CN107344762A - Bar bag and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation and its preparation and application - Google Patents

Bar bag and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation and its preparation and application Download PDF

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Publication number
CN107344762A
CN107344762A CN201710604065.0A CN201710604065A CN107344762A CN 107344762 A CN107344762 A CN 107344762A CN 201710604065 A CN201710604065 A CN 201710604065A CN 107344762 A CN107344762 A CN 107344762A
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stone
preparation
gull
good fortune
antiscale
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杜永健
林江
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    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/083—Mineral agents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/02—Non-contaminated water, e.g. for industrial water supply

Abstract

Bar bag and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation and its preparation and application belong to Physical Anti-fouling Technology field.The mesh bag and the sea-gull good fortune stone of inside that it is worked out by stainless steel monofilament are formed, using to natural crystal, monocrystalline and polycrystalline material carry out the reinforcing of high-temperature plasma surface relief and reinforcing, operating electrical stone is being just in water, the lifting and modification of the insulativity of negative electricity interpolar, porous natural crystal enrichment is strengthened, it is modified, optimization processing, improve its constitution, appearance form, increase specific surface area, obtain optimal height, low-k component ratio, enhancing absorption and desorption ability, improve far-infrared radiation rate, ultrasonic cavitation intensity, piezoelectricity and pyroelectricity intensity, lift anion-generating capacity, enhance the activity of oxidation and reduction, improve absorption and stripping capacity, lift antiscale activation capacity, ensure water quality alkalescent or neutrality, extend antiscale continuation.It can be used in various utensils and equipment to water heating, heat exchange and water cooling.

Description

Bar bag and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation and its preparation and application
First, invention field
The present invention relates to a kind of bar bag and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation (hereinafter referred to as antiscale system Agent) and its preparation and application, it is more particularly to a kind of using sea-gull good fortune standby suitable high-temperature high pressure water made of stones and flowing wetting system The bar bag used and ball pouch-type activation mineralization antiscale preparation and its preparation and application.Sea-gull good fortune stone be to natural crystal, monocrystalline and Polycrystalline material carries out high-temperature plasma, medium radio-frequency sputtering, the material of heat treatment preparation, i.e., using Physical to natural ore deposit Stone, monocrystal and polycrystalline material carry out surfacing and its internal structure and characteristic are modified, optimize and reinforcing at Manage the activation mineralization antiscale preparation prepared.In other words, with physical method to natural crystal, monocrystalline and polycrystalline material --- electrically Stone, Sibin floating stone, clinoptilolite, graphite silica, serpentine, medical stone, germanium ore, rutile ore, black day are according to stone, the Black Warrior Rock, hornblend, Kweiyang stone, polycrystal barium titanate, ferroelectric single crystal niobic acid Lithium, 316L stainless steel wire etc. carry out high pressure water logging respectively Bubble, stirring, cleaning and drying pretreatment, high-temperature plasma scan process, medium radio-frequency sputtering, heat ageing handling process are to its table Face is modified and nursed one's health and its internal structure and characteristic are modified, optimized and strengthened, so as to improve particle surface Appearance form, their specific surface area is increased, to obtain the high and low dielectric constant component ratio of optimization, realization most preferably rubs Efficiency is wiped, enhancing activity, enhancing absorption and desorption ability, improves far-infrared radiation rate, ultrasonic cavitation effect intensity, piezoelectricity With pyroelectric effect intensity, antiscale activation capacity is lifted, improves absorption and stripping capacity, lifts anion-generating capacity, strengthens oxygen Change and kill various bacteria ability with reduction reaction activity, enhancing, it is ensured that the sterile nontoxic, alkalescent of water quality or neutral extension antiscale system The continuation of agent, and save the several mineral materials beneficial to human body and trace element and metasilicic acid.Especially it is emphasized that, It can improve the isotopic ion ability removed and come from underground water (drinking water or industrial water), for137Cs and90Sr There is preferable reduction ability, quite there is novelty.The invention belongs to high temperature, high pressure wetting system and flowing wetting system antiscaling, descaling preparation Technical field.
2nd, background of invention
Well known to crowd, either industrial device --- boiler water heating system or cooling water system, or domestic use of water Device --- kettle, insulating pot, boiler, electric water boiler, electric heater, solar water heater etc. use a period of time Afterwards, because the salt dissolved in water is concentrated, the heat-transfer area or channel interior that are contacted with water will be caused, such as boiler inner wall, gone out Turn into incrustation scale from insoluble salt in water due to deposited on pipe inner wall or bottom of the pot, hot-water line side wall.Incrustation scale Species is more, wherein most important have three classes：1st, calcium system incrustation scale, such as：Calcium carbonate, calcium sulfate, calcium sulfite, calcium phosphate etc. Calcium system incrustation scale；2nd, silicon systems incrustation scale, such as：Silica, calcium silicates, magnesium silicate etc.；3rd, iron system incrustation scale, such as：Di-iron trioxide.Incrustation scale Harm it is very big, such as the harm of boiler scale is as follows：
Waste fuel
Incrustation scale makes the heat transfer property of heating surface be deteriorated, and small ten times to hundred times of its thermal conductivity ratio metal, fuel combustion is put Heat can not be delivered in time in pot water, substantial amounts of heat is taken away by flue gas, causes exhaust gas temperature too high, if smoke evacuation loss increase Add, boiler thermal output reduces to keep boiler nominal parameter, must just add fuel more.It is reported that 1 millimeter of incrustation scale is about It is one is wasted into fuel more.Therefore the fuel and electric power that waste every year, can in terms of tens million of ten thousand tons, tens million of ten thousand degree count.
2nd, heating surface damages
Incrusted boiler, because heat transfer property is deteriorated, the heat of fuel combustion can not promptly pass to a pot water, cause The temperature of burner hearth and flue gas raises.Therefore, the temperature difference increase of heating surface both sides, metal wall temperature rise, intensity decreases, in pot internal pressure Under power effect, bulge, or even explosion danger easily occurs.
3rd, the power output of boiler is reduced
After gyp, because heat transfer property is deteriorated, to reach rated capacity, it is necessary to more fuel are consumed, but With the increase of fouling thickness, combustion space is certain, and fuel consumption is restricted.Therefore, boiler power output will reduce.
4th, corrode
Metal is easily damaged by corrosion.Because containing oxygen in water, acid and alkaline matter will all corrode boiler Metal surface, boiler wall is thinned, depression, or even perforation.Especially hot-water boiler, quantity of circulating water is big, and corrosion is even more serious.Its The secondary metal erosion by below generation incrustation scale：Incrustation scale containing high price iron, easily causes the metal erosion being in contact with it, and iron Corrosion product easily forms incrustation scale again again.This is a kind of vicious circle, and it can rapidly result in boiler component damage and especially fire The harm of thermo oil boiler metallic corrosion products is bigger.
5th, vapour and water are risen altogether
When containing more sodium chloride, sodium phosphate, grease and silicide in stove water, or organic matter and alkali work in pot water During with saponification occurs, in pot boiling water evaporation process, liquid level just produces foam, forms priming phenomenon.
6th, the circulation of water is destroyed
Boiler divides Natural Circulation and forced circulation, and the internal circulating load of various boiler waters is that balance is certain, either tedge Or down-comer, it is necessary to have and enough block area.After boiler tube inwall scaling, just directly result in pipe inner section product and subtract It is few, the increase of steam resistance, the normal water circulation of boiler is destroyed so that heated metal wall temperature raises when pipeline is blocked by incrustation scale When, water circulation stops, and local boiler tube produces partial vaporization because of pipe temperature rise and burning or pipe explosion accident occurs.It is reported that 2015 Year one, changzhou in November city coal-fired steam boiler (model：DZL2-1.0-AII the serious scaling of shell, water-cooling wall) occurs Pipe booster seepage accident.Site inspection finds shell, pipe inner wall, 2~3mm of scaling on the outside of smoke pipe, coverage rate >=50%, enters Pipe inner wall scaling 1-2mm, coverage rate >=80%.Shell bottom and the serious scaling of front and rear tube sheet, thickness is about 5~ 6mm, bottom accumulation body refuse, more than incrustation scale 200mm.There is a longitudinal 35mm in a water pipe counter-fire face on fire door side on the right side of boiler, wide 30mm, high 10mm bulge, the longitudinally split long 50mm in summit of bulge, wide about 3mm's is split up mouth.Scaling seriously surpasses in the pipe Mark, it is local up to 3~5mm, cause the water pipe to rise thick and booster.
The antiscale preparation of present commercialization is worked using chemical method, and it is anti-to only have calcium system chemistry at present Dirty agent, and silicon systems scale preventative does not come out also.The Physical working mechanism of their operation principle and the present invention is entirely different.Close In the antiscale preparation prepared using natural crystal, the modification of monocrystal and polycrystal, optimization, intensive treatment and they in high temperature The scheme applied in high pressure wetting system and flowing water circulating apparatus has not yet seen report at home, outside at present.
3rd, goal of the invention
The purpose of the present invention be a kind of bar bag of exploitation and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation and its prepare with Using the bar bag and ball pouch-type that more particularly to a kind of suitable high-temperature high pressure water and flowing wetting system using sea-gull good fortune stone uses Sea-gull good fortune stone activation mineralization antiscale preparation and its preparation and application.The purpose of the present invention is real by following technical proposals and step Existing：
A kind of bar bag and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation and its preparation and application, it is crucial that it includes three Entries Technology：Design, bar bag and the ball pouch-type sea-gull good fortune stone activation mineralization of bar bag and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation The preparation technology and bar bag of antiscale preparation and the application process of ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation, it is characterized in that：
Bar bag and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation 10 are the 316L types by diameter 0.10mm~0.30mm The bar shaped of stainless steel monofilament establishment or spherical porous metal mesh bag 1, the component for being seated in its internal scale preventing and removing agent --- sea The sealing 3 of the particle of gull good fortune stone 4 and spot-welded is formed；
As shown in figure 1, the bar shaped of described stainless steel monofilament establishment or spherical porous metal mesh bag 1 using bottom without opening Mouthful, and the open-type structure type of the progressive closing in upper end；Bar shaped or spherical porous metal mesh bag 1 are to utilize 0.10mm~0.30mm 316L stainless steel flat wires worked out with circle wire material in the form of monofilament, the diameter dimension of bar shaped or spherical porous metal mesh bag 1 It can be worked out by adding pin, subtracting the skill of handling needles；Although its upper end takes progressive contraction mode to work out, but it is still necessary to retain opening 3, to load the particle of sea-gull good fortune stone 4 from opening 3；A diameter of 2.5mm of the mesh 2 of bar shaped or spherical porous metal mesh bag 1~ 3mm, the length of bar shaped porous metals mesh bag 1 can be 1m~number 100m cylinder or flat cylindricality, its cross-sectional diameter Usually 10~￠ of ￠ 45mm circle or the rectangle that cross section is 10mmx35mm；And the diameter of spherical porous metal mesh bag It should be less than or equal to ￠ 35mm；
Described bar bag and the preparation technology of ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation are：
From opening 3 load be diameter dimension ＞ ￠ 3.5 the particle of sea-gull good fortune stone 4；The particle of sea-gull good fortune stone 4 is to utilize thing Logos --- water under high pressure immersion, stirring, cleaning and drying pretreatment, high-temperature plasma scan process, medium radio-frequency sputtering, heat are old Change handling process its surface is modified and nursed one's health and its internal structure and characteristic is modified, optimized and strengthened be natural Ore, monocrystal and polycrystal component, i.e., using by modified and processing natural crystal, monocrystal and polycrystal component, example Such as：Modified verdelite, modified medical stone, modified clinoptilolite.
First to the particulate material of sea-gull good fortune stone 4 --- tourmaline, Sibin floating stone, clinoptilolite, graphite silica, serpentine, Medical stone, germanium ore, rutile ore, black day are according to stone, basalt, hornblend, Kweiyang stone, ferroelectric single crystal niobic acid Lithium, titanium Sour barium polycrystal and 316L stainless steel wires carry out the pretreatment of water under high pressure immersion, stirring, cleaning and drying etc. respectively；
In addition, according to the different classes of of the grain fraction of sea-gull good fortune stone 4, corresponding specially treated technique is taken respectively：
For non-porous natural crystal, monocrystal and polycrystal component the surface relief of high-temperature plasma must be used strong Change the far infrared radiation rate part with mechanical strength consolidation process technique and using high-temperature plasma heating lifting component Science and engineering skill；And for porous natural crystal component enrichment must be utilized to strengthen, modified, optimization processing technique；Wherein, for porous The clinoptilolite of natural crystal must carry out special modification process；
Must be to after-treatment must be carried out for tourmaline ore particles：1) concentration --- tourmaline low-grade ore It is changed into the high-grade ore of tourmaline；2) increase the insulativity between tourmaline positive and negative electrode, especially to lift tourmaline work in water The handling process of insulativity when making.
Described bar bag and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation 10 can be applied in solar water heater Thermal-collecting tube, the economizer of vertical boiler, evaporator, superheater, down-comer, saturated steam pipe water cooling tube in or saturated steam pipe In drum；
Its application process is as described below：
Using lay-up method is bar bag and ball pouch-type sea-gull good fortune stone activation antiscale mineralising preparation 10 is installed in heating or refrigeration is set In standby heat exchanger, or use welding or be suspended on the fixation of a welding column with every 300mm range points bar bag The metal mesh bag 1 of type sea-gull good fortune stone activation antiscale mineralising preparation 10 is fixed on heat exchanger inwall or water cooling tube, elbow or overheat In side wall in device pipe；The processing length of sea-gull good fortune stone activation antiscale mineralising preparation 10 depends on water cooling tube, economizer tube, vapour Bag, steam-water separator, heat exchanger, superheater tube, steam-water separator, heat exchanger, the effective of superheater tube use length, are usually 1m~number 100m；The diameter of bar pouch-type sea-gull good fortune stone activation antiscale mineralising preparation 10 is usually 10~￠ of ￠ 45mm；Bar pouch-type sea The cross-sectional area of gull good fortune stone activation antiscale mineralising preparation 10 should be equal to water cooling tube, economizer tube, drum, steam-water separator, change The 15%~20% of the cross-sectional area of hot device, superheater tube or elbow；
In fig. 2, spherical sea-gull good fortune stone activation antiscale mineralising preparation 10 kettle, insulating pot, boiler, electric water boiler, The preferred structure applied in electric heater is that spherical sea-gull good fortune stone activation antiscale mineralising preparation 10 is assemblied in four hole card holders 5, Spherical sea-gull good fortune stone activation antiscale mineralising preparation assembly 6 is constituted, the assembly 6 is then placed in described insulating pot etc again The bottom of device；
Natural crystal, monocrystal and the polycrystal component of described sea-gull good fortune stone activation antiscale mineralising preparation 10 be：It is modified Tourmaline, Sibin floating stone, modified clinoptilolite, graphite silica, modified medical stone, rutile ore, basalt, germanium ore, snake Line stone, Kweiyang stone, hornblend, black day are formed according to stone, polycrystal barium titanate, ferroelectric single crystal niobic acid Lithium components；By weight, The ratio of each component is as follows during it is formulated：Modified verdelite is 10~30%, Sibin floating stone is 2~10%, modified medical stone is 2~30%, rutile ore is 2~10%, modified clinoptilolite is 0.3~8%, graphite silica is 1~15%, germanium ore Be 1~10% for 1~10%, basalt, black day according to stone be 1~15%.It is serpentine 1~10%, hornblend 1~15%, expensive Positive stone 1~15%, polycrystal barium titanate 2~15%, ferroelectric single crystal niobic acid Lithium 1~18%.
As shown in Fig. 3, Fig. 4 and Fig. 5, bar shaped or spherical sea-gull good fortune stone activation antiscale mineralising preparation 10 can be applied too It is positive can the thermal-collecting tube of water heater, vertical boiler, economizer, evaporator, superheater, down-comer, saturated steam pipe water cooling tube in Or in saturated steam pipe drum.
In figure 3, the length of bar pouch-type sea-gull good fortune stone activation mineralization antiscale preparation 10 should be equal to the collection of solar water heater The 60% of the length of heat pipe 8.A diameter of 10~￠ of ￠ 45mm of bar pouch-type sea-gull good fortune stone activation mineralization antiscale preparation 10.For the sun 10 a diameter of ￠ 15mm of bar pouch-type sea-gull good fortune stone activation mineralization antiscale preparation of the heat collector 7 of energy water heater.In Fig. 4,9 be vertical Formula boiler, 10 be bar pouch-type sea-gull good fortune stone activation mineralization antiscale preparation.Fig. 5 be applied to economizer, evaporator, superheater, under The mounting structure schematic diagram of bar shaped type sea-gull good fortune stone activation mineralization antiscale preparation in water cooling tube in drop pipe, saturated steam pipe.Its In, Fig. 5 (A) is applied to bar shaped type sea-gull in the water cooling tube in economizer, evaporator, superheater, down-comer, saturated steam pipe The mounting structure schematic diagram of good fortune stone activation mineralization antiscale preparation.In the figure, 12 be economizer, evaporator, superheater, decline Pipe, the water cooling tube of saturated steam pipe.10 be bar pouch-type sea-gull good fortune stone activation mineralization antiscale preparation.Fig. 5 (B) is to be applied to save coal Device, evaporator, superheater, down-comer, saturated steam pipe drum in bar shaped type sea-gull good fortune stone activation mineralization antiscale preparation it Mounting structure schematic diagram.In the figure, 15 be drum.
The working mechanism of bar bag and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation 10 is as follows：
Due to the flowing of water, there is stronger friction between the particle of sea-gull good fortune stone 4 of modified optimization intensive treatment And collision, following effects will occur between 4 each particle surface of sea-gull good fortune stone：
Triboelectrification effect
Triboelectrification effect between 4 each particle surface of sea-gull good fortune stone is due to that the friction of water flowing and impact occur 's.It can be seen from electrostatics and electrodynamic knowledge, the quantity of electric charge caused by triboelectrification and Shi electricity Ti, Jie by both electric bodies The difference of electric constant is directly proportional, the big person's positively charged of dielectric constant, and the small person of dielectric constant is negatively charged.Therefore, sea-gull good fortune stone 4 of the present invention Particle is using the mixing of the maximum natural crystal of D-value of dielectric constant, artificial single crystal body and multicrystalline particles, their dielectric constant From 3.8~8 (such as the graphite silica of natural crystal is 3.6, cordierite 8.5, saponite 6.0, serpentine are 8.0, wheat Meal stone is 8.0) (such as barium-titanate polycrystal particle be 1500, and ferroelectric single crystal niobic acid Lithium is 700, rutile ore to 1500 For 100), the difference of their dielectric constant is up to 3 orders of magnitude.
The difference of dielectric constant between the impact of the invention do not flowed merely with water and friction, the adjacent particle of sea-gull good fortune stone 4, But also using the anisotropic properties of monocrystal in sea-gull good fortune stone 4, make friction that water flows and impact direction and monocrystal Crystallographic axis shaft orientation relation strengthens triboelectrification effect, such as the niobic acid Lithium of ferroelectric single crystal is processed into cylinder, its crystallographic axis Y-direction with Cylinder it is axially coincident, and make the axially vertical of the niobic acid Lithium cylinders of water (flow) direction and ferroelectric single crystal, it is as parallel as possible In Z axis to.
In short, synthetically using particle high-k is poor, anisotropy of ferroelectric single crystal and water flow direction it The electrostatic field strength of triboelectrification can be significantly increased in three factors.Obviously, quantity of electric charge convection current only caused by the triboelectrification The electrolytic effect contribution of dynamic water is very big.
2nd, piezo-electric effect produces electric charge
It can be seen from the knowledge of piezoelectricity, work as piezo-electric crystal, such as the barium titanate (piezo-electric crystal) that is polarized or be polarized Ferroelectric single crystal (niobic acid Lithium) when being acted on by certain fixed-direction external force, it is internal just to produce polarization, while at certain The opposite electric charge of symbol is produced on two surfaces；After external force removes, crystal returns to uncharged state again；When external force acts on When direction changes, the polarity of electric charge also changes therewith；The quantity of electric charge caused by crystal stress is directly proportional to the size of external force.Pipeline The impact and friction of middle flowing water will produce substantial amounts of electric charge on some natural crystals, artificial single crystal body and multicrystalline particles surface.
The piezoelectric property of tourmaline belongs to outstanding person in natural crystal.
3rd, pyroelectric effect produces electric charge
Due to the change of temperature, knot occurs in pyroelectric crystal (ferroelectric single crystal niobic acid Lithium) and piezoelectric ceramics barium titanate etc. Charge-site relative displacement on structure, makes their spontaneous polarization strength change, so as to produce contrary sign at their both ends Bound charge, this phenomenon is referred to as pyroelectric effect.In other words, pyroelectric crystal (ferroelectric single crystal niobic acid Lithium) and piezoelectricity pottery The bound charge that the spontaneous polarization of porcelain barium titanate produces contrary sign is due to just to have this property after have received infrared ray.Typically In the case of, if rate of temperature change is identical, caused pyroelectric charges are equal in magnitude in heating and cooling process, but symbol is opposite.
Described on end, the appearance of the electric charge of natural crystal, monocrystal and multicrystalline particles is due to the impact of flowing water and rubbed Wipe, rubbed caused by the movement between particulate matter, cause the low-grade fever of friction generation and the spoke of far infrared between particulate matter Penetrate and the radiation of the far infrared of boiler hot-water.Mechanical energy, heat energy are become electric energy using pyroelectric effect.Niobic acid The pyroelectric effect of Lithium, barium titanate etc. is very strong.Certainly, the pyroelectricity characteristic of tourmaline is also outstanding person in natural crystal.
4th, the cavitation effect of ultrasonic wave
The natural crystal of the present invention, some component particles of monocrystal and polycrystal and the friction and collision of current, hold very much Mechanical resonant phenomena easily occurs, and launches ultrasonic wave.When ul-trasonic irradiation is in water, substantial amounts of minute bubbles can be produced.Its One of reason is that locally " tension " occur in water, and so as to produce negative pressure, the reduction of pressure makes original gas mistake soluble in water Saturation, cause gas to be escaped from water, turn into minute bubbles.The two of reason are that powerful " tension " is empty into one water " tearing ", Referred to as cavitation effect.For vapor or other kinds of gases of water are dissolved in empty, in some instances it may even be possible to are vacuum.Because cavitation is formed Minute bubbles can constantly move with the vibration of surrounding medium, grow up or vanish suddenly.Water around when vanishing pours gas suddenly Steep and produce high temperature, high pressure, while produce shock wave.Adjoint interior friction can form electric charge with cavitation.Especially because match somebody with somebody Some piezoelectricity, ferroelectric particle are included in side, it is easier to promote the generation and reinforcing of ultrasonic wave.Therefore the ultrasonic wave radiates with component Far infrared superposition so that water clusters miniaturization；Water clusters after miniaturization are by natural crystal, monocrystal and more The effect of the electric field of crystal, magnetic field, far infrared and anion is by negative ionization, so as to prevent incrustation scale.
5th, the electrolytic effect of circulating water
Mechanical energy is become electric energy by above-mentioned natural crystal, monocrystal and multicrystalline particles, and is passed by conductor water power Lead, become electric current, be changed into electrochemical energy, part is flowed water electrolysis.The most critical effect of part flowing water electrolysis is to make The raw water of inflow by neutralisation and alkalescent, as a result no matter acidic aqueous solution, or alkaline aqueous solution can all become pH value Neutrality or alkalescent water for 7.6~6.5.
The water of neutralisation can stagnate the oxidation of ferrous metal, break off the extension of iron rust and continue to produce, while will generation Iron rust progressively remove or exclude.Obviously, the neutralisation of water plays crucial work in the activation of circulating water, mineralising, antiscale and scale removal With.
6th, the generation of trace hydrogen and bubble sol solutionses
Well known to crowd, during water electrolysis, hydrogen will be generated in cathode terminal, and oxygen is generated in anode tap.In the reaction, it is golden The reactions such as the precipitation of category, the dissolving of many kinds of substance, ionization decomposition are carried out simultaneously.Under given conditions, due to the electricity of oxygen Solution and reduction reaction, can produce hydrogen peroxide (H2O2).The extremely strong hydrogen atom of reproducibility caused by water electrolysis, becomes at once Hydrogen molecule.Its proportion is small, and is quite insoluble in water, therefore promptly overflows the water surface.Oxidisability pole caused by same water electrolysis Strong oxygen atom has also quickly become oxygen molecule.A portion is soluble in water, turns into dissolved oxygen, but its solubility is quite It is low, it is 8mg/L at 20 DEG C.Remaining overwhelming majority turns into small bubble, constitutes bubble solution.The atomic state of water electrolysis Hydrogen and oxygen there is extremely strong redox ability, being capable of sterilization.In addition, described bubble solution and solid colloidal particles Electric double layer is equally formd on surface, it is negatively charged, it is mutually exclusive, do not condense, do not rise and fall, with a kind of dispersed of stabilization for a long time Ground is present in the aqueous solution, and can with the flowing of dampening synchronization-moving active oxygen bubble solution.
The great advantage of the bubble sol solutionses is that it can be adsorbed organic matter well and including iron rust, impurity etc. Panoramic minute solid particles.Another advantage it possess eliminate flocculation colloidal sol function, can remove by organic matter, Incrustation scale, the dirt of the flocculations such as iron rust, bacterium formation.In other words, it can pierce incrustation scale, dirt, the inside of attachment, slit, In slight crack, supply active oxygen, play deflocculation, make the solidifying bodies such as incrustation scale, dirt occur colloidal sol phenomenon, cause incrustation scale, Soil dispersion is removed.
In short, bar bag and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation can be imitated synthetically using triboelectrification Should, piezo-electric effect, pyroelectric effect, ultrasonic wave effect, the electrolytic effect of water, bubble colloidal sol fluid effect directly in heat conductor or Established on container conduit wall on easy incrusted metallic object and repel inanimate matter ion in water --- the alternation electricity of calcium, magnesium, silicon etc. , or lifted on its periphery and repel or do not attract inanimate matter ion --- calcium, magnesium, the active force of silicon plasma, prevent inanimate matter Cohesion and mineralising reduction reaction occur on the waterpipe wall of heat conductor or container for ion, so as to prevent the hair of fouling It is raw.
The present invention specially treated natural crystal, monocrystal and the countless crystal on multicrystalline particles surface it is almost each It is individual all to become miniature water electrolyser.Atom state hydrogen caused by electrolytic cell and oxygen have extremely strong redox ability, can Sterilization, it can also form a kind of dispersed of stabilization and be present in for a long time in the aqueous solution, and can be with the flowing of dampening And synchronization-moving active oxygen bubble solution, undertake sterilization and remove the water formed by flocculations such as organic matter, iron rust, bacteriums Dirt, the task of dirt.Obviously, the miniature electrolytic cell is the basis of natural crystal, monocrystal and multicrystalline particles scale preventing and removing agent And key.
The preparation for the sea-gull good fortune stone activation antiscale mineralising preparation 10 being seated in inside porous mesh bag or tennis is of the invention Basis and the core of technology.
The natural crystal that sea-gull good fortune stone activation antiscale mineralising preparation 10 uses mainly has six major classes by its function point：1st, it is remote red Outer line style, 2, negative ion type, 3, oxidation and reduced form, 4, electrostatic, 5, porous absorption dissociative type.6th, by current friction and punching Hit easy resonance ejection ultrasonic type.
Sea-gull good fortune stone activation antiscale mineralising preparation 10 includes natural crystal, monocrystal and polycrystal, i.e., by modified verdelite, It is Sibin floating stone, modified clinoptilolite, graphite silica, modified medical stone, rutile ore, basalt, germanium ore, serpentine, expensive Positive stone, hornblend, black day are formed according to stone, polycrystal barium titanate, ferroelectric single crystal niobic acid Lithium components.By weight, it is formulated The ratio of middle each component is as follows：Modified verdelite is 10~30%, Sibin floating stone is 2~10%, modified medical stone be 2~ 30%th, rutile ore is 2~10%, modified clinoptilolite is 0.3~8%, graphite silica is 1~15%, germanium ore is 1 ~10%, basalt be 1~10%, black day according to stone be 1~15%.Serpentine 1~10%, hornblend 1~15%, Kweiyang stone 1~15%, polycrystal barium titanate 2~15%, ferroelectric single crystal niobic acid Lithium 1~18%.
The effect of above-mentioned each component and characteristic are summarized as follows：
Tourmaline is a kind of special polarity crystallization of structure, and itself can generate electricity, and for good and all discharges anion and remote red UV radiation.Be in tellurian mineral uniquely with nature can for good and all radiating electron ore, when tourmaline and water connect When touching, then moment will produce electric discharge, make the slight electrolysis of water generation.Cation will be attracted by negative electrode, the electronics with releasing With reference to being changed into hydrogen releasing, be changed into alkalescent so as to water.The result of electrolysis can obtain the activation at interface, the stabilisation of chlorine, iron Purifying, water reduction, certain micro-organisms aggregate etc. can be eliminated.It can reduce water clusters, usual hydrone (H2O) And non-singleton, its molecule will be combined with each other, micel is formed.The far infrared of tourmaline radiation can not only cut off water Molecular beam, chlorine or impurity in water are removed, makes the taste of water good, and small molecule beam can increase the penetration to the person, carry High immunity.
In normal temperature, radiation wavelength is more than 10 microns of far infrared, its far infrared emissivity nearly 91%, in water In handling process, interfacial activity that it can be made to be contacted with water.In order that its entirely appropriate bar bag and ball pouch-type sea-gull good fortune stone The requirement of activation mineralization antiscale preparation, the present invention are handled it using physical method, constitute modified verdelite, its side Introduced after method.It is up to 86%~90.6% according to the far-infrared radiation rate of stone, far-infrared radiation rate of the black day according to stone Reach as high as 92.5%, and contain substantial amounts of titania molecule, its anion-generating capacity up to 35~225/CC, so as to Oxidation and reduction reaction activity can be greatly promoted, it can sterilize, and realize the corrosion layer reduction of oxidation state, therefore can derust, Decontamination and some incrustation scales of removing.
Graphite silica is a kind of mineral that can semi-permanently radiate the μ m of mid and far infrared line 4~14 at normal temperatures.It Can emitting far-infrared play deep layer ripple effect, by resonant absorption produce heat, larger water clusters solution can be made From, become small water clusters or hydrone, and hydrogen ion quantity is added, blacklead silica or negative ion generating body, its Anion-generating capacity is about 25,000/CC or so.It is 3.6 and graphite silica dielectric constant is small, the big list with dielectric constant Brilliant, multicrystalline particles (such as：Barium-titanate polycrystal dielectric constant is 1500, and ferroelectric single crystal niobic acid Lithium is 700, rutile ore Stone is 100) to coordinate to use in circulating water, can produce very high electrostatic pressure, cause water to activate, it is special to improve its reduction Property, play antiscale and detergent action.In addition, also including magnetic iron ore composition in blacklead silica material, the magnetic iron ore composition can be sent out Penetrate ultramicron and along with faint Wave energy.Ultramicron and adjoint Wave energy all have antiscale and de-sludging Function.
The far infrared radiation peak value of most ores such as graphite silica, serpentine, medical stone, zircon, rutile ore Typically between 8~12 μm.Sibin floating stone is different from them, and it is 7~20 μm that wide can reach, as far as the ripple of extra-far infrared in Segment limit.This is a kind of most wide ore of current far infrared wavelength band.This stone that rubs can send 20~2,000,000 hertz Ultrasonic pulse, occupy first of all ore materials.
Basalt mainly (also has a small amount of oxidation by silica, alundum (Al2O3), iron oxide, calcium oxide, magnesia Potassium, sodium oxide molybdena), wherein SiO2 contents highest, general content is between 45%~52%, wherein K2O+Na2O content is compared with intrusive rock It is slightly higher, CaO, Fe2O3+ FeO, content of MgO are lower slightly compared with intrusive rock.Basaltic mineral composition is mainly by mafic feldspar and pyroxene group Into secondary mineral have olivine, hornblend and biotite etc..Experiment shows, after germanium ore is added, containing appropriate magnesium, iron into Point basalt, the strongly magnetic mineral of magnetic iron ore etc. water temperature can be made to improve 5~8 DEG C.
Germanium ore be it is a kind of can it is radiation infrared and release anion natural crystal.It can dissolution Ge element and Other trace elements beneficial to human body.Experiment shows that 200g germanium ore can discharge 4000 Ge anions, far infrared Radiance is up to more than 85%.
Clinoptilolite is a kind of composite alkali aluminum silicon for new aqueous that some characteristics are better than Conventional zeolites and clinoptilolite Hydrochlorate.Well known to crowd, the majority crystallographic structure that clinoptilolite is is by SiO4And AlO4The three dimensions point that tetrahedron is formed Group.Because its surface area is very big, therefore there is stronger ionic adsorption and exchange capacity.And its exchange capacity is by solution acidity and salt Have a great influence, optimum condition of work is 3 ＜ PH ＜ 10.In order that the entirely appropriate bar bag of clinoptilolite and ball pouch-type sea-gull good fortune The requirement of stone activation mineralization antiscale preparation, particularly increases its porosity, improves adsorptivity, lifted its removing radioactivity from Sub- ability, the present invention have carried out modification to clinoptilolite using physical method, have constituted " modified clinoptilolite ", and it is modified It will be introduced after processing method.
Medical stone is a kind of stronger igneous rock of neutral alkali half of adsorption capacity.The natural mineral matter included in medical stone is easy to From medical stone oxygen is discharged in countless apertures.Turn into purified water by absorbing bleaching powder and other noxious materials.Medical stone In the calcium, iron, the mineral matter such as sodium that give out can improve drinking water.It has stronger far-infrared radiation and anion release energy Power.The medical stone in Naiman Banner table mountain, Inner Mongolia Autonomous Region Zhelimu League is more satisfactory.The medical stone composition is as follows；(1) aoxidize Ferrous iron 1.29%；(2) iron oxide 1.40%；(3) anhydrous phosphorus (phosphorus shuttle acid anhydride) 0.26%；(4) manganese oxide 0.02%；(5) magnesium 3.55%；(6) potassium 3.19%；(7) water 1.10% is adsorbed；(8) calcium oxide 2.00%；(9) sodium 3.16%；(10) titanium 0.30%； (11) water 0.90% is combined；The medical stone is free of radiant.
In order to which suitable high-temperature high pressure water and flowing wetting system and civilian kettle, electric heater etc. use, the present invention is right Medical stone has carried out modification, is introduced after its method.
The far infrared radiation rate of hornblend is up to 98%, and negative ions radiation amount is up to 1732/cc, and Kweiyang stone is remote red External radiation rate and negative ions radiation amount are all very high, and the former is up to 96%, and the latter is up to 9451/cc.
Rutile ore is a kind of rutile eclogite, and its rutile content is 2%~3%.Rutile is purer two Titanium oxide, can be bar bag and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation typically containing titanium dioxide more than 95% Oxidation and reduction reaction provide the effect of catalyst.Polycrystal barium titanate, ferroelectric single crystal niobic acid Lithium dielectric constant are very big：It is more The dielectric constant of crystal barium titanate is 1500, and ferroelectric single crystal niobic acid Lithium is 700, and graphite silica is 3.6, serpentine 8.0, Medical stone is 8.0, and they are not soluble in water, quite stable.It is increase sea-gull good fortune using them as the purpose of antiscale formulation components D-value of dielectric constant between each component of stone activation antiscale mineralising preparation 10, lift the electrostatic potential of triboelectrification.
Different from the method for traditional natural crystal processing water formulation, the present invention is not that directly natural crystal component is loaded In bar shaped or spherical porous metal mesh bag, but strengthen by enrichment and just load with after Physical modification, optimization, intensive treatment In porous metals mesh bag.In other words, the component of antiscale preparation soaked using Physical, stirred, being cleaned, surface modification, Conditioning and its internal structure and characteristic are modified, optimized and intensive treatment.To natural crystal, artificial single crystal body and polycrystalline Body material carries out innovative combination and carries out pattern modification and modification to natural crystal component with physical method, for example, to tourmaline, Sibin floating stone, clinoptilolite, graphite silica, serpentine, medical stone, germanium ore, rutile ore, black day according to stone, basalt, Hornblend, Kweiyang stone, ferroelectric single crystal niobic acid Lithium, barium-titanate polycrystal, 316L stainless steel wires etc. are seated in bar shaped or spherical more Natural crystal component in mesoporous metal mesh bag, it is by soaking, stirring, cleaning, being enriched with, strengthening and Physical is modified, optimization, strong Just load in porous metals mesh bag after change processing, i.e., the component of antiscale preparation soaked using Physical, stirred, cleaned, Surface modification, conditioning and its internal structure and characteristic are modified, optimized and strengthening treatment process.
First to tourmaline, Sibin floating stone, clinoptilolite, graphite silica, serpentine, medical stone, germanium ore, rutile ore Stone, black day are according to stone, basalt, hornblend, Kweiyang stone, ferroelectric single crystal niobic acid Lithium, barium-titanate polycrystal, 316L stainless steel wires Water under high pressure immersion, stirring, cleaning and drying pretreatment are carried out respectively.Its treatment process steps are as follows：
Step 1: it is 1.0~1.8MPa in pressure, temperature is 20~40 DEG C, progress high pressure water logging under the conditions of the time is 8h Bubble, stirring, cleaning,
Step 2: being 90~110kPa in pressure, temperature is 80~120 DEG C, the time be 12h under the conditions of dried,
Step 3: through Step 1: after step 2 pretreatment, then respectively to non-porous component (including tourmaline), more Hole natural crystal carries out high-temperature plasma heating and lifts its far infrared radiation rate, medium radio-frequency sputtering processing, porous day The enrichment of right ore (such as medical stone) is strengthened, modified, optimization processing.
So as to obtain optimal high and low dielectric constant component ratio, improve the appearance form of particle, to realize optimal friction Efficiency；Increase their specific surface area, enhancing activity, absorption and desorption ability；Far-infrared radiation rate is improved, increases ultrasonic wave Cavitation effect intensity, the intensity of piezoelectricity and pyroelectric effect is lifted, increase anion-generating capacity, enhancing absorption and dissolution power, carry Oxidation and reduction reaction activity are risen, strengthens antiscale activation capacity and scale removal ability, it is more that Escherichia coli, staphylococcus etc. are killed in enhancing Kind bacterium ability, makes water quality sterile nontoxic, the several mineral materials and trace element and metasilicic acid beneficial to human body is contained in water, its PH value is 7.6 or so, it is ensured that the continuation of scale preventing and removing agent.It can be used for the various utensils heated to water with heat exchange and water cooling With being used in equipment, health, safety, energy-saving and environmental protection effect are played, the quality that the mankind boil water is changed, by the present invention's Contain several mineral materials beneficial to human body, micro in bar bag and the water of ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation processing Element, macroelement and metasilicic acid, body immunity can be improved, quite be adapted to most crowds to drink.
The Physical of the present invention --- HTHP immersion, stirring, cleaning, high-temperature plasma processing, frequency medium splash It is as follows to penetrate handling process：
To the graphite silica of non-porous component, serpentine, germanium ore, rutile ore, black day according to stone, basalt, angle It is strong that amphibole, Kweiyang stone component carry out HTHP immersion, stirring, cleaning, the surface relief reinforcing of high-temperature plasma and machinery Consolidation process is spent, its far infrared radiation rate is lifted using high-temperature plasma heating, medium radio-frequency sputtering is handled, porous natural The insulativity being enriched between reinforcing, modification, optimization processing, increase tourmaline positive and negative electrode of ore (such as medical stone), especially Be be lifted at the processing method of insulativity when being worked in water, for porous natural crystal clinoptilolite special modification side Method.
Specifically；
1st, the high-temperature plasma surface relief of non-porous component is strengthened and mechanical strength is reinforced and high-temperature plasma The processing of the far infrared radiation rate of heating lifting component
In order to adapt to use in high-temperature high pressure water and flowing wetting system, it is necessary to lift the mechanical strength of particle surface, change The appearance form of particle surface has been apt to it, convex-concave is strengthened, realizes optimal friction efficiency, increase their specific surface area, to obtain The high and low dielectric constant component ratio that must be optimized, enhancing activity, enhancing absorption and desorption ability, respectively to graphite silica, snake Stone, germanium ore, rutile ore, black day carry out the table of high-temperature plasma according to stone, basalt, hornblend, Kweiyang stone component Face convex-concave strengthens and the processing of mechanical strength consolidation process and high-temperature plasma heating far infrared radiation energy：
Pending component particles are laid in machine carousel first, then with high temperature of 1.0~2kw power outputs etc. from Beamlet rifle and cold air rifle irradiate respectively to particle surface.From conventional different using the method for hot plasma device, the present invention Using the synchronous reciprocating scan mode of high-temperature plasma beam rifle and cold air rifle, their beamwidth is all 0.4~0.6cm, high temperature etc. Spacing between ion beam and cold air rifle beam is 500~950mm, and its translational speed is 250~720cm/min, the rotation of rotating disk Speed is 20~500 turns/min.Pyroelectric infrared sensor and high-temperature plasma beam generator should be utilized in whole process Cooperation, detection and control particle surface temperature utilize the monitoring of high-resolution video monitor in the range of 550 ° ± 15 DEG C Grain surface topography, after reaching code requirement, drops to room temperature in atmosphere.
This method can be by adjusting the spacing between its beamwidth, high-temperature plasma beam and cold air rifle beam, translational speed, turning Velocity of rotation and positive and reverse steering the control particle surface thermograde of disk, its free degree is high, and flexibility is good.
Because the natural crystal particle surface of said components generally all contains substantial amounts of low form α Silica grains, when wait from When the temperature of daughter point of irradiation reaches more than 550 DEG C, low form α quartz will convert to high temperature modification β quartz, while occur acutely Volumetric expansion, if so the gas now sprayed using cold air rifle makes natural crystal particle surface rapidly cool down, due to quartz-crystal The thermal inertia of grain is big, then big quartz particles are easy to burst, and produce some new pits or projection；And small quartz The thermal inertia of component particle is small, is not easy to burst, keeps original structure substantially.Because Silica grain is far infrared radiation, energy is excellent Emissive material, they largely appear in the increase on surface and its specific surface area, far infrared radiation energy do not cover by other compositions, Stop, so far infrared radiation rate can be lifted.
In addition, other compositions in natural crystal, some hold modes are constant, some composition of ores, such as sodium metasilicate etc. Agent melts.Obviously, after complete cooled and solidified, mechanical strength second consolidation effect will occur.So as to particle surface occur It is convex, spill state is obvious, convex-concave is uniform, specific surface area increase, component far infrared radiation rate and mechanical strength lifting phenomenon.
It is emphasized that, the technique solves high-temperature high pressure water and flowing wetting system sea-gull good fortune stone activation mineralization antiscale (particle surface convex-concave degree height, good evenness, specific surface area is big, mechanical strength is excellent, frictional behaviour is good, remote red for the high-performance of preparation External radiation rate is lifted) and long-life, the contradiction of low cost.The plasma in process mechanism is gas-solid Coherent reaction, no Consumption water resource, chemical agent need not be added, it is environmentally safe, play the effect of killing two birds with one stone.
2nd, tourmaline low-grade ore is changed into the lifting of the insulativity between the positive and negative electrode of operating electrical stone in high-grade ore and water With modification method
Different from requirement of the conventional equipment to tourmaline, HTHP water installations and flowing wetting system are to the electricity that worked in water The requirement of gas stone is harsher：
Tourmaline particle surface distributed tourmaline positive and negative electrode should than comparatively dense, 2) with the tourmaline that contacts Grain surface electrode is more as much as possible, and its particle surface electrode is preferably same polarity, can be due to tourmaline in nature Complex genesis, the effectively distribution of tourmaline part and uneven in usual ore particles, in the regional area tourmaline composition having It is more, and the effective tourmaline composition of some regional areas is seldom, even zero.In addition tourmaline ore particles are deposited in one Rise, the positive and negative electrode of each tourmaline particle may contact with each other so that its external electric field weakens each other, or even offsets.In water In, the water majority of case in special HTHP wetting system is conductive, and the positive and negative electrode of tourmaline is often shorted, and is used Life-span substantially reduces.Therefore, after-treatment must be carried out to tourmaline ore particles：
1) concentration --- low-grade ore is changed into high-grade ore；2) insulativity between tourmaline positive and negative electrode is increased, it is special It is not the insulativity in ionized water.Particularly,
2.1 concentrations --- tourmaline low-grade ore is changed into the method for high-grade ore
It can be seen from solid-state physics knowledge, tourmaline is when nature generates, and original due to sharp cooling effect Form is compared, and its crystalline lattice structure intactly saves " distortion " occurred, so as to occur at the both ends of crystal The positive and negative electrode of tourmaline.Its size to distort determines the number of electric charge between the positive and negative electrode of tourmaline.
4th, optimal technical scheme
The concentration scheme of the present invention is to apply higher energy to the tourmaline of piezoelectricity and pyroelectricity characteristic, I.e. on the premise of tourmaline crystal lattice structure is not injured, " distortion " that is preserved it, more strongly.In other words, utilize High-temperature plasma fast heating method, the valence of other elements beyond the ferrous ion in tourmaline is set to change, And the change of the ionic radius associated with this, lift its thing due to heating and cooling down the expansion of caused tourmaline and shrinking Manage energy.In order to lift the far infrared radiation energy of tourmaline simultaneously, one layer is coated on tourmaline particle surface by silicic acid-boron The pastel that acid-Aluminum-zinc-potash glass powder is formed with ethanol, is then laid in them on rotating disk, the velocity of rotation of rotating disk is 20~500 turns/min.After ethanol volatilizees at room temperature in pastel, with the high-temperature plasma beam of 1.0~2kw power outputs Rifle irradiates particle surface, and tourmaline particle and the table of silicic acid-boric acid-Aluminum-zinc-potash glass powder are monitored with infrared thermometer Face temperature, its temperature is no more than 700 DEG C, after 30min, stop high-temperature plasma irradiation, it is progressively dropped to room temperature.Through Actual measurement shows that its far infrared radiation rate can improve 13~18%.
Insulativity between 2.2 increase tourmaline positive and negative electrodes, the method for being particularly lifted at insulativity when being worked in water, Attached method, radio frequency sputtering method etc. are blown to the one layer of softening of tourmaline ore particles surface spraying or sputtering, fusing using high-temperature plasma Point is less than 850 DEG C of alumina silicate glass or soda-lime glass layer, and its thickness is about 0.5~5 μm.This is equivalent to each electric Stone ore particles have put on isolation overcoat, prevent the positive and negative electrode between adjacent ore particles to be in contact short circuit phenomenon, also change It has been apt to due to the conductive positive and negative electrode contact short circuit problem occurred of water.So as to improve the service efficiency of piece electrical stone ore stone, Enhance the function of tourmaline.
Preferable scheme is spraying or sputtering alkali-free aluminosilicate glass or uses double glazing insulating barrier method.Alkali-free aluminosilicate glass With preferable chemical stability, electrical insulating property, mechanical strength and relatively low thermal coefficient of expansion.It is by RO-A12O3-SiO2 Composition, wherein RO represents the bivalent metal oxides such as magnesia, calcium oxide, barium monoxide, zinc oxide, due to composition not alkali metal containing Ion, therefore referred to as alkali-free aluminosilicate glass.It is not easy in ionized water to be had by ion aqueous corrosion, quite suitable long-term work High temperature resistant, double high characteristics of anti-high pressure, are quite adapted to use in HTHP ionized water.Here it is the glass of submarine all to make With the reason of alkali-free aluminosilicate glass.
Because alkali-free aluminosilicate glass softening point is very high, about 850 DEG C, and it is anxious with the viscosity of temperature reduction glass melt Increase severely big.Therefore, in order to improve its wear-resisting and resistance to mechanical impact characteristics, its technology difficulty is reduced, double glazing can be used Insulating barrier method or make secondary glass isolation overcoat method：Described double glazing insulating barrier method or make secondary glass isolation overcoat Method is as follows：The alkali-free aluminosilicate glass for being first less than 850 DEG C in one layer of softening point of tourmaline particle surface spraying or sputtering, it is thick Degree is not more than 2 μm, and it is low then to sputter one layer of softening point again --- and less than 650 DEG C of soda-lime glass insulating barrier, its thickness are about 0.5 ~2 μm.
This method not only increases the insulativity between positive and negative electrode when tourmaline works in water, and significantly changes It has been apt to its wearability and resistance to mechanical impact characteristics, has reduced technology difficulty
3rd, the enrichment of porous natural crystal (such as medical stone) is strengthened, is modified, the porous natural crystal of optimization processing, such as wheat Meal stone, because the reasons such as the origin cause of formation of natural crystal, exploitation, transport and processing are usually present some defect and impurities.Therefore, utilize The PROCESS FOR TREATMENTs such as conventional cleaning, heating are difficult some organic matter dirts, inorganic contaminants, the potassium remained in its each duct Ion, sodium ion, iron ion are removed, and the impurity and dirt especially remained in blind hole duct is more difficult to remove totally.They are deposited The purification, activation, mineralization function of water are not only being influenceed, and also reduce antiscale, scale removal ability.Therefore absorption must be removed Dirt and impurity, cleaning dredges porous duct, it is exposed fresh active surface, increase its specific surface area, it is net to lift its Change, activation, antiscale, scale removal ability, the present invention use following methods, realize the porous natural crystal such as medical stone enrichment strengthen, Modified, optimization is strengthened：
Medical stone and aqueous slkali, such as 0.5~5mol/L sodium hydroxide or potassium hydroxide aqueous slkali are mixed Or silicon source, such as Ludox, waterglass or silanes, mix, be made with described aqueous slkali according to given ratio Hydrogel.
The ratio of described aqueous slkali (volume unit is mL) and medical stone (unit of weight is g) is 5；1~20；1；And Silicon source, such as Ludox, waterglass or silanes are as follows with the mol ratio of aqueous slkali：Silica: alundum (Al2O3): Sodium oxide molybdena: water=(3~1): 1: (2~7): (300~120).Process conditions：Temperature be 50~80 DEG C, the reaction time be 8~ 24h, prepare hydrogel.Then, crystallized at 80~95 DEG C, crystallization time is 12~24h.After crystallization, use successively Separation, washing and baking operation, so as to obtain preliminary modification, optimization processing medical stone granule.Then tentatively changing Property, the medical stone granule of optimization processing be placed in Muffle furnace or other heaters and be heated to 450~600 DEG C, be incubated 4 hours, Room temperature is naturally cooling to again.The medical stone granule of preliminary modification, optimization processing is laid in rotating disk again again, utilizes 1.0 The high-temperature plasma beam rifle of~2kw power outputs, irradiation medical stone granule surface, its translational speed is 250~720cm/ Min, beamwidth are 0.4~0.6cm, and the velocity of rotation of rotating disk is 20~500 turns/min, is then naturally cooling to room temperature again, then obtains Enriched reinforcing, the modified, medical stone of optimization processing are obtained, becomes modified medical stone.Sampled detection understand, Chemical cleaning and The scan process of high-temperature plasma beam so that the organic matter in the through hole and blind hole duct of the porous natural crystal such as medical stone is dirty Thing, inorganic contaminants are virtually all cleaned, and expose fresh active surface, enhance layer silicate mineral structure The distribution of charges at elementary layer edge.The superposition of three Chemical cleaning, hydrogel and high-temperature plasma beam factors, causes duct to be tied The change of structure, the ratio increase shared by through hole, the increase of micropore quantity, the volume in duct and its specific surface area are significantly lifted, Layer silicate mineral construction unit layer fringe field is significantly strengthened.This is due to that aqueous slkali has dissolved and adhered on part surface Non-skeleton constituent impurity, porous duct is dredged, in addition the scan process of high-temperature plasma beam and the modification material of application Material --- Ludox, waterglass or silanes are attached to the surface of the porous natural crystals such as macropore inside or medical stone, right The lifting of ratio, pore ratio shared by the structure in duct, through hole, the decline of macropore ratio generate central role, while Improve its dielectric constant, the uniformity and stability of adsorptivity.
4th, the special modification of clinoptilolite, to lift its removing waterborne radioactivity ion energy, in order to remove Impurity in clinoptilolite, increase its porosity, improve its adsorptivity, more crucially to lift it and remove waterborne radioactivity Ion ability (because most of natural crystal all containing isotopic ion, in usual underground water also containing radioactivity from Son), so as to preferably apply HTHP water installations, flowing wetting system and kettle, insulating pot, boiler, electric water boiler, In the commercial devices such as electric heater, the present invention has carried out modification to clinoptilolite.
Clinoptilolite is sieved with 3.5~5mm mesh screens first, and 3h is boiled in the hydrochloric acid that concentration is 20%, To remove carbonate.Then 8h is dried at a temperature of 300 DEG C, then utilizes the high-temperature plasma of 1.0~2kw power outputs Body beam rifle, clinoptilolite particle surface is irradiated, its translational speed is 250~720cm/min, and beamwidth is 0.4~0.6cm, rotating disk Velocity of rotation be 20~500 turns/min, be finally naturally cooling to room temperature again in atmosphere.
So that the impurity in clinoptilolite is removed, turn into modified clinoptilolite.The increase of its porosity, improves suction Attached property, improve its cation exchange capacity (CEC) and remove the ability and heat-resisting ability of waterborne radioactivity ion.Utilize capillary Tubing string test method(s) understand, modified clinoptilolite for137The Cs other alkali metal groups of selectivity ratios and alkaline-earth metal race element sun from It is sub notable, it is right90Sr also has very strong adsorption function.
5th, example of the invention
The experiment of bar bag and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation and its activation, mineralising, good antiscale property effect are such as Under：
Tested using two same insulating pots：Two insulating pots are same models, same experimental condition, same Test frequency：Scheduled to last using 1 year, burn 3-8 kettle boiling water daily.Both differences are as follows：
The ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation of the present invention is inserted in one insulating pot.
Another is simply placed in the water with its equivalent.Both water quality is identical, be all hardness be 7~10.5GPG deep-well it is hard Water.But but there occurs two kinds of completely different phenomenons after 1 year：
1) do not insert in the insulating pot of ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation and be covered with incrustation scale, especially in kettle Bottom near, scale forming is up to 2mm~4mm.
2) insulating pot of built-in ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation is without any incrustation scale, in insulating pot Portion remains in that original stainless steel gloss.
3) Non-scale is exactly the activation mineralization performance of water, is safe and healthy, energy-saving and environmental protection performances.The electric water of Non-scale The service life of kettle can also extend 2~3 and accompany.
4) the processing water in the insulating pot of built-in ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation for137Cs selection Property is more notable than other alkali metal groups and alkaline-earth metal race thanide cation, right90Sr also has very strong adsorption function.
Because incrustation scale formed after with day increase, thick incrustation scale cause it is heat-insulated, therefore have to allow heater overtime work or Improve heater operating current.In the course of time, heater and connected cable, binding post can all accelerate because of overheat Aging, finally damage.
Pipe explosion accident so not only occurs to one hundred times of number in the small decades of times of thermal conductivity ratio steel of incrustation scale.Per 1mm incrustation scales The just fuel of more consumption 5%；12% fuel is just consumed as incrustation scale 4mm more；Just more consumption 30% as incrustation scale 7mm.Every year Because incrustation scale problem wastes substantial amounts of coal or other energy.Another problem is safety problem：When boiler tube inwall give birth to scaling, just Directly result in pipe inner section product to reduce, steam resistance increase, the normal water circulation for destroying boiler causes heated metal wall temperature liter High is blocked when pipeline by incrustation scale, and water circulation stops local boiler tube and partial vaporization generation burning or booster are produced because of pipe temperature rise Accident.
Ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation of the present invention, it can be used for various heated to water and heat exchange and water cooling But utensil plays health, safety, energy-saving and environmental protection effect with being used in equipment.
6th, The effect of invention
Show through relevant department's detection, to the organic matter overall average clearance in running water up to 98.2%, to alkane, The dirt clearance effect such as aromatic hydrocarbon, heterocycle is up to more than 99%, and poisonous, harmful, carcinogen, anion synthesis in water are washed Wash agent, sulfate, chloride, arsenic, mercury, cadmium, chromium (6 valency), lead, silver, nitrate, chloroform, carbon tetrachloride, DDT, BHC, The clearances such as thin mattress are up to more than 98%.For137The Cs other alkali metal groups of selectivity ratios and alkaline-earth metal race thanide cation shows Write, it is right90Sr also has very strong adsorption function, and water quality also becomes sweet.Especially it is worth what is pointed out, as shown in table 3, using the present invention Dissolution water in ' the sea-gull good fortune stone insulating pot ' of ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation, its potassium concentration are much larger than Na ion concentration.Therefore, quite suitable many people, especially middle old man, hyperpietic are drunk (it is known that sodium ion carries The effect of high human blood-pressure, and potassium ion plays the role of to reduce human blood-pressure).In addition from table 3 it is also seen that.Ball of the present invention The speed of pouch-type sea-gull good fortune stone activation mineralization antiscale preparation dissolution is much better than common medical stone mineral inorganic agent.
Water quality index of the table 3 after the processing of ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation
The working mechanism of bar bag and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation and common antiscale preparation are completely not Together, will not saturation, it is also nontoxic, and service life is very long, and can sterilize, sterilize.Therefore, the work of such a non-scaling is drunk Change, mineralized water, the activation of cell can be promoted, improve immunity, quite suitable many people, especially the elderly, hypertension are suffered from Person drinks.It is heated with being used in the utensil and equipment of heat exchange and water cooling available for various to water, plays health, safety, section Energy, environmental-protection function, change the quality that the mankind boil water, and the bar bag and ball pouch-type sea-gull good fortune stone activation mineralization by the present invention are prevented Contain several mineral materials, trace element, macroelement and the metasilicic acid beneficial to human body in the water of dirty preparation processing, people can be improved Body immunity, quite it is adapted to most crowds to drink.
Especially it is emphasized that, it can improve remove come from underground water (drinking water or industrial water) in radiation Property ion energy, for137Cs and90Sr has preferable reduction ability, quite there is novelty.
Brief description of the drawings
The bar shaped or spherical porous gold that Fig. 1 is worked out using a diameter of ￠ 0.10mm~0.30mm 316L type stainless steels monofilament Belong to mesh bag structural representation.
Fig. 2 is applied to kettle, insulating pot, boiler, electric water boiler, the ball pouch-type sea-gull good fortune stone activation mineralization of electric heater The mounting structure schematic diagram of antiscale preparation.
Fig. 3 is applied to the mounting structure signal of the bar pouch-type sea-gull good fortune stone activation mineralization antiscale preparation of solar water heater Figure.
Fig. 4 is applied to the mounting structure signal of the bar pouch-type sea-gull good fortune stone activation mineralization antiscale preparation of vertical steam boiler Figure.
Fig. 5 is applied to the bar pouch-type sea-gull good fortune stone activation ore deposit of economizer, evaporator, superheater, down-comer, saturated steam pipe The mounting structure schematic diagram of chemoprevention dirt preparation.Wherein,
Fig. 5 (A) is applied to bar pouch-type sea in the water cooling tube of economizer, evaporator, superheater, down-comer, saturated steam pipe The mounting structure schematic diagram of gull good fortune stone activation mineralization antiscale preparation.
Fig. 5 (B) is applied to the bar pouch-type sea-gull in economizer, evaporator, superheater, down-comer, saturated steam pipe drum The mounting structure schematic diagram of good fortune stone activation mineralization antiscale preparation.
Embodiment
By following examples, the present invention is described further, but present disclosure is not limited thereto.
Embodiment 1
As depicted in figs. 1 and 2, first by a diameter of ￠ 0.20mm 316L types stainless steel flat wire and circle wire material with monofilament Form establishment monofilament is compiled into spherical porous metal mesh bag 1, and its diameter dimension can be worked out by adding pin, subtracting the skill of handling needles, still A breach is left in certain of spherical porous metal mesh bag 1, and takes progressive contraction mode to continue to work out here, but still So retain an opening 3, wouldn't seal.Then the particle of sea-gull good fortune stone 4 is loaded from the breach 3 to its inside.The particle of sea-gull good fortune stone 4 Granularity be ￠ 3.5~￠ 4.5mm, after filling, then the spot welding of opening 3 secured, so as to constitute spherical sea-gull good fortune stone activation ore deposit Chemoprevention dirt preparation 10.In embodiment 1, the diameter of spherical porous metal mesh bag is less than or equal to ￠ 35mm, spherical porous metal The diameter of the mesh 2 of mesh bag 1 is necessarily less than ￠ 3.5, more preferably less than ￠ 2.5mm.
In order to prevent spherical sea-gull good fortune stone activation antiscale mineralising preparation 10 from sliding and colliding in insulating pot, the interior of kettle is scratched Surface, spherical sea-gull good fortune stone can be activated antiscale mineralising preparation 10 and be assemblied in four hole card holders 5, form an assembly 6, so Assembly 6 is placed in again afterwards the bottom of the insulating pot.
Described sea-gull good fortune stone 4 is to utilize to shine natural crystal, monocrystalline and polycrystalline material particle cleaning, high-temperature plasma Penetrate, medium radio-frequency sputtering, heat treatment modified technique prepare scale preventative component.
The sea-gull good fortune stone activation antiscale mineralising preparation 10 of embodiment 1 by modified verdelite, Sibin floating stone, modified medical stone, Modified clinoptilolite, germanium ore, rutile ore, graphite silica component are formed.By weight, the ratio of each component during it is formulated It is as follows：Modified verdelite is 30%, Sibin floating stone 10%, modified medical stone are 25%, modified clinoptilolite 4%, golden red Stone ore stone is 8%, graphite silica is 10%, germanium ore is 13%.
The tourmaline of raw material, Sibin floating stone, medical stone, clinoptilolite, germanium ore, rutile ore, graphite silica, The materials such as 316L stainless steel wires must carry out water under high pressure immersion, stirring respectively, (pressure is 1.0~1.8MPa, temperature 20 for cleaning ~40 DEG C, time 8h), after drying, then after the pretreatment such as high temperature and high pressure steam processing, then carry out respectively at high-temperature plasma Reason, radio-frequency sputtering, remove impurity.
Described germanium ore, rutile ore, the handling process of graphite silica according to " high temperature of non-porous component etc. from The method introduced in the reinforcing of daughter surface relief and mechanical strength consolidation process " is carried out.
The preparation of modified verdelite is according to " lifting of the insulativity in water between the positive and negative electrode of operating electrical stone and changing Property facture " in introduce method carry out.
The preparation of modified medical stone is according to " enrichment of porous natural crystal --- medical stone is strengthened, at modified, optimization The method introduced in reason " is carried out.
The preparation of modified clinoptilolite is carried out according to the method introduced in " modification of clinoptilolite ".
Embodiment 2
As shown in figures 1 and 3, that a diameter of ￠ 0.30mm 316L type stainless steel monofilament is compiled into bar pouch-type first is porous Metal mesh bag 1, its bottom imperforation, and upper end is the structure of the open-type of progressive closing in；Its appearance and size can be according to the sun Can water-heater system installation it needs to be determined that.In the present embodiment, the sea-gull good fortune stone in the supervisor of solar water heater 9 The length for activating antiscale mineralising preparation 10 is equal to the width dimensions of solar water heater 9, and sea-gull good fortune stone activates antiscale mineralising system The diameter in the cross section of agent 10 is equal to ￠ 35mm or so.
The length dimension for the sea-gull good fortune stone activation antiscale mineralising preparation 10 being placed in thermal-collecting tube 8 should be equal to solar water heater The 60% of thermal-arrest length of tube.The area in the cross section of bar shaped sea-gull good fortune stone activation antiscale mineralising preparation 10 is equal to solar water The 15%~20% of the area in the cross section of device thermal-collecting tube, about ￠ 15mm.
Bar shaped porous metals mesh bag 1 is 316L types stainless steel flat wire and circle wire material using ￠ 0.30mm in the form of monofilament Establishment.The diameter dimension of bar shaped porous metals mesh bag 1 can be worked out by adding pin, subtracting the skill of handling needles, although its upper end is taken gradually Enter contraction mode to work out, can be still necessary to retain opening 3, to load the particle of sea-gull good fortune stone 4 from opening 3.4, sea-gull good fortune stone The granularity of grain is 3.5~￠ of ￠ 4.5mm.A diameter of ￠ 2.0mm~￠ 2.5mm of the mesh 2 of bar shaped porous metals mesh bag 1, bar The length of shape porous metals mesh bag 1 can be 1m~number 100m cylinder or flat cylindricality, and its cross-sectional diameter is ￠ 35mm。
After the particle of sea-gull good fortune stone 4 is loaded its inside from the opening 3 of upper end, recycle dot welding method that opening 3 is welded envelope Jail, constitute bar shaped sea-gull good fortune stone activation antiscale mineralising preparation 10.
It is the tourmaline of the described raw material of sea-gull good fortune stone 4, Sibin floating stone, medical stone, clinoptilolite, rutile ore, profound The materials such as Wu Yan, Kweiyang stone, polycrystal barium titanate, 316L stainless steel wires must carry out water under high pressure immersion, stirring, cleaning respectively After (pressure is 1.0~1.8MPa, and temperature is 20~40 DEG C, time 8h), drying, then the pretreatment such as high temperature and high pressure steam processing Afterwards, then respectively high-temperature plasma processing, radio-frequency sputtering are carried out, removes impurity.
Described sea-gull good fortune stone 4 is to use to shine natural crystal, monocrystalline and polycrystalline material particle cleaning, high-temperature plasma Penetrate, the component for the scale preventative prepared by technique such as medium radio-frequency sputtering, heat treatment are modified.
The sea-gull good fortune stone activation antiscale mineralising preparation 10 of embodiment 2 by modified verdelite, Sibin floating stone, modified medical stone, Modified clinoptilolite, rutile ore, basalt, Kweiyang stone, polycrystal barium titanate component are formed.By weight, in its formula The ratio of each component is as follows：Modified verdelite is 25%, Sibin floating stone 4%, modified medical stone are 25%, modified clinoptilolite For 7%, rutile ore 9%, basalt 10%, Kweiyang stone be 11%, polycrystal barium titanate be 9%.
The processing of described rutile ore, Kweiyang stone, basalt, polycrystal barium titanate is according to " non-porous component The method introduced in the reinforcing of high-temperature plasma surface relief and mechanical strength consolidation process " is carried out.
The preparation of modified verdelite is according to " lifting of the insulativity in water between the positive and negative electrode of operating electrical stone and changing Property facture " in introduce method carry out.
The preparation of modified medical stone is according to " enrichment of porous natural crystal --- medical stone is strengthened, at modified, optimization The method introduced in reason " is carried out.
The preparation of modified clinoptilolite is carried out according to the method introduced in " modification of clinoptilolite ".
Embodiment 3
Preparing for bar pouch-shaped sea-gull good fortune stone activation antiscale mineralising preparation is same as Example 2, referring to Fig. 1.As shown in figure 4, Appearance and size for the every bar pouch-shaped sea-gull good fortune stone activation antiscale mineralising preparation 10 in vertical boiler 12 is ￠ 45mmx2000mm or so, its cross-sectional area should be equal to 20% left side of the cross-sectional area of economizer tube, superheater tube or elbow It is right.9 represent the bar pouch-shaped sea-gull good fortune stone activation antiscale mineralising preparation of the economizer tube in vertical boiler 12.4 be sea-gull good fortune stone Antiscale mineralising formulation components particle is activated, 11 represent the bar pouch-shaped sea-gull good fortune stone activation antiscale mineralising of vertical boiler heater tube Preparation..
It is the tourmaline of the described raw material of sea-gull good fortune stone 4, Sibin floating stone, medical stone, clinoptilolite, rutile ore, expensive Positive stone, polycrystal barium titanate, black day must be carried out respectively according to materials such as stone, ferroelectric single crystal niobic acid Lithium, 316L stainless steel wires After water under high pressure immersion, stirring, cleaning (pressure is 1.0~1.8MPa, and temperature is 20~40 DEG C, time 8h), drying, then high temperature After the pretreatment such as high steam processs, then high-temperature plasma processing, radio-frequency sputtering are carried out respectively, remove impurity.
Described sea-gull good fortune stone activation antiscale mineralising preparation granules are a kind of to natural crystal, monocrystalline and polycrystalline material Grain cleaned, high-temperature plasma scanning, medium radio-frequency sputtering, heat treatment preparation scale preventing and removing agent component.Sea-gull good fortune stone 4 The granularity of particle is 3.5~￠ of ￠ 4.5mm.
The bar pouch-shaped sea-gull good fortune stone activation antiscale mineralising preparation of embodiment 3 is by modified verdelite, Sibin floating stone, modified wheat meal Stone, modified clinoptilolite, rutile ore, Kweiyang stone, black day are formed according to stone, ferroelectric single crystal niobic acid Lithium components.By weight Meter, the ratio of each component is as follows during it is formulated：Modified verdelite is 25%, Sibin floating stone 3%, modified medical stone are 25%, Modified clinoptilolite is 4%, rutile ore 10%, Kweiyang stone are 12%, black day according to stone is 11%, ferroelectric single crystal niobium Sour Lithium is 10%.
Described rutile ore, Kweiyang stone, black day according to stone, ferroelectric single crystal niobic acid Lithium processing according to " non-multi The method introduced in the high-temperature plasma surface relief reinforcing of hole component and mechanical strength consolidation process " is carried out.
The preparation of modified verdelite is according to " lifting of the insulativity in water between the positive and negative electrode of operating electrical stone and changing Property facture " in introduce method carry out.
The preparation of modified medical stone is according to " enrichment of porous natural crystal --- medical stone is strengthened, at modified, optimization The method introduced in reason " is carried out.
The preparation of modified clinoptilolite is carried out according to the method introduced in " modification of clinoptilolite ".
Embodiment 4
Preparing for the bar shaped sea-gull good fortune stone activation antiscale mineralising preparation of embodiment 4 is same as Example 2, as shown in Figure 1.Only Its appearance and size is different, and the appearance and size of every is ￠ 15mmx300mm.As shown in Fig. 5 (A) and Fig. 5 (B), it is placed in water cooling tube Or the bar shaped sea-gull good fortune stone activation antiscale mineralising preparation 10 in superheater tube, its cross-sectional area should be respectively equal to water cooling tube or overheat The 10%~15% of pipe cross-sectional area.When being placed in water cooling tube or superheater tube, dot welding method can be used, per 1 welding of 300mm Point, bar shaped sea-gull good fortune stone activation antiscale mineralising preparation 10 is fixed on the inside of pipe 12.Bar shaped sea-gull good fortune stone activates antiscale mineralising The usage quantity of preparation 10 depends on the length of water cooling tube or superheater tube.In Fig. 5 (A) and Fig. 5 (B), 12 represent economizer, steam Device, superheater, down-comer, the water cooling tube of saturated steam pipe are sent out, 15 represent economizer, evaporator, superheater, down-comer, saturation The drum of steam pipe.
Preparing for the bar shaped sea-gull good fortune stone activation antiscale mineralising preparation 10 of embodiment 4 is same as Example 2.It is the difference is that real The sea-gull good fortune stone activation antiscale mineralising preparation 10 of example 4 is applied by modified verdelite, Sibin floating stone, modified medical stone, modified tiltedly hair boiling Stone, rutile ore, serpentine, hornblend, polycrystal barium titanate, ferroelectric single crystal niobic acid Lithium components are formed.By weight, its The ratio of each component is as follows in formula：Modified verdelite is 28%, Sibin floating stone 2%, modified medical stone are 25%, modified oblique Ptilolite is 4%, rutile ore 8%, serpentine 8%, hornblend 10%, polycrystal barium titanate are 8%, ferroelectricity list Crystal niobic acid Lithium is 7%.
Described rutile ore, serpentine, hornblend, the processing of polycrystal barium titanate, ferroelectric single crystal niobic acid Lithium presses The method introduced in " the high-temperature plasma surface relief of non-porous component strengthens and mechanical strength consolidation process " is impinged upon to carry out.
The preparation of modified verdelite is according to " lifting of the insulativity in water between the positive and negative electrode of operating electrical stone and changing Property facture " in introduce method carry out.
The preparation of modified medical stone is according to " enrichment of porous natural crystal --- medical stone is strengthened, at modified, optimization The method introduced in reason " is carried out.
The preparation of modified clinoptilolite is carried out according to the method introduced in " modification of clinoptilolite ".

Claims (7)

1. a kind of bar bag and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation and its preparation and application, it includes three Entries key skills Art：Design, bar bag and the ball pouch-type sea-gull good fortune stone activation ore deposit of bar bag and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation (10) The preparation technology and bar bag of chemoprevention dirt preparation (10) and the application process of ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation (10), It is characterized in that：
Bar bag and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation (10) be by diameter 0.10mm~0.30mm 316L types not The bar shaped of rust steel monofilament establishment or spherical porous metal mesh bag (1), the component for being seated in its internal scale preventing and removing agent --- sea The sealing (3) of gull good fortune stone (4) particle and spot-welded is formed；
The bar shaped of described stainless steel monofilament establishment or spherical porous metal mesh bag (1) use bottom imperforation, and upper end is progressive The open-type structure type of closing in；Bar shaped or spherical porous metal mesh bag (1) are the 316L types using ￠ 0.10mm~0.30mm Stainless steel flat wire is worked out with circle wire material in the form of monofilament, and the diameter dimension of bar shaped or spherical porous metal mesh bag (1) can lead to Cross plus pin, subtract the skill of handling needles and work out；Although its upper end takes progressive contraction mode to work out, but it is still necessary to retain opening (3), To load sea-gull good fortune stone (4) particle from opening (3)；A diameter of ￠ of the mesh (2) of bar shaped or spherical porous metal mesh bag (1) 2.5mm~3mm, the length of bar shaped porous metals mesh bag 1 can be 1m~number 100m cylinder or flat cylindricality, it cross-section The rectangle that face diameter is usually 10~￠ of ￠ 45mm circle or cross section is 10mm x 35mm；And spherical porous metal net The diameter of bag should be less than or equal to ￠ 35mm；
Described bar bag and the preparation technology of ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation are：
From opening (3) load be diameter dimension ＞ ￠ 3.5 sea-gull good fortune stone (4) particle；Sea-gull good fortune stone (4) particle is to utilize thing Logos --- water under high pressure immersion, stirring, cleaning and drying pretreatment, high-temperature plasma scan process, medium radio-frequency sputtering, heat are old Change handling process its surface is modified and nursed one's health and its internal structure and characteristic is modified, optimized and strengthened be natural Ore, monocrystal and polycrystal component, i.e., using by modified and processing natural crystal, monocrystal and polycrystal component, example Such as：Modified verdelite, modified medical stone, modified clinoptilolite；
First to sea-gull good fortune stone (4) particulate material --- tourmaline, Sibin floating stone, clinoptilolite, graphite silica, serpentine, wheat Meal stone, germanium ore, rutile ore, black day are according to stone, basalt, hornblend, Kweiyang stone, ferroelectric single crystal niobic acid Lithium, metatitanic acid Barium polycrystal and 316L stainless steel wires should carry out the pretreatment of water under high pressure immersion, stirring, cleaning and drying respectively；In addition, root According to the different classes of of the grain fraction of sea-gull good fortune stone 4, corresponding specially treated technique is taken respectively：
For non-porous natural crystal, monocrystal and polycrystal component must use high-temperature plasma surface relief strengthen and Mechanical strength consolidation process technique and lifted using high-temperature plasma heating its component far infrared radiation rate processing Technique；
And for porous natural crystal component must be used to be enriched with, strengthen, modified, optimization processing technique；Wherein, for porous day The clinoptilolite of right ore must carry out special modification process；The after-treatment technique that must be carried out for tourmaline： A) concentration --- low-grade ore is changed into high-grade ore；B) increase the insulativity between tourmaline positive and negative electrode, especially to be lifted The handling process of insulativity when tourmaline works in water；
Described bar bag and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation (10) can apply insulating pot, electric water boiler, The thermal-collecting tube of electric heater solar water heater, the economizer of vertical boiler, evaporator, superheater, down-comer, saturated steam pipe Water cooling tube in or saturated steam pipe drum in；
The application process of bar bag and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation is：
Bar bag and ball pouch-type sea-gull good fortune stone are activated antiscale mineralising preparation (10) using lay-up method and are installed in heating or chilling unit Heat exchanger in, or use welding or be suspended on the fixation of a welding column with every some bar bag of 300mm distance The metal mesh bag (1) of type sea-gull good fortune stone activation antiscale mineralising preparation (10) be fixed on heat exchanger inwall or water cooling tube, elbow or In side wall in superheater tube；The processing length of sea-gull good fortune stone activation antiscale mineralising preparation (10) depends on water cooling tube, economizer Pipe, drum, steam-water separator, heat exchanger, superheater tube, steam-water separator, heat exchanger, the effective of superheater tube use length, Usually 1m~number 100m；The cross-sectional area of bar shaped sea-gull good fortune stone activation antiscale mineralising preparation (10) should be equal to water cooling tube, save Coal device pipe, drum, steam-water separator, heat exchanger, superheater tube or elbow cross-sectional area 15%~20%, its diameter is usual For 10~￠ of ￠ 45mm；
Bar bag and ball pouch-type sea-gull good fortune stone activation antiscale mineralising preparation (10) are in kettle, insulating pot, boiler, electric water boiler, electricity The preferred structure applied in water heater is that ball pouch-type sea-gull good fortune stone activation antiscale mineralising preparation (10) is assemblied in four hole card holders (5) In, spherical sea-gull good fortune stone activation antiscale mineralising preparation assembly (6) is constituted, the assembly (6) is then placed in the electricity again The bottom of kettle etc device；
Natural crystal, monocrystal and the polycrystal component of described sea-gull good fortune stone activation antiscale mineralising preparation (10) be：Modified electricity Gas stone, Sibin floating stone, modified clinoptilolite, graphite silica, modified medical stone, rutile ore, basalt, germanium ore, snake Stone, Kweiyang stone, hornblend, black day are formed according to stone, polycrystal barium titanate, ferroelectric single crystal niobic acid Lithium components；By weight, its The ratio of each component is as follows in formula：Modified verdelite is 10~30%, Sibin floating stone is 2~10%, modified medical stone be 2~ 30%th, rutile ore is 2~10%, modified clinoptilolite is 0.3~8%, graphite silica is 1~15%, germanium ore be 1~ 10%th, basalt be 1~10%, black day according to stone be 1~15%.Serpentine 1~10%, hornblend 1~15%, Kweiyang stone 1 ~15%, polycrystal barium titanate 2~15%, ferroelectric single crystal niobic acid Lithium 1~18%.
2. bar bag according to claim 1 and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation and its preparation and application, It is characterized in that：
To sea-gull good fortune stone (4) particulate material --- tourmaline, Sibin floating stone, clinoptilolite, graphite silica, serpentine, medical stone, Germanium ore, rutile ore, black day are according to stone, basalt, hornblend, Kweiyang stone, ferroelectric single crystal niobic acid Lithium, barium titanate polycrystalline Body, 316L stainless steel wires carry out the pretreatment of water under high pressure immersion, stirring, cleaning and drying respectively；Its processing step is as follows：
Step 1: being 1.0~1.8MPa in pressure, temperature is 20~40 DEG C, the time be 8h under the conditions of carry out water under high pressure immersion, stir Mix, clean,
Step 2: being 90~110kPa in pressure, temperature is 80~120 DEG C, the time be 12h under the conditions of dried,
Step 3: through Step 1: step 2 pretreatment after, then respectively to non-porous component, tourmaline, porous natural crystal carry out High-temperature plasma heats and the processing of lifting far infrared radiation rate, medium radio-frequency sputtering processing, porous natural crystal (such as wheat Meal stone) enrichment, reinforcing, modification, optimization processing.
3. bar bag according to claim 1 and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation and its preparation and application, It is characterized in that：
To the graphite silica of non-porous component, serpentine, germanium ore, rutile ore, black day according to stone, basalt, hornblend, The surface relief that Kweiyang stone component carries out high-temperature plasma is strengthened and mechanical strength consolidation process and lifts its Far-infrared spoke The step of penetrating rate processing is as follows：
Step 1: pending component particles are laid in machine carousel,
Step 2: with the high-temperature plasma beam rifles of 1.0~2kw power outputs and cold air rifle to the particle that is laid in machine carousel Surface is irradiated respectively, and their beamwidth is all 0.4~0.6cm, the spacing between high-temperature plasma beam and cold air rifle beam be 500~ 950mm, its translational speed are 250~720cm/min, and the velocity of rotation of rotating disk is 20~500 turns/min,
Step 3: handled using the synchronous reciprocating scan mode of high-temperature plasma beam rifle and cold air rifle,
Step 4: particle surface temperature is detected and controlled using the cooperation of pyroelectric infrared sensor and high-temperature plasma beam generator Degree is maintained in the range of 550 ° ± 15 DEG C, and monitors particle surface pattern state using high-resolution video monitor simultaneously,
Step 4: after reaching fixed code requirement, then the temperature of processed component particles is dropped to room temperature in atmosphere.
4. bar bag according to claim 1 and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation and its preparation and application, It is characterized in that：
The concentration of tourmaline --- the step for low-grade ore being changed into the processing method of high-grade ore is as follows：
Step 1: one layer of paste being made up of silicic acid-boric acid-Aluminum-zinc-potash glass powder and ethanol is coated on tourmaline particle surface Shape mixture,
Step 2: they are laid on rotating disk, the velocity of rotation of rotating disk is 20~500 turns/min,
Step 3: when in pasty mixture ethanol volatilize at room temperature 1h after, with the high-temperature plasma of 1.0~2kw power outputs Beam rifle irradiates the surface of tourmaline particle,
Step 4: monitor tourmaline particle and the surface temperature of silicic acid-boric acid-Aluminum-zinc-potash glass powder with infrared thermometer Degree, and high-temperature plasma beam rifle power output is adjusted, its temperature is no more than 700 DEG C,
Step 5: after 30min, stop high-temperature plasma irradiation, it is progressively dropped to room temperature.
5. bar bag according to claim 1 and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation and its preparation and application, It is characterized in that：
Increase the insulativity between tourmaline positive and negative electrode, the method for being particularly lifted at insulativity when being worked in water is as follows：
Attached method or radio frequency sputtering method are blown to one layer of softening of tourmaline ore particles surface spraying or sputtering, molten using high-temperature plasma Change point as less than 850 DEG C of alumina silicate glass or soda-lime glass layer, its thickness is about 0.5~5 μm, and preferable scheme is spraying Or sputter alkali-free aluminosilicate glass or use double glazing insulating barrier method；
Described alkali-free aluminosilicate glass is made up of RO-Al203-SiO2, and wherein RO represents magnesia, calcium oxide, barium monoxide, oxidation The bivalent metal oxides such as zinc；
Described double glazing insulating barrier method or to make secondary glass isolation overcoat method as follows：Sprayed first on tourmaline particle surface Apply or alkali-free aluminosilicate glass that one layer of softening point of sputtering is less than 850 DEG C, its thickness be not more than 2 μm, then sputter again one layer it is soft It is low to change point --- less than 650 DEG C of soda-lime glass insulating barrier, its thickness are about 0.5~2 μm.
6. bar bag according to claim 1 and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation and its preparation and application, It is characterized in that：
It is as follows for porous natural crystal, such as medical stone, its enrichment, reinforcing, modification, optimized treatment method：
Step 1: medical stone is mixed with 0.5~5mol/L sodium hydroxide or the aqueous slkali of potassium hydroxide, described aqueous slkali (volume unit is mL) and the ratio of medical stone (unit of weight is g) are 5；1~20；1；
Or medical stone is mixed with hydrogel；The preparation method of hydrogel is as follows：Ludox, waterglass or silanes, Mixed according to given ratio with described aqueous slkali, then hydrogel can be made；
Described hydrogel is to be made up of Ludox, waterglass (or silanes) with aqueous slkali, three kinds of groups of hydrogel Point --- Ludox, the mol ratio of waterglass (or silanes) and aqueous slkali are as follows：
Silica: alundum (Al2O3): sodium oxide molybdena: water=(3~1): 1: (2~7): (300~120)；
Prepare hydrogel techniques condition：Temperature is 50~80 DEG C, and the reaction time is 8~24h；
Step 2: being crystallized at 80~95 DEG C, crystallization time is 12~24h；After crystallization, successively using separation, washing And baking operation, so as to obtain preliminary modification, optimization processing medical stone granule,
Heated Step 3: the medical stone granule of preliminary modification, optimization processing is placed in Muffle furnace or other heaters To 450~600 DEG C, 4h is incubated, then is naturally cooling to room temperature,
Step 4: be cooled to the preliminary modification of room temperature, the medical stone granule of optimization processing is laid in rotating disk again, utilize 1.0 The high-temperature plasma beam rifle of~2kw power outputs, irradiation medical stone granule surface, its translational speed is 250~720cm/ Min, beamwidth are 0.4~0.6cm, and the velocity of rotation of rotating disk is 20~500 turns/min,
Step 5: being naturally cooling to room temperature, after 3h, then enriched, reinforcing, the modified, medical stone of optimization processing are obtained, turns into and changes The medical stone of property.
7. bar bag according to claim 1 and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation and its preparation and application, It is characterized in that：
The special modification processing method of clinoptilolite concretely comprises the following steps：
Step 1: clinoptilolite particle is sieved with 3.5~5mm mesh screens,
Step 2: 3h is boiled in the hydrochloric acid that concentration is 20%,
Step 3: 8h is dried at a temperature of 300 DEG C,
Step 4: using the high-temperature plasma beam rifle of 1.0~2kw power outputs, the surface of clinoptilolite particle is irradiated, it is moved Dynamic speed is 250~720cm/min, and beamwidth is 0.4~0.6cm, and the velocity of rotation of rotating disk is 20~500 turns/min,
Step 5: room temperature is naturally cooling in atmosphere.
CN201710604065.0A 2017-07-17 2017-07-17 Bar bag and ball pouch-type sea-gull good fortune stone activation mineralization antiscale preparation and its preparation and application Pending CN107344762A (en)

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CN110294537A (en) * 2019-06-03 2019-10-01 常州大学 Scaling prevention device
CN114380398A (en) * 2021-12-29 2022-04-22 同济大学 Cathode regulation and control method for electrochemical scale inhibition technology
CN114477872A (en) * 2022-02-11 2022-05-13 广东奥林格电器有限公司 Spray coating containing medical stone for inner container of kettle and preparation method thereof

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