CN101481169B - Compound active mineralization treating agent for improving quality of drinking water and method for producing the same - Google Patents
Compound active mineralization treating agent for improving quality of drinking water and method for producing the same Download PDFInfo
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- CN101481169B CN101481169B CN2008100638182A CN200810063818A CN101481169B CN 101481169 B CN101481169 B CN 101481169B CN 2008100638182 A CN2008100638182 A CN 2008100638182A CN 200810063818 A CN200810063818 A CN 200810063818A CN 101481169 B CN101481169 B CN 101481169B
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Abstract
The invention relates to a compound type active mineralization processing agent for improving drinking water quality and a method for producing same. The invention is characterized in that medical stone is compounded, modified and processed by using a physical method so as to adjust the specific surface area of the medical stone, increase the far infrared radiation rate, increase the potassium ion content, accelerate sterilizing, odor removing, activating and mineralizing speeds, particularly rapidly kill colon bacteria, staphylococcal bacteria and common bacteria in water, increase the potassium ion concentration and increase the sodium ion concentration so that the water has high potassium ion content, low active oxygen and oxidized free bases, many trace elements necessary to the human body and no bacterium and toxin. Thus, the water processed by the invention is suitable for most people to drink, in particular to middle-age and old-age people and patients with high blood pressure. The processing agent of the invention is prepared by using 30 to 40 weight percentages of medical stone, 20 to 30 weight percentages of tourmaline and 20 to 40 weight percentages of magnesium stone as main materials and 5 to 15 weight percentages of eleolite syenite as assistant material.
Description
One, invention field
The present invention relates to a kind of compound active mineralization treating agent that improves bottled water or tap water quality and preparation method thereof, particularly relating to a kind of physical method that utilizes to natural crystal---medical stone carries out fast processing, modification, processing and compound, the sterilization that its suitable barreled drinking water or tap water are used, deodorizing, dechlorination, purify, the water correction treatment agent of activation and mineralising, promptly with natural medical stone, tourmalinite and wagnerite are main raw material (through pyroprocessing), and be the combined type USING NATURAL MINERAL ADDITIVE that auxiliary material is made with nepheline syenite (preferably potassium felspar sand), the water quality after the processing has aseptic, low sodium, high potassium, low activity oxygen and oxidisability radical, suitable redox potential, the characteristics such as various trace elements of pH value and needed by human.Therefore, suitable most drunk by people, especially suitable the elderly and hypertensive patient's drinking-water demand.
Two, background of invention
Many in common knowledge, Ming Dynasty's physician's LI Shi-Zhen had very detailed record to medical stone in Compendium of Material Medica, say that it is in the mountain stream, its stone such as fist, and as the goose ovum, profile is quite as a wheat meal that bonds together.Swell with its treatment ulcer carbuncle on the back, sore, efficacious invariably.Prove that now in a single day medical stone puts into water is not the stripping mineral substance, and the effect that makes the water sensitization is arranged.Its effect is as follows:
(1) adsorptive power is strong
Medical stone has porousness.Do the time spent as catalyzer and water, its huge surface-area will make water that some physics and chemical reaction take place, for example:
Chemisorption---intermolecular solvent action makes it be decomposed into positively charged ion and negatively charged ion.The atom, the ion that decompose are attracted on other materials.
Physisorption---the atom of contact medium surface adsorption is attracted to come, become positively charged ion and negatively charged ion.Its adsorption is mainly determined by three factors of granularity, ionization, temperature of medical stone.
A this neutron coupling and two electron coupling of being adsorbed with, medical stone is two electron coupling.It has stronger adsorptive power to harmful element such as cadmium, lead and to bacterial mass etc.Therefore, when dropping into medical stone in the water, can be with absorption, decomposition such as the free chlorine in the water and some impurity, organism, the bacterium of mixing.
(2) stripping mineral substance
After medical stone is immersed in water, can stripping potassium, indispensable nearly 20 kinds of trace elements of human body and mineral substance such as sodium, calcium, magnesium, silicon, manganese, titanium, phosphorus.Contain an amount of mineral substance in the water, can improve water quality, the effect of inhibition bacterium (propagation of bacterium class is stopped) also being arranged.Therefore, it can prevent the sealing corruption.
(3) adjust water quality
In water, there is not iron, magnesium, during mineral substance such as fluorine, then they are dissolved, on the contrary when having too much iron, magnesium, fluorine in the water, then they are adsorbed.
(4) medical stone has stronger far infrared radiation ability, and its radiant ratio is 93%.This can bacteria growing inhibiting and has a stronger deodorization.
In a word, as if energy long-term drinking Chinese medical stone water, can strengthen the immunologic function of human body, improve nutrition, improve the resistibility of health, yet anything be divided into two all, medical stone is no exception.Also there is some problem and shortage in it:
(1) potassium in the medical stone, sodium, calcium, silicon, magnesium, manganese, titanium, phosphorus plasma are indispensable to human body, but the amount of the potassium in the medical stone usually only be sodium amount 10%.We know that sodium ion has the effect that increases human blood-pressure, and potassium ion has the effect that reduces human blood-pressure.For the blood pressure that makes human body keeps normal value, particularly be fit to the needs of the elderly, Hypertensive Population, must adjust medical stone water quality, promptly adopt combined type medical stone water quality to regulate additive in order to increase the content of potassium.Certainly, also can adopt the reinforced medical stone water quality of sodium ion to regulate additive formulations, so that adapt to ypotension crowd's demand.
(2), in the tap water of China usually with chlorine as sterilizing agent, disinfectant.Therefore, the water that long-term drinking is chloride will bring very big injury to health.Modern scientific research shows that after the chlorine in the water is by the human intake, chlorine will destroy the VITAMIN in the food, perhaps enters skin and destroys cell, kills intravital beneficial microorganism.In addition, after the chlorination, it will react with the organic soil ulmin in the water, produces haloform in the water.Its main resultant comprises chloroform (CHCl
3), a bromodichloromethane (CHBrCl
2), dibromo monochloro methane (CHBr
2Cl), bromofom (CHBr
3) etc., they all have carcinogenic danger.
Though medical stone water purifier in the past utilizes the characterization of adsorption of medical stone can remove a certain amount of chlorine in the tap water, can not produce the water of suboxide reduction potential that contains a large amount of active hydrogens and the pH value that suits.Obviously, combined type medical stone water quality conditioner formulations must be considered this point.
(3) a lot of bottled water water dispensers of selling in the market are because the defective or the improper use of design, (alkalescent water is full of active hydrogen perhaps bottled water to be adjusted to weakly alkaline, its redox potential is low, can reduce the active oxygen in the source of ten thousand diseases), but bring side effect:
Often grow a large amount of bacteriums, therefore do not play water dispenser and produce safety, health, healthy with effect at bottleneck.In other words, though fresh weakly alkaline bottled water is quite helpful to human body, but weak base water helps the breeding of some germ, particularly intestinal bacteria, a large amount of breeding of staphylococcus.Because the top layer of bacterium such as intestinal bacteria, staphylococcus (outer wall) is anionic, so bacteriums such as intestinal bacteria, staphylococcus are difficult for existence in neutral water.Therefore, combined type medical stone water quality conditioner formulations must be considered this point.
When (4) using medical stone for a long time, the impurity that the surface of its particle pore often is adsorbed is full of, and the surface is contaminated, has therefore reduced the surface-area that contacts with water molecules, thereby causes the meltage of trace element to reduce sharply, and has to medical stone granule: is cleaned.There are a lot of corner angle in the non-sphere of the particle of present most medical stones, and sharper, causes unnecessary damages to the people easily during cleaning.In addition, the medical stone granule: particle diameter difference of employing, the particle diameter ratio that has is big (〉=￠ 15), the particle diameter ratio that has less (≤￠ 1).If particle diameter 〉=￠ 15, particulate weight is too big so, and particle is difficult for moving or vibration, is unfavorable for water quality regulation; If particle diameter≤￠ 1, particle grain size is too little so, and the landing net hole of sealing of medical stone must be thinner, in case particle spills.Therefore, all be unfavorable for the fast processing and the adjustment of water quality.In other words, the specific surface area of medical stone granule: is not maximum, thereby the ion speed of separating out of sterilization and filtering speed and trace element is neither good.
(5) present tap water mineral processing additive purifies usually, the processing of activation and mineralising and adjust overlong time, and great majority need about eight hours.This far can not satisfy service requirements.
(6) well-known, oxygen is the essential material of human survival.In the past, people think mistakenly that always oxygen has hundred benefits and none evil; And modern medicine identification recently, oxygen also has the disadvantageous one side of pair human health, active oxygen particularly, and it is the source of ten thousand diseases.
According to the literature, active oxygen and oxidisability radical are rather harmful to human body.They have become recycle system obstacle (myocardial infarction, arrhythmia, arteriosclerosis etc.), respiratory system obstacle (respiratory tract infection, pneumonia, pulmonary emphysema etc.), cerebral nervous system obstacle, Digestive tract obstacle (stomach ulcer, ulcerative colitis, hepatitis, liver cirrhosis etc.), the endocrine system obstacle of human body, and the inducement of illness such as diabetes, adrenal gland metabolic disturbance.For example, the chlorine in the tap water is a kind of strong oxidizer, so tap water has become the very strong water of oxidizing power.In other words, the redox potential of tap water is higher, and this will encourage oxygen production, causes the dysoxidation disease, but medical stone but can not produce the water of suboxide reduction potential that contains a large amount of active hydrogens and the pH value that suits.
In view of above-mentioned condition, a lot of people improve conventional Chinese medical stone water treatment agent, for example: Chinese patent CN1436738 (ecological water and production method thereof), CN1413921 (anion ceramic material for water purifying), CN1091397 (water mineralizing agent using Chinese medical stone), CN1093061 (little sintered compact of All Pure Nature and production skill thereof), CN1087875 (a kind of purifying and mineralizing material that is used for tap water), CN1089922 (mineral water made by soaking bagged mineral), CN1101014 (a kind of mineralizing and filtering agent for drink water), CN1121489 (preparation method of high-effect drinking-water mineralizing agent), CN1144774 (pure-mineralized material for drinking water), CN1153744 (a kind of solute of producing mineral water), CN1220846 (beverage and the manufacturing process thereof that contain medical stone granule :) etc., but also nobody utilizes physical method that the natural medical stone ore is carried out Combined Processing at present, processing and integration, regulate the potassium in the medical stone, containing of sodium is proportional, increase its specific surface area, improve its far infrared radiation rate, reduce active oxygen and oxidisability radical thereby reach, adjust the pH value of water, for a long time, kill intestinal bacteria effectively, staphylococcus and general bacterium, make its water quality have low sodium, high potassium, suboxide reduction potential and suitable pH value, so that be fit to most drunk by people, especially suitable the elderly, the hypertensive patient drinks water, and (we know demand, sodium ion has the effect that improves human blood-pressure, and potassium ion has the effect that reduces human blood-pressure).
The present invention proposes a kind of physical method that utilizes natural crystal is carried out Combined Processing, processing and integration, has made sterilization, deodorizing, dechlorination, purification, activation, mineralising and the low activity oxygen of suitable bottled water or tap water use and the water quality treatment agent of oxidisability radical.Its suitable all kinds of crowd's (in comprising, the elderly and hypertensive patient and ypotension crowd) drinking-water demand.Be main raw material (being placed on stainless steel seals in the sack of bag) promptly, and be the combined type natural mineral water conditioner of auxiliary material (being placed in the pouch that stainless steel seals bag) making with nepheline syenite (preferably potassium felspar sand) with natural medical stone, tourmalinite (through pyroprocessing) and wagnerite (magnesia stone).
Three, goal of the invention
In view of the defective of present medical stone water quality treatment agent, the objective of the invention is to make a kind of water conditioner of combined type natural mineral.It is with natural medical stone, tourmalinite and wagnerite (magnesia stone) are main raw material (being placed on stainless steel seals in the sack of bag), with nepheline syenite (preferably potassium felspar sand) is auxiliary material (being placed on stainless steel seals in the pouch of bag), potassium in the water conditioner of adjusting combined type natural mineral, containing of sodium is proportional, increase its specific surface area, improve its far infrared radiation rate, reduce active oxygen and oxidisability radical thereby reach, adjust the pH value of water, for a long time, kill intestinal bacteria effectively, staphylococcus and general bacterium, make its treated water matter have aseptic, nontoxic, low sodium, high potassium, the suboxide reduction potential, the suitable pH value and the trace element of multiple needed by human, so that satisfy most crowd demands, especially suitable the elderly, the hypertensive patient drinks.
Four, optimal technical scheme
If with " specific surface area is big, far infrared energy radiant ratio height, strong to the colibacillary power of killing, to staphylococcus kill that power is good, reactivity good, mineralising is good " be the technical examination index, use any in medical stone, tourmalinite, wagnerite (magnesia stone), the nepheline syenite (preferably potassium felspar sand) so individually, its effect all can not be satisfactory.In other words, necessary employing is compound.Experiment shows that the compound of above-mentioned four kinds of mineral is not the simple superposition of their independent effects, but " strong and strong associating ", or even multiplying each other of effect separately.
The present invention be utilize physical method to natural crystal transform, Combined Processing, processing, make the water correction treatment agent of sterilization, deodorizing, dechlorination, purification, activation and mineralising that a kind of suitable bottled water or tap water use.
We know that tourmalinite is a kind of very precious non-metallic ore.It is unique with the state of nature ore of radiating electron for good and all in the tellurian mineral, and its main component has more than 10 kind of trace elements to the human body beneficial such as magnesium, iron, boron.Tourmalinite is the special polarity xln of a kind of structure, and self can generate electricity, and for good and all discharges negative ion and far infrared rays.Its principal feature is as follows:
(1) can produce a large amount of negative ions chronically
Human now living environment has many factors of impelling positively charged ion to generate, so people's health often is in nervous state.Obviously, negative ion is the indispensable material of modern.Tourmalinite has stronger piezoelectricity and pyroelectricity characteristic, can produce a large amount of negative ions.Many in common knowledge, negative ion has the effect of the human body of adjusting ionic equilibrium, and people's body and mind is loosened, and makes its cell activation, improves effects such as nature curative ratio, and can play oxidation and the solarization that suppresses health.
(2) electrolytic effect of water (activating effect of water)
When tourmalinite contacted with water, then moment will produce discharge, made water that slight electrolysis take place.Positively charged ion will be attracted by negative potential, combine with the electronics of emitting, and become hydrogen and emit, thereby water become weakly alkaline.Electrolytic result can obtain passivation, the water of stabilization, the iron of activation, the chlorine at interface reductive action, can eliminate certain micro-organisms aggregate etc.Present soapless soap and some chemical substance all are difficult to the problem of solution, and the electrolytic reaction that utilizes tourmalinite to contact with water just can make problem be readily solved.
(3) dwindle the water molecules bundle, make it become delicious aseptic tap water
Usually, water molecules (H
2O) be not Individual existence, its molecule will mutually combine, and forms molecule group (being called molecular beam).Tourmalinite radiating far infrared rays not only can cut off the water molecules bundle, removes chlorine or impurity in the water, makes the taste of water good, and can increase the seepage force to health, improves immunizing power.
(4) a large amount of wavelength of radiation is 4～14 microns a far infrared rays
As everyone knows, wavelength is the deep layer position that 4～14 microns far infrared rays can be penetrated into health, and activating cells stimulates circulation, and makes metabolism more smooth and easy.The far infrared rays emittance of tourmalinite nearly 91%, more much higher than some natural mineral.
(5) contain multiple effective trace mineral
Tourmalinite contains multiple natural mineral matter, and it is human essential wherein having many.It can be by the effect of weak current, makes that multiple natural mineral matter is easier to be absorbed.
Actual measurement shows that the far infrared energy radiant ratio of tourmalinite is 91%, is 67% to staphylococcic eradicative rate, and only is 75% to colibacillary eradicative rate.Regrettably, during the direct treating water of tourmalinite, the sodium ion of generation is more.If do not transform, Combined Processing, it is not suitable for the elderly and the hypertensive patient drinks.Experiment showed, that after making tourmalinite water-soluble sodium ion but reduces tempestuously in the tourmalinite, and can keep stable by water-soluble calcium ion through 450～750 ℃ thermal treatment.Different with it is, medical stone is insensitive to the heat treated temperature, and along with the rising of thermal treatment temp, potassium ion soluble in water, sodium ion and calcium ion almost remain unchanged.
As everyone knows, wagnerite (magnesia stone) is one of main source of magnesium oxide (MgO) production, and its MgO content accounts for about 47%.Actual measurement shows that its far infrared rays emittance is up to 95%, and more valuable is extremely strong to intestinal bacteria and the staphylococcic power of killing.It is 98% to staphylococcic eradicative rate, is 99% to colibacillary eradicative rate.It is in order to improve the far infrared radiation rate that the present invention uses the purpose of wagnerite (magnesia stone), replenish the deficiency of medical stone, make the mineral processing additive have sterilization efficiently and go out virus capable and the sterilization quite grown is held time intestinal bacteria and the staphylococcic power of killing.
Lasting, long-acting for the effect that makes the mineral processing additive, must carry out suitable calcination processing to wagnerite (magnesia stone).Calcining temperature and time are the keys of decision MgO activity, dispersity.Magnesite decomposition reaction in calcining is thermo-negative reaction in the time of 400 ℃～600 ℃.Owing to decomposite CO
2And H
2O, the porous crack crystalline structure that makes MgO form is not fine and close, and product activity is good, and dispersity is big.Crystal densification when temperature is higher than 900 ℃, dispersity is little, and activity is also little.Calcination time is longer, and crystalline structure is just finer and close, is difficult to aquation.In other words, calcining temperature is higher, and calcination time is longer, and then the mineral processing additive effectiveness time is longer.
The purpose that the present invention adds nepheline syenite is the potassium content that improves in the processed water.We know that nepheline syenite and potassium felspar sand are the higher feldspars of a kind of potassium content, and its molecular formula is K
2OAl
2O
36SiO
2, K wherein
2O accounts for 9.55%, Al
2O
3Account for more than 16% SiO
2Account for more than 70%, its density is 2.56g/cm
3The proportion of potassium felspar sand is 2.56～2.59g/cm
3, its theoretical composition is SiO
2Account for 64.7%, Al
2O
3Account for 18.4%, K
2O accounts for 16.9%.It has potassium amount height, and the far infrared energy radiant ratio is than characteristics such as height.
In sum, the far infrared energy radiant ratio of medical stone is 93%, is 70% to staphylococcic eradicative rate, and is 65% to colibacillary eradicative rate.The far infrared energy radiant ratio of tourmalinite is 91%, is 67% to staphylococcic eradicative rate, and only is 75% to colibacillary eradicative rate.The far infrared energy radiant ratio of wagnerite (magnesia stone) is 95%, is 98% to the staphylococcus eradicative rate, only is 99% to colibacillary eradicative rate.In addition, above-mentioned mineral all include more silica, and therefore, they all have certain deodorizing characteristic.Obviously, use medical stone, tourmalinite, wagnerite (magnesia stone), nepheline syenite (preferably using potassium felspar sand) separately, its characteristic all can not be satisfactory.Therefore, must adopt the composite natural mineral additive.
The present invention is to be that (promptly medical stone accounts for 30%～40% weight ratio to main raw material in prescription with natural medical stone, tourmalinite and wagnerite (magnesia stone), tourmalinite accounts for 20%～30% weight ratio, wagnerite (magnesia stone) accounts for 20%～40% weight ratio, and be auxiliary material with nepheline syenite (preferably using potassium felspar sand), promptly wherein nepheline syenite (or potassium felspar sand) accounts for the combined type natural mineral treatment agent that 5%～15% (its ratio is a weight ratio) made, and makes bottled water or tap water purification, activation and mineralising.
In order to enhance productivity, reduce the probability that pollutes, improve the specific surface area of combined type natural mineral treatment agent, increase processing speed, make its long-actingization, the grain diameter of natural medical stone, tourmalinite, wagnerite (magnesia stone) and nepheline syenite is processed into ￠ 1～￠ 10mm, and (the medical stone particle diameter is Φ 2.0mm, the tourmalinite particle diameter is Φ 3.0mm, the wagnerite particle diameter is Φ 6.0mm, and the nepheline syenite particle diameter is Φ 2.0mm), promptly the ratio of their particle diameter is 1: 1.5: 3: 1.
If particle diameter 〉=￠ 10, particulate weight is too big so, and particle is difficult for moving or vibration, is unfavorable for water quality regulation; If particle diameter≤￠ 1, particulate weight is too little so, and sealing the landing net hole must be thinner, therefore, is unfavorable for the adjustment of the fast processing and the water quality of water.In addition, processed water is reasonably flowed, allow the particle of mineral processing agent and current collide as far as possible, so that increase contact area and duration of contact, the probability that increases frequency of exposure and contact, the speed of acceleration drink water purifying, activation and mineralising with various components.
In order to improve the life-span of combined type natural mineral treatment agent, prevent that (for example, non-woven bag) breakage and going mouldy, the present invention adopts 316 Stainless Steel Wires or the bag weaved packing of 304 Stainless Steel Wires in conventional packing bag.Big packed be major ingredient, little packed be auxiliary material.
Five, example of the present invention
Compound active mineralization treatment additive of the present invention is to be major ingredient with medical stone (weight ratio 30～40%), tourmalinite (weight ratio 20～30%) and wagnerite (weight ratio 20～40%), is that auxiliary material is made with nepheline syenite (weight ratio 5～15%).
Medical stone in the prescription is the natural mineral in Naiman Banner tafelberg, Zhelimu League, Inner Mongolia Autonomous Region.This medical stone composition is as follows:
(1) iron protoxide 1.29%; (2) ferric oxide 1.40%; (3) anhydrous phosphorus (phosphoric anhydride) 0.26%; (4) manganese oxide 0.02%; (5) magnesium 3.55%; (6) potassium 3.19%; (7) planar water 1.10%; (8) calcium oxide 2.00%; (9) sodium 3.16%; (10) titanium 0.30%; (11) combination water 0.90% (+).This medical stone does not contain radiant.
Tourmalinite in the prescription is the wide first mineral products process plants of the Bei Tun of Altay Prefecture, Xinjiang, and its chemical ingredients is as shown in table 1.
The chemical ingredients of table 1 tourmalinite (weight %)
| ?MgO | ?K 2O | ?Na 2O | ?TiO 2 | ?Li 2O |
| ?8.71 | ?0.48 | ?1.90 | ?0.76 | ?0.008 |
| ?B 2O 3 | ?SiO 2 | ?Fe 2O 3 | ?AL 2O 3 | ?CaO |
| ?9.72 | ?36.72 | ?4.77 | ?31.08 | ?0.98 |
Wagnerite in the prescription (magnesia stone) is that Haicheng City, Liaoning Province produces.The composition of its wagnerite is as follows:
MgO≥47％，SiO
2≥0.6％，CaO≤0.6％
Nepheline syenite is that Fengcheng City, Liaoning Province horse racing limited liability company produces in the prescription.The chemical ingredients of the nepheline syenite of domestic main manufacturer is as shown in table 2.
The chemical ingredients of the nepheline syenite of the domestic major vendor of table 2 (%)
| SiO 2 | Al 2O 3 | Fe 2O 3 | ?FeO | ?Na 2O | ?K 2O | ?CaO | ?MgO | ?TiO 2 | MnO | ?Cr 2O 3 | ?P 2O 5 | ?NiO | ?SrO | ?CO 2 | |
| Yongsheng village, Huadian, Jilin raw ore | 59.2 | ?18.18 | Contain: 5.43 | ?6.65 | ?5.38 | ||||||||||
| Yongsheng village, Huadian, Jilin concentrate | 59.2 | ?19.67 | ?19.67 | ?- | ?7.56 | ?6.52 |
| Liaoning Feng Cheng horse racing | 54.13 | ?17.58 | ?6.11 | ?1.04 | ?4.46 | ?10.13 |
The potassium content of the nepheline syenite that Fengcheng City, Liaoning horse racing company produces is much larger than its sodium content.Therefore, decision selects for use the nepheline syenite of Fengcheng City horse racing company production as raw material of the present invention.
Preparation example 1
Adopt 316 Stainless Steel Wires or 304 Stainless Steel Wires bag weaved (or other aseptic nontoxic packing bag) packing.Big packed be major ingredient, little packed be auxiliary material.
In order to enhance productivity, reduce the probability that pollutes, improve the specific surface area of combined type natural mineral treatment agent, improve the processing speed of combined type natural mineral treatment agent, make its long-actingization, the grain diameter of natural medical stone, tourmalinite, wagnerite (magnesia stone) and potassium felspar sand is processed into ￠ 1～￠ 10mm, preferably the medical stone particle diameter is Φ 2.0mm, the tourmalinite particle diameter is Φ 3.0mm, sparring stone particle diameter Φ 6.0mm,, the potassium felspar sand particle diameter is Φ 2.0mm, the ratio of their particle diameter is 1: 1.5: 3: 1.
Its manufacture method is as follows:
(1) by following specification requirement each component raw material is processed into the work in-process particle:
The medical stone particle diameter is Φ 2.0mm, and the tourmalinite particle diameter is Φ 3.0mm, and the wagnerite particle diameter is Φ 6.0mm, and the nepheline syenite particle diameter is Φ 2.0mm, and the ratio of their particle diameter is 1: 1.5: 3: 1.
Each component particles that (2) will prepare is heat-treated by following technical qualification:
The medical stone granule: that has prepared is placed in retort furnace or other heating unit, under natural atmosphere, heats 300～600 ℃, be incubated after 6 hours, be cooled to room temperature more naturally;
The tourmaline particle that has prepared is placed in retort furnace or other heating unit, under natural atmosphere, is heated to 400～650 ℃, be incubated after 4 hours, be cooled to room temperature more naturally;
The wagnerite particle that has prepared is placed in retort furnace or other heating unit, under natural atmosphere, is heated to 300～750 ℃, be incubated after 4 hours, be cooled to room temperature more naturally;
(3) mixing in following ratio (weight ratio): medical stone 30～40%, tourmalinite 20～30%, wagnerite 20～40%, nepheline syenite 5～15% through heat treated each component particles;
(4) utilize mechanical mixing method, making, blended medical stone, tourmalinite, wagnerite and nepheline syenite particle stir, mix;
(5) the medical stone that stirs, tourmalinite, wagnerite and nepheline syenite particulate mineral intermixture according to certain weight requirement, what the stainless steel woven wire of packing into was made seals in the bag (or other aseptic nontoxic packing bag), after 100～120 ℃ of sterilizations, pack in the aseptic nontoxic packing box, be finished product.Wherein, medical stone, tourmalinite, wagnerite particulate mineral intermixture are loaded into sealing greatly in the bag (or other aseptic nontoxic packing bag) that the stainless steel woven wire makes, and the nepheline syenite particulate mineral is packed in the parcel envelope (or other aseptic nontoxic packing bag) that the stainless steel woven wire makes.
The former general population's drinking-water demand of (comprising the ypotension crowd) that suits, and the latter mainly is fit to the elderly and hypertensive patient's drinking-water demand.
Preparation example 2
Be that with example 1 difference the medical stone in the sack accounts for 30%～35%, tourmalinite accounts for 25%～30%, wagnerite (magnesia stone) accounts for 35%4～0%, and they sealing greatly in the bag (or other aseptic nontoxic packing bag) that the stainless steel woven wire makes of packing into.At this moment, place this bag (together with raw material wherein) process furnace (120 ℃) under natural atmosphere, to be incubated 1 hour again, 350 ℃ of insulations 3 hours, drop to room temperature at last then, pack in the aseptic nontoxic packing box, just become product.Its suitable popular crowd's drinking-water demand.
Six, Fa Ming effect
Detection shows through relevant department, organism overall average clearance in the tap water is reached 98.2%, dirt clearance effects such as alkane, aromatic hydrocarbon, heterocycle are obviously reached more than 99%, clearances such as poisonous in the water, harmful, carcinogenic substance, anion synthetic detergent, vitriol, muriate, fluorochemical, prussiate, arsenic, mercury, cadmium, chromium (6 valency), lead, silver, nitrate, chloroform, tetracol phenixin, dichlorodiphenyl trichloroethane, phenyl-hexachloride, bacterium are reached more than 98%.Simultaneously, stripping potassium, calcium, sodium and magnesium etc. are of value to the material of HUMAN HEALTH, and its water quality is as clear as crystal, the taste slightly sweet.
It is worthy of note especially, as shown in table 3, adopt in the water of combined type mineral processing additive of the present invention stripping, its potassium concentration is much larger than Na ion concentration.Therefore, quite suitable numerous crowds, especially the elderly, hyperpietic drink (we know that sodium ion has the effect that improves human blood-pressure, and potassium ion has the effect that reduces human blood-pressure).From table 3 also as can be seen, the dissolution rate of combined type mineral processing additive of the present invention is much better than common medical stone mineral treatment agent.In other words, the speed of purification, activation and the mineralising of combined type mineral processing additive of the present invention is fast.
The principal element amount of table 3 combined type mineral processing of the present invention agent stripping
| Dissolution time | The kind of the principal element of stripping | |||
| K | ?Ca | ?Na | ?Mg | |
| 30 seconds | 0.15 | ?0.14 | ?0.14 | ?0.14 |
| 60 seconds | 0.26 | ?0.27 | ?0.25 | ?0.27 |
| 10 minutes | 2.12 | ?3.18 | ?0.80 | ?1.33 |
| 30 minutes | 4.96 | ?4.66 | ?3.20 | ?5.48 |
| 90 minutes | 19.34 | ?18.73 | ?11.51 | ?15.55 |
| 180 minutes | 31.72 | ?26.52 | ?17.43 | ?35.13 |
This is because medical stone, acetylene, the reasonable ratio of the combined type natural mineral treatment agent of wagnerite (magnesia stone) and nepheline syenite, the specific surface area of mineral intermixture is big, the radiation of far infrared energy is strong, thereby the resonance that causes energy in the water, make the objectionable impurities (heavy metal etc.) in the water promptly be adsorbed and eliminate, multiple beneficial is dissolved in the material of HUMAN HEALTH, and the link between the water molecules is cut off, reduced the coupling between them, it is little to become the molecule bonding force, the water that proportion is bigger has changed pH value (pH value) simultaneously, becomes the ideal activated water, mineralized water.
Because the top layer of bacterium such as intestinal bacteria, staphylococcus (outer wall) is anionic, so bacteriums such as intestinal bacteria, staphylococcus are difficult for existence in neutral water.The present invention utilizes medical stone, tourmalinite, wagnerite (magnesia stone) and nepheline syenite to have the positively charged ion that very high far infrared energy radiant ratio is produced, make that the top layer (outer wall) of bacteriums such as the intestinal bacteria present anionic, staphylococcus is destroyed, make and its bacterium protein sex change cause expiratory dyspnea and death.
Combined type mineral processing additive of the present invention not exclusively is common physical adsorption and chemisorption to the deodorizing mechanism of hydrogen sulfide and ammonia, but because the Decomposition that the far-infrared ray power radiation produces.It is different with common physical adsorption and chemisorption, can not be saturated, and also nontoxic, and can exist for a long time.Its sterilization, sterilization functions also are like this.Therefore, drink this kind activation, mineralized water, can promote the activation of cell, improve immunizing power, its quite suitable numerous crowd, especially the elderly, hyperpietic drink.
Claims (3)
1. compound active mineralization treating agent that improves quality of drinking water, it is to be made of major ingredient bag and accessory package, and be loaded into aseptic, in the nontoxic packing box, the major ingredient bag that it is characterized in that this compound active mineralization treating agent is medical stone, tourmalinite and wagnerite particulate mineral intermixture pack that the stainless steel woven wire makes into seals greatly and constitutes in the bag, accessory package is the nepheline syenite particulate mineral to be packed into constitute in the parcel envelope that the stainless steel woven wire makes, the weight percent content of above-mentioned each component is respectively: medical stone is 30～40%, tourmalinite is 20～30%, wagnerite is 20～40%, and nepheline syenite is 5～15%.
2. according to the described compound active mineralization treating agent that improves quality of drinking water of claim 1, it is characterized in that the medical stone particle diameter is Φ 2.0mm, the tourmalinite particle diameter is Φ 3.0mm, the wagnerite particle diameter is Φ 6.0mm, the nepheline syenite particle diameter is Φ 2.0mm, and their particle diameter ratio is 1: 1.5: 3: 1.
3. making method of improving the compound active mineralization treating agent of quality of drinking water is characterized in that comprising following processing step:
(1) each component raw material is prepared raw material work in-process particle by following specification requirement:
The medical stone particle diameter is Φ 2.0mm, and the tourmalinite particle diameter is Φ 3.0mm, and the wagnerite particle diameter is Φ 6.0mm, and the nepheline syenite particle diameter is Φ 2.0mm, and its particle diameter ratio is 1: 1.5: 3: 1;
(2) heat-treating by following technical qualification at each component raw material particle of step (1) preparation:
The medical stone granule: that has prepared is placed in the retort furnace, under natural atmosphere, heats 300～600 ℃, be incubated after 6 hours, be cooled to room temperature more naturally; The tourmaline particle of preparation is placed in the retort furnace, under natural atmosphere, is heated to 400～650 ℃, be incubated after 4 hours, be cooled to room temperature more naturally; The wagnerite particle that has prepared is placed in the retort furnace, under natural atmosphere, is heated to 300～750 ℃, be incubated after 4 hours, be cooled to room temperature more naturally;
(3), should the employing ratio prepare, promptly through heat treated each component particles of step (2)
Medical stone is 30～40%, and tourmalinite is 20～30%, and wagnerite is 20～40%, and nepheline syenite is 5～15%;
(4) utilizing mechanical mixing method, is proportioning 30～40% medical stone, 20～30% tourmalinite, 20～40% wagnerite particle mixing, the formation that stirs major ingredient;
(5) the medical stone that stirs in step (4), tourmalinite, wagnerite particulate mineral intermixture according to certain weight require to weigh, packing, that puts into that the stainless steel woven wire makes seals bag greatly, constitutes the major ingredient bag;
(6) the nepheline syenite particle of in step (3), weighing according to the weight of step (5) require to weigh, packing, put into the parcel envelope that the stainless steel woven wire is made, constitute accessory package;
(7) the major ingredient bag through 100～120 ℃ of sterilizations after, pack in the aseptic nontoxic packing box I, be the finished product I;
(8) major ingredient bag and accessory package through 100～120 ℃ of sterilizations after, pack in the aseptic nontoxic packing box II, be the finished product II.
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| CN102161545A (en) * | 2011-02-26 | 2011-08-24 | 福建金源泉科技发展有限公司 | Function faucet activator |
| CN102697279A (en) * | 2012-06-14 | 2012-10-03 | 王美岭 | Drinking water bottle capable of generating hydrogen rich water |
| CN106554060A (en) * | 2015-09-28 | 2017-04-05 | 中国环境科学研究院 | A kind of nitrogen-phosphorus wastewater processes method and medicament with resource reclaim |
| LT6452B (en) | 2015-10-07 | 2017-09-11 | Kauno technologijos universitetas | Safe and healthy drinking water and method of its preparation |
| CN107344762A (en) * | 2017-07-17 | 2017-11-14 | 杜永健 | Bar bag and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation and its preparation and application |
| CN107176636A (en) * | 2017-08-01 | 2017-09-19 | 广州好茗源净水设备有限公司 | A kind of production method of hydrogen-rich filter core |
| CN109517409B (en) * | 2018-11-12 | 2021-01-29 | 金官根 | Modified medical stone powder and application thereof in environment-friendly coating |
| CN110436557A (en) * | 2019-07-29 | 2019-11-12 | 平武县颐生泉生物科技开发有限公司 | A kind of preparation method of mountain spring water |
| CN112960746A (en) * | 2021-02-04 | 2021-06-15 | 中国科学院沈阳应用生态研究所 | Method for removing escherichia coli and pathogens in wastewater by using active material |
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