CN101466659B - 乙酸和乙酸与乙酸酐的混合物的制造 - Google Patents
乙酸和乙酸与乙酸酐的混合物的制造 Download PDFInfo
- Publication number
- CN101466659B CN101466659B CN200780021487.XA CN200780021487A CN101466659B CN 101466659 B CN101466659 B CN 101466659B CN 200780021487 A CN200780021487 A CN 200780021487A CN 101466659 B CN101466659 B CN 101466659B
- Authority
- CN
- China
- Prior art keywords
- acetic acid
- product
- diacetyl oxide
- liquid
- vaporizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title claims abstract description 356
- WFDIJRYMOXRFFG-UHFFFAOYSA-N acetic acid anhydride Natural products CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 title claims abstract description 161
- 239000000203 mixture Substances 0.000 title claims abstract description 61
- 238000004519 manufacturing process Methods 0.000 title abstract description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 148
- 230000006315 carbonylation Effects 0.000 claims abstract description 78
- 238000005810 carbonylation reaction Methods 0.000 claims abstract description 78
- 239000003054 catalyst Substances 0.000 claims abstract description 53
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 claims abstract description 49
- 238000001704 evaporation Methods 0.000 claims abstract description 44
- 238000000034 method Methods 0.000 claims abstract description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 39
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims abstract description 34
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims abstract description 32
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 24
- 239000007791 liquid phase Substances 0.000 claims abstract description 4
- 239000007788 liquid Substances 0.000 claims description 95
- 239000006200 vaporizer Substances 0.000 claims description 72
- 238000006243 chemical reaction Methods 0.000 claims description 46
- 239000007858 starting material Substances 0.000 claims description 39
- 150000001875 compounds Chemical class 0.000 claims description 13
- 239000011541 reaction mixture Substances 0.000 claims description 13
- 238000007670 refining Methods 0.000 claims description 7
- 239000010948 rhodium Substances 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- 229910052703 rhodium Inorganic materials 0.000 claims description 5
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 4
- 229910052741 iridium Inorganic materials 0.000 claims description 3
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims 2
- 230000008020 evaporation Effects 0.000 abstract description 4
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 abstract 2
- 239000000047 product Substances 0.000 description 51
- 230000008016 vaporization Effects 0.000 description 15
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 14
- 239000000463 material Substances 0.000 description 14
- 238000009834 vaporization Methods 0.000 description 13
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Natural products OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 12
- HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Chemical compound [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 description 8
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 7
- 239000006227 byproduct Substances 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 235000006408 oxalic acid Nutrition 0.000 description 6
- 239000012043 crude product Substances 0.000 description 5
- 230000006837 decompression Effects 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 238000011084 recovery Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- LEKJTGQWLAUGQA-UHFFFAOYSA-N acetyl iodide Chemical compound CC(I)=O LEKJTGQWLAUGQA-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- -1 alkali metal salt Chemical class 0.000 description 3
- 229940107816 ammonium iodide Drugs 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 3
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 3
- 229910000765 intermetallic Inorganic materials 0.000 description 3
- ICIWUVCWSCSTAQ-UHFFFAOYSA-M iodate Chemical compound [O-]I(=O)=O ICIWUVCWSCSTAQ-UHFFFAOYSA-M 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- LSMAIBOZUPTNBR-UHFFFAOYSA-N phosphanium;iodide Chemical compound [PH4+].[I-] LSMAIBOZUPTNBR-UHFFFAOYSA-N 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 3
- MCTWTZJPVLRJOU-UHFFFAOYSA-N 1-methyl-1H-imidazole Chemical compound CN1C=CN=C1 MCTWTZJPVLRJOU-UHFFFAOYSA-N 0.000 description 2
- XZXYQEHISUMZAT-UHFFFAOYSA-N 2-[(2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound CC1=CC=C(O)C(CC=2C(=CC=C(C)C=2)O)=C1 XZXYQEHISUMZAT-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 229910004373 HOAc Inorganic materials 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 125000006615 aromatic heterocyclic group Chemical group 0.000 description 2
- 238000007701 flash-distillation Methods 0.000 description 2
- 239000012442 inert solvent Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000012263 liquid product Substances 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 150000002897 organic nitrogen compounds Chemical class 0.000 description 2
- 239000010970 precious metal Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000031068 symbiosis, encompassing mutualism through parasitism Effects 0.000 description 2
- 239000011269 tar Substances 0.000 description 2
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- NHZSOFZGOJWTFQ-UHFFFAOYSA-N CN1C(C=C(C=C1)C)C.I(=O)(=O)O Chemical compound CN1C(C=C(C=C1)C)C.I(=O)(=O)O NHZSOFZGOJWTFQ-UHFFFAOYSA-N 0.000 description 1
- HTLHXAIKYRDABQ-UHFFFAOYSA-N CN1CC(=CC=C1)C.I(=O)(=O)O Chemical compound CN1CC(=CC=C1)C.I(=O)(=O)O HTLHXAIKYRDABQ-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- KJLPWIOVCYTBQS-UHFFFAOYSA-N [NH+]1=CNC=C1.I(=O)(=O)[O-] Chemical class [NH+]1=CNC=C1.I(=O)(=O)[O-] KJLPWIOVCYTBQS-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- NTEVYDVXXMVLIS-UHFFFAOYSA-N butylphosphane;hydroiodide Chemical class [I-].CCCC[PH3+] NTEVYDVXXMVLIS-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 229910001505 inorganic iodide Inorganic materials 0.000 description 1
- 229910001511 metal iodide Inorganic materials 0.000 description 1
- JNMIXMFEVJHFNY-UHFFFAOYSA-M methyl(triphenyl)phosphanium;iodide Chemical compound [I-].C=1C=CC=CC=1[P+](C=1C=CC=CC=1)(C)C1=CC=CC=C1 JNMIXMFEVJHFNY-UHFFFAOYSA-M 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 150000004714 phosphonium salts Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000011027 product recovery Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 150000003284 rhodium compounds Chemical group 0.000 description 1
- KXAHUXSHRWNTOD-UHFFFAOYSA-K rhodium(3+);triiodide Chemical compound [Rh+3].[I-].[I-].[I-] KXAHUXSHRWNTOD-UHFFFAOYSA-K 0.000 description 1
- SONJTKJMTWTJCT-UHFFFAOYSA-K rhodium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Rh+3] SONJTKJMTWTJCT-UHFFFAOYSA-K 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000009518 sodium iodide Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000005207 tetraalkylammonium group Chemical group 0.000 description 1
- 125000005497 tetraalkylphosphonium group Chemical group 0.000 description 1
- DPKBAXPHAYBPRL-UHFFFAOYSA-M tetrabutylazanium;iodide Chemical compound [I-].CCCC[N+](CCCC)(CCCC)CCCC DPKBAXPHAYBPRL-UHFFFAOYSA-M 0.000 description 1
- AEFPPQGZJFTXDR-UHFFFAOYSA-M tetraphenylphosphanium;iodide Chemical compound [I-].C1=CC=CC=C1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 AEFPPQGZJFTXDR-UHFFFAOYSA-M 0.000 description 1
- DXJLCRNXYNRGRA-UHFFFAOYSA-M tributyl(methyl)azanium;iodide Chemical compound [I-].CCCC[N+](C)(CCCC)CCCC DXJLCRNXYNRGRA-UHFFFAOYSA-M 0.000 description 1
- RLZMYANQLOCZOB-UHFFFAOYSA-M tributyl(methyl)phosphanium;iodide Chemical compound [I-].CCCC[P+](C)(CCCC)CCCC RLZMYANQLOCZOB-UHFFFAOYSA-M 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- TUQOTMZNTHZOKS-UHFFFAOYSA-N tributylphosphine Chemical compound CCCCP(CCCC)CCCC TUQOTMZNTHZOKS-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/54—Preparation of carboxylic acid anhydrides
- C07C51/56—Preparation of carboxylic acid anhydrides from organic acids, their salts, their esters or their halides, e.g. by carboxylation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/423,383 | 2006-06-09 | ||
| US11/423,383 US7737298B2 (en) | 2006-06-09 | 2006-06-09 | Production of acetic acid and mixtures of acetic acid and acetic anhydride |
| PCT/US2007/012457 WO2007145795A2 (en) | 2006-06-09 | 2007-05-25 | Production of acetic acid and mixtures of acetic acid and acetic anhydride |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101466659A CN101466659A (zh) | 2009-06-24 |
| CN101466659B true CN101466659B (zh) | 2013-09-25 |
Family
ID=38564364
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200780021487.XA Active CN101466659B (zh) | 2006-06-09 | 2007-05-25 | 乙酸和乙酸与乙酸酐的混合物的制造 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7737298B2 (enExample) |
| EP (1) | EP2029514B1 (enExample) |
| JP (1) | JP5281000B2 (enExample) |
| CN (1) | CN101466659B (enExample) |
| TW (1) | TWI398435B (enExample) |
| WO (1) | WO2007145795A2 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101659607B (zh) * | 2008-08-29 | 2013-04-10 | 上海焦化有限公司 | 制备乙酸、乙酸酐或同时制备乙酸和乙酸酐的方法 |
| US9012683B2 (en) * | 2010-11-12 | 2015-04-21 | Eastman Chemical Company | Coproduction of acetic acid and acetic anhydride |
| US8637699B2 (en) | 2011-04-15 | 2014-01-28 | Lyondell Chemical Technology, L.P. | Process for the manufacture of acetic acid |
| US9415366B2 (en) * | 2012-12-31 | 2016-08-16 | Eastman Chemical Company | Systems and methods for processing variable acetyl streams |
| US10988432B2 (en) * | 2013-03-07 | 2021-04-27 | Ineos Acetyls Uk Limited | Process for the co-production of acetic acid and acetic anhydride |
| US9908835B2 (en) | 2015-11-13 | 2018-03-06 | Celanese International Corporation | Processes for purifying acetic and hydrating anhydride |
| US9907305B2 (en) | 2016-03-22 | 2018-03-06 | Solvay Sa | Production of disinfecting solutions |
| CN114031492B (zh) * | 2021-12-13 | 2023-08-29 | 上海簇睿低碳能源技术有限公司 | 一种采用微通道反应器合成醋酸或醋酐的工艺系统及制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1234641A (enExample) * | 1967-04-05 | 1971-06-09 | ||
| EP0087870A1 (en) * | 1982-02-13 | 1983-09-07 | BP Chemicals Limited | Process for the production of acetic anhydride and acetic acid |
| EP0087869A1 (en) * | 1982-02-13 | 1983-09-07 | BP Chemicals Limited | Process for the coproduction of carboxylic acids and acid anhydrides |
| CN1039410A (zh) * | 1988-07-13 | 1990-02-07 | 赫彻斯特股份公司 | 乙酸和乙酸酐制法 |
| CN1228408A (zh) * | 1998-01-31 | 1999-09-15 | 英国石油化学品有限公司 | 制备乙酸的无水羰基化方法 |
Family Cites Families (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3772380A (en) | 1970-03-12 | 1973-11-13 | Monsanto Co | Production of carboxylic acids and esters |
| US3927078A (en) | 1972-08-21 | 1975-12-16 | Chevron Res | Methylene and oxymethylene bis-ester production |
| US4559183A (en) | 1973-09-04 | 1985-12-17 | The Halcon Sd Group, Inc. | Preparation of carboxylic acid anhydrides |
| DE2450965C2 (de) | 1974-10-26 | 1983-06-09 | Hoechst Ag, 6230 Frankfurt | Verfahren zur Herstellung von Essigsäureanhydrid |
| US4115444A (en) | 1975-03-10 | 1978-09-19 | Halcon International, Inc. | Process for preparing carboxylic acid anhydrides |
| DE2836084A1 (de) | 1978-08-17 | 1980-03-06 | Hoechst Ag | Verfahren zur herstellung von essigsaeureanhydrid |
| JPS5538369A (en) | 1978-09-01 | 1980-03-17 | Texaco Development Corp | Manufacture of carboxylic acids and their esters |
| US4252741A (en) | 1978-10-06 | 1981-02-24 | Halcon Research & Development Corp. | Carbonylation with Group VIII noble metal catalysts |
| US4358411A (en) | 1979-06-29 | 1982-11-09 | The Halcon Sd Group, Inc. | Preparation of carbonylation products |
| DE2939839A1 (de) | 1979-10-02 | 1981-04-23 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von essigsaeureanhydrid |
| US4417077A (en) | 1980-10-01 | 1983-11-22 | University Of Illinois Foundation | Heterogeneous anionic transition metal catalysts |
| US4374070A (en) * | 1980-11-21 | 1983-02-15 | Eastman Kodak Company | Preparation of acetic anhydride |
| US4366259A (en) | 1981-10-29 | 1982-12-28 | Texaco, Inc. | Production of acetic acid and propionic acid and their esters |
| DE3148006A1 (de) | 1981-12-04 | 1983-06-09 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von essigsaeureanhydrid und/oder essigsaeure und/oder ethylidendiacetat |
| ZA833528B (en) | 1982-05-22 | 1984-12-24 | Bp Chem Int Ltd | Process for the production of one or more carboxylic acid anhydrides |
| EP0109212B1 (en) | 1982-11-04 | 1987-05-27 | BP Chemicals Limited | Process for the preparation of acids |
| US4629809A (en) | 1983-07-21 | 1986-12-16 | Texaco Inc. | Process for selectively preparing acetic acid by carbonylation of methanol in the presence of a novel iodide-free catalyst system |
| GB8404136D0 (en) | 1984-02-16 | 1984-03-21 | Bp Chem Int Ltd | Carbonylation process |
| US5144068A (en) | 1984-05-03 | 1992-09-01 | Hoechst Celanese Corporation | Methanol carbonylation process |
| US5003104A (en) | 1987-03-03 | 1991-03-26 | Bp Chemicals Limited | Carbonylation process and catalyst |
| GB8807284D0 (en) | 1988-03-26 | 1988-04-27 | Bp Chem Int Ltd | Chemical process |
| GB8809027D0 (en) | 1988-04-16 | 1988-05-18 | British Petroleum Co Plc | Carbonylation of allylic alcohols |
| US5442107A (en) | 1989-04-06 | 1995-08-15 | Bp Chemicals Limited | Preparing carboxylic acids |
| JP2839367B2 (ja) | 1989-04-06 | 1998-12-16 | ビーピー ケミカルズ リミテッド | カルボン酸類の製造方法 |
| GB9021454D0 (en) | 1990-10-03 | 1990-11-14 | Bp Chem Int Ltd | Process |
| DE69108567T2 (de) | 1990-12-20 | 1995-08-03 | Eastman Chem Co | Kontinuierliches verfahren zur herstellung von essigsäureanhydrid oder einer mischung von essigsäureanhydrid und essigsäure. |
| GB9211671D0 (en) | 1992-06-02 | 1992-07-15 | Bp Chem Int Ltd | Process |
| US5488143A (en) | 1992-06-30 | 1996-01-30 | Korea Institute Of Science And Technology | Processes for the carbonylation of methanol to form acetic acid, methyl acetate and acetic anhydride |
| GB9218346D0 (en) | 1992-08-28 | 1992-10-14 | Bp Chem Int Ltd | Process |
| CN1040101C (zh) * | 1993-08-18 | 1998-10-07 | 大世吕化学工业株式会社 | 乙酸酐或乙酸酐和乙酸的制备方法 |
| US5510524A (en) | 1995-02-21 | 1996-04-23 | Bp Chemicals Limited | Process for the production of a carboxylic acid |
| US5696284A (en) | 1995-06-21 | 1997-12-09 | Bp Chemicals Limited | Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof |
| US5900505A (en) | 1997-02-04 | 1999-05-04 | Eastman Chemical Company | Heterogeneous vapor phase carbonylation process |
| EP1071647A1 (en) | 1998-04-17 | 2001-01-31 | BP Chemicals Limited | Process for the production of acetic acid and/or acetic anhydride |
| US5922911A (en) | 1998-04-24 | 1999-07-13 | Eastman Chemical Company | Process for the manufacture of acetic anhydride |
| GB9816385D0 (en) | 1998-07-29 | 1998-09-23 | Bp Chem Int Ltd | Process |
| US6211405B1 (en) | 1998-10-23 | 2001-04-03 | Celanese International Corporation | Addition of iridium to the rhodium/inorganic iodide catalyst system |
| US6452043B1 (en) | 2000-04-05 | 2002-09-17 | Eastman Chemical Company | Carbonylation of lower alkyl alcohols and their derivatives using metals supported on carbonized polysulfonated divinylbenzene-styrene copolymers |
| DE10138778A1 (de) * | 2001-08-07 | 2003-02-20 | Basf Ag | Flexibles Verfahren zur gemeinsamen Herstellung von Ameisensäure sowie einer Carbonsäure mit mindestens zwei Kohlenstoffatomen und/oder deren Derivaten |
| JP3660982B2 (ja) | 2001-11-08 | 2005-06-15 | 独立行政法人産業技術総合研究所 | カルボン酸塩の製造方法 |
| US6667418B2 (en) | 2002-04-16 | 2003-12-23 | Celanese International Corporation | Oxidation treatment of a recycle stream in production of acetic acid by methanol carbonylation |
| CN1315771C (zh) | 2002-05-06 | 2007-05-16 | 伊斯曼化学公司 | 连续羰基化工艺 |
| FR2839972B1 (fr) | 2002-05-23 | 2005-08-19 | Inst Francais Du Petrole | Procede de carbonylation des alcools utilisant un catalyseur a base de rhodium ou d'iridium dans un liquide ionique non-aqueux,avec un recyclage efficace du catalyseur |
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2006
- 2006-06-09 US US11/423,383 patent/US7737298B2/en active Active
-
2007
- 2007-05-25 CN CN200780021487.XA patent/CN101466659B/zh active Active
- 2007-05-25 JP JP2009514302A patent/JP5281000B2/ja not_active Expired - Fee Related
- 2007-05-25 EP EP07777273.9A patent/EP2029514B1/en active Active
- 2007-05-25 WO PCT/US2007/012457 patent/WO2007145795A2/en not_active Ceased
- 2007-06-07 TW TW096120444A patent/TWI398435B/zh active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1234641A (enExample) * | 1967-04-05 | 1971-06-09 | ||
| EP0087870A1 (en) * | 1982-02-13 | 1983-09-07 | BP Chemicals Limited | Process for the production of acetic anhydride and acetic acid |
| EP0087869A1 (en) * | 1982-02-13 | 1983-09-07 | BP Chemicals Limited | Process for the coproduction of carboxylic acids and acid anhydrides |
| CN1039410A (zh) * | 1988-07-13 | 1990-02-07 | 赫彻斯特股份公司 | 乙酸和乙酸酐制法 |
| CN1228408A (zh) * | 1998-01-31 | 1999-09-15 | 英国石油化学品有限公司 | 制备乙酸的无水羰基化方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2029514A2 (en) | 2009-03-04 |
| WO2007145795A3 (en) | 2008-03-27 |
| JP2009539835A (ja) | 2009-11-19 |
| CN101466659A (zh) | 2009-06-24 |
| EP2029514B1 (en) | 2014-10-01 |
| US20070287862A1 (en) | 2007-12-13 |
| JP5281000B2 (ja) | 2013-09-04 |
| TWI398435B (zh) | 2013-06-11 |
| WO2007145795A2 (en) | 2007-12-21 |
| TW200804265A (en) | 2008-01-16 |
| US7737298B2 (en) | 2010-06-15 |
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