CN101450995B - 低介电常数的等离子聚合薄膜及其制造方法 - Google Patents

低介电常数的等离子聚合薄膜及其制造方法 Download PDF

Info

Publication number
CN101450995B
CN101450995B CN2008101825701A CN200810182570A CN101450995B CN 101450995 B CN101450995 B CN 101450995B CN 2008101825701 A CN2008101825701 A CN 2008101825701A CN 200810182570 A CN200810182570 A CN 200810182570A CN 101450995 B CN101450995 B CN 101450995B
Authority
CN
China
Prior art keywords
thin film
plasma
film
substrate
plasma polymerized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN2008101825701A
Other languages
English (en)
Chinese (zh)
Other versions
CN101450995A (zh
Inventor
郑东根
李晟宇
禹知亨
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sungkyunkwan University Foundation for Corporate Collaboration
Original Assignee
Sungkyunkwan University Foundation for Corporate Collaboration
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sungkyunkwan University Foundation for Corporate Collaboration filed Critical Sungkyunkwan University Foundation for Corporate Collaboration
Publication of CN101450995A publication Critical patent/CN101450995A/zh
Application granted granted Critical
Publication of CN101450995B publication Critical patent/CN101450995B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/62Plasma-deposition of organic layers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
    • C08J5/2206Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218Synthetic macromolecular compounds
    • C08J5/2256Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions other than those involving carbon-to-carbon bonds, e.g. obtained by polycondensation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
    • C08J5/2287After-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/01Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/54Silicon-containing compounds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/20Deposition of semiconductor materials on a substrate, e.g. epitaxial growth solid phase epitaxy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0254After-treatment
CN2008101825701A 2007-12-06 2008-12-05 低介电常数的等离子聚合薄膜及其制造方法 Active CN101450995B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR1020070126331 2007-12-06
KR10-2007-0126331 2007-12-06
KR1020070126331A KR100962044B1 (ko) 2007-12-06 2007-12-06 저유전 플라즈마 중합체 박막 및 그 제조 방법

Publications (2)

Publication Number Publication Date
CN101450995A CN101450995A (zh) 2009-06-10
CN101450995B true CN101450995B (zh) 2012-05-09

Family

ID=40382806

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2008101825701A Active CN101450995B (zh) 2007-12-06 2008-12-05 低介电常数的等离子聚合薄膜及其制造方法

Country Status (5)

Country Link
US (1) US7897521B2 (US07897521-20110301-C00006.png)
EP (1) EP2070601B1 (US07897521-20110301-C00006.png)
KR (1) KR100962044B1 (US07897521-20110301-C00006.png)
CN (1) CN101450995B (US07897521-20110301-C00006.png)
AT (1) ATE555859T1 (US07897521-20110301-C00006.png)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013025768A1 (en) 2011-08-15 2013-02-21 The Procter & Gamble Company Cosmetic applicators
US9371430B2 (en) 2013-08-19 2016-06-21 Research & Business Foundation Sungkyunkwan University Porous film with high hardness and a low dielectric constant and preparation method thereof
CN104356390A (zh) * 2014-11-07 2015-02-18 中国科学院上海有机化学研究所 含苯并环丁烯基团的有机硅氧烷及其制备和应用
US10351729B2 (en) * 2016-03-03 2019-07-16 Motorola Mobility Llc Polysiloxane films and methods of making polysiloxane films
CN108933088B (zh) * 2017-05-25 2020-05-29 上海稷以科技有限公司 一种封装的方法及封装结构
KR102578827B1 (ko) 2018-04-24 2023-09-15 삼성전자주식회사 유연한 유무기 보호막 및 그 제조방법
KR102138102B1 (ko) * 2018-09-05 2020-07-27 성균관대학교산학협력단 저유전 플라즈마 중합체 박막 및 이의 제조 방법

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101435073A (zh) * 2007-04-23 2009-05-20 韩商奥拓股份有限公司 使用十字型烃类化合物形成无定形碳层和形成低k值介电层的方法

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5000113A (en) 1986-12-19 1991-03-19 Applied Materials, Inc. Thermal CVD/PECVD reactor and use for thermal chemical vapor deposition of silicon dioxide and in-situ multi-step planarized process
US4894532A (en) * 1988-03-28 1990-01-16 Westinghouse Electric Corp. Optical fiber sensor with light absorbing moisture-sensitive coating
US4877641A (en) * 1988-05-31 1989-10-31 Olin Corporation Process for plasma depositing silicon nitride and silicon dioxide films onto a substrate
US5203956A (en) * 1990-01-08 1993-04-20 Lsi Logic Corporation Method for performing in-situ etch of a CVD chamber
US5288325A (en) * 1991-03-29 1994-02-22 Nec Corporation Chemical vapor deposition apparatus
JP2703694B2 (ja) * 1992-05-28 1998-01-26 信越半導体株式会社 ガス供給装置
JPH06240456A (ja) * 1992-12-21 1994-08-30 Kawasaki Steel Corp 半導体装置のアルミニウム配線の形成方法及び装置
US5444217A (en) * 1993-01-21 1995-08-22 Moore Epitaxial Inc. Rapid thermal processing apparatus for processing semiconductor wafers
JPH06333857A (ja) * 1993-05-27 1994-12-02 Semiconductor Energy Lab Co Ltd 成膜装置および成膜方法
US6303523B2 (en) 1998-02-11 2001-10-16 Applied Materials, Inc. Plasma processes for depositing low dielectric constant films
US6147009A (en) 1998-06-29 2000-11-14 International Business Machines Corporation Hydrogenated oxidized silicon carbon material
US6312793B1 (en) * 1999-05-26 2001-11-06 International Business Machines Corporation Multiphase low dielectric constant material
TW425635B (en) * 1999-08-23 2001-03-11 Promos Technologies Inc Rapid thermal processing method and its device
EP1149933A1 (en) * 2000-04-28 2001-10-31 STMicroelectronics S.r.l. Deposition method of dielectric films having a low dielectric constant
DE10034737C2 (de) * 2000-07-17 2002-07-11 Fraunhofer Ges Forschung Verfahren zur Herstellung einer permanenten Entformungsschicht durch Plasmapolymerisation auf der Oberfläche eines Formteilwerkzeugs, ein nach dem Verfahren herstellbares Formteilwerkzeug und dessen Verwendung
US6441491B1 (en) * 2000-10-25 2002-08-27 International Business Machines Corporation Ultralow dielectric constant material as an intralevel or interlevel dielectric in a semiconductor device and electronic device containing the same
US6486082B1 (en) * 2001-06-18 2002-11-26 Applied Materials, Inc. CVD plasma assisted lower dielectric constant sicoh film
KR20030002993A (ko) * 2001-06-29 2003-01-09 학교법인 포항공과대학교 저유전체 박막의 제조방법
US20040058090A1 (en) * 2001-09-14 2004-03-25 Carlo Waldfried Low temperature UV pretreating of porous low-k materials
DE60322347D1 (de) * 2002-02-05 2008-09-04 Dow Global Technologies Inc Chemische dampfphasenabscheidung auf einem substrat mittels eines korona-plasmas
US6797643B2 (en) 2002-10-23 2004-09-28 Applied Materials Inc. Plasma enhanced CVD low k carbon-doped silicon oxide film deposition using VHF-RF power
TWI282124B (en) * 2002-11-28 2007-06-01 Tosoh Corp Insulating film material containing an organic silane compound, its production method and semiconductor device
US7288292B2 (en) 2003-03-18 2007-10-30 International Business Machines Corporation Ultra low k (ULK) SiCOH film and method
US20040197474A1 (en) * 2003-04-01 2004-10-07 Vrtis Raymond Nicholas Method for enhancing deposition rate of chemical vapor deposition films
US8137764B2 (en) 2003-05-29 2012-03-20 Air Products And Chemicals, Inc. Mechanical enhancer additives for low dielectric films
US7611996B2 (en) * 2004-03-31 2009-11-03 Applied Materials, Inc. Multi-stage curing of low K nano-porous films
US7491658B2 (en) * 2004-10-13 2009-02-17 International Business Machines Corporation Ultra low k plasma enhanced chemical vapor deposition processes using a single bifunctional precursor containing both a SiCOH matrix functionality and organic porogen functionality
US7678712B2 (en) * 2005-03-22 2010-03-16 Honeywell International, Inc. Vapor phase treatment of dielectric materials
US7901743B2 (en) 2005-09-30 2011-03-08 Tokyo Electron Limited Plasma-assisted vapor phase treatment of low dielectric constant films using a batch processing system
US7381659B2 (en) * 2005-11-22 2008-06-03 International Business Machines Corporation Method for reducing film stress for SiCOH low-k dielectric materials
US20070173071A1 (en) * 2006-01-20 2007-07-26 International Business Machines Corporation SiCOH dielectric
US20070190808A1 (en) 2006-02-10 2007-08-16 Stowell Michael W Low-k dielectric layers for large substrates
JP2007221039A (ja) 2006-02-20 2007-08-30 National Institute For Materials Science 絶縁膜および絶縁膜材料
KR100845941B1 (ko) 2007-03-27 2008-07-14 성균관대학교산학협력단 저유전 상수값을 갖는 박막 제조 방법 및 이에 의하여제조된 박막

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101435073A (zh) * 2007-04-23 2009-05-20 韩商奥拓股份有限公司 使用十字型烃类化合物形成无定形碳层和形成低k值介电层的方法

Also Published As

Publication number Publication date
EP2070601B1 (en) 2012-05-02
ATE555859T1 (de) 2012-05-15
US7897521B2 (en) 2011-03-01
US20090054612A1 (en) 2009-02-26
CN101450995A (zh) 2009-06-10
EP2070601A2 (en) 2009-06-17
EP2070601A3 (en) 2010-02-24
KR100962044B1 (ko) 2010-06-08
KR20090059462A (ko) 2009-06-11

Similar Documents

Publication Publication Date Title
CN101450995B (zh) 低介电常数的等离子聚合薄膜及其制造方法
US6432846B1 (en) Silicone polymer insulation film on semiconductor substrate and method for forming the film
EP1586674A1 (en) Coatings, and methods and devices for the manufacture thereof
US6653719B2 (en) Silicone polymer insulation film on semiconductor substrate
US6383955B1 (en) Silicone polymer insulation film on semiconductor substrate and method for forming the film
US6440876B1 (en) Low-K dielectric constant CVD precursors formed of cyclic siloxanes having in-ring SI—O—C, and uses thereof
CN101109074B (zh) 在硅和有机前驱物的pecvd工艺中减少气相反应以沉积无缺陷起始层方法
EP1466035B1 (en) Method for depositing inorganic/organic films
CN101316945B (zh) 低介电常数薄膜的灰化/湿法蚀刻损伤的抵抗性以及整体稳定性的改进方法
KR20000075433A (ko) 유전상수가 낮은 나노 다공성 공중합체 필름
US6852650B2 (en) Insulation film on semiconductor substrate and method for forming same
KR19990088593A (ko) 유전율이낮은수소화된옥시탄화규소막의제조방법
CN101107383A (zh) 改善低k叠层之间粘附性的界面工程
JPH11288931A (ja) 絶縁膜及びその製造方法
EP2412011B1 (en) Chemical vapor deposition method
JP4881153B2 (ja) 水素化シリコンオキシカーバイド膜の生成方法。
KR100845941B1 (ko) 저유전 상수값을 갖는 박막 제조 방법 및 이에 의하여제조된 박막
KR100987183B1 (ko) 저유전 플라즈마 중합체 박막 및 그 제조 방법
Seo et al. Organic and organic–inorganic hybrid polymer thin films deposited by PECVD using TEOS and cyclohexene for ULSI interlayer-dielectric application
US20150048487A1 (en) Plasma polymerized thin film having high hardness and low dielectric constant and manufacturing method thereof
JP3197008B2 (ja) 半導体基板上のシリコン重合体絶縁膜及びその膜を形成する方法
US9371430B2 (en) Porous film with high hardness and a low dielectric constant and preparation method thereof
US20120043640A1 (en) Material having a low dielectric konstant and method of making the same
Cho et al. A low dielectric study on hybrid plasma-polymer thin films of different ratio between toluene and TEOS
CN105453222A (zh) 薄膜制造方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant