KR101893639B1 - Loessal water including mineral elements - Google Patents

Abstract

The present invention relates to a mineral preparation for producing a mineral detergent containing a mineral component. The mineral detergent comprises a mixture of 60 wt% of yellow earth, 10 wt% of cerasite, 20 wt% of elvan, 10 wt% Treating it by high heat treatment, dissolving it in water or deep sea water, filtering the supernatant, filtering and sterilizing it to produce trap water. Mineral materials made by mixing yellow loess, cerasite, elvan sand, and Dongsan NC, which contain large amounts of minerals, are easy to carry and can easily be melted in deep seawater and general fresh water. .

Description

[0001] The present invention relates to a mineral preparation containing a mineral component,

The present invention relates to a mineral preparation containing a mineral component and to a mineral support produced using the same. More particularly, the present invention relates to a method for producing a mineral retainer containing a mineral component which can be used in various fields by producing a mineral retainer prepared by mixing a solid inorganic material which is easily dissolved in water such as yellow clay.

Hwangto is a natural soil composed of silica and soil containing iron oxide and anhydrous iron oxide. It can be easily obtained from all over Korea. In particular, loess in Jeollanamdo region contains a lot of iron oxide and strong red color. It has a strong yellow color.

In terms of microbiology, it is known that loess is excellent in living tissues, and it is known that about 200 million microorganisms live in a spoon of loess, and microorganisms have various enzymatic circulation functions. There are about 50 kinds of enzymes active in the soil, Thiophenol oxidase, saccharase, and protease.

Catalase (Kataliase) is a detoxifying effect that removes toxins by decomposing lipid peroxidation that accelerates the aging of human body into water and oxygen, Diphenoloxydase is an organic substance decomposition function which acts as a sulfating agent, Protease activates the activity of growth, which acts as a protease to hydrolyze the amino acid in the protein to eliminate the body waste and anti-corruption function.

Yellow clay is a loamy soil, also known as water-free water. If you dig a pit more than 60cm in the loamy soil of a sunny field or deep ridges, the soil like blue stripes will come out. And yellow loess at a suitable ratio, and then, after a few times of mixing, the impurities fall down to a certain amount of time, and the result is a pale yellowish water. Since Hwangtojigusu contains the advantages of Hwangto component, it has been applied to various methods until now.

The general production process of yellow clay loam is as follows. Yellow loess is generally used with red ocher, and ground ocher which is about 1m from surface layer is taken in consideration of soil contamination. Fine ground loess is mixed with ground water coming out from 150m deep well for at least 24 hours. When ground water is put into fine ground loess, microscopic impurities come out along with bubbles, and these impurities are filtered using a filter box. After the impurities are filtered out, the mixture is left to stand for 3 days after stirring, and only the supernatant is extracted from the stirred tank.

Hwangpo jigyeo is a water containing good ingredients of loess, cleansing the blood, normalizing hormone secretion of the body endocrine gland, separating and releasing harmful components to the body, maintaining the acidified body as a weak alkaline body fluid, And so on.

On the other hand, deep ocean water is a sea water of 200m or more, which is almost no sunlight. It is located far away from the coast and has a structure that is not mixed with surface water or surface water due to difference in surface water, temperature and density. And is known as a marine water resource that maintains clean characteristics. Especially, since deep seawater contains a large amount of various minerals such as zinc, selenium and manganese as well as the four major minerals (magnesium, calcium, potassium and sodium) in the deep sea water, Has been utilized as a field.

The minerals contained in deep ocean water are one of the five nutrients needed by humans, and play a role in body composition, body function control, and so on. Deficiency and excess of minerals hinders physical and mental development and causes various diseases, so it is important to maintain the mineral balance in the body. Mineral components contained in deep seawater are 100% water-soluble, so they can easily be absorbed into the body and become a very useful mineral source for modern people whose mineral balance has fallen due to erroneous eating habits and environmental pollution.

The present invention relates to a method for producing a mineral material by mixing minerals such as sericite, elvan, feldspar and the like in a loess soil and melting the mineral material of a ring type produced through a heat treatment at a high temperature in deep sea water containing water or a large amount of minerals and cleanliness The present invention also provides a method for producing a mineral detergent containing minerals which not only contain minerals but also can produce port water easily.

Application No. 10-2012-0030271 discloses a method for reducing eco-friendly aquaculture production, preventing various diseases, producing healthy eels, using yellow clam chowder as aquaculture, And an eel culture method using earthworm as a feed additive. The application No. 10-2006-0053099 discloses that the filtered yellow clay loam and the loess clay are mixed and crushed at the time of crushing the rice bran, and the crushed rice cake and rice are crushed by adding steam to the steamer, And a method for producing rice cakes using the same. Application No. 10-2008-0092974 discloses a method for preparing a hwangsan medicine by using yellow clay extract which has been expanded as a functional food material by increasing the amount of the active ingredient of the herb medicine by repeating the process of drying the herb with the yellow clay, The present invention relates to a red blood cell drug produced by the method. However, in the prior art, such a technical feature of the present invention is that the mineral formulations of the ring type produced through the heat treatment of high temperature by mixing the yellow loess, sericite, elvan, and feldspar are subjected to the water desalination process This method is different from the method of producing mineral water containing minerals produced by fusing them to the generated concentrated water and generated water, respectively.

The present invention relates to a method of producing a mineral mineral water containing minerals by melting a mineral mineral material such as loess and sericite, which is inexpensive but easy to obtain, into a deep ocean water subjected to a water or water purification purification process Energetic enzymatic action, far-infrared emission effect, mineral minerals that contain a large amount of mineral ingredients.

In order to solve the above problems, the present invention provides a method for manufacturing a high-strength steel sheet, comprising: heat treating and pulverizing a material prepared at a ratio of 60 wt% of loess, 10 wt% of cerasite, 20 wt% of elvan, 10 wt% Blending the high heat treated and ground material according to a specific method; Placing the compounded material in a machine and mixing to form a predetermined shape; High heat treatment to solidify the mixed material; And dissolving the highly heat-treated solid material in water or a deep sea water, filtering the supernatant, filtering and sterilizing the resulting material to produce a trap water.

In the high-temperature treatment and crushing step, the loess is milled to 300-325 mesh, followed by high-temperature treatment at 1,100 ° C, and the cerasite and crushed stone are crushed to 325 mesh after heat treatment at 1,100 ° C as a mass of mineral. The calcite is 300-325 mesh , Followed by high-temperature treatment at 1,100 ° C, high-temperature treatment at 600 ° C again, and the step of blending the high-temperature treated and pulverized material, the ceratite and the elvan are blended with the feldspar.

In the high heat treatment step, the heat is continuously heated for 8 ~ 10 hours, the temperature is raised to 1,100 ° C. or more, the temperature is maintained for 3 to 4 hours, the fire is turned off and the heat is gradually cooled, the deep sea water is pretreated, And a dialysis membrane. The present invention also provides a method for producing a mineral agglomerate containing a mineral component.

Analysis of the components of minerals showed that a large amount of anions and minerals, high emissivity and radiant energy and far infrared rays were emitted. In addition, it has been recognized that it has an enzymatic action such as detoxification, organic decomposition, growth activity and anti-corruption action through the water quality inspection, cosmetic quality control inspection and various examples of the water purifier using mineral trapping water, Or the number of components of cosmetics.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a flow chart of a mineral preparation of the present invention and a method for producing mineral detergent using the same.
FIG. 2 is a graph showing the emission energy as a line graph by measuring the contrast of the mineral base of the present invention.
FIG. 3 shows the water purification performance test result of the water purifier using the mineral agent of the present invention.
4 shows the water purification performance and the effective water amount inspection result of the water purifier using the mineral agent of the present invention.
FIG. 5 shows results of water quality inspection of a water purifier using the mineral agent of the present invention.

BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, preferred embodiments of a mineral preparation to which a mineral component according to the present invention is added and a method for producing mineral detention water using the same will be described with reference to the accompanying drawings.

Ⅰ. Mineral and minerals added with minerals

BRIEF DESCRIPTION OF DRAWINGS FIG. 1 is a flow chart of a mineral preparation containing a mineral component of the present invention and a method for producing a mineral component using the same. The method for producing mineral inert water containing the mineral component according to the present invention is as follows.

Preparing 60% by weight of yellow clay, 10% by weight of cerasite, 20% by weight of elvan, 10% by weight of fumed silica, removing harmful substances and subjecting the materials to high heat treatment and pulverization; Blending the high heat treated and pulverized material according to a specific method; A mixing step of mixing the ingredients into a machine and mixing and shaping them in a predetermined shape; Subjecting the mixed material to high heat treatment to complete a ring-shaped mineral material; After the high-heat-treated mineral materials are dissolved in the production water and the concentrated water produced through the water desalination process of the water or the deep sea water, the supernatant is filtered, filtered and sterilized to prepare the minerals.

1. Securing mineral materials and high-temperature treatment and grinding steps

end. Securing loess and high-temperature treatment and crushing

Because loess is made by weathering stones, it has sterilization effect to prevent decay, deodorant effect to remove bad smell, moisturizing effect to automatically adjust indoor humidity, As a synonym of antidote, it has the effect of detoxifying poisonous poison, poisonous pesticide, and blowfish poisoning, and is characterized by strong neutralization, degradation and revitalization.

In consideration of soil contamination, the yellow loess used in the present invention is obtained by securing underground loess from about 0.8-1 m from the surface layer. The loess is milled into a soft powder of 300-350 mesh and can be heat treated at 1,100 ℃ to completely remove iron and harmful substances. Table 1 shows the analytical values of the loess components.

Analysis of chemical composition of loess b. Securing Mineral Minerals and High Heat Treatment and Crushing ingredient SIO2 AlO3 Fe₂O₃ FeO TIO2 CaO MgO Other Content (%) 50-60 8-12 2-4 0.8-1.1 0.5 4-16 2-6 0

In producing a mineral material, which is a raw material for producing a mineral retainer containing the mineral component of the present invention, sericite and fascicide, which are minerals containing a large amount of minerals in addition to yellow clay, are blended together and used.

Since sericite or cerasite contains a large amount of minerals with an alkali concentration of pH 8.5 to 9%, it is known that groundwater, which is made of cerasite rock, is used as mineral water to treat diseases. Especially in Japan, Korea imported cerasite and crushed it into 1,000 mesh, and used it as some gastrointestinal medicine, and the rest is used as raw material for cosmetics. However, since Korea is difficult to make with 1,000 mesh, it is the most used mineral in water purifier because it is all imported and is expensive.

Quartz has been used as a "gemstone" for the dissolution of numerous trace minerals and the generation of oxygen, which is used for the activation of bioenergy and the rapid growth of plants. In China, 2,000 years ago, it was regarded as the best of the pomegranate as sweet, hot, and nontoxic. In the 1980s, the mineral water purifier was recognized as a popular product by consumers because of its high far infrared ray emissivity, strong adsorption power, rich mineral content and porosity. In recent years, a lot of health products using the mineral have been developed.

It is said to be a fossil, and is classified as an acidic granite. It is mainly buried in the Yangsan mountain. The feldspar has the calcium content of minerals of 7.8%, which is the highest among the minerals and has the ability to stimulate metabolism and has a high emissivity with a far infrared efficiency of 94%, which is effective for strong adsorption action and maintenance of plant growth. In particular, fumigants are used in the fields of health used in saunas and healthcare facilities, industrial water treatment facilities, industrial fields used in soaps and cosmetics, fisheries used for mixing of diets, animal feeds for livestock, It is used in various fields such as agriculture and livestock industry.

Mineral materials are desirably treated with high heat to remove toxic substances and increase the radiant energy of far infrared rays. Heat treatment is to heat treatment for 3 ~ 4 hours at high temperature above 1,100 ℃.

Cerasite and elvanite were treated with high-temperature heat treatment at 1,100 ℃ and then crushed into 325 mesh, and crushed into soft powder of 325 mesh, and then treated by the same method as yellow clay which was heat treated at 1,100 ℃. Process. Table 2 shows the results of the chemical composition analysis of the minerals.

Analysis of chemical composition of minerals Minerals ingredient SIO2 Al₂O₃ Fe₂O₃ CaO MgO TIO2 K₂O Na2O TiO Cerasite ratio 56.24 20.39 9.59 10 1.47 0.84 6.69 - - Elven stone ratio 65 16 3.88 4 1.30 - 3.26 3.59 0.13 Maple ratio 58 15.1 2.24 7.8 1.32 - 6.0 0.21 0.21

2. Steps to Generate Mineral Agents

Since cerasite and elvanite have a property of pushing each other out of each other, it is difficult to bond them together. Therefore, when the materials subjected to the above heat treatment and pulverization step are mixed, yellow soil is mixed with cerasite and elvan stone is mixed with feldspar , And a certain amount of water is kneaded into each combination. When blending the blend, the proportion of the blend may vary depending on the water temperature applied.

When the kneaded components are combined and rotated in a molding machine manufactured in the shape of a recrystallization size, a solid material having various large and small round rings can be produced. Solid materials are moisture-sensitive and prone to deformation and must be heat-treated.

The heating process of the solid material is continued for 8 ~ 10 hours to raise the temperature to 1,100 ° C. or more, and the temperature is maintained for 3 to 4 hours, then the fire is turned off and the heat is gradually cooled. The high temperature treatment process takes about 24 hours, and the color of the material may change depending on the temperature. For example, treatment at a high temperature of 1,300 ° C or higher may make the ring material appear to be coated, and the most suitable temperature is 1,100 ° C. After the heat treatment process, a substance having a ring shape is produced, which is easily dissolved in the liquid.

3. Steps to generate minerals

Mineral agents and water are blended in appropriate proportions to dissolve the mineral agent in water, resulting in a mineral trapping agent. The above-mentioned trapping water is allowed to stand for a certain period of time, so that the impurities of the trapping water are settled. Then, the supernatant liquid is separately extracted and subjected to filtration and sterilization treatment steps to produce a mineral trapped with minerals.

4. Manufacturing of mineral water using deep sea water

Deep sea water is a sea water with a depth of less than 200m, which is almost the depth of the sun. It is easier to decompose organic matter than organic matter production by photosynthesis. It is rich in nutrients such as phosphorus and nitrogen, but it is difficult to infect pathogenic bacteria and harmful substances from the ground. It has the characteristics of cleanliness, low water humidity and water quality, and is used in various fields such as inorganic ion water, beer, soy sauce, and cosmetics.

In the present invention, mineral groundwater can be prepared by mixing with mineral materials using general ground water, but it can also be used as a melting solution for manufacturing mineral mineral water using deep sea water. The 100% water-soluble minerals contained in deep seawater have the advantage of easy absorption in the body, but the water desalination process that removes salt is required to utilize deep seawater because it contains a large amount of salinity. The present invention dissolves the produced water and the concentrated water produced through the water desalination process of the deep ocean water together with the mineral agent.

4.1. Water withdrawal and warming process of seawater deep seawater

Deep seawater is taken from the deep sea bed at depths of 200m below sea level from sea level and warmed to 20 ~ 30 ℃ so that subsequent treatment can be smoothly processed. The deep sea water intake method is to take down the pipeline down to 200m below the sea floor from the ship, and to install the pipeline from the sea surface to the depth of the sea floor below 200m depth and to pump it. Install the pipeline from the sea level to the depths of the sea floor deeper than 200m and install the water intake below sea level and take the water by the Siphon principle.

Deep sea water taken in the catchment tank is low in temperature and high in viscosity due to its low treatment efficiency. Therefore, it is supplied with heat from boiler (in summer, water temperature of surface sea water may be used) Process.

4.2. Pretreatment filtration process

In the pretreatment filtration process, sand filtration, filtration using a microfilter, and filtration using an ultrafilter may be used. The suspended solid is removed from the filtrate once or three times, Deep ocean water is sent to the desalination process.

4.3. Primary desalination process

Deep sea water treated in the pretreatment filtration process can be subjected to primary desalination by reverse osmosis treatment, electrodialysis, electrodeposition, refrigeration, evaporation / condensation or ion exchange, but evaporation / condensation and ion exchange Since the process is not economical, it is preferable in the present invention that the first desalination treatment is performed by one step selected from the reverse osmosis treatment and the electrodialysis process to proceed to the pH adjustment step of the second desalination treatment step.

4.4. Secondary desalination process (pH adjustment process)

Table 3 shows the compositional analysis results of the deep sea water before and after the desalination process of the present invention.

Analysis of composition of deep sea water before and after desalination process ingredient Before and after desalination ion Deep sea water (%) Deep sea water after processing Goat 55.04 0.15 salt 30.62 1.20 Sulfuric acid 7.68 0.1 magnesium 3.69 3.50 calcium 1.15 1.12 potassium 1.10 0.97 Bicarbonate 0.41 0.39 bromine 0.19 0.01

Through the primary desalination process, deep sea water with more than 90% of sulfate ion removed is sent to the secondary desalination process to reduce the content of boric acid and precipitate in alkaline water with pH between 10 and 13, Produce production water with low salt content.

4.5. Mineral agglomerate production stage using deep sea water

The produced mineral water and the concentrated water are melted in the production water and the concentrated water at an appropriate ratio to the production water and concentrated water produced through the water quality desalination process of the deep ocean water necessary for producing the mineral water water using the deep sea water production water, To prepare a water-in-oil containing water and concentrated water. After the impregnation of the trap water is allowed to settle by allowing the trap water containing the produced water and the trapped water containing the concentrated water to stand for a certain time, the supernatant liquid is separately extracted and subjected to the filtration and sterilization treatment steps, whereby the mineral water- A trapped water is prepared.

Ⅱ. Quality inspection and performance test results of mineral materials

The following shows the results of quality inspection and performance test for using mineral materials for various purposes.

1. Mineral component analysis experiment

The mineral component analysis of the mineral preparation of the present invention was conducted by the Korea Institute of Science and Technology. The results of the analysis of the components of the mineral agent are shown in Table 3 below.

Mineral composition analysis table (Unit: wt.%) Type of sample Fe Si Mg Mn Na Ti Ca Al K Mineral materials 1.93 27.8 0.24 0.032 0.28 0.28 0.28 18.5 1.34 Analysis method AAS WET ICP AAS AAS ICP ICP ICP AAS Type of sample Ni Ga Pb V Cu Sn Sr Cr Ba Mineral materials 10 ^-3 10 ^-4 10 ^-4 10 ^-3 10 ^-3 10 ^-2 10 ^-3 10 ^-2 10 ^-2

2. Emissivity and Radiation Energy Detection Experiment

The emissivity and radiant energy detection experiments of the mineral materials used in the present invention were conducted at the Far Infrared Application Evaluation Center of KICM Korea Institute of Construction Materials. The experimental conditions were tested at 40 ° C and the results were shown by measuring the contrast of BLACKBODY using FT-ER Spectrometer. The emissivity (5 ~ 20 ㎛) and radiative energy (W / m ² ) of the mineral agent were 0.926 and 3.74 × 10 ² , respectively. FIG. 2 is a graph showing emission energy of a mineral material according to the present invention measured as a contrast of BLACKBODY.

3. Anion detection experiment

The anion detection experiment of the mineral agent of the present invention was conducted at the Far Infrared Application Evaluation Center of KICM Korea Institute of Construction Materials. The test method was KICM-FIR-1042, and it was tested under the condition of room temperature 23 ℃, humidity 45%, and atmospheric anion number 58 / cc using charge particle measuring device. As a result of measuring the anions emitted from the measurement object, the ION / cc number per unit volume was measured as 116.

The water purification performance test of the mineral water containing minerals of the present invention was carried out at Kyung Hee University Earth Environment Research Institute which is an inspection agency of quality control system of the Ministry of Environment, and the mineral filter of the present invention was replaced with a ceramic ball One water was used as a sample.

FIG. 3 shows the water purification performance test result of the water purifier using the mineral agent of the present invention. The effluent purified by the minerals produced by the mineral preparations is a typical environmental pollutant, a total of trihalomethanes known as carcinogens, tetrachlorethylene, toluene, benzene, carbon tetrachloride, known as an ozone depleting substance, Diazinon, malathion, phenol used as a disinfectant, anionic surfactant, heavy metals, fertilizer, toxic gas, nitrate nitrogen showing organic pollution degree, and chlorine ion are suitable for water quality standards that are not investigated.

4 shows the water purification performance and the effective water amount inspection result of the water purifier using the mineral agent of the present invention. The residual chlorine of the effluent after the purification process was not detected under the experimental conditions of water temperature 15 ℃ and water pressure 1.0㎏f / ㎠, and it showed a level suitable for water quality standards such as color, turbidity and general bacteria. Also, chlorine remaining in the effluent was not detected even if the effective purified water amount became 80 to 120% under free residual chlorine (2.0 mg / l).

FIG. 5 shows results of water quality inspection of a water purifier using the mineral agent of the present invention. This inspection was carried out on items other than the items that are deemed to have a removal rate higher than the standard water purification performance test and the specific water purification performance test.

The high water purification effect and the sterilizing effect of the mineral detergent manufactured using the mineral agent can be confirmed.

4. Cosmetic quality control inspection

The quality control test was conducted by the Korea Research Institute of Chemical Technology using the mineral agent of the present invention to which the mineral component of the present invention was added as a sample. Table 5 shows a chemical test report of raw materials of cosmetics which was tested using the present invention as a sample. As a result of the survey, it is considered that the minerals added with mineral components can be used as a cosmetic ingredient.

Cosmetic raw material chemical test report Test Items unit Sample classification Results Test Methods heavy metal ppm Less than 50 Korea Food and Drug Administration Notice 98-21 pH (20 ° C) - 6.6 Korea Food and Drug Administration Notice 98-21 Ignition residue % 0.7 Korea Food and Drug Administration Notice 98-21 Dry weight loss % 0.3 Korea Food and Drug Administration Notice 98-21 importance - 0.889 Korea Food and Drug Administration Notice 98-21 Pb ppm Not detected Korea Food & Drug Administration Notice 98-21 Korea Food and Drug Administration Notice 98-21 As ppm Not detected

As a result of the measurement as described above, the mineral agent of the present invention and the mineral agent prepared by using the mineral agent of the present invention can be used as water for drinking water and general industry.

The minerals manufactured by mixing the yellow loess, cerasite, elvan stone and fumed stone containing a large amount of minerals at high temperature are easy to carry and easy to melt even in deep seawater and general fresh water. In addition to seafood processing methods, It is possible to utilize it as an efficient mineral source and thus have industrial applicability.

Claims (5)

a) a material prepared at a ratio of 60 wt% of loess, 10 wt% of cerasite, 20 wt% of elvan, 10 wt% of fumed silica;
The loess is milled to 300-325 mesh and then heat treated at 1,100 ° C. Cerasite and elvan are crushed to 325 mesh after high temperature treatment at 1,100 ° C. The crushed stone is crushed to 300-325 mesh and then heated to 1,100 ° C And further heat treatment at 600 占 폚;
b) blending the high heat treated and pulverized material with ceratite and elvan in combination with feldspar;
c) mixing the blended material into a molding machine and mixing to form a predetermined shape;
d) continuously heating the mixed material for 8 to 10 hours to raise the temperature to 1,100 ° C or more, continuing the temperature for 3 to 4 hours, and then digesting and gradually cooling the heat, A mineral agent containing a mineral component. delete delete delete delete

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