CN101687737B - 通过卤代烃的催化脱卤化氢制备氟化烯烃 - Google Patents

通过卤代烃的催化脱卤化氢制备氟化烯烃 Download PDF

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Publication number
CN101687737B
CN101687737B CN200880023701XA CN200880023701A CN101687737B CN 101687737 B CN101687737 B CN 101687737B CN 200880023701X A CN200880023701X A CN 200880023701XA CN 200880023701 A CN200880023701 A CN 200880023701A CN 101687737 B CN101687737 B CN 101687737B
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metal
fluorinated
catalyst
chlorinated
combinations
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CN101687737A (zh
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H·王
童雪松
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Honeywell International Inc
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Honeywell International Inc
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/272—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions
    • C07C17/275—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions of hydrocarbons and halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/10—Chlorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/12—Fluorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B35/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving a change in the type of bonding between two carbon atoms already directly linked
    • C07B35/06—Decomposition, e.g. elimination of halogens, water or hydrogen halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C21/00—Acyclic unsaturated compounds containing halogen atoms
    • C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
    • C07C21/18—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN200880023701XA 2007-07-06 2008-07-03 通过卤代烃的催化脱卤化氢制备氟化烯烃 Active CN101687737B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US95846807P 2007-07-06 2007-07-06
US60/958,468 2007-07-06
US12/167,159 US9040759B2 (en) 2007-07-06 2008-07-02 Preparation of fluorinated olefins via catalytic dehydrohalogenation of halogenated hydrocarbons
US12/167,159 2008-07-02
PCT/US2008/069160 WO2009009421A1 (en) 2007-07-06 2008-07-03 Preparation of fluorinated olefins via catalytic dehydrohalogenation of halogenated hydrocarbons

Publications (2)

Publication Number Publication Date
CN101687737A CN101687737A (zh) 2010-03-31
CN101687737B true CN101687737B (zh) 2013-10-30

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CN200880023701XA Active CN101687737B (zh) 2007-07-06 2008-07-03 通过卤代烃的催化脱卤化氢制备氟化烯烃

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Country Link
US (2) US9040759B2 (enExample)
EP (1) EP2164824B1 (enExample)
JP (1) JP5436417B2 (enExample)
KR (3) KR101875204B1 (enExample)
CN (1) CN101687737B (enExample)
ES (1) ES2719478T3 (enExample)
MX (1) MX2009013376A (enExample)
WO (1) WO2009009421A1 (enExample)

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US8846990B2 (en) 2007-07-06 2014-09-30 Honeywell International Inc. Process for producing 2,3,3,3-tetrafluoropropene
US8119557B2 (en) * 2007-12-10 2012-02-21 Honeywell International Inc. Method for making catalyst compositions of alkali metal halide-doped bivalent metal fluorides and process for making fluorinated olefins
US9040759B2 (en) * 2007-07-06 2015-05-26 Honeywell International Inc. Preparation of fluorinated olefins via catalytic dehydrohalogenation of halogenated hydrocarbons
US9416074B2 (en) 2007-07-06 2016-08-16 Honeywell International Inc. Process for producing 2,3,3,3-tetrafluoropropene
EP2075066B1 (en) * 2007-12-10 2016-08-17 Honeywell International Inc. Method for making catalyst compositions of alkali metal halide-doped bivalent metal fluorides and a process for making fluorinated olefins
US7803283B2 (en) 2008-03-31 2010-09-28 Honeywell Internationl Inc. Azeotrope-like compositions of 2-chloro-3,3,3-trifluoropropene (HCFC-1233xf) and 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb)
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US8263817B2 (en) * 2010-07-06 2012-09-11 E I Du Pont De Nemours And Company Synthesis of 1234YF by selective dehydrochlorination of 244BB
CN101913989B (zh) * 2010-09-07 2013-06-05 西安近代化学研究所 2,3,3,3-四氟丙烯的生产方法
US9724684B2 (en) 2011-02-21 2017-08-08 The Chemours Company Fc, Llc Selective catalytical dehydrochlorination of hydrochlorofluorocarbons
US9012702B2 (en) * 2011-02-21 2015-04-21 E. I. Du Pont De Nemours And Company Catalytic dehydrochlorination of hydrochlorofluorocarbons
US8884082B2 (en) 2011-02-21 2014-11-11 E. I. Du Pont De Nemours And Company Selective catalytical dehydrochlorination of hydrochlorofluorocarbons
US8884083B2 (en) * 2011-02-21 2014-11-11 E. I. Du Pont De Nemours And Company Selective catalytical dehydrochlorination of hydrochlorofluorocarbons
CN102887812A (zh) * 2011-07-20 2013-01-23 中化蓝天集团有限公司 1,1,3,3,3-五氟丙烯的合成方法
US8796493B2 (en) * 2011-09-30 2014-08-05 Honeywell International Inc. Methods to separate halogentated olefins from 2-chloro-1,1,1,2-tetrafluoropropane using a solid adsorbent
ES2791768T3 (es) * 2011-10-14 2020-11-05 Honeywell Int Inc Proceso para producir 2,3,3,3-tetrafluoropropeno
CN103946193B (zh) * 2011-10-14 2015-11-25 霍尼韦尔国际公司 制备2,3,3,3-四氟丙烯的方法
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CN104707608B (zh) * 2013-12-12 2017-02-15 西安近代化学研究所 用于气相氟化制备2‑氯‑3,3,3‑三氟丙烯的催化剂的制备方法
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CN105327695A (zh) * 2014-08-06 2016-02-17 浙江蓝天环保高科技股份有限公司 一种用于脱氟化氢的铬基催化剂、其制备方法及应用
US9850188B2 (en) * 2014-09-05 2017-12-26 Honeywell International Inc. Process for producing chlorotrifluoroethylene
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CN108136355A (zh) * 2015-10-15 2018-06-08 霍尼韦尔国际公司 脱卤化氢反应器及方法
CN105251516B (zh) * 2015-11-06 2018-03-13 西安近代化学研究所 一种用于合成含氟卤代烃的催化剂及其制备方法
CN105399599B (zh) * 2015-12-28 2018-05-29 浙江工业大学 一种制备六氟丁二烯的方法
FR3066926B1 (fr) * 2017-06-06 2020-05-22 Arkema France Procede de modification de la distribution en fluor dans un compose hydrocarbure.
CA3068057A1 (en) * 2017-07-27 2019-01-31 The Chemours Company Fc, Llc Process for preparing (z)-1,1,1,4,4,4-hexafluoro-2-butene
JP6974221B2 (ja) 2018-03-14 2021-12-01 株式会社クレハ アルケンの製造方法
KR102549545B1 (ko) * 2018-03-22 2023-06-29 삼성전자주식회사 스토리지 장치 및 스토리지 장치의 동작 방법
CN119118781A (zh) 2018-06-06 2024-12-13 霍尼韦尔国际公司 用于HCFC-244bb的脱氯化氢以制备HFO-1234yf的方法
CN110639493B (zh) * 2019-09-24 2023-02-10 西安近代化学研究所 一种高选择性脱氯化氢催化剂的成型方法
CN110841722B (zh) * 2019-10-16 2022-09-06 鄂尔多斯市瀚博科技有限公司 一种用于氯乙烯合成的无汞催化剂钝化工艺
CN114078605B (zh) * 2021-11-02 2025-08-08 武汉理工大学 一种放射性金属卤化物废物的脱卤及玻璃固化方法
CN119528682A (zh) * 2024-11-04 2025-02-28 西安近代化学研究所 一种含氟双氯烯烃、制备方法及应用

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Publication number Publication date
EP2164824A1 (en) 2010-03-24
KR101711140B1 (ko) 2017-02-28
CN101687737A (zh) 2010-03-31
US20150368169A1 (en) 2015-12-24
JP5436417B2 (ja) 2014-03-05
US10807925B2 (en) 2020-10-20
WO2009009421A1 (en) 2009-01-15
US9040759B2 (en) 2015-05-26
JP2010532762A (ja) 2010-10-14
KR20170024136A (ko) 2017-03-06
KR20100040897A (ko) 2010-04-21
KR20150129062A (ko) 2015-11-18
EP2164824B1 (en) 2019-01-16
US20090043136A1 (en) 2009-02-12
KR101875204B1 (ko) 2018-07-06
ES2719478T3 (es) 2019-07-10
MX2009013376A (es) 2010-01-25
EP2164824A4 (en) 2011-11-16

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