CN101302336A - 一种阻燃ppo/pa合金及其制备方法 - Google Patents
一种阻燃ppo/pa合金及其制备方法 Download PDFInfo
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- CN101302336A CN101302336A CNA2008100673415A CN200810067341A CN101302336A CN 101302336 A CN101302336 A CN 101302336A CN A2008100673415 A CNA2008100673415 A CN A2008100673415A CN 200810067341 A CN200810067341 A CN 200810067341A CN 101302336 A CN101302336 A CN 101302336A
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- ppo
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- alloy
- composite
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 50
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 229910001125 Pa alloy Inorganic materials 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000002131 composite material Substances 0.000 claims abstract description 29
- 238000002156 mixing Methods 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 238000005469 granulation Methods 0.000 claims abstract description 4
- 230000003179 granulation Effects 0.000 claims abstract description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 67
- 229920006380 polyphenylene oxide Polymers 0.000 claims description 67
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 13
- 238000005303 weighing Methods 0.000 claims description 12
- 239000012752 auxiliary agent Substances 0.000 claims description 11
- 239000012757 flame retardant agent Substances 0.000 claims description 11
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 9
- 239000004677 Nylon Substances 0.000 claims description 7
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 7
- 229920001778 nylon Polymers 0.000 claims description 7
- 238000012545 processing Methods 0.000 claims description 7
- 235000010290 biphenyl Nutrition 0.000 claims description 6
- 239000004305 biphenyl Substances 0.000 claims description 6
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 6
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 5
- UOYVDHYHTPDWJD-UHFFFAOYSA-N benzene-1,3-diol;phosphoric acid Chemical compound OP(O)(O)=O.OP(O)(O)=O.OC1=CC=CC(O)=C1 UOYVDHYHTPDWJD-UHFFFAOYSA-N 0.000 claims description 5
- 239000003112 inhibitor Substances 0.000 claims description 4
- 150000007974 melamines Chemical class 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 206010013786 Dry skin Diseases 0.000 claims description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 3
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 claims description 3
- 239000006096 absorbing agent Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 229920001971 elastomer Polymers 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 239000005060 rubber Substances 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- 239000007858 starting material Substances 0.000 claims description 3
- 238000001291 vacuum drying Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 14
- 238000000034 method Methods 0.000 abstract description 6
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000012745 toughening agent Substances 0.000 abstract 1
- 239000004952 Polyamide Substances 0.000 description 11
- 229920002647 polyamide Polymers 0.000 description 11
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 8
- 239000011159 matrix material Substances 0.000 description 8
- 238000005453 pelletization Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 6
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- -1 melamine salt compound Chemical class 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920005669 high impact polystyrene Polymers 0.000 description 2
- 239000004797 high-impact polystyrene Substances 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 2
- ASMQGLCHMVWBQR-UHFFFAOYSA-N Diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(O)OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-N 0.000 description 1
- 229920002633 Kraton (polymer) Polymers 0.000 description 1
- WIFGOPTYNDMXGD-UHFFFAOYSA-N P(=O)(O)(O)O.P(=O)(O)(O)O.OC(CC)(C1=CC=CC=C1)O Chemical compound P(=O)(O)(O)O.P(=O)(O)(O)O.OC(CC)(C1=CC=CC=C1)O WIFGOPTYNDMXGD-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical class C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/918—Thermal treatment of the stream of extruded material, e.g. cooling characterized by differential heating or cooling
- B29C48/9185—Thermal treatment of the stream of extruded material, e.g. cooling characterized by differential heating or cooling in the direction of the stream of the material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92514—Pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92561—Time, e.g. start, termination, duration or interruption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
组成 | 实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 实施例6 |
PPO(%) | 30 | 40 | 50 | 30 | 40 | 50 |
PA6(%) | 46.3 | 36.3 | 26.3 | / | / | / |
PA66(%) | / | / | / | 46.3 | 36.3 | 26.3 |
SEBS(%) | 5 | 5 | 5 | 5 | 5 | 5 |
RDP(%) | 10 | 10 | 10 | 10 | 10 | 10 |
MCA(%) | 5 | 5 | 5 | 5 | 5 | 5 |
相容剂(%) | 3 | 3 | 3 | 3 | 3 | 3 |
加工助剂(%) | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 |
1010(%) | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.5 |
168(%) | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
缺口冲击强度(KJ/m2) | 28 | 33 | 35 | 30 | 32.5 | 36 |
拉伸强度(Mpa) | 79 | 65 | 58 | 82 | 70 | 63 |
断裂伸长率(%) | 40 | 52 | 48 | 39 | 43 | 43 |
弯曲强度(Mpa) | 86 | 79 | 75 | 89 | 81 | 78 |
弯曲模量(Mpa) | 2230 | 2150 | 2000 | 2500 | 2210 | 2059 |
热变形温度(0.45mpa,℃) | 184 | 193 | 205 | 185 | 196 | 204 |
阻燃(1.5mm) | V0 | V0 | V0 | V0 | V0 | V0 |
组成 | 对比例1 | 对比例2 |
PPO(%) | 30 | 30 |
PA6(%) | 46.3 | 46.3 |
SEBS(%) | 5 | 5 |
RDP(%) | 15 | / |
MCA(%) | / | 15 |
相容剂(%) | 3 | 3 |
加工助剂(%) | 0.3 | 0.3 |
1010(%) | 0.2 | 0.2 |
168(%) | 0.2 | 0.2 |
缺口冲击强度(KJ/m2) | 27 | 20 |
拉伸强度(Mpa) | 76.5 | 66 |
断裂伸长率(%) | 43 | 50 |
弯曲强度(Mpa) | 88 | 80 |
弯曲模量(Mpa) | 2250 | 2150 |
热变形温度(0.45mpa,℃) | 178 | 173 |
阻燃(1.5mm) | V1 | V2 |
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2008100673415A CN101302336B (zh) | 2008-05-21 | 2008-05-21 | 一种阻燃ppo/pa合金及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2008100673415A CN101302336B (zh) | 2008-05-21 | 2008-05-21 | 一种阻燃ppo/pa合金及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101302336A true CN101302336A (zh) | 2008-11-12 |
CN101302336B CN101302336B (zh) | 2011-03-16 |
Family
ID=40112448
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2008100673415A Expired - Fee Related CN101302336B (zh) | 2008-05-21 | 2008-05-21 | 一种阻燃ppo/pa合金及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101302336B (zh) |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102225987A (zh) * | 2011-05-19 | 2011-10-26 | 深圳市科聚新材料有限公司 | Ppo接枝马来酸酐、其制备方法和应用 |
CN102311633A (zh) * | 2011-04-29 | 2012-01-11 | 深圳市科聚新材料有限公司 | Ppo/pa66合金材料、其制备方法和应用 |
CN102311641A (zh) * | 2010-10-15 | 2012-01-11 | 深圳市科聚新材料有限公司 | 一种高灼热丝阻燃pa/ppo合金及其制备方法 |
CN102399441A (zh) * | 2011-11-23 | 2012-04-04 | 上海日之升新技术发展有限公司 | 一种永久抗静电pa66/ppo合金及制备方法 |
CN102702732A (zh) * | 2012-06-15 | 2012-10-03 | 昆山聚威工程塑料有限公司 | 一种pa/pc/ppo三元合金及其制备方法 |
CN102702734A (zh) * | 2012-01-19 | 2012-10-03 | 五行材料科技(江苏)有限公司 | 一种高灼热丝红磷阻燃增强pa66与ppe合金材料及其制备方法 |
CN102942784A (zh) * | 2012-10-10 | 2013-02-27 | 惠州市华聚塑化科技有限公司 | 一种耐湿态无铅锡焊的尼龙46复合材料及其制备方法 |
CN102942785A (zh) * | 2012-10-10 | 2013-02-27 | 惠州市华聚塑化科技有限公司 | 一种耐湿态无铅锡焊的尼龙46复合材料及其制备方法 |
CN103160108A (zh) * | 2011-12-09 | 2013-06-19 | 上海杰事杰新材料(集团)股份有限公司 | 无卤阻燃聚苯醚/尼龙6共混合金及其制备方法与应用 |
CN103160107A (zh) * | 2011-12-09 | 2013-06-19 | 上海杰事杰新材料(集团)股份有限公司 | 一种聚苯醚/尼龙6共混合金材料及其制备方法与应用 |
CN103497500A (zh) * | 2013-10-12 | 2014-01-08 | 苏州市沃特新材料科技有限公司 | 聚苯醚树脂合金材料、其制备方法和应用 |
CN103788626A (zh) * | 2014-01-13 | 2014-05-14 | 惠州市沃特新材料有限公司 | Ppo/pa/hips复合材料及其制备方法 |
CN103865256A (zh) * | 2014-03-11 | 2014-06-18 | 广州市聚赛龙工程塑料有限公司 | 一种高耐热无卤阻燃尼龙6及其制备方法和应用 |
CN103923460A (zh) * | 2014-03-25 | 2014-07-16 | 金发科技股份有限公司 | 一种聚亚芳基醚和聚酰胺复合材料、制备方法和应用 |
CN103923452A (zh) * | 2014-03-25 | 2014-07-16 | 金发科技股份有限公司 | 一种阻燃增强聚亚芳基醚和聚酰胺复合材料、制备方法和应用 |
CN104086974A (zh) * | 2014-06-17 | 2014-10-08 | 惠州市沃特新材料有限公司 | 阻燃聚苯醚复合材料及其制备方法 |
CN106084770A (zh) * | 2016-04-05 | 2016-11-09 | 南京聚隆科技股份有限公司 | 一种耐热老化、低温高抗冲聚苯醚/尼龙复合材料及其制备方法 |
CN108403281A (zh) * | 2018-03-23 | 2018-08-17 | 常州市第人民医院 | 一种颈椎牵引装置 |
CN108659502A (zh) * | 2018-03-30 | 2018-10-16 | 青岛国恩科技股份有限公司 | 一种pa66/ppo复合材料及其制备方法 |
CN110626028A (zh) * | 2019-09-27 | 2019-12-31 | 厦门长塑实业有限公司 | 一种耐高温阻燃聚酰胺薄膜及其制备方法 |
-
2008
- 2008-05-21 CN CN2008100673415A patent/CN101302336B/zh not_active Expired - Fee Related
Cited By (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102311641A (zh) * | 2010-10-15 | 2012-01-11 | 深圳市科聚新材料有限公司 | 一种高灼热丝阻燃pa/ppo合金及其制备方法 |
CN102311633A (zh) * | 2011-04-29 | 2012-01-11 | 深圳市科聚新材料有限公司 | Ppo/pa66合金材料、其制备方法和应用 |
CN102225987A (zh) * | 2011-05-19 | 2011-10-26 | 深圳市科聚新材料有限公司 | Ppo接枝马来酸酐、其制备方法和应用 |
CN102225987B (zh) * | 2011-05-19 | 2015-11-25 | 深圳市科聚新材料有限公司 | Ppo接枝马来酸酐、其制备方法和应用 |
CN102399441A (zh) * | 2011-11-23 | 2012-04-04 | 上海日之升新技术发展有限公司 | 一种永久抗静电pa66/ppo合金及制备方法 |
CN103160107A (zh) * | 2011-12-09 | 2013-06-19 | 上海杰事杰新材料(集团)股份有限公司 | 一种聚苯醚/尼龙6共混合金材料及其制备方法与应用 |
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