A kind of blue-green algae processing and utilizing method of improvement
(1) technical field
The present invention relates to the changing waste into resources processing technology field, be specially blue-green algae and feces of livestock and poultry or mud producing marsh gas through mixed anaerobic fermentation method.
(2) background technology
In nutritious water body, blue-green algae often breeds in a large number summer, and forms one deck blue-greenish colour and stench floating foam of distinguishing the flavor of is arranged at the water surface, is called " wawter bloom ", and large-scale blue algae bloom is called as " green tide " (with the red tide correspondence of ocean generation).Green tide causes water quality deterioration, exhausts water oxygen gas when serious and causes the death of fish.Even more serious is that some kind (as Microcystis aeruginosa) also can produce toxin (being called for short MC) in the blue-green algae, contains a large amount of MC in about 50% the green tide.MC also is the major incentive of liver cancer except directly fish, people and animals being produced the murder by poisoning.
It is a lot of that blue algae water is handled approach, such as: be processed into similar spirulina, livestock protein feed, effective amino-acid fertilizer; With stalk composting fertilizer together; With rubbish landfill together; Blue algae water is directly applied nonirrigated farmland, forest land, paddy field; Carry out biogas anaerobic fermentation or the like as raw material.Concluding gets up is: industrialization development, harmless treatment, recycling.These treatment processs have has become reality abroad, has to report the blue-green algae capsule that goes out produced in USA, and its health properties surpasses spirulina; States such as Mexico adopt the method for artificial culture, produce blue-green algae dry powder, and the per kilogram export price is more than 5 dollars; Concentrated feed is then raiseeed with water bloom dry powder food prepared therefrom nutritional additive and high-quality fowl by states such as Japan, and therefrom extracts vitamin-E or other drug.The research of China blue-green algae development and use aspect is not less than international counterparts, does not just carry out industrialization development as yet, and supporting technology still needs to explore.
Recycling should be the primary selection that blue-green algae is handled.If 5-10 ton blue algae water is watered in every mu of nonirrigated farmland, forest land, the blue-green algae that salvage every day only needs 150-300 mu soil (to salvage 1500 tons of reckonings every day).Utilize mode to compare with other, direct returning to farmland is most economical way, but not safest way, because contain the algae toxin in the blue-green algae, these algae toxin to the influence of seed, root, stem, leaf how, in soil to clear up rule still not clear, though peasant along the lake has the tradition of utilizing water bloom to make fertilizer, this tradition has reasonableness, but may not have science.
(3) summary of the invention
At the problems referred to above, the invention provides a kind of blue-green algae processing and utilizing method of improvement, it can automatization control, working cost is low, non-secondary pollution, convenient management, can realize the innoxious and recycling treatment of blue-green algae.
The technical program is such, it is characterized in that: biomass such as blue-green algae and feces of livestock and poultry or mud are produced biogas as fermentation raw material by anaerobically fermenting together, marsh gas power generation or direct burning are used, and biogas residue and biogas liquid is the field also, perhaps the natural pond slag is developed to feed or organic fertilizer.
It is further characterized in that: the whole process of blue-green algae and feces of livestock and poultry or mud producing marsh gas through mixed anaerobic fermentation is finished in anaerobic reactor, and be (2~3) with blue-green algae and feces of livestock and poultry or mud in material dry weight ratio in reactor: 1 mixes, and feeds N then
2Cause anaerobic state,, in reactor, regularly add raw material by phased manner, control blue-green algae water ratio 3%~6%, feces of livestock and poultry water ratio 20%~30%, moisture percentage in sewage sludge 10%~20% at 33 ℃~37 ℃ condition bottom fermentations.
The advantage of the technology of the present invention:
1), accomplished the innoxious and recycling of waste with blue-green algae and feces of livestock and poultry or mud producing marsh gas through mixed anaerobic fermentation.
2) can directly handle blue-green algae, need not blue-green algae is carried out pre-treatment, therefore, save processing cost.
3) influence of interference-free material of fermentation such as plastics, wooden unit, sandstone etc. need not to spend manpower and equipment detects it before fermentation.
4) set up the solid fermentation chamber of moudle type, be convenient to enlarge and produce.
5) the fermentation residuum does not have the natural pond liquid of wet-fermentation, and without processed, the fermentation residuum is through simply sieving and the compost of short period of time promptly can be used as garden fertilizer, thereby storage and aftertreatment expense are low, are worth high.
6) water loss reduces more than 80% compared with wet method, does not almost have sewage discharge.
7) initial investment of blue algae fermentation technology, operation cost and Environmental costs all should be far below conventional wet technology (reducing more than the 30-40%).
(4) description of drawings
Fig. 1 is a schema of the present invention.
(5) embodiment
Below in conjunction with embodiment the course of processing of the present invention is described:
Embodiment 1, and blue-green algae and feces of livestock and poultry are in anaerobic reactor to mix at 2: 1 in the dry weight ratio, feed N then
2Cause anaerobic state, N
2Feed volume and be the long-pending residual volume that deducts after the useful volume of overall reactor, at 33 ℃ of condition bottom fermentations, in reactor, regularly add raw material by phased manner, control blue-green algae water ratio 3%, feces of livestock and poultry water ratio 30%.
Embodiment 2, and blue-green algae and feces of livestock and poultry are in anaerobic reactor to mix at 3: 1 in the dry weight ratio, feed N then
2Cause anaerobic state, N
2Feed volume and be the long-pending residual volume that deducts after the useful volume of overall reactor, at 37 ℃ of condition bottom fermentations, in reactor, regularly add raw material by phased manner, control blue-green algae water ratio 4.5%, feces of livestock and poultry water ratio 20%.
Embodiment 3, and blue-green algae and feces of livestock and poultry are in anaerobic reactor to mix at 2.5: 1 in the dry weight ratio, feed N then
2Cause anaerobic state, N
2Feed volume and be the long-pending residual volume that deducts after the useful volume of overall reactor, at 35 ℃ of condition bottom fermentations, in reactor, regularly add raw material by phased manner, control blue-green algae water ratio 6%, feces of livestock and poultry water ratio 25%.
Embodiment 4, and blue-green algae and mud are in anaerobic reactor to mix at 2: 1 in the dry weight ratio, feed N then
2Cause anaerobic state, N
2Feed volume and be the long-pending residual volume that deducts after the useful volume of overall reactor, at 33 ℃ of condition bottom fermentations, in reactor, regularly add raw material by phased manner, control blue-green algae water ratio 3%, moisture percentage in sewage sludge 15%.
Embodiment 5, and blue-green algae and mud are in anaerobic reactor to mix at 3: 1 in the dry weight ratio, feed N then
2Cause anaerobic state, N
2Feed volume and be the long-pending residual volume that deducts after the useful volume of overall reactor, at 37 ℃ of condition bottom fermentations, in reactor, regularly add raw material by phased manner, control blue-green algae water ratio 4.5%, moisture percentage in sewage sludge 10%.
Embodiment 6, and blue-green algae and mud are in anaerobic reactor to mix at 2.5: 1 in the dry weight ratio, feed N then
2Cause anaerobic state, N
2Feed volume and be the long-pending residual volume that deducts after the useful volume of overall reactor, at 35 ℃ of condition bottom fermentations, in reactor, regularly add raw material by phased manner, control blue-green algae water ratio 6%, moisture percentage in sewage sludge 20%.