UA98643C2 - Процесс получения катализатора на основе кобальта на подкладке для синтеза фишера-тропша - Google Patents

Процесс получения катализатора на основе кобальта на подкладке для синтеза фишера-тропша

Info

Publication number
UA98643C2
UA98643C2 UAA200912562A UAA200912562A UA98643C2 UA 98643 C2 UA98643 C2 UA 98643C2 UA A200912562 A UAA200912562 A UA A200912562A UA A200912562 A UAA200912562 A UA A200912562A UA 98643 C2 UA98643 C2 UA 98643C2
Authority
UA
Ukraine
Prior art keywords
precursor
treated
tropsch synthesis
synthesis catalyst
supported cobalt
Prior art date
Application number
UAA200912562A
Other languages
English (en)
Ukrainian (uk)
Inventor
Якобус Лукас Візажі
Ян Маттеус Ботха
Йоханнес Герхардус Коортзен
Майкл Стівен Датт
Алта Бохмер
де Лоосдрехт Ян ван
Абдул Мутхаліб Саіб
Original Assignee
Сасол Текнолоджи (Проприетари) Лимитед
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Сасол Текнолоджи (Проприетари) Лимитед filed Critical Сасол Текнолоджи (Проприетари) Лимитед
Publication of UA98643C2 publication Critical patent/UA98643C2/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/703—Activation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Thermal Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Процесс получения катализатора на основе кобальта на подкладке для синтеза Фишера-Тропша, который включает: на первом этапе активации – обработку предшественника катализатора газом-восстановителем при первой скорости нагревания HR1, пока предшественник не достигнет температуры Т1, где 80 °C(Т1(180 °C для получения частично обработанного предшественника катализатора; на втором этапе активации – обработку частично обработанного предшественника катализатора газом-восстановителем при второй скорости нагревания HR2 с x шаговым приростом, где x – целое число, более 1, и где 0<HR2<HR1, в течение времени действия, где t1 составляет от 0,1 до 20 часов, для получения частично восстановленного предшественника катализатора; и после этого – на третьем этапе активации – обработку частично восстановленного предшественника катализатора газом-восстановителем при третьей скорости нагревания HR3, где HR3>HR2, пока частично восстановленный предшественник катализатора не достигнет температуры Т2, где 300 °C≤Т2≤600 °C и выдержку частично восстановленного предшественника катализатора при Т2 в течение времени t2, где 0<t2≤20 часов для получения активированного катализатора.
UAA200912562A 2007-05-04 2008-05-05 Процесс получения катализатора на основе кобальта на подкладке для синтеза фишера-тропша UA98643C2 (ru)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ZA200703621 2007-05-04

Publications (1)

Publication Number Publication Date
UA98643C2 true UA98643C2 (ru) 2012-06-11

Family

ID=39874005

Family Applications (2)

Application Number Title Priority Date Filing Date
UAA200912562A UA98643C2 (ru) 2007-05-04 2008-05-05 Процесс получения катализатора на основе кобальта на подкладке для синтеза фишера-тропша
UAA200912556A UA98330C2 (ru) 2007-05-04 2008-05-05 Процесс получения катализатора на основе кобальта на подкладке для синтеза фишера-тропша

Family Applications After (1)

Application Number Title Priority Date Filing Date
UAA200912556A UA98330C2 (ru) 2007-05-04 2008-05-05 Процесс получения катализатора на основе кобальта на подкладке для синтеза фишера-тропша

Country Status (11)

Country Link
US (2) US8062992B2 (ru)
EP (2) EP2155837B1 (ru)
JP (2) JP5284346B2 (ru)
CN (2) CN101688123B (ru)
AU (2) AU2008247041B2 (ru)
BR (2) BRPI0810701A2 (ru)
CA (2) CA2685135C (ru)
RU (2) RU2458100C2 (ru)
UA (2) UA98643C2 (ru)
WO (3) WO2008135940A2 (ru)
ZA (2) ZA200907932B (ru)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8809215B2 (en) 2007-05-11 2014-08-19 Sasol Technology (Proprietary) Limited Catalysts
WO2009127990A1 (en) * 2008-04-15 2009-10-22 Sasol Technology (Proprietary) Limited Catalysts
CN102310004B (zh) * 2010-07-07 2013-04-10 中国石油化工股份有限公司 一种钴基费托合成催化剂的还原方法
GB2482171B (en) * 2010-07-22 2018-04-11 Gtl F1 Ag Catalyst treatment
RU2551433C1 (ru) 2011-04-28 2015-05-27 Сэсол Текнолоджи (Проприетери) Лимитед Катализаторы
US9687822B2 (en) * 2011-05-06 2017-06-27 Sasol Technology (Proprietary) Limited Process for preparing a cobalt-containing hydrocarbon synthesis catalyst precursor
CN103501898B (zh) * 2011-05-06 2016-01-20 沙索技术有限公司 用于制备含钴烃合成催化剂前体的方法
CN103120953B (zh) * 2011-11-18 2014-11-26 中国石油化工股份有限公司 歧化与烷基转移催化剂的还原方法
FR2984347B1 (fr) * 2011-12-14 2015-03-20 IFP Energies Nouvelles Procede de fabrication d'hydrocarbures avec conditionnement du catalyseur
JP2015519687A (ja) 2012-04-20 2015-07-09 レンセレイアー ポリテクニック インスティテュート 照明空間を特性評価するための検知照明システム及び方法
CN103769244B (zh) * 2012-10-24 2016-03-30 中国石油化工股份有限公司 一种钴基费托合成催化剂的还原方法
CN104107703B (zh) * 2013-04-16 2016-08-24 中国石油化工股份有限公司 用于烯烃歧化反应催化剂的再生方法
CN107583647B (zh) * 2016-07-08 2020-09-01 神华集团有限责任公司 一种固定床费托合成钴催化剂及其焙烧方法
US10434506B1 (en) 2018-12-18 2019-10-08 Emerging Fuels Technology, Inc. Method for activation or regeneration of a catalyst
CN113117689B (zh) * 2020-01-16 2022-05-31 中国科学院大连化学物理研究所 一种催化剂在费托合成反应中的应用

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4605679A (en) * 1981-10-13 1986-08-12 Chevron Research Company Activated cobalt catalyst and synthesis gas conversion using same
US4413064A (en) * 1981-10-13 1983-11-01 Gulf Research & Development Company Fluid bed catalyst for synthesis gas conversion and utilization thereof for preparation of diesel fuel
US4801573A (en) * 1987-10-23 1989-01-31 501 Den Norske Stats Oljeslenskap A.S. Catalyst for production of hydrocarbons
GB9114314D0 (en) * 1991-07-02 1991-08-21 British Petroleum Co Plc Catalyst treatment for fisher-tropsch process
US5292705A (en) * 1992-09-24 1994-03-08 Exxon Research & Engineering Co. Activation of hydrocarbon synthesis catalyst
DZ2013A1 (fr) * 1995-04-07 2002-10-23 Sastech Ltd Catalyseurs.
NO313086B1 (no) * 1995-08-04 2002-08-12 Inst Francais Du Petrole Fremgangsmåte for fremstilling av en katalysator, katalysator som kan oppnås derved, katalysatorblanding oppnådd derved samtfremgangsmåte for syntese av hydrokarboner
DZ2724A1 (fr) 1998-02-20 2003-09-01 Sasol Tech Pty Ltd Procédé pour la production d'hydrocarbures à partir d'un gaz de synthèse et leurs catalyseurs.
NZ510952A (en) * 1998-10-05 2003-04-29 Sasol Tech Pty Ltd Impregnation process for preparing a catalyst precursor and the catalyst
EP1237652A1 (en) 1999-12-01 2002-09-11 Sasol Technology (Proprietary) Limited Cobalt catalysts
US6337353B1 (en) * 2000-01-04 2002-01-08 Exxonmobil Research And Engineering Company Activation of hydrocarbon synthesis catalysts with hydrogen and ammonia
AU6258001A (en) * 2000-06-12 2001-12-24 Sasol Tech Pty Ltd Cobalt catalysts
CN1094786C (zh) * 2000-06-28 2002-11-27 中国科学院山西煤炭化学研究所 一种高活性钴基催化剂及其制备方法
AR037036A1 (es) * 2001-10-25 2004-10-20 Sasol Tech Pty Ltd Un proceso para obtener un catalizador fischer-tropsch soportado
US6753351B2 (en) * 2002-01-29 2004-06-22 Exxonmobil Research And Engineering Company Supported catalyst activation
AU2003209195A1 (en) * 2002-02-22 2003-09-09 Conoco Inc. Promoted nickel-magnesium oxide catalysts and process for producing synthesis gas
WO2004043583A2 (en) * 2002-11-11 2004-05-27 Conocophillips Company Improved supports for high surface area catalysts
CN1460546A (zh) * 2003-05-29 2003-12-10 中国科学院山西煤炭化学研究所 一种钴锆费托合成催化剂的制备方法
GB0510316D0 (en) 2005-05-20 2005-06-29 Johnson Matthey Plc Catalyst manufacture
CN100374200C (zh) * 2005-07-27 2008-03-12 新奥新能(北京)科技有限公司 一种合成气转化催化剂及其制备方法

Also Published As

Publication number Publication date
CN101688124B (zh) 2013-01-23
UA98330C2 (ru) 2012-05-10
AU2008247040A1 (en) 2008-11-13
JP2010525935A (ja) 2010-07-29
CN101688123B (zh) 2013-02-27
EP2155837A2 (en) 2010-02-24
RU2009143198A (ru) 2011-06-10
CA2685139A1 (en) 2008-11-13
RU2456329C2 (ru) 2012-07-20
CN101688124A (zh) 2010-03-31
BRPI0810701A2 (pt) 2014-10-29
CA2685135C (en) 2015-02-10
AU2008247040B2 (en) 2011-08-04
EP2155837B1 (en) 2015-07-15
WO2008135941A2 (en) 2008-11-13
RU2009143199A (ru) 2011-06-10
AU2008247041B2 (en) 2011-05-26
US20100144520A1 (en) 2010-06-10
EP2155836A2 (en) 2010-02-24
WO2008135940A2 (en) 2008-11-13
RU2458100C2 (ru) 2012-08-10
JP2010525936A (ja) 2010-07-29
CA2685135A1 (en) 2008-11-13
ZA200907930B (en) 2010-07-28
WO2008135941A3 (en) 2009-03-12
JP5284346B2 (ja) 2013-09-11
AU2008247041A1 (en) 2008-11-13
WO2008135939A3 (en) 2009-03-12
BRPI0810702A2 (pt) 2014-10-21
CA2685139C (en) 2014-10-07
CN101688123A (zh) 2010-03-31
US20100152035A1 (en) 2010-06-17
WO2008135940A3 (en) 2009-03-12
ZA200907932B (en) 2010-07-28
US8062992B2 (en) 2011-11-22
EP2155836B1 (en) 2016-05-04
WO2008135939A2 (en) 2008-11-13
JP5284347B2 (ja) 2013-09-11
US8067333B2 (en) 2011-11-29

Similar Documents

Publication Publication Date Title
UA98643C2 (ru) Процесс получения катализатора на основе кобальта на подкладке для синтеза фишера-тропша
JP2010525935A5 (ru)
EP2236204A4 (en) METHOD FOR PRODUCING A CATALYST FOR THE REFORMATION OF TEAR-CONTAINING GAS, METHOD FOR TEERE-REFORMING AND METHOD FOR REGENERATING CATALYSTS FOR THE REFORMATION OF TEAR-CONTAINING GAS
EP2409761A4 (en) CATALYST FOR PRODUCING HYDROGEN AND METHOD FOR PRODUCING HYDROGEN ON THE BASIS OF THE CATALYST AND CATALYST FOR AMMONIA COMBUSTION, METHOD FOR THE PRODUCTION OF THE CATALYST AND AMMONIA COMBUSTION AGAINST THE CATALYST
DOP2006000048A (es) Production of ferronickel (producción de ferroniquel)
MY155540A (en) Process for regenerating a catalyst
WO2013135710A3 (de) Verfahren zur durchführung der rwgs-reaktion in einem rohrbündelreaktor
EP1896177A4 (en) COBALTOXIDE CATALYST FOR HYDROGEN PRODUCTION AND METHOD OF MANUFACTURING THEREOF
ZA201100518B (en) &#34;composite oxide for hydrocarbon reforming catalyst,process for producing the same,and process for producing syngas using the same&#34;
EA200800170A1 (ru) Способ конверсии синтез-газа в оксигенаты, содержащие спирты с+
UA104721C2 (ru) Катализаторы
EP2335824A4 (en) PROCESS FOR PRODUCTION OF CAT-REFORMING CATALYST OF TAR-CONTAINING GAS, METHOD FOR TAR REFORMING, AND METHOD FOR REGENERATING RE-FORMING CATALYST OF TAR-CONTAINING GAS
PH12015501928A1 (en) Method for producing solid carbon by reducing carbon oxides
IL202140A (en) Hydrogen Ammonia Boran Production and its Derivatives by Homogeneous Catalytic Solubilization Response
UA96032C2 (en) Process for the production of methyl acetate
EP1949960A4 (en) HYDROGEN PRODUCTION CATALYST, PROCESS FOR PRODUCING THE SAME, FUEL REFORMER, AND FUEL CELL
MY192307A (en) Process for converting feeds derived from renewable sources with pre-treatment of feeds by hot dephosphatation
WO2010074787A3 (en) Process and apparatus for continuous flow synthesis of nanocrystals
UA98644C2 (ru) Процесс регенерации отработанного катализатора на основе кобальта для синтеза фишера-тропша
WO2010059660A3 (en) Method for activating strengthened iron catalyst for slurry reactors
MY179281A (en) A process for producing ammonia synthesis gas with high temperature shift and low steam-to-carbon ratio
WO2012004334A3 (de) Verfahren zur herstellung eines schalenkatalysators und schalenkatalysator
MY144180A (en) Method for producing strontium ranelate and its hydrates
EP2045011A4 (en) CATALYST SUPPORT PARTS, MANUFACTURING METHOD AND EMISSION CONTROL CATALYST
EP2184104A4 (en) Catalyst for the production of hydrogen at low temperature, process for production of the catalyst, and process for production of hydrogen