MX2009013376A - Preparacion de olefinas fluoradas mediante deshidrohalogenacion catalitica de hidrocarburos halogenados. - Google Patents

Preparacion de olefinas fluoradas mediante deshidrohalogenacion catalitica de hidrocarburos halogenados.

Info

Publication number
MX2009013376A
MX2009013376A MX2009013376A MX2009013376A MX2009013376A MX 2009013376 A MX2009013376 A MX 2009013376A MX 2009013376 A MX2009013376 A MX 2009013376A MX 2009013376 A MX2009013376 A MX 2009013376A MX 2009013376 A MX2009013376 A MX 2009013376A
Authority
MX
Mexico
Prior art keywords
preparation
halogenated hydrocarbons
fluorinated olefins
via catalytic
olefins via
Prior art date
Application number
MX2009013376A
Other languages
English (en)
Inventor
Hsueh Sung Tung
Haiyou Wang
Original Assignee
Honeywell Int Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Honeywell Int Inc filed Critical Honeywell Int Inc
Publication of MX2009013376A publication Critical patent/MX2009013376A/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/272—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions
    • C07C17/275—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions of hydrocarbons and halogenated hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/10—Chlorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/12—Fluorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B35/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving a change in the type of bonding between two carbon atoms already directly linked
    • C07B35/06—Decomposition, e.g. elimination of halogens, water or hydrogen halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C21/00—Acyclic unsaturated compounds containing halogen atoms
    • C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
    • C07C21/18—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un proceso para elaborar una olefina fluorada que comprende la etapa de someter a deshidrocloración un hidroclorofluorocarburo que tiene por lo menos un átomo de hidrógeno y por lo menos un átomo de cloro en átomos de carbono adyacentes de preferencia se lleva a cabo en la presencia de un catalizador seleccionado de un grupo que consiste de (i) uno o más haluros metálicos, (ii) uno o más óxidos de metal halogenados, (iii) uno o más metales/aleaciones de metal con valencia cero, y (iv) una combinación de dos o más de los anteriores.
MX2009013376A 2007-07-06 2008-07-03 Preparacion de olefinas fluoradas mediante deshidrohalogenacion catalitica de hidrocarburos halogenados. MX2009013376A (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US95846807P 2007-07-06 2007-07-06
US12/167,159 US9040759B2 (en) 2007-07-06 2008-07-02 Preparation of fluorinated olefins via catalytic dehydrohalogenation of halogenated hydrocarbons
PCT/US2008/069160 WO2009009421A1 (en) 2007-07-06 2008-07-03 Preparation of fluorinated olefins via catalytic dehydrohalogenation of halogenated hydrocarbons

Publications (1)

Publication Number Publication Date
MX2009013376A true MX2009013376A (es) 2010-01-25

Family

ID=40228992

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2009013376A MX2009013376A (es) 2007-07-06 2008-07-03 Preparacion de olefinas fluoradas mediante deshidrohalogenacion catalitica de hidrocarburos halogenados.

Country Status (8)

Country Link
US (2) US9040759B2 (es)
EP (1) EP2164824B1 (es)
JP (1) JP5436417B2 (es)
KR (3) KR20100040897A (es)
CN (1) CN101687737B (es)
ES (1) ES2719478T3 (es)
MX (1) MX2009013376A (es)
WO (1) WO2009009421A1 (es)

Families Citing this family (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8530708B2 (en) * 2003-07-25 2013-09-10 Honeywell International Inc. Processes for selective dehydrohalogenation of halogenated alkanes
US8952208B2 (en) * 2006-01-03 2015-02-10 Honeywell International Inc. Method for prolonging a catalyst's life during hydrofluorination
US8664455B2 (en) * 2008-08-08 2014-03-04 Honeywell International Inc. Process to manufacture 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb)
US8034251B2 (en) 2007-01-03 2011-10-11 Honeywell International Inc. Azeotropic compositions of 2-chloro-3,3,3-trifluoropropene (HCFC-1233xf), 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb), and hydrogen fluoride (HF)
US8846990B2 (en) 2007-07-06 2014-09-30 Honeywell International Inc. Process for producing 2,3,3,3-tetrafluoropropene
US8119557B2 (en) * 2007-12-10 2012-02-21 Honeywell International Inc. Method for making catalyst compositions of alkali metal halide-doped bivalent metal fluorides and process for making fluorinated olefins
US9416074B2 (en) 2007-07-06 2016-08-16 Honeywell International Inc. Process for producing 2,3,3,3-tetrafluoropropene
US9040759B2 (en) * 2007-07-06 2015-05-26 Honeywell International Inc. Preparation of fluorinated olefins via catalytic dehydrohalogenation of halogenated hydrocarbons
EP2075066B1 (en) * 2007-12-10 2016-08-17 Honeywell International Inc. Method for making catalyst compositions of alkali metal halide-doped bivalent metal fluorides and a process for making fluorinated olefins
US7803283B2 (en) 2008-03-31 2010-09-28 Honeywell Internationl Inc. Azeotrope-like compositions of 2-chloro-3,3,3-trifluoropropene (HCFC-1233xf) and 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb)
US8845921B2 (en) 2008-04-09 2014-09-30 Honeywell International Inc. Separation of close boiling compounds by addition of a third compound
LT2634232T (lt) * 2008-05-07 2022-06-10 The Chemours Company Fc, Llc Kompozicijos
US8053612B2 (en) * 2008-05-30 2011-11-08 Honeywell International Inc. Process for dehydrochlorinating 1,1,1,2-tetrafluoro-2-chloropropane to 2,3,3,3-tetrafluoropropene in the presence of an alkali metal-doped magnesium oxyfluoride catalyst and methods for making the catalyst
US8975454B2 (en) 2008-07-31 2015-03-10 Honeywell International Inc. Process for producing 2,3,3,3-tetrafluoropropene
US8158549B2 (en) 2009-09-04 2012-04-17 Honeywell International Inc. Catalysts for fluoroolefins hydrogenation
US8618340B2 (en) 2009-11-03 2013-12-31 Honeywell International Inc. Integrated process for fluoro-olefin production
US8674147B2 (en) * 2010-04-02 2014-03-18 Solvay Sa Process for dehydrochlorination of hydrochlorofluoroalkanes
US8426656B2 (en) * 2010-04-05 2013-04-23 Honeywell International Inc. Integrated process to co-produce trans-1-chloro-3,3,3-trifluoropropene and trans-1,3,3,3-tetrafluoropropene
US8927791B2 (en) 2010-04-29 2015-01-06 Honeywell International Inc. Method for producing tetrafluoropropenes
US8263817B2 (en) * 2010-07-06 2012-09-11 E I Du Pont De Nemours And Company Synthesis of 1234YF by selective dehydrochlorination of 244BB
CN101913989B (zh) * 2010-09-07 2013-06-05 西安近代化学研究所 2,3,3,3-四氟丙烯的生产方法
US8884082B2 (en) 2011-02-21 2014-11-11 E. I. Du Pont De Nemours And Company Selective catalytical dehydrochlorination of hydrochlorofluorocarbons
US8884083B2 (en) * 2011-02-21 2014-11-11 E. I. Du Pont De Nemours And Company Selective catalytical dehydrochlorination of hydrochlorofluorocarbons
US9012702B2 (en) * 2011-02-21 2015-04-21 E. I. Du Pont De Nemours And Company Catalytic dehydrochlorination of hydrochlorofluorocarbons
US9724684B2 (en) 2011-02-21 2017-08-08 The Chemours Company Fc, Llc Selective catalytical dehydrochlorination of hydrochlorofluorocarbons
CN102887812A (zh) * 2011-07-20 2013-01-23 中化蓝天集团有限公司 1,1,3,3,3-五氟丙烯的合成方法
US8796493B2 (en) * 2011-09-30 2014-08-05 Honeywell International Inc. Methods to separate halogentated olefins from 2-chloro-1,1,1,2-tetrafluoropropane using a solid adsorbent
JP6223346B2 (ja) * 2011-10-14 2017-11-01 ハネウェル・インターナショナル・インコーポレーテッドＨｏｎｅｙｗｅｌｌ Ｉｎｔｅｒｎａｔｉｏｎａｌ Ｉｎｃ． ２，３，３，３−テトラフルオロプロペンの製造方法
CN107973694A (zh) * 2011-10-14 2018-05-01 霍尼韦尔国际公司 制备2,3,3,3-四氟丙烯的方法
US9000239B2 (en) 2012-05-15 2015-04-07 Honeywell International Inc. Methods for producing 1-chloro-3,3,3-trifluoropropene from 2-chloro-3,3,3-trifluoropropene
US9180433B2 (en) 2013-03-14 2015-11-10 Honeywell International, Inc. Catalysts for 2-chloro-1,1,1,2-tetrafluoropropane dehydrochlorination
CN104707608B (zh) * 2013-12-12 2017-02-15 西安近代化学研究所 用于气相氟化制备2‑氯‑3,3,3‑三氟丙烯的催化剂的制备方法
GB2528690B (en) 2014-07-28 2017-03-01 Mexichem Amanco Holding Sa Process for preparing a (hydro)(chloro)fluoroalkene
CN105327695A (zh) * 2014-08-06 2016-02-17 浙江蓝天环保高科技股份有限公司 一种用于脱氟化氢的铬基催化剂、其制备方法及应用
US9850188B2 (en) * 2014-09-05 2017-12-26 Honeywell International Inc. Process for producing chlorotrifluoroethylene
WO2017066603A1 (en) 2015-10-15 2017-04-20 Honeywell International Inc. Dehydrohalogenation reactor and process
CN105251516B (zh) * 2015-11-06 2018-03-13 西安近代化学研究所 一种用于合成含氟卤代烃的催化剂及其制备方法
CN105399599B (zh) * 2015-12-28 2018-05-29 浙江工业大学 一种制备六氟丁二烯的方法
FR3066926B1 (fr) * 2017-06-06 2020-05-22 Arkema France Procede de modification de la distribution en fluor dans un compose hydrocarbure.
JP6974221B2 (ja) 2018-03-14 2021-12-01 株式会社クレハ アルケンの製造方法
KR102549545B1 (ko) * 2018-03-22 2023-06-29 삼성전자주식회사 스토리지 장치 및 스토리지 장치의 동작 방법
WO2019236720A1 (en) 2018-06-06 2019-12-12 Honeywell International Inc. Method for dehydrochlorination of hcfc-244bb to manufacture hfo-1234yf
CN110639493B (zh) * 2019-09-24 2023-02-10 西安近代化学研究所 一种高选择性脱氯化氢催化剂的成型方法
CN110841722B (zh) * 2019-10-16 2022-09-06 鄂尔多斯市瀚博科技有限公司 一种用于氯乙烯合成的无汞催化剂钝化工艺

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2774799A (en) * 1954-04-01 1956-12-18 Kellogg M W Co Selective dehydrohalogenation of fluorohaloalkanes using a copper catalyst
DE1074568B (de) * 1955-04-05 1960-02-04 Ethyl Corporation, New York N Y (V St A) Verfahren zur Herstellung von Vinylchlorid oder Vinylidenchlorid 5 4 5ö V St Amerika
DE1068695B (de) * 1958-02-06 1959-11-12 Farbwerke Hoechst Aktiengesellschaft vormals Meister Lucius 6. Brüning, Frankfurt/M Verfahren zur Herstellung von Fluoräthylenen
US3444251A (en) * 1965-12-23 1969-05-13 Phillips Petroleum Co Production of gem-difluoroalkenes
US3691240A (en) * 1969-10-06 1972-09-12 Detrex Chem Ind Process for chlorination,dehydrochlorination and purification of organic compounds
US4465786A (en) 1982-09-27 1984-08-14 General Electric Company Catalyst composition for the preparation of 3,3,3-trifluoropropene
BR8907438A (pt) * 1989-03-17 1991-05-21 Dow Chemical Co Processo e catalisador para a desidrohalogenacao de hidrocarbonetos halogenados ou halohidrinas de alquileno
US5180860A (en) * 1990-06-28 1993-01-19 E. I. Du Pont De Nemours And Company Dehydrohalogenation process
US5276240A (en) 1991-10-18 1994-01-04 Board Of Regents, The University Of Texas System Catalytic hydrodehalogenation of polyhalogenated hydrocarbons
GB9311742D0 (en) * 1992-06-10 1993-07-21 Ici Plc Production of hydrofluoroalkanes
DE69940828D1 (de) * 1998-12-18 2009-06-10 Solvay Verfahren zur trennung einer mischung, die mindestlt, und verfahren zur herstellung eines hydrofluoralkans
US7329786B2 (en) * 2001-09-28 2008-02-12 Great Lakes Chemical Corporation Processes for producing CF3CFHCF3
US7230146B2 (en) * 2003-10-27 2007-06-12 Honeywell International Inc. Process for producing fluoropropenes
US8530708B2 (en) * 2003-07-25 2013-09-10 Honeywell International Inc. Processes for selective dehydrohalogenation of halogenated alkanes
US7880040B2 (en) * 2004-04-29 2011-02-01 Honeywell International Inc. Method for producing fluorinated organic compounds
US7592494B2 (en) * 2003-07-25 2009-09-22 Honeywell International Inc. Process for the manufacture of 1,3,3,3-tetrafluoropropene
US7091388B2 (en) * 2003-09-26 2006-08-15 Honeywell International Inc. Method of making 1,1,3,3,3-pentafluoropropene
US7674939B2 (en) 2004-04-29 2010-03-09 Honeywell International Inc. Method for producing fluorinated organic compounds
US8084653B2 (en) 2004-04-29 2011-12-27 Honeywell International, Inc. Method for producing fluorinated organic compounds
CA2564991C (en) * 2004-04-29 2013-03-19 Honeywell International Inc. Processes for synthesis of 1,3,3,3-tetrafluoropropene and 2,3,3,3-tetrafluoropropene
DE06844260T1 (de) * 2005-11-03 2008-12-24 Honeywell International Inc. Verfahren zur herstellung fluorinierter organischer verbindungen
WO2007056194A1 (en) * 2005-11-03 2007-05-18 Honeywell International Inc. Method for producing fluorinated organic compounds
US7560602B2 (en) * 2005-11-03 2009-07-14 Honeywell International Inc. Process for manufacture of fluorinated olefins
US8071825B2 (en) * 2006-01-03 2011-12-06 Honeywell International Inc. Method for producing fluorinated organic compounds
DE07716229T1 (de) 2006-01-03 2009-02-05 Honeywell International Inc. Verfahren zur geometrischen Isomerisation halogenierter Olefine
JP5416587B2 (ja) 2006-10-03 2014-02-12 メキシケム、アマンコ、ホールディング、ソシエダッド、アノニマ、デ、カピタル、バリアブレ プロセス
US9040759B2 (en) * 2007-07-06 2015-05-26 Honeywell International Inc. Preparation of fluorinated olefins via catalytic dehydrohalogenation of halogenated hydrocarbons
US8119557B2 (en) * 2007-12-10 2012-02-21 Honeywell International Inc. Method for making catalyst compositions of alkali metal halide-doped bivalent metal fluorides and process for making fluorinated olefins
EP2075066B1 (en) * 2007-12-10 2016-08-17 Honeywell International Inc. Method for making catalyst compositions of alkali metal halide-doped bivalent metal fluorides and a process for making fluorinated olefins
US8053612B2 (en) * 2008-05-30 2011-11-08 Honeywell International Inc. Process for dehydrochlorinating 1,1,1,2-tetrafluoro-2-chloropropane to 2,3,3,3-tetrafluoropropene in the presence of an alkali metal-doped magnesium oxyfluoride catalyst and methods for making the catalyst

Also Published As

Publication number Publication date
US9040759B2 (en) 2015-05-26
US20090043136A1 (en) 2009-02-12
KR20170024136A (ko) 2017-03-06
JP2010532762A (ja) 2010-10-14
US20150368169A1 (en) 2015-12-24
KR101711140B1 (ko) 2017-02-28
EP2164824B1 (en) 2019-01-16
WO2009009421A1 (en) 2009-01-15
JP5436417B2 (ja) 2014-03-05
CN101687737A (zh) 2010-03-31
US10807925B2 (en) 2020-10-20
KR20100040897A (ko) 2010-04-21
KR101875204B1 (ko) 2018-07-06
ES2719478T3 (es) 2019-07-10
KR20150129062A (ko) 2015-11-18
CN101687737B (zh) 2013-10-30
EP2164824A1 (en) 2010-03-24
EP2164824A4 (en) 2011-11-16

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