CN101365733B - 具有改进的相容性的乙烯/α-烯烃共聚体的聚合物掺合物 - Google Patents

具有改进的相容性的乙烯/α-烯烃共聚体的聚合物掺合物 Download PDF

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CN101365733B
CN101365733B CN2006800084087A CN200680008408A CN101365733B CN 101365733 B CN101365733 B CN 101365733B CN 2006800084087 A CN2006800084087 A CN 2006800084087A CN 200680008408 A CN200680008408 A CN 200680008408A CN 101365733 B CN101365733 B CN 101365733B
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ethylene
polymer blend
weight
alpha
polymkeric substance
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CN101365733A (zh
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K·L·瓦顿
M·M·胡菲斯
Y·W·张
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Dow Global Technologies LLC
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  • Chemical Kinetics & Catalysis (AREA)
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  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
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CN2006800084087A 2005-03-17 2006-03-15 具有改进的相容性的乙烯/α-烯烃共聚体的聚合物掺合物 Active CN101365733B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
USPCT/US2005/008917 2005-03-17
PCT/US2005/008917 WO2005090427A2 (en) 2004-03-17 2005-03-17 Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
US71782505P 2005-09-16 2005-09-16
US60/717,825 2005-09-16
PCT/US2006/009402 WO2006101924A2 (en) 2005-03-17 2006-03-15 Polymer blends from interpolymer of ethylene/alpha-olefin with improved compatibility

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CN101365733A CN101365733A (zh) 2009-02-11
CN101365733B true CN101365733B (zh) 2012-06-20

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EP (1) EP1858942B1 (enExample)
JP (2) JP5231984B2 (enExample)
KR (1) KR101319124B1 (enExample)
CN (1) CN101365733B (enExample)
AR (1) AR053694A1 (enExample)
AU (1) AU2006227663A1 (enExample)
BR (1) BRPI0609852B1 (enExample)
CA (1) CA2601241A1 (enExample)
MX (1) MX2007011329A (enExample)
RU (1) RU2408622C2 (enExample)
TW (1) TWI377214B (enExample)
WO (1) WO2006101924A2 (enExample)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8273826B2 (en) * 2006-03-15 2012-09-25 Dow Global Technologies Llc Impact modification of thermoplastics with ethylene/α-olefin interpolymers
TW200635961A (en) * 2005-03-17 2006-10-16 Dow Global Technologies Inc Cap liners, closures and gaskets from multi-block polymers
EP1871817B1 (en) * 2005-03-17 2016-12-28 Dow Global Technologies LLC IMPACT MODIFICATION OF THERMOPLASTICS WITH ETHYLENE/alpha-OLEFIN INTERPOLYMERS
US7906587B2 (en) * 2005-09-16 2011-03-15 Dow Global Technologies Llc Polymer blends from interpolymer of ethylene/α olefin with improved compatibility
CN101802086B (zh) * 2007-07-13 2013-10-02 陶氏环球技术有限责任公司 具有受控的嵌段序列分布和至少一个低结晶度硬嵌段的催化的烯烃嵌段共聚物
KR101406772B1 (ko) 2007-10-22 2014-06-19 다우 글로벌 테크놀로지스 엘엘씨 중합체 조성물 및 제품의 성형방법
WO2010039628A2 (en) * 2008-10-03 2010-04-08 Dow Global Technologies Inc. POLYMER BLENDS WITH ETHYLENE/α-OLEFIN INTERPOLYMERS
WO2010135244A2 (en) 2009-05-19 2010-11-25 Polyone Corporation Thermoplastic elastomers exhibiting superior food contact compliance
JP5806218B2 (ja) * 2009-10-02 2015-11-10 ダウ グローバル テクノロジーズ エルエルシー ブロック複合材及び耐衝撃性改質組成物
SG11201404816XA (en) 2012-03-07 2014-10-30 Dow Global Technologies Llc Polyolefin based formulations for membranes and fabrics
KR101286918B1 (ko) * 2012-07-20 2013-07-19 이영기 폼타이어용 조성물
SG11201504673QA (en) * 2012-12-31 2015-07-30 Dow Global Technologies Llc Thermoplastic vulcanizate with crosslinked olefin block copolymer
EP3039071B1 (en) * 2013-08-28 2019-04-10 SABIC Global Technologies B.V. Soft touch compositions and articles thereof
WO2016064479A1 (en) 2014-10-24 2016-04-28 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizate compositions
RU2599574C1 (ru) * 2015-09-17 2016-10-10 Публичное Акционерное Общество "Нижнекамскнефтехим" Полиэтиленовая композиция для наружного слоя покрытий стальных труб
KR101987782B1 (ko) * 2015-12-07 2019-06-11 주식회사 엘지화학 폴리프로필렌계 복합재
US10227483B2 (en) 2016-09-21 2019-03-12 Exxonmobil Chemical Patents Inc. Compositions of olefin block copolymers and propylene-based elastomers
WO2018057078A1 (en) 2016-09-21 2018-03-29 Exxonmobil Chemical Patents Inc. Compositions of olefin block copolymers and propylene-based elastomers
US10435527B2 (en) * 2017-09-26 2019-10-08 Chevron Phillips Chemical Company Lp Dual component LLDPE copolymers with improved impact and tear resistance
US11566122B2 (en) 2017-11-01 2023-01-31 Avient Corporation Damping thermoplastic olefin elastomers
EP3788104A1 (en) 2018-05-03 2021-03-10 Dow Global Technologies LLC Propylene-based polymer compositions with excellent flexibility and hot air weldability
WO2019216311A1 (ja) * 2018-05-09 2019-11-14 Nok株式会社 ゴム組成物
WO2020089196A1 (en) * 2018-10-31 2020-05-07 Borealis Ag Upgraded recycled polyethylene polypropylene blend
JP2024545058A (ja) * 2021-12-08 2024-12-05 ダウ グローバル テクノロジーズ エルエルシー 熱可塑性ポリオレフィン及びそれからの成形品

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1149301A (zh) * 1994-04-06 1997-05-07 埃克森化学专利公司 乙烯α-烯烃嵌段共聚物以及它们的制备方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69415518T2 (de) * 1993-04-28 1999-05-20 The Dow Chemical Co., Midland, Mich. Produkte aus ethylenenpolymergemischen
US6177377B1 (en) * 1996-12-18 2001-01-23 Amherst Polymer Technology, Inc. Polymer blends and process for preparation
CA2277111A1 (en) * 1997-02-07 1998-08-13 Exxon Chemical Patents, Inc. Thermoplastic elastomer compositions from branched olefin copolymers
EP1002814A4 (en) * 1998-06-05 2001-11-28 Japan Polychem Corp PROPYLENE SEQUENCE COPOLYMER AND PROPYLENE RESIN COMPOSITION
JP2000239405A (ja) * 1999-02-18 2000-09-05 Nippon Polyolefin Kk エチレン（共）重合体の配向フィルムおよびその製造方法
WO2002079322A1 (en) 2001-03-29 2002-10-10 Idemitsu Petrochemical Co., Ltd. Propylene polymer composition, molded object, and polyolefin copolymer
JP2004204058A (ja) 2002-12-25 2004-07-22 Mitsui Chemicals Inc オレフィン系ブロック共重合体
JP4068953B2 (ja) * 2002-12-25 2008-03-26 三井化学株式会社 プロピレン系樹脂組成物
EP2357203B1 (en) * 2004-03-17 2017-05-24 Dow Global Technologies LLC Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
AU2005224258B2 (en) * 2004-03-17 2010-09-02 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for ethylene copolymer formation
JP5133050B2 (ja) * 2004-03-17 2013-01-30 ダウ グローバル テクノロジーズ エルエルシー エチレンマルチブロックコポリマーを形成するためのシャトリング剤を含む触媒組成物
JP2007084806A (ja) * 2005-08-22 2007-04-05 Mitsui Chemicals Inc プロピレン系樹脂組成物

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1149301A (zh) * 1994-04-06 1997-05-07 埃克森化学专利公司 乙烯α-烯烃嵌段共聚物以及它们的制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
K. Nitta, et al.Polypropylene-block-poly(ethylene-co-propylene) addition topolypropylene/poly(ethylene-co-propylene) blends:morphology and mechanical properties.Polymer41.2000,416765-6771. *

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