KR101295405B1 - Manufacturing method of ceramic - Google Patents

Manufacturing method of ceramic Download PDF

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KR101295405B1
KR101295405B1 KR1020120152446A KR20120152446A KR101295405B1 KR 101295405 B1 KR101295405 B1 KR 101295405B1 KR 1020120152446 A KR1020120152446 A KR 1020120152446A KR 20120152446 A KR20120152446 A KR 20120152446A KR 101295405 B1 KR101295405 B1 KR 101295405B1
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mixture
water
ppb
ceramic
weight
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김진도
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(주)원윤
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/16Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
    • C04B35/18Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K20/00Accessory food factors for animal feeding-stuffs
    • A23K20/20Inorganic substances, e.g. oligoelements
    • A23K20/28Silicates, e.g. perlites, zeolites or bentonites
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605Treating the starting powders individually or as mixtures
    • C04B35/6261Milling
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605Treating the starting powders individually or as mixtures
    • C04B35/62625Wet mixtures
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00Other inorganic fertilisers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068Ingredients with a function or property not provided for elsewhere in C04B2103/00
    • C04B2103/0097Anion- and far-infrared-emitting materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite

Abstract

PURPOSE: A manufacturing method of ceramics is provided to produce ceramics with improved peculiarities of natural minerals to be used as a fungicide, an environmentally-friendly fertilizer, a soil improver, a odor and poisonous gas adsorption agent, a deodorization agent, an electromagnetic interference shielding agent, environmentally-friendly construction material raw materials, etc. CONSTITUTION: A manufacturing method of ceramics comprises the steps of: preparing a mixture (11) of sericite (10) and sepiolite (20), smectite (30), and illite (40), pulverizing the mixture to the size of 400-600 mesh, heating the pulverizing mixture at 400-600°C and adding water of 1-3L about the mixture of 1kg, and molding the water-added mixture (14) within the particle diameter of 10- 50 um. The sericite are collected in Saenggeuk-myeon, Eumsung-gun, Chungchungbuk-do and contain germanium 20-60 ppb, silver 20-60 ppb and cerium 10-20 ppb.

Description

세라믹의 제조방법 {Manufacturing method of ceramic}Manufacturing method of ceramics

본 발명은 견운모를 이용한 세라믹의 제조방법에 관한 것이다.The present invention relates to a method for producing a ceramic using the mica.

현대인들은 생활문화와 환경의 급격한 변화에 의해 정신적, 육체적 활동과 과도한 스트레스 등으로 체력의 저하를 다양한 증상으로 느끼며 살아가고 있다.Modern people are experiencing various symptoms of depression of physical strength due to mental, physical activity and excessive stress due to rapid change of living culture and environment.

이에 편승하여 유기농 농작물 재배 및 자양강장 음료 등의 개발이 활발히 진행되고 있으며, 이러한 제품들의 판매가 급증하고 있으며, 이미 일부는 일반화 되어 있고 자연 식품을 원료로 하는 제조방법은 이미 널리 알려져 왔다.In this context, the development of organic crops and nourishment tonic beverages are actively underway, and the sales of these products are rapidly increasing, and some of them have been generalized and manufacturing methods using natural foods have been widely known.

또한 천연 광물 및 합성광물을 이용하여, 물에 함침시켜 광물에서 추출된 물을 사용함으로써 광물의 추출물에 함유된 건강물질을 섭취하는 방법이 널리 알려져 있어 왔다.In addition, a method of ingesting healthy substances contained in the extract of minerals by using water extracted from minerals by impregnating with water using natural minerals and synthetic minerals has been widely known.

대한민국공개특허공보 공개번호 제99-43936호 및 제93-413에는 일라이드를 모르타르에 함유시켜 시멘트의 독성 및 냄새를 중화시켜 혈액순환, 피로회복, 공기정화기능과 각종성인병을 예방할 수 있는 일라이트 모르타르의 제조방법이 기재되어 있고,Korean Patent Laid-Open Publication Nos. 99-43936 and 93-413 contain illide in mortar to neutralize the toxicity and odor of cement, thereby improving blood circulation, fatigue recovery, air purification, and various adult diseases. A method for producing mortar is described,

대한민국공개특허공보 공개번호 10-1992-655호에는 맥반석과 생극 견운모의 자력을 주재료로 한 혼동자장조성물의 제조방법이 기술되어 있으며,Korean Laid-Open Patent Publication No. 10-1992-655 describes a method for producing a confusing magnetic composition based on the magnetic force of barley stones and biotite mica.

대한민국공개특허공보 공개번호 특2003-47957호에는 운모를 침전하였다가 웃물만 미용수로 활용하면 잔주름제거, 자외선차단, 기미제거, 검버섯제거, 피부가 윤택해지는 환희미용수가 공개되어 있고,Korean Patent Application Publication No. 2003-47957 discloses blissful beauty water that removes fine wrinkles, sunscreen, removes spots, removes mushrooms, and moisturizes skin when sediment of mica is used as beauty water.

대한민국공개특허공보 공개번호 제91-14148호에는 일라이트광석을 분쇄한 후, 황산알루미늄 및 수산화 칼슘을 혼합하여 정수제를 제조한 다음, 상기 정수제에 의해 수중에 녹아 있는 중금속이온, 방사는 페기물 이론과 유기물이온을 흡착하는 응접재의 응접작용으로 폐수를 정수시키는 흡착 침강형 정수제의 제조방법이 기재되어 있으나, Korean Unexamined Patent Publication No. 91-14148 discloses a water purifier prepared by crushing an illite ore, mixing aluminum sulfate and calcium hydroxide, and then dissolving heavy metal ions and spinning waste water in the water by the water purifier. The theory and method for producing an adsorption settling type water purifying agent for purifying wastewater by the reaction of a binder adsorbing organic ions are described.

상기 종래의 기술들은 천연 광물을 물리적인 처리를 하여 사용하거나, 단순히 천연광물에 중금속용액을 넣고 교반하여 중금속을 흡착하는 폐기물처리에 이용되는 기술로서 천연광물의 고유성질을 향상시키지 못한 문제점이 있어 왔다. The conventional techniques have been used to treat natural minerals by physical treatment, or simply by adding heavy metal solution to natural minerals and stirring to adsorb heavy metals. .

본 발명은 천연광물의 고유성질을 향상시킨 세라믹을 제조하여 살균제, 친환경 비료, 토양개선제, 악취 및 유독가스 흡착, 탈취, 전자파 차폐, 친환경 건축자재 원료 등으로 사용되는 세라믹의 제조 방법 및 세라믹의 용도를 제공하고자 한다. The present invention provides a method for producing ceramics and ceramics used as a disinfectant, eco-friendly fertilizer, soil improver, odor and toxic gas adsorption, deodorization, electromagnetic shielding, environmentally friendly building materials, etc. To provide.

본 발명은 견운모와 세피오라이트, 스맥타이트, 일라이트를 혼합하여 혼합물을 준비하는 단계; 상기 혼합물을 400 내지 600매쉬 의 크기로 분쇄하는 단계; 상기 분쇄된 혼합물을 400 내지 600 ℃ 로 가열하는 단계; 상기 가열된 혼합물에 상기 혼합물 1kg 대비 1 내지 3 ℓ 의 물을 첨가하는 단계; 상기 물이 첨가된 혼합물을 10 내지 50 ㎛의 입경으로 성형하는 단계를 포함하는 세라믹의 제조방법을 제공한다.The present invention comprises the steps of preparing a mixture by mixing the mica and sepiolite, smackite, illite; Grinding the mixture to a size of 400 to 600 mesh; Heating the milled mixture to 400 to 600 ° C .; Adding 1 to 3 liters of water to 1 kg of the mixture to the heated mixture; It provides a method for producing a ceramic comprising the step of molding the mixture to which the water is added to a particle diameter of 10 to 50 ㎛.

또한 상기 견운모는, 상기 견운모는 충청북도 음성군 생극면에서 채취한 것을 특징으로 할 수 있고, 상기 견운모는, 게르마늄 20 내지 60 ppb, 은 20 내지 40 ppb 및 세륨 10 내지 20 ppb 를 포함할 수 있다.In addition, the biotite, the biotite may be characterized in that it was taken from the Cheongcheongbuk-do, Eumseong-gun, Chungcheongbuk-do, the biotite may include germanium 20 to 60 ppb, silver 20 to 40 ppb and cerium 10 to 20 ppb.

또한 상기 혼합물은, 견운모 65 내지 75 중량%, 세피오라이트 5 내지 15 중량%, 스맥타이트 5 내지 15 중량%, 일라이트 5 내지 15 중량% 인 것일 수 있다.In addition, the mixture may be 65 to 75% by weight of the mica, 5 to 15% by weight of sepiolite, 5 to 15% by weight of smackite, 5 to 15% by weight of the illite.

본 발명은 상기 세라믹의 제조방법에 의해 제조된 세라믹을 함유하는 비료를 제공한다. The present invention provides a fertilizer containing a ceramic produced by the method for producing a ceramic.

또한 상기 세라믹의 제조방법에 의해 제조된 세라믹을 함유하는 친환경 건축자재를 제공한다.In addition, it provides an environmentally friendly building material containing a ceramic produced by the method for producing a ceramic.

또한 상기 세라믹의 제조방법에 의해 제조된 세라믹을 함유하는 피부보호제를 제공한다.It also provides a skin protectant containing a ceramic produced by the method for producing a ceramic.

또한 상기 세라믹의 제조방법에 의해 제조된 세라믹을 함유하는 가축사료첨가제를 제공한다.In addition, there is provided a livestock feed additive containing a ceramic produced by the method for producing a ceramic.

본 발명에 따른 세라믹의 제조방법은 천연광물의 고유한 성질을 살려 살균제, 친환경 비료, 토양개선제, 악취 및 유독가스 흡착, 탈취, 전자파 차폐, 친환경 건축자재 원료, 피부질환 등에 매우 효과가 있으며, 나이가 고성능 해독제, 건강 보조식품, 건축 자제 내-외장재, 피부보호제, 의류 및 원사사용, 동물사료 및 식물비료 등으로 사용할 수 있는 세라믹을 제조하는 효과가 있다.Ceramic manufacturing method according to the present invention is very effective in disinfectant, eco-friendly fertilizer, soil improver, odor and toxic gas adsorption, deodorization, electromagnetic wave shielding, environmentally friendly building materials, skin diseases utilizing the unique properties of natural minerals, age It has the effect of producing a ceramic that can be used as a high performance antidote, health supplements, building materials, interior and exterior materials, skin protection agents, clothing and yarn use, animal feed and plant fertilizers.

도 1은 본 발명에 따른 세라믹 제조방법의 모식도이다.1 is a schematic diagram of a ceramic manufacturing method according to the present invention.

본 발명은 견운모와 세피오라이트, 스맥타이트, 일라이트를 혼합하여 혼합물을 준비하는 단계; 상기 혼합물을 400 내지 600매쉬의 크기로 분쇄하는 단계; 상기 분쇄된 혼합물을 400 내지 600 ℃ 로 가열하는 단계; 상기 가열된 혼합물에 상기 혼합물 1kg 대비 1 내지 3 ℓ의 물을 첨가하는 단계; 상기 물이 첨가된 혼합물을 10 내지 50 ㎛의 입경으로 성형하는 단계를 포함하는 세라믹의 제조방법을 제공한다.The present invention comprises the steps of preparing a mixture by mixing the mica and sepiolite, smackite, illite; Grinding the mixture to a size of 400 to 600 mesh; Heating the milled mixture to 400 to 600 ° C .; Adding 1 to 3 liters of water to 1 kg of the mixture to the heated mixture; It provides a method for producing a ceramic comprising the step of molding the mixture to which the water is added to a particle diameter of 10 to 50 ㎛.

본 발명의 한 구체예에서, 상기 견운모는 게르마늄, 은 및 세륨을 포함 할 수 있다.In one embodiment of the present invention, the biotite may comprise germanium, silver and cerium.

상기 게르마늄은 20 내지 60 ppb, 상기 은은 20 내지 40 ppb 및 상기 세륨은 10 내지 20 ppb 를 포함할 수 있다.The germanium may include 20 to 60 ppb, the silver may include 20 to 40 ppb, and the cerium may include 10 to 20 ppb.

본 발명의 한 구체예에서, 상기 견운모는 상기 혼합물 100 중량% 대비 65 내지 75 중량%, 60 내지 70 중량% 또는 65 내지 70 중량% 일 수 있으나 이에 제한되는 것은 아니다.In one embodiment of the present invention, the biotite may be 65 to 75% by weight, 60 to 70% by weight or 65 to 70% by weight relative to 100% by weight of the mixture, but is not limited thereto.

또한 상기 세피오라이트는 상기 혼합물 100 중량% 대비 5 내지 15 중량%, 5 내지 10 중량% 또는 10 내지 15 중량% 일 수 있으나 이에 제한되는 것은 아니다.In addition, the sepiolite may be 5 to 15% by weight, 5 to 10% by weight or 10 to 15% by weight relative to 100% by weight of the mixture, but is not limited thereto.

또한 상기 스맥타이트는 상기 혼합물 100 중량% 대비 5 내지 15 중량%, 5 내지 10 중량% 또는 10 내지 15 중량% 일 수 있으나 이에 제한되는 것은 아니다.In addition, the smectite may be 5 to 15% by weight, 5 to 10% by weight or 10 to 15% by weight relative to 100% by weight of the mixture, but is not limited thereto.

또한 상기 일라이트는 상기 혼합물 100 중량% 대비 5 내지 15 중량%, 5 내지 10 중량% 또는 10 내지 15 중량% 일 수 있으나 이에 제한되는 것은 아니다.In addition, the illite may be 5 to 15% by weight, 5 to 10% by weight or 10 to 15% by weight relative to 100% by weight of the mixture, but is not limited thereto.

이상과 같은 본 발명의 제조방법에 따르면, 천연광물의 고유한 성질을 살려 살균제, 친환경 비료, 토양개선제, 악취 및 유독가스 흡착, 탈취, 전자파 차폐, 친환경 건축자재 원료, 피부질환 등에 매우 효과가 있으며, 나이가 고성능 해독제, 건강 보조식품, 건축 자재 내-외장재, 피부보호제, 의류 및 원사사용, 동물사료 및 식물비료 등으로 사용할 수 있는 세라믹을 얻을 수 있다.According to the production method of the present invention as described above, by utilizing the unique properties of natural minerals, it is very effective in disinfectant, eco-friendly fertilizer, soil improver, odor and toxic gas adsorption, deodorization, electromagnetic shielding, environmentally friendly building materials, skin diseases You can get ceramics that can be used for older, high-performance antidote, health supplements, interior and exterior materials for building materials, skin protectants, clothing and yarn use, animal feed and plant fertilizers.

본 발명에 사용되는 견운모는 운모의 일종으로 충청북도 음성군 생극면에서 채취된다. 상기 견운모는 일반적인 견운모에 비해 게르마늄, 은 및 세륨의 함량이 높아 해독성이 강하고, 피부와 건강에 좋고, 향균, 탈취 및 정화의 효과가 있다.Cicada used in the present invention is a kind of mica, which is collected from Saeng-myeon, Eumseong-gun, Chungcheongbuk-do. The biotite has a higher content of germanium, silver, and cerium than the general biotite, has a strong detoxification, good for skin and health, and has the effect of antibacterial, deodorizing and purifying.

본 발명에서 사용되는 견운모는 은을 함유하고 있어 질산은 코팅을 하지 않고, 함침 처리한 후 200~300℃에서 재가열하여 세라믹을 제조할 수 있다.The biotite used in the present invention contains silver, so that the ceramic may be prepared by reheating at 200 to 300 ° C. after the impregnation treatment without silver nitrate coating.

상기 은은 현재까지의 실험결과 지구상의 거의 모든 단세포 병원균을 살균하는 효과가 있다.The silver has the effect of killing almost all single cell pathogens on earth as a result of experiments to date.

본 발명에 사용되는 세피오라이트는 섬유질 조직체로 되어 있는데, 섬유질 조직은 섬유소에 중심을 맞춰서 평행한 줄처럼 되어 있으며, 이 섬유소는 규소 사면체에 맞춘 두 기층으로 되어 있는데, 규소 사면체 한 층과 나머지 산소원자를 통해 생성된 마그네슘 판면체가 다른 한 층이다. 그 배열을 바꾸면 섬유소의 방향에 따라 섬유관의 나타나게 되며, 그 조직 구성체로서 세피오라이트는 흡인수분 결정체 수분과 화학 수산기 수분이 있다. 그래서 상기 세피오라이트는 수분 교환이 많이 일어나고, 섬유관에서는 유일하게 다른 소분자를 흡수하게 됨에 따라, 상기 세피오라이트를 통해 과망간산칼륨과 향균제 세라믹의 생성을 돕고, 활발한 흡수를 시작하게 되는 것이다.Sepiolite used in the present invention is a fibrous structure, the fibrous tissue is like a parallel line centered on the fiber, this fiber is composed of two substrates aligned to the silicon tetrahedron, one layer of silicon tetrahedron and the remaining oxygen atoms The resulting magnesium platelet is another layer. When the arrangement is changed, the fibrous tube appears according to the direction of the fibrin, and as the tissue construct, sepiolite has moisture of absorbing crystalline water and chemical hydroxyl. Therefore, the sepiolite is a lot of water exchange, and as the fiber tube absorbs only other small molecules, it helps to generate potassium permanganate and the antimicrobial ceramic through the sepiolite, and starts active absorption.

방사율 : 0.99㎛Emissivity: 0.99㎛

방사에너지 : 3.18×102(W/㎡ ㎛ 40℃)Radiated energy: 3.18 × 102 (W / ㎡ ㎛ 40 ℃)

따라서, 본 발명에 사용되는 스맥타이트의 첨가로 광범위한 향균력과 인체에 대한 독성이 전혀 없으며, 환경 친화적인 소재이며, 자외선에 의한 변색의 없으며, 식품의 신선도를 장기간 유지시키며, 미생물 증식에 의한 악취발생을 억제하며, 냄새분자를 흡착, 분해시키며, 동식물의 생육촉진을 증대시킬 수 있는 이점이 있다. Therefore, the addition of smacktite used in the present invention has no widespread antibacterial activity and toxicity to the human body, is an environmentally friendly material, no discoloration by ultraviolet rays, maintains the freshness of food for a long time, and causes odor due to microbial growth. It has the advantage of suppressing, adsorbing and decomposing odor molecules, and increasing the growth of plants and animals.

본 발명에 사용되는 일라이트는 광물학적인 구조가 삼층인편상 구조를 가지며 주성분으로서 SiO2, Al2O3, K2O로서 황백색(백색, 적색)의 합성광물이며, 상온에서 3~25마이크론 파장의 원적외선을 89-92%방사하고, 탈취력(98%)이 매우 강하며, 강력한 기(氣)를 발산하며, 수중에서 물분자를 활성화시켜 용존산소를 3배 이상 확보하고 산소응집력이 강하고, 수중에서 -2가 전하를 가지며, 용수중의 양이온 유기질이온을 흡착하며, 자체함수 기능으로 보습효과가 크고 직사자외선을 방지하며 활도가 높고, 토양의 지력을 향상시키며(산소, 원적외선, 음이온, 지 등에 의함), 강력한 음이온을 발산(건식 분말상태: 14ion/cc)한다.The illite used in the present invention has a three-layered mineral structure with a mineral structure, SiO 2 , Al 2 O 3 , K 2 O as a main component is a yellow-white (white, red) synthetic mineral, 3 ~ 25 micron wavelength at room temperature It emits 89-92% of far-infrared rays, has a strong deodorizing power (98%), emits strong groups, activates water molecules in water to secure more than three times of dissolved oxygen, and has strong oxygen cohesiveness. -2 has an electric charge, adsorbs cationic organic ions in the water, has a self-functioning function, has a great moisturizing effect, prevents direct ultraviolet rays, high activity, and improves the soil's intellect (oxygen, far infrared ray, anion, paper, etc.). ), Releasing strong anions (dry powder state: 14ion / cc).

도 1은 본 발명의 세라믹의 제조방법을 모식도로 나타낸 것이다.1 is a schematic view showing a method of manufacturing a ceramic of the present invention.

도 1을 참조하여 세라믹의 제조방법을 살펴보면,Looking at the manufacturing method of the ceramic with reference to Figure 1,

상기 세라믹의 제조방법은 견운모(10)와 세피오라이트(20), 스맥타이트(30), 일라이트(40)를 바람직하게는 7:1:1:1의 비율로 혼합하여 혼합물(11)을 준비한다. 상기 견운모는 바람직하게는 칼슘, 알루미늄, 게르마늄, 은 및 필수미네랄을 포함할 수 있다.In the method of manufacturing the ceramic, the mixture 11 is prepared by mixing the mica 10, the sepiolite 20, the smackite 30, and the illite 40 in a ratio of 7: 1: 1: 1. . The mica may preferably comprise calcium, aluminum, germanium, silver and essential minerals.

상기 혼합물(11)을 400 내지 600매쉬의 크기로 분쇄한다. The mixture 11 is ground to a size of 400 to 600 mesh.

상기 분쇄된 혼합물(12)을 400 내지 600 ℃ 로 가열한다. The ground mixture 12 is heated to 400 to 600 ° C.

상기 가열된 혼합물(13)에 상기 혼합물 1kg 대비 1 내지 3 ℓ의 물(50)을 첨가한다. To the heated mixture 13 is added 1 to 3 liters of water 50 relative to 1 kg of the mixture.

상기 물이 첨가된 혼합물(14)을 10 내지 50 ㎛의 입경으로 성형한다.The mixture (14) to which the water is added is molded into a particle diameter of 10 to 50 mu m.

본 발명에 따른 세라믹의 제조방법에 의해 제조된 세라믹은 생극면에서 채취한 견운모의 이용으로 음이온을 다량 방출해 토양 내 중금속과 가스등을 흡착, 작물의 뿌리 발달에 도움을 주는 효과가 있다. The ceramic produced by the method of manufacturing a ceramic according to the present invention has the effect of adsorbing heavy metals and gases in the soil by using large amounts of negative ions collected from live poles, and helping to develop crop roots.

또한 상기 세라믹을 축산물 폐기물 등과 함께 발효시켜 제조된 유기농 미생물을 번식, 발효시켜 비료를 기존비료에 1~5 중량% 로 하여 재배 시 사용하면 식물의 재배속도가 빠르며, 바이러스에 인한 병에 강하고, 과일수의 경우 당도가 높은 과일을 재배하는 등의 효과가 나타난다. In addition, the organic microorganism produced by fermenting the ceramic with livestock waste, etc., breed and ferment the fertilizer to 1 ~ 5% by weight of the existing fertilizer when used in the cultivation rate of plants, the disease caused by viruses, fruit, fruit In the case of water, the effect is such as growing a high sugar content.

또한 상기 세라믹은 생극면에서 채취한 견운모의 이용으로 피부에 바른 경우 피부의 보습효과가 높으며, 특히 건성피부의 경우 피부의 건성도가 감소된다.In addition, the ceramic has a high moisturizing effect when applied to the skin by the use of the biotite collected from the polar surface, especially in the case of dry skin, the dryness of the skin is reduced.

또한 상기 세라믹은 생극면에서 채취한 견운모를 이용하여 건조시켜 미세분말화 한 다음 건축재료로 사용하여 건축자재물 제조하여 시공한 후에 사용한 결과 전자파 차단의 효과가 있다.
In addition, the ceramic is dried by using the biotite collected from the surface of the polar pole, and then finely powdered and then used as a building material after construction and construction of the building material has the effect of blocking the electromagnetic waves.

이하, 본 발명의 바람직한 실시예를 통하여 구체적으로 설명하면 다음과 같다.Hereinafter, described in detail through the preferred embodiment of the present invention.

<실시예1>&Lt; Example 1 >

견운모 700g, 세피오라이트 100g, 스맥타이트 100g 및 일라이트 100g을 볼밀에 투입하여 500매쉬의 크기를 분쇄한 다음, 온도 400~600℃로 가열한 후에, 물 1ℓ을 넣어 10~50㎛ 크기로 통상의 성형장치를 이용하여 성형한 다음, 물에 16시간 동안 함침시킨 후에, 200-300℃에서 재가열하여 세라믹을 제조하였다.
700 g of mica, 100 g of sepiolite, 100 g of smackite and 100 g of illite were put into a ball mill to pulverize the size of 500 meshes, heated to a temperature of 400 to 600 ° C., and then 1 liter of water was added to form a normal mold having a size of 10 to 50 μm. Molded using the apparatus, and then impregnated with water for 16 hours, and then reheated at 200-300 ℃ to prepare a ceramic.

<실시예2>&Lt; Example 2 >

견운모 700g, 세피오라이트 100g, 스맥타이트 100g 및 일라이트 100g을 볼밀에 투입하여 500매쉬의 크기를 분쇄한 다음, 온도 400~600℃로 가열한 후에, 물 1ℓ을 넣어 10~50㎛ 크기로 통상의 성형장치를 이용하여 성형한 다음, 물에 8시간 동안 함침시킨 후에, 200-300℃에서 재가열하여 세라믹을 제조하였다.
700 g of mica, 100 g of sepiolite, 100 g of smackite and 100 g of illite were put into a ball mill to pulverize the size of 500 meshes, heated to a temperature of 400 to 600 ° C., and then 1 liter of water was added to form a normal mold having a size of 10 to 50 μm. Molded using the apparatus, and then impregnated with water for 8 hours, and then reheated at 200-300 ℃ to prepare a ceramic.

<실시예3>&Lt; Example 3 >

상기 실시예1 및 2과 같이 제조된 세라믹을 물에 6시간 정도 침지시켜 세라믹을 제조하였다.
The ceramics prepared as in Examples 1 and 2 were immersed in water for about 6 hours to prepare ceramics.

[실험예]
[Experimental Example]

납 함량 시험Lead content test 납검출여부Lead Detection 검사방법method of inspection 실시예1Example 1 검출되지않음Not detected ICP분석기ICP Analyzer 실시예2Example 2 검출되지않음Not detected ICP분석기ICP Analyzer 실시예3Example 3 검출되지않음Not detected ICP분석기ICP Analyzer

유해중금속검출 여부Hazardous Heavy Metal Detection 중금속검출여부Heavy metal detection 검사방법method of inspection 실시예1Example 1 검출되지않음Not detected ICP분석기ICP Analyzer 실시예2Example 2 검출되지않음Not detected ICP분석기ICP Analyzer 실시예3Example 3 검출되지않음Not detected ICP분석기ICP Analyzer

이상의 본 발명에 따른 세라믹의 제조방법은 천연광물의 고유한 성질을 살려 살균제, 친환경 비료, 토양개선제, 악취 및 유독가스 흡착, 탈취, 전자파 차폐, 친환경 건축자재 원료, 피부질환 등에 매우 효과가 있으며, 나이가 고성능 해독제, 건강 보조식품, 건축 자제 내-외장재, 피부보호제, 의류 및 원사사용, 동물사료 및 식물비료 등으로 사용할 수 있는 효과가 있다.Ceramic manufacturing method according to the present invention is very effective in disinfectant, eco-friendly fertilizer, soil improver, odor and toxic gas adsorption, deodorization, electromagnetic shielding, environmentally friendly building materials, skin diseases, utilizing the unique properties of natural minerals, There is an effect that can be used as a high-performance antidote, health supplements, building materials, interior and exterior materials, skin protection agents, clothing and yarn use, animal feed and plant fertilizers.

이상으로 본 발명의 특정한 부분을 상세히 기술하였는 바, 당업계의 통상의 지식을 가진 자에게 있어서, 이러한 구체적 기술은 단지 바람직한 실시예일 뿐이며, 이에 의해 본 발명의 범위가 제한되는 것이 아닌 점은 명백할 것이다. 따라서, 본 발명의 실질적인 범위는 첨부된 청구항들과 그것들의 등가물에 의하여 정의된다고 할 것이다.While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that such detail is solved by the person skilled in the art without departing from the scope of the invention. will be. Accordingly, the actual scope of the present invention will be defined by the appended claims and their equivalents.

10: 견운모 20: 세피오라이트
30: 스맥타이트 40: 일라이트
50: 물 11: 혼합물
12: 분쇄된 혼합물 13: 가열된 혼합물
14: 물이 첨가된 혼합물
10: Cicada 20: Sepiolite
30: Smactite 40: Illite
50: water 11: mixture
12: pulverized mixture 13: heated mixture
14: mixture with water added

Claims (8)

견운모와 세피오라이트, 스맥타이트, 일라이트를 혼합하여 혼합물을 준비하는 단계;
상기 혼합물을 400 내지 600매쉬의 크기로 분쇄하는 단계;
상기 분쇄된 혼합물을 400 내지 600 ℃ 로 가열하는 단계;
상기 가열된 혼합물에 상기 혼합물 1kg 대비 1 내지 3 ℓ의 물을 첨가하는 단계;
상기 물이 첨가된 혼합물을 10 내지 50 ㎛의 입경으로 성형하는 단계를 포함하며,
상기 견운모는 충청북도 음성군 생극면에서 채취하고, 게르마늄 20 내지 60 ppb, 은 20 내지 40 ppb 및 세륨 10 내지 20 ppb 를 포함한 것을 특징으로 하는 세라믹의 제조방법.
Preparing a mixture by mixing mica and sepiolite, smackite and illite;
Grinding the mixture to a size of 400 to 600 mesh;
Heating the milled mixture to 400 to 600 ° C .;
Adding 1 to 3 liters of water to 1 kg of the mixture to the heated mixture;
Molding the mixture to which the water is added to a particle diameter of 10 to 50 μm,
The biotite is collected from the polar surface of the negative group, Chungcheongbuk-do, germanium 20 to 60 ppb, silver 20 to 40 ppb and cerium manufacturing method characterized in that it comprises 10 to 20 ppb.
삭제delete 삭제delete 제1항에 있어서,
상기 혼합물은,
견운모 65 내지 75 중량%, 세피오라이트 5 내지 15 중량%, 스맥타이트 5 내지 15 중량%, 일라이트 5 내지 15 중량% 인 것인 세라믹의 제조방법.
The method of claim 1,
The mixture may contain,
Method of producing a ceramic which is 65 to 75% by weight of mica, 5 to 15% by weight of sepiolite, 5 to 15% by weight of smackite, 5 to 15% by weight of illite.
삭제delete 삭제delete 삭제delete 삭제delete
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KR102132577B1 (en) * 2020-01-29 2020-07-09 우창수 Odor reduction composition and method for manufacturing the same

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KR100614107B1 (en) * 2004-09-13 2006-08-22 남윤미 The method for manufacturing of Ceramics and It's use
KR20060121447A (en) * 2005-05-24 2006-11-29 안기환 Ceramic ball mixture for producing mineral ion water
KR100940067B1 (en) * 2009-06-19 2010-02-05 (주)세일Tnc Manufacturing method of bio ceramics composition

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KR100614107B1 (en) * 2004-09-13 2006-08-22 남윤미 The method for manufacturing of Ceramics and It's use
KR20060121447A (en) * 2005-05-24 2006-11-29 안기환 Ceramic ball mixture for producing mineral ion water
KR100940067B1 (en) * 2009-06-19 2010-02-05 (주)세일Tnc Manufacturing method of bio ceramics composition

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KR102132577B1 (en) * 2020-01-29 2020-07-09 우창수 Odor reduction composition and method for manufacturing the same

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