CN101341195B - 制备大孔阴离子交换树脂的方法 - Google Patents
制备大孔阴离子交换树脂的方法 Download PDFInfo
- Publication number
- CN101341195B CN101341195B CN2006800478500A CN200680047850A CN101341195B CN 101341195 B CN101341195 B CN 101341195B CN 2006800478500 A CN2006800478500 A CN 2006800478500A CN 200680047850 A CN200680047850 A CN 200680047850A CN 101341195 B CN101341195 B CN 101341195B
- Authority
- CN
- China
- Prior art keywords
- weight
- aqueous phase
- exchange resin
- pore
- monomer mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
- B01D15/08—Selective adsorption, e.g. chromatography
- B01D15/26—Selective adsorption, e.g. chromatography characterised by the separation mechanism
- B01D15/36—Selective adsorption, e.g. chromatography characterised by the separation mechanism involving ionic interaction
- B01D15/361—Ion-exchange
- B01D15/363—Anion-exchange
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28078—Pore diameter
- B01J20/28085—Pore diameter being more than 50 nm, i.e. macropores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/305—Addition of material, later completely removed, e.g. as result of heat treatment, leaching or washing, e.g. for forming pores
- B01J20/3064—Addition of pore forming agents, e.g. pore inducing or porogenic agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/04—Processes using organic exchangers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/08—Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/12—Macromolecular compounds
- B01J41/14—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/20—Anion exchangers for chromatographic processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/36—Amides or imides
- C08F222/38—Amides
- C08F222/385—Monomers containing two or more (meth)acrylamide groups, e.g. N,N'-methylenebisacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
- C08J9/286—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum the liquid phase being a solvent for the monomers but not for the resulting macromolecular composition, i.e. macroporous or macroreticular polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/326,682 | 2005-12-21 | ||
US11/326,682 US7674835B2 (en) | 2005-12-21 | 2005-12-21 | Method of making macroporous anion exchange resins |
PCT/US2006/047957 WO2007075442A2 (en) | 2005-12-21 | 2006-12-15 | Method of making macroporous anion exchange resins |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101341195A CN101341195A (zh) | 2009-01-07 |
CN101341195B true CN101341195B (zh) | 2011-12-14 |
Family
ID=38174581
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2006800478500A Expired - Fee Related CN101341195B (zh) | 2005-12-21 | 2006-12-15 | 制备大孔阴离子交换树脂的方法 |
Country Status (5)
Families Citing this family (52)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7098253B2 (en) * | 2004-05-20 | 2006-08-29 | 3M Innovative Properties Company | Macroporous ion exchange resins |
CN101039734B (zh) * | 2004-10-15 | 2010-09-08 | 3M创新有限公司 | 褶式多层过滤介质及滤筒 |
US7674835B2 (en) * | 2005-12-21 | 2010-03-09 | 3M Innovative Properties Company | Method of making macroporous anion exchange resins |
US7683100B2 (en) * | 2005-12-21 | 2010-03-23 | 3M Innovative Properties Company | Method of making macroporous cation exchange resins |
US7674836B2 (en) * | 2006-07-28 | 2010-03-09 | 3M Innovative Properties Company | Method of making macroporous cation exchange resins |
WO2009061759A1 (en) * | 2007-11-09 | 2009-05-14 | 3M Innovative Properties Company | Porous polymeric resins |
JP5814360B2 (ja) | 2010-06-25 | 2015-11-17 | スリーエム イノベイティブ プロパティズ カンパニー | 半相互貫入ポリマー網状組織 |
JP5734320B2 (ja) * | 2011-02-10 | 2015-06-17 | 積水メディカル株式会社 | イオン交換クロマトグラフィー用充填剤及び核酸鎖の分離検出方法 |
WO2012154314A1 (en) | 2011-03-31 | 2012-11-15 | 3M Innovative Properties Company | Method and device for indicating moisture based on bis (glyoxime) -transition metal complexes |
CN104335040A (zh) | 2012-03-27 | 2015-02-04 | 3M创新有限公司 | 双(乙二肟)-过渡金属比色湿气指示器 |
CN103387629B (zh) * | 2012-05-07 | 2015-09-09 | 江苏苏青水处理工程集团有限公司 | 一种双孔道大孔结构的高强度离子交换树及其脂制备方法 |
MY178616A (en) | 2012-09-17 | 2020-10-19 | Grace W R & Co | Chromatography media and devices |
US10119918B2 (en) | 2012-11-14 | 2018-11-06 | 3M Innovative Properties Company | Adjustable Colorimetric Moisture Indicators |
CN103008026B (zh) * | 2012-11-27 | 2015-12-23 | 安徽皖东化工有限公司 | 强碱性丙烯酸系阴离子交换树脂的制备方法 |
CN105074455B (zh) | 2013-03-15 | 2018-02-16 | 3M创新有限公司 | 蒸汽灭菌后湿气指示制品 |
WO2015050767A1 (en) | 2013-10-03 | 2015-04-09 | 3M Innovative Properties Company | Ligand-functionalized substrates with enhanced binding capacity |
EP3083036B1 (en) | 2013-12-18 | 2020-03-18 | 3M Innovative Properties Company | Porous articles for separation |
JP6853670B2 (ja) | 2014-01-16 | 2021-04-07 | ダブリュー・アール・グレース・アンド・カンパニー−コーンW R Grace & Co−Conn | 親和性クロマトグラフィー媒体及びクロマトグラフィーデバイス |
CN107847907A (zh) | 2014-05-02 | 2018-03-27 | 格雷斯公司 | 官能化载体材料以及制备和使用官能化载体材料的方法 |
BR112016028955B1 (pt) | 2014-06-12 | 2020-12-01 | Biosyn Arzneimittel Gmbh | métodos para produção de hemocianina de lapa californiana sintética, de imunocianina e de remoção de vírus de uma preparação de hemocianina, hemocianina de lapa californiana sintética, e, imunocianina sintética |
LT3154578T (lt) * | 2014-06-12 | 2019-02-11 | Biosyn Arzneimittel Gmbh | Naujos kartos biologinių požiūriu saugių klh produktų, naudojamų vėžio gydymui, gavimo būdai, skirti konjuguotų terapinių vakcinų ir kaip stimuliuojančių agentų pagerinimui |
US10286100B2 (en) | 2014-10-01 | 2019-05-14 | 3M Innovative Properties Company | Medical dressings comprising fluid management articles and methods of using same |
US11505894B2 (en) | 2014-10-01 | 2022-11-22 | 3M Innovative Properties Company | Articles including fibrous substrates and porous polymeric particles and methods of making same |
CN104689601B (zh) * | 2015-02-27 | 2017-11-14 | 神华集团有限责任公司 | 丙烯精制系统及丙烯精制方法 |
WO2016144515A1 (en) | 2015-03-06 | 2016-09-15 | 3M Innovative Properties Company | Compositions and adhesive articles including porous polymeric particles and methods of coating substrates |
US20180057770A1 (en) | 2015-03-23 | 2018-03-01 | 3M Innovative Properties Company | Polymeric composite particles |
EP3302784B1 (en) | 2015-06-05 | 2021-10-06 | W.R. Grace & Co.-Conn. | Adsorbent bioprocessing clarification agents and methods of making and using the same |
KR102360735B1 (ko) * | 2016-08-10 | 2022-02-08 | 에이지씨 엔지니아링 가부시키가이샤 | 기재 시트의 처리 방법, 개질 기재 시트의 제조 방법, 그래프트 중합 사슬이 형성된 기재, 및 이온 교환막 |
JP7085533B2 (ja) | 2016-09-09 | 2022-06-16 | スリーエム イノベイティブ プロパティズ カンパニー | 官能化コポリマー及びその使用 |
CN109689674A (zh) | 2016-09-09 | 2019-04-26 | 3M创新有限公司 | 从生物溶液中的单体蛋白质分离聚集蛋白质的方法 |
US10150056B2 (en) | 2016-11-14 | 2018-12-11 | Lilac Solutions, Inc. | Lithium extraction with coated ion exchange particles |
EP3661619A4 (en) * | 2017-08-02 | 2021-05-05 | Lilac Solutions, Inc. | LITHIUM EXTRACTION WITH POROUS ION EXCHANGE BEADS |
CN111182953A (zh) | 2017-08-02 | 2020-05-19 | 锂莱克解决方案公司 | 用于锂提取的离子交换系统 |
CN109718869B (zh) * | 2017-10-31 | 2022-05-27 | 罗门哈斯电子材料有限责任公司 | 离子交换树脂、纯化方法和制备离子树脂的方法 |
US11732104B2 (en) | 2017-11-16 | 2023-08-22 | 3M Innovative Properties Company | Polymer matrix composites comprising dielectric particles and methods of making the same |
US10913834B2 (en) | 2017-11-16 | 2021-02-09 | 3M Innovative Properties Company | Polymer matrix composites comprising indicator particles and methods of making the same |
EP3710156A1 (en) | 2017-11-16 | 2020-09-23 | 3M Innovative Properties Company | Polymer matrix composites comprising functional particles and methods of making the same |
US11807732B2 (en) | 2017-11-16 | 2023-11-07 | 3M Innovative Properties Company | Method of making polymer matrix composites |
US10927228B2 (en) | 2017-11-16 | 2021-02-23 | 3M Innovative Properties Company | Polymer matrix composites comprising intumescent particles and methods of making the same |
US10836873B2 (en) | 2017-11-16 | 2020-11-17 | 3M Innovative Properties Company | Polymer matrix composites comprising thermally insulating particles and methods of making the same |
US10648090B2 (en) | 2018-02-17 | 2020-05-12 | Lilac Solutions, Inc. | Integrated system for lithium extraction and conversion |
WO2019168941A1 (en) | 2018-02-28 | 2019-09-06 | Lilac Solutions, Inc. | Ion exchange reactor with particle traps for lithium extraction |
US11045773B2 (en) * | 2018-08-31 | 2021-06-29 | Pall Corporation | Salt tolerant porous medium |
US10737259B2 (en) * | 2018-08-31 | 2020-08-11 | Pall Corporation | Salt tolerant anion exchange medium |
WO2020071505A1 (ja) * | 2018-10-03 | 2020-04-09 | ダイキン工業株式会社 | 排水から含フッ素化合物を除去する方法 |
CN109608585B (zh) * | 2018-12-20 | 2021-06-15 | 华东理工大学 | 表面接枝聚合型阴离子色谱固定相及其制备方法和离子色谱柱 |
CN114729084B (zh) | 2019-11-25 | 2023-09-15 | 3M创新有限公司 | 含生物素的单体及由其形成的制品 |
JP2023514803A (ja) | 2020-01-09 | 2023-04-11 | ライラック ソリューションズ,インク. | 望ましくない金属を分離するための方法 |
US20230203221A1 (en) | 2020-04-14 | 2023-06-29 | 3M Innovative Properties Company | Monomers, polymers, and articles for biomaterial capture |
JP2023529444A (ja) | 2020-06-09 | 2023-07-10 | ライラック ソリューションズ,インク. | スケール物質存在下におけるリチウム抽出 |
EP4247759A1 (en) | 2020-11-20 | 2023-09-27 | Lilac Solutions, Inc. | Lithium production with volatile acid |
CN112898481B (zh) * | 2021-01-22 | 2022-05-13 | 广西民族大学 | 一种含叔胺盐酸盐功能基团的大孔交联吸附树脂及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5906747A (en) * | 1995-11-13 | 1999-05-25 | Biosepra Inc. | Separation of molecules from dilute solutions using composite chromatography media having high dynamic sorptive capacity at high flow rates |
US6045697A (en) * | 1992-06-19 | 2000-04-04 | Life Technologies, Inc. | Passivated porous polymer supports and methods for the preparation and use of same |
Family Cites Families (52)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2527300A (en) | 1948-03-18 | 1950-10-24 | American Cyanamid Co | Copolymers of unsaturated sulfonic acids and polyunsaturated compounds |
US3058594A (en) | 1960-06-06 | 1962-10-16 | Purolator Products Inc | Pleated paper filter |
CS171962B1 (US07674835-20100309-C00002.png) | 1974-02-01 | 1976-11-29 | ||
CS177507B1 (US07674835-20100309-C00002.png) | 1974-02-12 | 1977-07-29 | ||
US3929741A (en) | 1974-07-16 | 1975-12-30 | Datascope Corp | Hydrophilic acrylamido polymers |
US4071508A (en) | 1975-02-11 | 1978-01-31 | Plastomedical Sciences, Inc. | Anionic hydrogels based on hydroxyalkyl acrylates and methacrylates |
US4134815A (en) * | 1976-05-31 | 1979-01-16 | Ici Australia Limited | Amphoteric composite resins and method of preparing same by polymerization of a two-phase dispersion of monomers |
US4153661A (en) | 1977-08-25 | 1979-05-08 | Minnesota Mining And Manufacturing Company | Method of making polytetrafluoroethylene composite sheet |
JPS54100489A (en) * | 1978-01-26 | 1979-08-08 | Asahi Chem Ind Co Ltd | New basic crosslinked copolymer and its preparation |
US4157418A (en) | 1978-02-08 | 1979-06-05 | Minnesota Mining And Manufacturing Company | Acrylic functional aminocarboxylic acids and derivatives as components of pressure sensitive adhesives |
FR2482112B1 (fr) | 1980-05-09 | 1985-06-07 | Pharmindustrie | Nouveaux copolymeres hydrophiles a base de n-(tris (hydroxymethyl) methyl) acrylamide, procedes pour leur preparation, gels aqueux desdits copolymeres et leur utilisation comme echangeurs d'ions |
JPS57158209A (en) | 1981-03-25 | 1982-09-30 | Kao Corp | Production of bead-form highly water-absorbing polymer |
US4565663A (en) | 1981-06-26 | 1986-01-21 | Minnesota Mining And Manufacturing Company | Method for making water-swellable composite sheet |
US4439545A (en) * | 1981-11-19 | 1984-03-27 | Societe D "Expansion Scientifique "Expansia" | Acrylic copolymers of N-acryloylpolymethyleneimines or N-acryloyldialkylamides, N,N'-acryloyldiaminoalcanes and N-acryloylaminoacids (or esters) their preparation and use as cation exchangers |
US4552939A (en) | 1983-12-19 | 1985-11-12 | Exxon Research And Engineering Co. | Preparation of sulfonated copolymers by suspension copolymerization |
US4833198A (en) | 1985-07-22 | 1989-05-23 | The Dow Chemical Company | Suspending agent for the suspension polymerization of water-soluble monomers |
US5336742A (en) | 1987-03-13 | 1994-08-09 | Minnesota Mining And Manufacturing Company | Polymeric supports |
US4842739A (en) | 1987-08-20 | 1989-06-27 | Minnesota Mining And Manufacturing Company | High surface area filter cartridge |
US4810381A (en) | 1987-12-28 | 1989-03-07 | Minnesota Mining And Manufacturing Company | Composite chromatographic article |
US4971736A (en) | 1987-12-28 | 1990-11-20 | Minnesota Mining And Manufacturing Company | Method of preparing composite chromatographic article |
US6323249B1 (en) * | 1988-09-26 | 2001-11-27 | Purolite International, Ltd. | Macroporous resins having large pores but with high crush strength |
US4957943A (en) | 1988-10-14 | 1990-09-18 | Minnesota Mining And Manufacturing Company | Particle-filled microporous materials |
US5264125A (en) | 1989-09-08 | 1993-11-23 | Ionics' Incorporated | Process for manufacturing continuous supported ion selective membranes using non-polymerizable high boiling point solvents |
US5171808A (en) | 1990-06-11 | 1992-12-15 | American Cyanamid Company | Cross-linked anionic and amphoteric polymeric microparticles |
US5037858A (en) | 1990-06-21 | 1991-08-06 | Ionics, Incorporated | Anion selective polymers prepared from concentrated solutions of N,N'-methylenebisacrylamide |
US5104729A (en) | 1990-08-20 | 1992-04-14 | Monsanto Company | Process for surface modifying a support membrane and product produced |
US5993935A (en) | 1991-10-11 | 1999-11-30 | 3M Innovative Properties Company | Covalently reactive particles incorporated in a continous porous matrix |
JP3301628B2 (ja) | 1992-03-06 | 2002-07-15 | 日立化成工業株式会社 | りん酸基を有する陽イオン交換樹脂及びその製造法 |
ATE197556T1 (de) * | 1992-06-19 | 2000-12-15 | Life Technologies Inc | Passivierte und stabilisierte träger und methoden zu deren herstellung und verwendung |
JPH06228215A (ja) | 1993-02-03 | 1994-08-16 | Dainippon Ink & Chem Inc | 感温性多孔質重合体の製造方法 |
JPH06228216A (ja) | 1993-02-03 | 1994-08-16 | Dainippon Ink & Chem Inc | pH応答性多孔質重合体の製造方法 |
US5468847A (en) | 1994-03-10 | 1995-11-21 | Minnesota Mining And Manufacturing Company | Method of isolating and purifying a biomacromolecule |
US5561097A (en) | 1994-04-28 | 1996-10-01 | Minnesota Mining And Manufacturing Company | Method of controlling density of ligand coupled onto supports and products produced therefrom |
FR2722097B1 (fr) | 1994-07-11 | 1997-05-16 | Oreal | Composition cosmetique et/ou dermatologique gelifiee, riche en solvant et contenant des particules creuses, ses application |
CA2248003A1 (en) * | 1996-04-04 | 1997-10-02 | Commonwealth Scientific And Industrial Research Organisation | Process for manufacture of a porous polymer by use of a porogen |
US6059975A (en) * | 1997-09-02 | 2000-05-09 | Lockheed Martin Energy Research Corporation | Bifunctional anion-exchange resins with improved selectivity and exchange kinetics |
DE19907023A1 (de) | 1999-02-19 | 2000-08-24 | Bayer Ag | Verfahren zur Isolierung von Nucleinsäuren |
US6423666B1 (en) * | 1999-10-05 | 2002-07-23 | Bio-Rad Laboratories, Inc. | Large-pore chromatographic beads prepared by suspension polymerization |
DE19959264A1 (de) | 1999-12-03 | 2001-07-12 | Elipsa Gmbh | Templat-geprägte Kompositmaterialien mit hoher Bindungsspezifität und Selektivität, Verfahren zu ihrer Herstellung und ihre Verwendung |
DE10009982A1 (de) * | 2000-03-03 | 2001-09-06 | Qiagen Gmbh | Polymere Anionenaustauscher und deren Verwendung in chromatographischen Verfahren |
US6664305B2 (en) | 2000-06-27 | 2003-12-16 | Bia Separations D.O.O. | Chromatography material and a process of manufacturing that material |
DE10033583A1 (de) | 2000-07-11 | 2002-01-24 | Bayer Ag | Superparamagnetische Perlpolymerisate |
BR0113999A (pt) | 2000-09-21 | 2003-08-12 | Rohm & Haas | Processo para preparar uma dispersão polimérica aquosa nanocompósita de argila, dispersão nanocompósita aquosa, espessador, dispersante, aglutinante, composição de tinta flexográfica, verniz de sobre impressão, modificador de pó de cimento seco, semente polimérica nanocompósita de argila, composição polimérica nanocompósita de argila, e, método para preparar uma pluralidade de partìculas poliméricas nanocompósitas de argila ocas |
US6783838B2 (en) | 2001-04-30 | 2004-08-31 | 3M Innovative Properties Company | Coated film laminate having an ionic surface |
FR2824734B1 (fr) | 2001-05-16 | 2003-06-27 | Oreal | Composition pulverulente pour la decoloration des fibres keratiniques humaines |
US6756462B2 (en) * | 2001-07-03 | 2004-06-29 | Rohm And Haas Company | Method for preparation of anion exchange resins |
FI20011575A0 (fi) | 2001-07-26 | 2001-07-26 | Fortum Oyj | Polttoainekomponentit ja niiden selektiiviset valmistusmenetelmät |
US7098253B2 (en) * | 2004-05-20 | 2006-08-29 | 3M Innovative Properties Company | Macroporous ion exchange resins |
US20060070950A1 (en) * | 2004-10-01 | 2006-04-06 | 3M Innovative Properties Company | Composite filtration article |
US7683100B2 (en) | 2005-12-21 | 2010-03-23 | 3M Innovative Properties Company | Method of making macroporous cation exchange resins |
US7674835B2 (en) * | 2005-12-21 | 2010-03-09 | 3M Innovative Properties Company | Method of making macroporous anion exchange resins |
US7674836B2 (en) * | 2006-07-28 | 2010-03-09 | 3M Innovative Properties Company | Method of making macroporous cation exchange resins |
-
2005
- 2005-12-21 US US11/326,682 patent/US7674835B2/en active Active
-
2006
- 2006-12-15 CN CN2006800478500A patent/CN101341195B/zh not_active Expired - Fee Related
- 2006-12-15 WO PCT/US2006/047957 patent/WO2007075442A2/en active Application Filing
- 2006-12-15 EP EP20060845567 patent/EP1969039B1/en not_active Not-in-force
- 2006-12-15 JP JP2008547355A patent/JP2009521553A/ja active Pending
-
2010
- 2010-01-18 US US12/689,095 patent/US8338497B2/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6045697A (en) * | 1992-06-19 | 2000-04-04 | Life Technologies, Inc. | Passivated porous polymer supports and methods for the preparation and use of same |
US5906747A (en) * | 1995-11-13 | 1999-05-25 | Biosepra Inc. | Separation of molecules from dilute solutions using composite chromatography media having high dynamic sorptive capacity at high flow rates |
Also Published As
Publication number | Publication date |
---|---|
EP1969039A2 (en) | 2008-09-17 |
CN101341195A (zh) | 2009-01-07 |
US7674835B2 (en) | 2010-03-09 |
WO2007075442A3 (en) | 2007-11-01 |
WO2007075442A2 (en) | 2007-07-05 |
EP1969039B1 (en) | 2013-03-13 |
US20070142590A1 (en) | 2007-06-21 |
JP2009521553A (ja) | 2009-06-04 |
US8338497B2 (en) | 2012-12-25 |
US20100116748A1 (en) | 2010-05-13 |
EP1969039A4 (en) | 2011-09-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101341195B (zh) | 制备大孔阴离子交换树脂的方法 | |
CN101341196B (zh) | 大孔阳离子交换树脂的制备方法 | |
CN101910268B (zh) | 多孔聚合物树脂 | |
CN102959018B (zh) | 半互穿聚合物网络 | |
CN100577292C (zh) | 大孔离子交换树脂 | |
Okay | Macroporous copolymer networks | |
US7540962B2 (en) | Method of preparing spheroid polymer particles having a narrow size distribution by dispersion polymerization, particles obtainable by the method and use of these particles | |
JPH11271294A (ja) | 球状多孔質架橋重合体粒子およびその製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20111214 Termination date: 20141215 |
|
EXPY | Termination of patent right or utility model |