JP5284346B2 - 触媒 - Google Patents
触媒 Download PDFInfo
- Publication number
- JP5284346B2 JP5284346B2 JP2010504988A JP2010504988A JP5284346B2 JP 5284346 B2 JP5284346 B2 JP 5284346B2 JP 2010504988 A JP2010504988 A JP 2010504988A JP 2010504988 A JP2010504988 A JP 2010504988A JP 5284346 B2 JP5284346 B2 JP 5284346B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- activation stage
- temperature
- catalyst precursor
- activation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 239000003054 catalyst Substances 0.000 title claims description 145
- 239000012018 catalyst precursor Substances 0.000 claims description 116
- 230000004913 activation Effects 0.000 claims description 102
- 238000000034 method Methods 0.000 claims description 74
- 239000007789 gas Substances 0.000 claims description 60
- 230000015572 biosynthetic process Effects 0.000 claims description 55
- 229910017052 cobalt Inorganic materials 0.000 claims description 54
- 239000010941 cobalt Substances 0.000 claims description 54
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 54
- 238000003786 synthesis reaction Methods 0.000 claims description 54
- 229910052739 hydrogen Inorganic materials 0.000 claims description 46
- 239000001257 hydrogen Substances 0.000 claims description 44
- 238000010438 heat treatment Methods 0.000 claims description 41
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 37
- 238000004519 manufacturing process Methods 0.000 claims description 19
- 239000002243 precursor Substances 0.000 claims description 14
- 239000011261 inert gas Substances 0.000 claims description 9
- 238000012545 processing Methods 0.000 claims description 9
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 7
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 6
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 6
- 238000001994 activation Methods 0.000 description 85
- 239000002002 slurry Substances 0.000 description 28
- 238000005470 impregnation Methods 0.000 description 27
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 21
- 229910002091 carbon monoxide Inorganic materials 0.000 description 21
- 238000001035 drying Methods 0.000 description 15
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 15
- 238000011946 reduction process Methods 0.000 description 15
- 239000000203 mixture Substances 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 238000001354 calcination Methods 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000012153 distilled water Substances 0.000 description 7
- 150000002431 hydrogen Chemical class 0.000 description 7
- 229910052710 silicon Inorganic materials 0.000 description 7
- 239000010703 silicon Substances 0.000 description 7
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 6
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 6
- QGUAJWGNOXCYJF-UHFFFAOYSA-N cobalt dinitrate hexahydrate Chemical compound O.O.O.O.O.O.[Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QGUAJWGNOXCYJF-UHFFFAOYSA-N 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 150000001869 cobalt compounds Chemical class 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 239000013067 intermediate product Substances 0.000 description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 150000001868 cobalt Chemical class 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 239000003607 modifier Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 235000011089 carbon dioxide Nutrition 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 2
- -1 that is Chemical compound 0.000 description 2
- 238000001291 vacuum drying Methods 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910001593 boehmite Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- SAXCKUIOAKKRAS-UHFFFAOYSA-N cobalt;hydrate Chemical compound O.[Co] SAXCKUIOAKKRAS-UHFFFAOYSA-N 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000012686 silicon precursor Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8913—Cobalt and noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
- C10G2300/703—Activation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Thermal Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ZA200703621 | 2007-05-04 | ||
| ZA2007/03621 | 2007-05-04 | ||
| PCT/IB2008/051723 WO2008135939A2 (en) | 2007-05-04 | 2008-05-05 | Catalysts |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010525935A JP2010525935A (ja) | 2010-07-29 |
| JP2010525935A5 JP2010525935A5 (enExample) | 2011-05-06 |
| JP5284346B2 true JP5284346B2 (ja) | 2013-09-11 |
Family
ID=39874005
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010504988A Active JP5284346B2 (ja) | 2007-05-04 | 2008-05-05 | 触媒 |
| JP2010504989A Active JP5284347B2 (ja) | 2007-05-04 | 2008-05-05 | 触媒 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010504989A Active JP5284347B2 (ja) | 2007-05-04 | 2008-05-05 | 触媒 |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US8067333B2 (enExample) |
| EP (2) | EP2155837B1 (enExample) |
| JP (2) | JP5284346B2 (enExample) |
| CN (2) | CN101688124B (enExample) |
| AU (2) | AU2008247041B2 (enExample) |
| BR (2) | BRPI0810701A2 (enExample) |
| CA (2) | CA2685135C (enExample) |
| RU (2) | RU2456329C2 (enExample) |
| UA (2) | UA98643C2 (enExample) |
| WO (3) | WO2008135940A2 (enExample) |
| ZA (2) | ZA200907930B (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2008249609B2 (en) | 2007-05-11 | 2011-11-03 | Sasol Technology (Proprietary) Limited | Catalysts |
| WO2009127990A1 (en) * | 2008-04-15 | 2009-10-22 | Sasol Technology (Proprietary) Limited | Catalysts |
| CN102310004B (zh) * | 2010-07-07 | 2013-04-10 | 中国石油化工股份有限公司 | 一种钴基费托合成催化剂的还原方法 |
| GB2482171B (en) * | 2010-07-22 | 2018-04-11 | Gtl F1 Ag | Catalyst treatment |
| US9527061B2 (en) | 2011-04-28 | 2016-12-27 | Sasol Technology (Proprietary) Limited | Catalysts |
| AU2012252073B2 (en) | 2011-05-06 | 2016-07-14 | Sasol Technology (Proprietary) Limited | Process for preparing a cobalt - containing hydrocarbon synthesis catalyst precursor |
| AP2013007245A0 (en) | 2011-05-06 | 2013-11-30 | Sasol Tech Pty Ltd | A process for preparing a cobalt-containing hydrocarbon synthesis catalyst precursor |
| CN103120953B (zh) * | 2011-11-18 | 2014-11-26 | 中国石油化工股份有限公司 | 歧化与烷基转移催化剂的还原方法 |
| FR2984347B1 (fr) * | 2011-12-14 | 2015-03-20 | IFP Energies Nouvelles | Procede de fabrication d'hydrocarbures avec conditionnement du catalyseur |
| US9363859B2 (en) | 2012-04-20 | 2016-06-07 | Rensselaer Polytechnic Institute | Sensory lighting system and method for characterizing an illumination space |
| CN103769244B (zh) * | 2012-10-24 | 2016-03-30 | 中国石油化工股份有限公司 | 一种钴基费托合成催化剂的还原方法 |
| CN104107703B (zh) * | 2013-04-16 | 2016-08-24 | 中国石油化工股份有限公司 | 用于烯烃歧化反应催化剂的再生方法 |
| CN107583647B (zh) * | 2016-07-08 | 2020-09-01 | 神华集团有限责任公司 | 一种固定床费托合成钴催化剂及其焙烧方法 |
| US10434506B1 (en) | 2018-12-18 | 2019-10-08 | Emerging Fuels Technology, Inc. | Method for activation or regeneration of a catalyst |
| CN113117689B (zh) * | 2020-01-16 | 2022-05-31 | 中国科学院大连化学物理研究所 | 一种催化剂在费托合成反应中的应用 |
| US12042785B1 (en) | 2023-09-13 | 2024-07-23 | Dimensional Energy, Inc. | Fischer-Tropsch catalysts |
| WO2025206289A1 (ja) * | 2024-03-29 | 2025-10-02 | Ｅｎｅｏｓ株式会社 | フィッシャー・トロプシュ合成用触媒の製造方法 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4605679A (en) | 1981-10-13 | 1986-08-12 | Chevron Research Company | Activated cobalt catalyst and synthesis gas conversion using same |
| US4413064A (en) * | 1981-10-13 | 1983-11-01 | Gulf Research & Development Company | Fluid bed catalyst for synthesis gas conversion and utilization thereof for preparation of diesel fuel |
| US4801573A (en) * | 1987-10-23 | 1989-01-31 | 501 Den Norske Stats Oljeslenskap A.S. | Catalyst for production of hydrocarbons |
| GB9114314D0 (en) | 1991-07-02 | 1991-08-21 | British Petroleum Co Plc | Catalyst treatment for fisher-tropsch process |
| US5292705A (en) | 1992-09-24 | 1994-03-08 | Exxon Research & Engineering Co. | Activation of hydrocarbon synthesis catalyst |
| DZ2013A1 (fr) | 1995-04-07 | 2002-10-23 | Sastech Ltd | Catalyseurs. |
| NO313086B1 (no) * | 1995-08-04 | 2002-08-12 | Inst Francais Du Petrole | Fremgangsmåte for fremstilling av en katalysator, katalysator som kan oppnås derved, katalysatorblanding oppnådd derved samtfremgangsmåte for syntese av hydrokarboner |
| DZ2724A1 (fr) | 1998-02-20 | 2003-09-01 | Sasol Tech Pty Ltd | Procédé pour la production d'hydrocarbures à partir d'un gaz de synthèse et leurs catalyseurs. |
| AU747207B2 (en) | 1998-10-05 | 2002-05-09 | Sasol Technology (Proprietary) Limited | Impregnation process for catalysts |
| BR0016078B1 (pt) | 1999-12-01 | 2014-04-01 | Sasol Tech Pty Ltd | Processo para preparar um precursor de catalisador de cobalto de fischer-tropsch. |
| US6337353B1 (en) * | 2000-01-04 | 2002-01-08 | Exxonmobil Research And Engineering Company | Activation of hydrocarbon synthesis catalysts with hydrogen and ammonia |
| WO2001096015A2 (en) * | 2000-06-12 | 2001-12-20 | Sasol Technology (Proprietary) Limited | Cobalt catalysts |
| CN1094786C (zh) * | 2000-06-28 | 2002-11-27 | 中国科学院山西煤炭化学研究所 | 一种高活性钴基催化剂及其制备方法 |
| RU2301110C2 (ru) * | 2001-10-25 | 2007-06-20 | Сэсол Текнолоджи (Проприетери) Лимитед | Способ активации катализаторов на основе кобальта |
| US6753351B2 (en) * | 2002-01-29 | 2004-06-22 | Exxonmobil Research And Engineering Company | Supported catalyst activation |
| US7223354B2 (en) * | 2002-02-22 | 2007-05-29 | Conocophillips Company | Promoted nickel-magnesium oxide catalysts and process for producing synthesis gas |
| AU2003297257A1 (en) * | 2002-11-11 | 2004-06-03 | Conocophillips Company | Improved supports for high surface area catalysts |
| CN1460546A (zh) * | 2003-05-29 | 2003-12-10 | 中国科学院山西煤炭化学研究所 | 一种钴锆费托合成催化剂的制备方法 |
| GB0510316D0 (en) | 2005-05-20 | 2005-06-29 | Johnson Matthey Plc | Catalyst manufacture |
| CN100374200C (zh) * | 2005-07-27 | 2008-03-12 | 新奥新能(北京)科技有限公司 | 一种合成气转化催化剂及其制备方法 |
-
2008
- 2008-05-05 CA CA2685135A patent/CA2685135C/en active Active
- 2008-05-05 BR BRPI0810701-7A2A patent/BRPI0810701A2/pt active IP Right Grant
- 2008-05-05 CA CA2685139A patent/CA2685139C/en active Active
- 2008-05-05 EP EP08738082.0A patent/EP2155837B1/en active Active
- 2008-05-05 AU AU2008247041A patent/AU2008247041B2/en not_active Ceased
- 2008-05-05 US US12/598,742 patent/US8067333B2/en active Active
- 2008-05-05 AU AU2008247040A patent/AU2008247040B2/en not_active Ceased
- 2008-05-05 RU RU2009143198/04A patent/RU2456329C2/ru active
- 2008-05-05 EP EP08738081.2A patent/EP2155836B1/en active Active
- 2008-05-05 CN CN200880014754.5A patent/CN101688124B/zh active Active
- 2008-05-05 WO PCT/IB2008/051724 patent/WO2008135940A2/en not_active Ceased
- 2008-05-05 RU RU2009143199/04A patent/RU2458100C2/ru active
- 2008-05-05 CN CN200880014696.6A patent/CN101688123B/zh active Active
- 2008-05-05 WO PCT/IB2008/051723 patent/WO2008135939A2/en not_active Ceased
- 2008-05-05 US US12/598,687 patent/US8062992B2/en active Active
- 2008-05-05 JP JP2010504988A patent/JP5284346B2/ja active Active
- 2008-05-05 UA UAA200912562A patent/UA98643C2/ru unknown
- 2008-05-05 WO PCT/IB2008/051726 patent/WO2008135941A2/en not_active Ceased
- 2008-05-05 BR BRPI0810702-5A2A patent/BRPI0810702A2/pt active IP Right Grant
- 2008-05-05 JP JP2010504989A patent/JP5284347B2/ja active Active
- 2008-05-05 UA UAA200912556A patent/UA98330C2/ru unknown
-
2009
- 2009-11-11 ZA ZA200907930A patent/ZA200907930B/xx unknown
- 2009-11-11 ZA ZA200907932A patent/ZA200907932B/xx unknown
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
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