
CN101688124A CN101688124A (zh) 2010-03-31
CN101688124B true CN101688124B (zh) 2013-01-23

Family

ID=39874005

Family Applications (2)

Application Number Title Priority Date Filing Date
CN200880014754.5A Active CN101688124B (zh) 2007-05-04 2008-05-05 催化剂
CN200880014696.6A Active CN101688123B (zh) 2007-05-04 2008-05-05 催化剂

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN200880014696.6A Active CN101688123B (zh) 2007-05-04 2008-05-05 催化剂

Country Status (11)

Country Link
US (2) US8067333B2 (enExample)
EP (2) EP2155837B1 (enExample)
JP (2) JP5284346B2 (enExample)
CN (2) CN101688124B (enExample)
AU (2) AU2008247041B2 (enExample)
BR (2) BRPI0810701A2 (enExample)
CA (2) CA2685135C (enExample)
RU (2) RU2456329C2 (enExample)
UA (2) UA98643C2 (enExample)
WO (3) WO2008135940A2 (enExample)
ZA (2) ZA200907930B (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107583647A (zh) * 2016-07-08 2018-01-16 神华集团有限责任公司 一种固定床费托合成钴催化剂及其焙烧方法

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AU2008249609B2 (en) 2007-05-11 2011-11-03 Sasol Technology (Proprietary) Limited Catalysts
WO2009127990A1 (en) * 2008-04-15 2009-10-22 Sasol Technology (Proprietary) Limited Catalysts
CN102310004B (zh) * 2010-07-07 2013-04-10 中国石油化工股份有限公司 一种钴基费托合成催化剂的还原方法
GB2482171B (en) * 2010-07-22 2018-04-11 Gtl F1 Ag Catalyst treatment
US9527061B2 (en) 2011-04-28 2016-12-27 Sasol Technology (Proprietary) Limited Catalysts
AU2012252073B2 (en) 2011-05-06 2016-07-14 Sasol Technology (Proprietary) Limited Process for preparing a cobalt - containing hydrocarbon synthesis catalyst precursor
AP2013007245A0 (en) 2011-05-06 2013-11-30 Sasol Tech Pty Ltd A process for preparing a cobalt-containing hydrocarbon synthesis catalyst precursor
CN103120953B (zh) * 2011-11-18 2014-11-26 中国石油化工股份有限公司 歧化与烷基转移催化剂的还原方法
FR2984347B1 (fr) * 2011-12-14 2015-03-20 IFP Energies Nouvelles Procede de fabrication d'hydrocarbures avec conditionnement du catalyseur
US9363859B2 (en) 2012-04-20 2016-06-07 Rensselaer Polytechnic Institute Sensory lighting system and method for characterizing an illumination space
CN103769244B (zh) * 2012-10-24 2016-03-30 中国石油化工股份有限公司 一种钴基费托合成催化剂的还原方法
CN104107703B (zh) * 2013-04-16 2016-08-24 中国石油化工股份有限公司 用于烯烃歧化反应催化剂的再生方法
US10434506B1 (en) 2018-12-18 2019-10-08 Emerging Fuels Technology, Inc. Method for activation or regeneration of a catalyst
CN113117689B (zh) * 2020-01-16 2022-05-31 中国科学院大连化学物理研究所 一种催化剂在费托合成反应中的应用
US12042785B1 (en) 2023-09-13 2024-07-23 Dimensional Energy, Inc. Fischer-Tropsch catalysts
WO2025206289A1 (ja) * 2024-03-29 2025-10-02 Ｅｎｅｏｓ株式会社 フィッシャー・トロプシュ合成用触媒の製造方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1625441A (zh) * 2002-01-29 2005-06-08 埃克森美孚研究工程公司 费托负载型催化剂的活化
CN1736594A (zh) * 2005-07-27 2006-02-22 新奥新能(北京)科技有限公司 一种合成气转化催化剂及其制备方法

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US4605679A (en) 1981-10-13 1986-08-12 Chevron Research Company Activated cobalt catalyst and synthesis gas conversion using same
US4413064A (en) * 1981-10-13 1983-11-01 Gulf Research & Development Company Fluid bed catalyst for synthesis gas conversion and utilization thereof for preparation of diesel fuel
US4801573A (en) * 1987-10-23 1989-01-31 501 Den Norske Stats Oljeslenskap A.S. Catalyst for production of hydrocarbons
GB9114314D0 (en) 1991-07-02 1991-08-21 British Petroleum Co Plc Catalyst treatment for fisher-tropsch process
US5292705A (en) 1992-09-24 1994-03-08 Exxon Research & Engineering Co. Activation of hydrocarbon synthesis catalyst
DZ2013A1 (fr) 1995-04-07 2002-10-23 Sastech Ltd Catalyseurs.
NO313086B1 (no) * 1995-08-04 2002-08-12 Inst Francais Du Petrole Fremgangsmåte for fremstilling av en katalysator, katalysator som kan oppnås derved, katalysatorblanding oppnådd derved samtfremgangsmåte for syntese av hydrokarboner
DZ2724A1 (fr) 1998-02-20 2003-09-01 Sasol Tech Pty Ltd Procédé pour la production d'hydrocarbures à partir d'un gaz de synthèse et leurs catalyseurs.
AU747207B2 (en) 1998-10-05 2002-05-09 Sasol Technology (Proprietary) Limited Impregnation process for catalysts
BR0016078B1 (pt) 1999-12-01 2014-04-01 Sasol Tech Pty Ltd Processo para preparar um precursor de catalisador de cobalto de fischer-tropsch.
US6337353B1 (en) * 2000-01-04 2002-01-08 Exxonmobil Research And Engineering Company Activation of hydrocarbon synthesis catalysts with hydrogen and ammonia
WO2001096015A2 (en) * 2000-06-12 2001-12-20 Sasol Technology (Proprietary) Limited Cobalt catalysts
CN1094786C (zh) * 2000-06-28 2002-11-27 中国科学院山西煤炭化学研究所 一种高活性钴基催化剂及其制备方法
RU2301110C2 (ru) * 2001-10-25 2007-06-20 Сэсол Текнолоджи (Проприетери) Лимитед Способ активации катализаторов на основе кобальта
US7223354B2 (en) * 2002-02-22 2007-05-29 Conocophillips Company Promoted nickel-magnesium oxide catalysts and process for producing synthesis gas
AU2003297257A1 (en) * 2002-11-11 2004-06-03 Conocophillips Company Improved supports for high surface area catalysts
CN1460546A (zh) * 2003-05-29 2003-12-10 中国科学院山西煤炭化学研究所 一种钴锆费托合成催化剂的制备方法
GB0510316D0 (en) 2005-05-20 2005-06-29 Johnson Matthey Plc Catalyst manufacture

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
CN1625441A (zh) * 2002-01-29 2005-06-08 埃克森美孚研究工程公司 费托负载型催化剂的活化
CN1736594A (zh) * 2005-07-27 2006-02-22 新奥新能(北京)科技有限公司 一种合成气转化催化剂及其制备方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107583647A (zh) * 2016-07-08 2018-01-16 神华集团有限责任公司 一种固定床费托合成钴催化剂及其焙烧方法
CN107583647B (zh) * 2016-07-08 2020-09-01 神华集团有限责任公司 一种固定床费托合成钴催化剂及其焙烧方法

Also Published As

Publication number Publication date
US8067333B2 (en) 2011-11-29
JP5284346B2 (ja) 2013-09-11
BRPI0810702A2 (pt) 2014-10-21
RU2009143198A (ru) 2011-06-10
CA2685139A1 (en) 2008-11-13
WO2008135940A2 (en) 2008-11-13
CA2685135A1 (en) 2008-11-13
RU2009143199A (ru) 2011-06-10
BRPI0810701A2 (pt) 2014-10-29
EP2155837A2 (en) 2010-02-24
JP2010525935A (ja) 2010-07-29
CN101688123A (zh) 2010-03-31
CN101688124A (zh) 2010-03-31
JP5284347B2 (ja) 2013-09-11
CA2685139C (en) 2014-10-07
EP2155836B1 (en) 2016-05-04
WO2008135939A2 (en) 2008-11-13
WO2008135939A3 (en) 2009-03-12
ZA200907930B (en) 2010-07-28
US20100152035A1 (en) 2010-06-17
CN101688123B (zh) 2013-02-27
RU2456329C2 (ru) 2012-07-20
WO2008135941A3 (en) 2009-03-12
EP2155837B1 (en) 2015-07-15
EP2155836A2 (en) 2010-02-24
US8062992B2 (en) 2011-11-22
RU2458100C2 (ru) 2012-08-10
AU2008247040B2 (en) 2011-08-04
UA98330C2 (ru) 2012-05-10
UA98643C2 (ru) 2012-06-11
WO2008135940A3 (en) 2009-03-12
AU2008247041A1 (en) 2008-11-13
JP2010525936A (ja) 2010-07-29
AU2008247040A1 (en) 2008-11-13
CA2685135C (en) 2015-02-10
AU2008247041B2 (en) 2011-05-26
US20100144520A1 (en) 2010-06-10
ZA200907932B (en) 2010-07-28
WO2008135941A2 (en) 2008-11-13

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