CN101503278B - 一种幻彩微粉抛光砖 - Google Patents
一种幻彩微粉抛光砖 Download PDFInfo
- Publication number
- CN101503278B CN101503278B CN2008102204385A CN200810220438A CN101503278B CN 101503278 B CN101503278 B CN 101503278B CN 2008102204385 A CN2008102204385 A CN 2008102204385A CN 200810220438 A CN200810220438 A CN 200810220438A CN 101503278 B CN101503278 B CN 101503278B
- Authority
- CN
- China
- Prior art keywords
- percent
- raw material
- color
- micro
- full impregnated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011449 brick Substances 0.000 title claims description 18
- 239000000843 powder Substances 0.000 title abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 18
- 238000005498 polishing Methods 0.000 claims abstract description 18
- 239000000126 substance Substances 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims abstract description 3
- 239000004744 fabric Substances 0.000 claims description 20
- 239000011230 binding agent Substances 0.000 claims description 15
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 4
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 238000000498 ball milling Methods 0.000 claims description 2
- 238000010410 dusting Methods 0.000 claims description 2
- 238000013467 fragmentation Methods 0.000 claims description 2
- 238000006062 fragmentation reaction Methods 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- -1 polyoxyethylene Polymers 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 12
- 239000011435 rock Substances 0.000 abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 238000010923 batch production Methods 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 230000005855 radiation Effects 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000000465 moulding Methods 0.000 description 4
- 239000004575 stone Substances 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 3
- 229910052573 porcelain Inorganic materials 0.000 description 3
- 238000009700 powder processing Methods 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 239000003086 colorant Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910001600 chlorastrolite Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5025—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
- C04B41/5041—Titanium oxide or titanates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
- C04B2111/82—Coloured materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
一种新型幻彩微粉抛光砖，包括花纹面料层和底料层，所述花纹面料层在光线照射下产生幻彩效果。本发明提供的幻彩微粉抛光砖，面料层局部或全部使用了全透明熔块原料，全透明熔块原料加入有有机粘结剂，全透明熔块原料化学成分为：SiO2 62~68％，Al2O3 6~12％，Fe2O3+TiO2 0.1~0.4％，CaO 4~6％ MgO 0.5~2.5％，K2O 2~5％，Na2O 2~5％，BaO 1~3％。烧成抛光后产生幻彩效果，色彩鲜艳，纹理自然，使制品表面质感达到或超越了天然石材；幻彩微粉抛光砖经过1180～1220℃烧制并抛光，产品强度高；能适应机械化批量生产，可以替代天然石材，因此成本较低。
Description
技术领域：
本发明涉及建筑陶瓷砖技术领域，尤其是指一种地面或墙面装饰用的幻彩微粉抛光砖。
背景技术：
目前市场聚晶微粉抛光砖，为了达到仿石效果，在面料层中使用了一种或几种半透明料，现有半透明料为了适应生产成型要求，在配方中加入了10-25％的粘土原料，大量粘土的引入既提高了配方中铝的含量，产生部分乳浊效果，又使配方烧失变大，杂质增加，透明度下降。产品经抛光后半透明料的光泽度、透明度及防污性都受到影响。本发明用全透明熔块原料代替现有半透明料，大大提高了产品透明性及光泽度，发色效果也有明显改善。
发明内容：
本发明目的在于克服现有生产技术的不足，提供一种用全透明熔块原料代替现有半透明料，大大提高产品透明性、光泽度及发色效果，且表面色彩鲜艳，纹理自然，在光线照射下产生幻彩效果的幻彩微粉抛光砖。
为实现上述目的，本发明提供的技术方案为：一种幻彩微粉抛光砖，包括花纹面料层和底料层，花纹面料层局部或全部使用全透明熔块原料；全透明熔块原料加入有有机粘结剂，全透明熔块原料化学成分为：SiO262~68％，Al2O36~12％，Fe2O3+TiO20.1~0.4％，CaO 4~6％MgO0.5~2.5％，K2O 2~5％，Na2O 2~5％，BaO 1~3％。
达到压机成型所需塑性要求的透明熔块原料加工方法有以下两种：a、全透明熔块原料与有机粘合剂混合球磨喷粉制备成一种花纹面料。其中有机粘合剂加入比例为0.3～2％；喷粉颗粒级配为：30目上：≥12％，60目上：≥65％，80目下：≤10％；b、将有机粘合剂破碎后与全透明熔块原料按比例15∶85混合制备成一种花纹面料，其中有机、粘结剂破碎为10～40目，全透明熔块原料级配为40～100目。
本发明幻彩微粉抛光砖是在现有瓷质砖生产工艺(粉料加工、布料干压成型、干燥、烧成)过程的基础上，使用全透明熔块原料替代面料层中的一种或几种微粉与其它常规花纹面料、底料加工成型。全透明熔块原料比例参数根据不同效果适当调整；全透明熔块可以着色实现不同的显色效果。
全透明熔块原料使用的有机粘合剂具有700℃下完全烧失、烧后无残留物、无异味的特征，如水性石蜡，聚乙二醇，聚乙烯醇等。
本发明生产的幻彩微粉抛光砖：面料层局部或全部使用了全透明熔块原料，烧成抛光后产生透明效果，色彩鲜艳，纹理自然，使制品表面质感达到或超越了天然石材；幻彩微粉抛光砖经过1180～1220烧制且抛光，产品强度高；本产品能机械化批量生产，可以替代天然石材，因此成本较低。
附图说明：
图1为本发明实施例1的截面图。
图2为本发明实施例2的截面图。
具体实施方式：
实施例1：
如图1所示，该实施例是通过在陶瓷基料层1上(基料层厚度15～18mm)，通过压机布料器的动作和格栅的造型，布出各种仿石图案(如万寿红、伯利黄、绿星石、英国棕)的面料层2，在此图案基础上布上一层厚度0.5～2mm范围的其它色粉层3(厚度可调)，再将一层粉料将多余的空位填补(俗称回填层4)，用格栅将框内粉料填平，通过压机冲压成型。上述的面料层、色粉层、回填层可部分或全部使用本发明的全透明熔块原料，通过不同的色料着色达到不同的石材效果。全透明熔块原料化学成分为：SiO262~68％，Al2O36~12％，Fe2O3+TiO20.1~0.4％，CaO 4~6％MgO 0.5~2.5％，K2O 2~5％，Na2O 2~5％，BaO 1~3％。成型砖坯通过干燥、烧结、抛光得到本发明的抛光砖产品。本实施例的幻彩微粉抛光砖是在现有瓷质砖生产工艺：粉料加工、布料干压成型、干燥、烧成过程的基础上，在其花纹面料层中加入至少一种或几种透明熔块原料，与其它常规花纹面料、底料加工成型。
实施例2；
如图2所示，该实施例是通过在陶瓷基料层1上(基料层厚度15～18mm)，通过压机布料器3～4个面料料斗将不同的着色粉料不均匀混合落到面料料斗中，通过格栅将面料布到基料层上，得到随机布料的仿石材效果，上述的着色粉料可部分或全部使用本发明的全透明熔块原料2，通过不同的色料着色达到不同的石材效果。全透明熔块原料化学成分为：SiO262~68％，Al2O3 6~12％，Fe2O3+TiO2 0.1~0.4％，CaO 4~6％ MgO 0.5~2.5％，K2O 2~5％，Na2O 2~5％，BaO 1~3％。本实施例的幻彩微粉抛光砖是在现有瓷质砖生产工艺：粉料加工、布料干压成型、干燥、烧成过程的基础上，在其花纹面料层中加入至少一种或几种透明熔块原料，与其它常规花纹面料、底料加工成型。
Claims (4)
1.一种幻彩微粉抛光砖，包括花纹面料层和底料层，其特征在于：花纹面料层局部或全部使用全透明熔块原料；在全透明熔块原料中加入有机粘结剂，全透明熔块原料化学成分为：SiO2 62～68％，Al2O36～12％，Fe2O3+TiO2 0.1～0.4％，CaO 4～6％ MgO 0.5～2.5％，K2O 2～5％，Na2O 2～5％，BaO 1～3％，上述各组分含量之和为100％。
2.根据权利要求1所述的一种幻彩微粉抛光砖，其特征在于：全透明熔块原料与有机粘结剂混合球磨喷粉制备成一种花纹面料，其中有机粘结剂加入比例为0.3～2％；喷粉颗粒级配为：30目上：≥12％，60目上：≥65％，80目下：≤10％。
3.根据权利要求1所述的一种幻彩微粉抛光砖，其特征在于：将有机粘结剂破碎后与全透明熔块原料按比例15∶85混合制备成一种花纹面料，其中有机粘结剂破碎为10～40目，全透明熔块原料级配为40～100目。
4.根据权利要求1所述的一种幻彩微粉抛光砖，其特征在于：所述的有机粘结剂为水性石蜡，聚乙二醇，聚乙烯醇中的一种或几种。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008102204385A CN101503278B (zh) | 2008-12-25 | 2008-12-25 | 一种幻彩微粉抛光砖 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008102204385A CN101503278B (zh) | 2008-12-25 | 2008-12-25 | 一种幻彩微粉抛光砖 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101503278A CN101503278A (zh) | 2009-08-12 |
| CN101503278B true CN101503278B (zh) | 2011-06-15 |
Family
ID=40975669
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008102204385A Active CN101503278B (zh) | 2008-12-25 | 2008-12-25 | 一种幻彩微粉抛光砖 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101503278B (zh) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2671826Y (zh) * | 2003-12-18 | 2005-01-19 | 广东蒙娜丽莎陶瓷有限公司 | 一种抛光砖 |
| CN101260731A (zh) * | 2007-11-18 | 2008-09-10 | 广东博华陶瓷有限公司 | 一种抛光砖及其制造方法 |
-
2008
- 2008-12-25 CN CN2008102204385A patent/CN101503278B/zh active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2671826Y (zh) * | 2003-12-18 | 2005-01-19 | 广东蒙娜丽莎陶瓷有限公司 | 一种抛光砖 |
| CN101260731A (zh) * | 2007-11-18 | 2008-09-10 | 广东博华陶瓷有限公司 | 一种抛光砖及其制造方法 |
Non-Patent Citations (2)
| Title |
|---|
| JP特开平6-72754A 1994.03.15 |
| 吕淑珍.微晶玻璃陶瓷复合材料的研制.《装饰装修材料》.2003,(第7期),52-53. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101503278A (zh) | 2009-08-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107032772B (zh) | 一种透光陶瓷砖及其制备方法 | |
| CN103626523B (zh) | 一种干粒釉装饰表面的陶瓷砖及其制造方法 | |
| CN100408516C (zh) | 一种用于瓷砖坯釉一次压成形生产的干式釉料及制备方法 | |
| CN105330158B (zh) | 一种深色陶瓷的釉料及其制备方法 | |
| CN106986540B (zh) | 一种下陷剥开大理石釉制作配方 | |
| CN111233333B (zh) | 一种止滑釉料与止滑陶瓷砖及其制备方法 | |
| CN102731169A (zh) | 全抛釉瓷片及其制备方法 | |
| CN108129027B (zh) | 表面有金星石效果的析晶釉面砖、基础釉及其制备方法 | |
| CN112723870B (zh) | 一种具有颜色玉石效果的陶瓷岩板及其制备方法 | |
| CN103332968B (zh) | 一种全抛釉生产工艺及所制备的产品 | |
| CN104926281A (zh) | 一种低成本超白瓷质砖的制备方法 | |
| CN107266023B (zh) | 表面温润如玉有透光性的喷墨渗花瓷质抛光砖及制备方法 | |
| CN101634185A (zh) | 一种仿玉质大规格瓷板砖及其制备方法 | |
| CN102503583A (zh) | 一种大红釉骨质瓷的制备方法 | |
| CN106219976B (zh) | 一种综合装饰金属质陶瓷砖及其制造方法 | |
| CN110845252B (zh) | 特殊坯体大颗粒结合数码布料仿古砖及其制备方法 | |
| CN101164961A (zh) | 利用磷渣生产陶瓷砖的配方及生产方法 | |
| CN101306956B (zh) | 一种铜钱花釉的制作方法 | |
| CN104402531B (zh) | 一种3d釉料及其制备方法 | |
| CN101007731A (zh) | 一种半透明陶瓷砖及其制备方法 | |
| CN1640849A (zh) | 使微粉陶瓷抛光砖具有逼真石材效果的方法 | |
| CN101871254B (zh) | 硅质页岩炻质釉面砖瓦及生产方法 | |
| CN101503278B (zh) | 一种幻彩微粉抛光砖 | |
| CN109251019A (zh) | 玉质陶瓷砖及其生产方法 | |
| KR101017359B1 (ko) | 초강화자기, 초강화자기용 소지 및 그 제조방법 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: GUANGDONG MONOLISA NEW TYPE MATERIALS GROUP CO., L Free format text: FORMER OWNER: XIAO HUA Effective date: 20110705 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 528211 GUANGDONG MONALISA CERAMICS CO., LTD., TAIPING INDUSTRIAL ZONE, XIQIAO, NANHAI DISTRICT, FOSHAN CITY, GUANGDONG PROVINCE TO: 528211 TAIPING INDUSTRIAL ZONE, XIQIAO, NANHAI DISTRICT, FOSHAN CITY, GUANGDONG PROVINCE |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20110705 Address after: 528211 Taiping Industrial Zone, Nanhai District, Guangdong, Foshan, Xiqiao Patentee after: Guangdong Monalisa New Material Group Co., Ltd. Address before: 528211, Foshan Nanhai Xiqiao Taiping Industrial Zone Guangdong Guangdong Monalisa Ceramic Co., Ltd. Patentee before: Xiao Hua |
|
| C56 | Change in the name or address of the patentee | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 528211 Taiping Industrial Zone, Nanhai District, Guangdong, Foshan, Xiqiao Patentee after: MONALISA GROUP CO., LTD. Address before: 528211 Taiping Industrial Zone, Nanhai District, Guangdong, Foshan, Xiqiao Patentee before: Guangdong Monalisa New Material Group Co., Ltd. |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20211112 Address after: 528211 Xiqiao Textile City Industrial Park, Nanhai District, Foshan City, Guangdong Province Patentee after: Mona Lisa Group Co., Ltd Patentee after: Guangxi Monalisa New Material Co., Ltd Address before: 528211 Xiqiao Taiping Industrial Zone, Nanhai District, Foshan City, Guangdong Province Patentee before: Mona Lisa Group Co., Ltd |
|
| TR01 | Transfer of patent right |