CN101233844A - Watersoluble cleaning sterilization gel - Google Patents

Watersoluble cleaning sterilization gel Download PDF

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Publication number
CN101233844A
CN101233844A CNA2008100650555A CN200810065055A CN101233844A CN 101233844 A CN101233844 A CN 101233844A CN A2008100650555 A CNA2008100650555 A CN A2008100650555A CN 200810065055 A CN200810065055 A CN 200810065055A CN 101233844 A CN101233844 A CN 101233844A
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gum
cleaning sterilization
gel according
watersoluble cleaning
sterilization gel
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CNA2008100650555A
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Chinese (zh)
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周加权
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Individual
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Abstract

The invention relates to an aqueous clean sterilization gel, which comprises the flowing components by weight percentage: 65-98.8 percent of water, 1-22 percent of sizing, 0.1-5 percent of gelling agent, 0.1-7 percent of germicide, and 0-33.7 percent of adjuvant; the clean sterilization gel made according to the components has low tackiness, good tractility, stretching performance and good adhesive performance after broken; therefore, the aqueous clean sterilization gel has comparatively high capability of dust and dirt wrapping; bactericide components are added into the gel, thus leading the disinfection ability of the obtained gel for ordinary bacteria and virus to be more than 80 percent.

Description

A kind of watersoluble cleaning sterilization gel
[technical field]
The present invention relates to daily cleaning sterilizing article field, relate in particular to a kind of watersoluble cleaning sterilization gel.
[background technology]
Various germs that occurring in nature exists and virus are brought very big threat to human health, have humanly also taked several different methods to resist germ and virus in the self-growth process gradually, and this wherein sterilizes is one of the most basic effective means.Sterilization is meant adopts medicine (disinfectant) to come the method for killing pathogenic bacteria and virus.Because the raising of people's living standard, the enhancing gradually of personal hygiene, personal protection and public health consciousness is to the requirement of sterile products with use also more widespread, and also more and more higher to the requirement of the ease of use of sterile products.Like this, advantage such as the disinfectant of gel formulation is strong because of its ductility, parcel property is good is easy to use, becomes a kind of personal hygiene sterilizing article that enjoys great popularity.
But present gel cleaning and sterilizing agent is generally all developed towards the personal daily disinfecting, be mainly used in skin, body surface, oral cavity or feminine care etc., but to being applied to object surface---especially the gel-type cleaning and sterilizing agent Application and Development of the rough surface of electrical appliance button and button slot, leather and timber and seaming position etc. is relative less, and the product of taking into account personal hygiene nursing and object surface cleaning sterilization simultaneously is just still less.
[summary of the invention]
Goal of the invention of the present invention provides a kind of watersoluble cleaning sterilization gel, to be applied to the nursing of electrical equipment slit, object seam and rough surface sterilization and personal hygiene.
To achieve the above object of the invention, the present invention proposes following technical scheme:
A kind of watersoluble cleaning sterilization gel comprises following component by weight percentage:
Water 65-98.8%
Sizing material 1-22%
Gelling agent 0.1-5%
Bactericide 0.1-7%
Adjuvant 0-33.7%,
Wherein, the content of described gelling agent is in active ingredient.
Preferably, described sizing material is selected from PVAC polyvinylalcohol and/or galactomannans Galactomannane series sizing material; Wherein, PVAC polyvinylalcohol comprises the PVA model of the different molecular weight of partial hydrolysis and whole hydrolysis; Galactomannans is selected from one or more combinations in following sizing material and their physics and the chemical modification kind: guar gum Guar Gum, locust bean gum (algaroba glue) Locust Bean Gum, the hydroxypropyl guar bean gum, sesbania gum Sesbania Gum, fenugreek gum (trigonella bean gum) Fenugreek Gum, tara gum Tara Gum, and Chinese honey locust bean gum Chinese honey locust gum.
Preferably, the concrete kind of described gelling agent comprises one or more combinations in inorganic boric acid and salt, metatitanic acid and salt thereof, aluminic acid and salt thereof, phosphoric acid and its esters, organic boron, organic titanium, organo-aluminium, organic phosphor or the organic zirconate.
Preferably, described bactericide is to be selected from Ao Maiding (pyrithione) salt Omadine, parachlorometaxylenol PCMX. bronopol Bronopol, Hexetidine Hexetidine, chlohexidine Chlorhexidine, alkyl (C 12-C 22) trimethyl (or dimethyl) ammonium bromide and chloride Alkyl (C 12-C 22)-trimethyl (dimethyl) ammonium, bromide and chloride, Chlorphenesin Hlorphenesin, hydrochloric acid gathers (1-hexamethylene biguan-ide) Poly (1-hexamethylenebiguanide hydrochloride), the own miaow salt of dibromo Dibromohexamidine, polyquaternium Quatemium, Phenoxyethanol Phenoxyethanol, extremely beautiful Diazolidinyl urea, iodine propilolic alcohol butyl mephenesin Carbamate Iodopropnyl butylcarbamate, triclosan Triclosan, o-phthalaldehyde(OPA) o-Phthalaldehyde, glutaraldehyde Glutaral, one or more combinations among isothiazolinone BIT.kraon or nipagin esters and the salt 4-Hydroxybenzoic acid and its salts and esters.
Wherein, described adjuvant is to be selected from:
Alcohol: improve biocidal efficacies and soak into effect, can improve sizing material exsiccation speed, the colloid mechanical strength that enters in the slit is improved, also can reduce the temperature of contact-making surface;
Enzyme preparation: can destroy microorganisms top layer diaphragm, or dissolved cell wall (contain and be partly dissolved), hinder functions such as microbial metabolism and active breeding, as lysozyme. muramidase;
Surfactant: make not hydrophilic composition and water-based sizing material be emulsified into one, and improve the function and the clean effect of bactericide, comprise cation, two surfacant and nonionic and anion surfactant;
Penetrant: improve the gel sterilization degree of depth, bacteria on surfaces dissipation not only, also dissipation effect that can be certain to the deep layer microorganisms mainly is surfactant, azone etc.;
Humectant: the too fast volatilization exsiccation of control gel hardening can prolong the gel useful life, as glycerine, propane diols, sorbierite etc.;
Antifreeze: reduce the gel freezing point, gel is still had use value, when lower temperature as glycerine, propane diols, sorbierite etc.;
PH regulator agent: keep the rational pH system of gel, improve the ability of gel opposing varying environment, as hydrophosphate, citric acid, citrate etc.;
Colouring agent: be made into different colors, improve outward appearance and different consumer demands, as pigment and dyestuff etc.;
Deodorant tune: be made into different odor types, improve sense organ and different consumption demands, as essence, spices etc.;
Odor absorber: the bad smell in the absorption environment, as active carbon, bamboo charcoal, charcoal etc.;
Lubricant: improve the inside and outside lubricated sense of gel, as hydrophilic silicone oil, fatty acid etc.;
Softening agent: improve gel feel and draftability and plastic performance, as glycerine, propane diols, sorbierite etc.;
Ornamental inserts: change sense organ and different consumption demands, as pearl essence, luminescent powder, glitter powder, variable color powder, calcium carbonate, talcum powder etc.;
Supplementary thickener: cooperate the major ingredient sizing material to increase denseness. improve the performance such as substantial full of gel, as cellulose ether, linseed glue, tragacanth, xanthans, tamarind gum etc.
To achieve the above object of the invention, the present invention also proposes following technical scheme:
A kind of watersoluble cleaning sterilization gel is characterized in that, comprises following component by weight percentage:
Water 70.5~95.2%
Sizing material 1.1~13%
Gelling agent 0.2~2.5%
Bactericide 0.3~1.5%
Adjuvant 0.1~18.8%,
Wherein, the content of described gelling agent is in active ingredient; Described sizing material is to be selected from sesbania gum, PVAC polyvinylalcohol BF05 #, PVA 1799 #, at least a in hydroxypropyl guar bean gum, locust bean gum or the guar gum; Described gelling agent is to be selected from least a in Boratex, borax pentahydrate, borax decahydrate, boric acid, sodium hydrogen phosphate, sodium dihydrogen phosphate, sodium aluminate or the chelating titanium; Described bactericide is to be selected from sodium omadine, dodecyl dimethyl ammonium chloride, Dodecyl trimethyl ammonium chloride, extremely U.S., methyl hydroxybenzoate, chlorhexidine gluconate, hydrochloric acid poly-(1-hexamethylene biguan-ide), Hexetidine, Chlorphenesin, polyquaternium-15 #, at least a in Phenoxyethanol, iodine propilolic alcohol butyl mephenesin Carbamate, triclosan, glutaraldehyde or the bronopol; Described adjuvant is to be selected from least a in ethanol, glycerine, citric acid, titanium dioxide, water-soluble silicon oil, dodecyl sulfobetaines, lysozyme, propane diols, bamboo charcoal, essence, coconut oleoyl amine diethanol amine, pearl essence or the toner.
Watersoluble cleaning sterilization gel provided by the present invention can add dissolving or swelling in the entry to sizing material separately, forms colloidal sol, adds bactericide and adjuvant, and then uses gelling agent, is cross-linked to form gel; Also can earlier part or all gel be added in advance mix in the sizing material after, again this mixture is added in the aqueous solution of bactericide and/or adjuvant and dissolves swelling, be cross-linked to form gel then.
As can be seen from the above technical solutions, watersoluble cleaning sterilization gel of the present invention is that sizing material is soluble in water and react with gelling agent, be cross-linked to form the macromolecular structure of netted or side chain, the lower sticking chirality that has the colloid that makes can and extend preferably performance, tensile property and break after bond properties again, therefore have the higher parcel dust and the ability of foul; Simultaneously owing to be added with microbiocidal composition in the sizing material, the colloid that makes reaches more than 80% the ability of killing of common germ with virus, therefore can be in the cleaning objects surface to the sterilizing effect of playing of this object.Be compared to present cleaning-sterilizing gel on the market, watersoluble cleaning sterilization gel of the present invention has following advantage:
1. because this gel is water miscible, and moisture is locked in the cross-linked gel, is difficult to become free water, so not have moisture residual for the surface after the sterilization;
2. because the extension performance of cross-linked gel, can immerse in the slit, thereby solve slit and lines (as electrical equipment slit, object seam crossing and rough surface etc.) that other cleaning and sterilizing agent can not be handled, and can accomplish that gel-free remains in the slit, reach cleaning and bactericidal action simultaneously;
3. can directly contact with hand, bactericide is crosslinked gel and effectively wraps up, and it is bactericide compounded to add choose reasonable, and low to skin irritation, disinfecting gel is safe and reliable;
4. the combination of materials mode is various, can make the different cross-linked gels that require according to different purposes, reaches different effects.
[embodiment]
Embodiment 1
Take by weighing each raw material components by following formula rate:
Water 82.9g
Guar gum 6.2g
Glycerine 8.0g
Boratex 0.2g
Triclosan 0.2g
Dodecyl dimethyl ammonium chloride 0.1g
Dodecyl sulfobetaines 0.4g
Toner 1.5g
Essence 0.5g
The preparation method 1: add the gel Boratex in the guar gum in advance earlier, it is standby to mix the back, all add glycerine, triclosan, dodecyl dimethyl ammonium chloride, dodecyl sulfobetaines, toner, essence in the entry again, after stirring, add the mixture of Boratex and guar gum rubber powder again, heating or stirring at normal temperature, keep weak acid to weakly alkaline environment, begin thickening after a few minutes, be cross-linked into even jelly at last, promptly.
The preparation method 2: all add gel Boratex and glycerine, triclosan, dodecyl dimethyl ammonium chloride, dodecyl sulfobetaines, toner, essence in the entry earlier, after stirring, add the guar gum rubber powder again, heating or stirring at normal temperature, keep weak acid to weakly alkaline environment, begin thickening after a few minutes, be cross-linked into even jelly at last, promptly.
In the present embodiment, Boratex can be replaced with boric acid, because can change into Boratex at the alkaline environment mesoboric acid, and in sour environment, Boratex then changes into boric acid.So Boratex and boric acid can be replaced, by regulating acid-base value, the gel that can obtain requiring.
Embodiment 2
Take by weighing each raw material components by following formula rate:
Water 74.09g
Sesbania gum 4.6g
Alcohol 11g
Glycerine 5g
Sodium hydrogen phosphate 0.5g
Citric acid 0.9g
Borax decahydrate 1.0g
Sodium omadine 0.4g
Dodecyl dimethyl ammonium chloride 0.2g
Extremely beautiful 0.5g
Titanium dioxide 1.1g
Water-soluble silicon oil 0.4g
Glutaraldehyde 0.2g
Toner 0.1g
Lysozyme 0.01g
Preparation method: earlier with sodium hydrogen phosphate and bactericide sodium omadine, dodecyl dimethyl ammonium chloride, U.S. extremely, all add in the entry with auxiliary material alcohol, glycerine, titanium dioxide, water-soluble silicon oil, glutaraldehyde, toner, lysozyme, after stirring, add the sesbania gum rubber powder again, stir, add aqueous citric acid solution again, begin thickening after a few minutes, add borax soln at last, be cross-linked into even jelly, promptly
Embodiment 3
Take by weighing each raw material components by following prescription:
Water 70.5g
PVA?BF05 # 13g
Propane diols 12.6g
Borax decahydrate 0.8g
Boric acid 1.6g
Methyl hydroxybenzoate 0.2g
Chlorhexidine gluconate 0.2g
Hydrochloric acid gathers (1-hexamethylene biguan-ide) 0.2g
Hexetidine 0.1g
Bamboo charcoal 0.8g
Preparation method: earlier with PVA BF05 #(Changchun, Taiwan company low viscosity polyvinyl alcohol commercial disignation) adds in the entry, heated and stirred also dissolves it, add propane diols, methyl hydroxybenzoate, chlorhexidine gluconate, hydrochloric acid poly-(1-hexamethylene biguan-ide) and Hexetidine and bamboo charcoal again, after stirring, the solution that adds boric acid and borax decahydrate again, stir, be cross-linked into even jelly, promptly.
Propane diols has humectant, softening agent, the triple purposes of antifreeze in the present embodiment.
Embodiment 4
Take by weighing each raw material components by following prescription:
Water 95.2g
Hydroxypropyl guar bean gum 1.1g
Sodium dihydrogen phosphate 1.0g
Borax pentahydrate 1.5g
Chlorphenesin 0.2g
Polyquaternium-15 #0.2g
Phenoxyethanol 0.7g
Essence 0.1g
Preparation method: earlier with bactericide Chlorphenesin, polyquaternium-15 #All add in the entry with Phenoxyethanol and auxiliary material essence, after stirring, add hydroxypropyl guar bean gum powder again, stir, add the biphosphate sodium water solution again, begin thickening after a few minutes, the solution that adds borax pentahydrate at last is cross-linked into even jelly, promptly.
Sodium dihydrogen phosphate has gelling agent and acid-base modifier double duty in the present embodiment.
Embodiment 5
Take by weighing each raw material components by following prescription:
Water 91g
PVA?1799 # 4.2g
Locust bean gum 0.7g
Borax decahydrate 0.2g
Sodium aluminate 0.1g
Boric acid 0.2g
Propylben 0.2g
Extremely beautiful 0.5g
Iodine propilolic alcohol butyl mephenesin Carbamate 0.1g
Triclosan 0.2g
Coconut oleoyl amine diethanol amine 0.6g
Glycerine 2g
Preparation method: earlier with PVA1799 #(homemade medium viscosity polyvinyl alcohol commercial disignation), locust bean gum add in the entry, heated and stirred, it is dissolved, add glycerine again, bactericide methyl hydroxybenzoate, extremely beautiful, iodine propilolic alcohol butyl mephenesin Carbamate and triclosan and auxiliary material coconut oleoyl amine diethanol amine are after stirring, the mixed aqueous solution that adds borax decahydrate, sodium aluminate, boric acid again, stir while adding, be cross-linked into even jelly, promptly.
Embodiment 6
Take by weighing each raw material components by following prescription:
Water 78.7g
Alcohol 16.8g
Guar gum 1.7g
Borax pentahydrate 0.2g
Sodium dihydrogen phosphate 0.6g
Phenoxyethanol 0.8g
Chelating titanium 0.3g
Extremely beautiful 0.5g,
Bronopol 0.1g
Dodecyl trimethyl ammonium chloride 0.1g
Toner 0.1g
Pearl essence 0.1g
The preparation method 1: earlier all add bactericide Phenoxyethanol, bronopol and Dodecyl trimethyl ammonium chloride and auxiliary material toner and pearl essence in the entry, after stirring, add guar gum again, stir while adding, add sodium dihydrogen phosphate, borax pentahydrate and chelating titanium mixture solution again, be cross-linked to form even colloid, promptly.
The preparation method 2: earlier borax pentahydrate and guar gum mixed, and standby; All add bactericide Phenoxyethanol, bronopol and Dodecyl trimethyl ammonium chloride and auxiliary material toner and pearl essence in the entry, after stirring, add the blend glue stuff that contains borax again, stir while adding, add sodium dihydrogen phosphate again, add the chelating titanium solution at last, form even colloid, promptly.
The preparation method 3: earlier all add a part of borax pentahydrate, bactericide Phenoxyethanol, bronopol and Dodecyl trimethyl ammonium chloride and auxiliary material toner and pearl essence in the entry, after stirring, add guar gum again, stir while adding, add sodium dihydrogen phosphate again, add remaining borax pentahydrate and chelating titanium mixture solution at last, be cross-linked to form even colloid, promptly.
The preparation method 4: earlier a part of borax pentahydrate and guar gum mixed, and standby; All add bactericide Phenoxyethanol, bronopol and Dodecyl trimethyl ammonium chloride and auxiliary material toner and pearl essence in the entry, after stirring, add the blend glue stuff that contains borax again, stir while adding, add sodium dihydrogen phosphate again, add remaining borax pentahydrate and chelating titanium mixture solution at last, be cross-linked to form even colloid, promptly.
The above embodiment has only expressed several embodiment of the present invention, and it describes comparatively concrete and detailed, but can not therefore be interpreted as the restriction to claim of the present invention.Should be pointed out that for the person of ordinary skill of the art without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.

Claims (14)

1. a watersoluble cleaning sterilization gel is characterized in that, comprises following component by weight percentage:
Water 65~98.8%
Sizing material 1~22%
Gelling agent 0.1~5%
Bactericide 0.1~7%
Adjuvant 0~33.7%,
Wherein, the content of described gelling agent is in active ingredient.
2. watersoluble cleaning sterilization gel according to claim 1 is characterized in that, described sizing material is to be selected from polyvinyl alcohol and/or galactomannan gum material.
3. watersoluble cleaning sterilization gel according to claim 2, it is characterized in that described galactomannan gum material is to be selected from least a in guar gum, locust bean gum, hydroxypropyl guar bean gum, sesbania gum, fenugreek gum, tara gum or Chinese honey locust bean gum and their the modification kind.
4. watersoluble cleaning sterilization gel according to claim 1, it is characterized in that described gelling agent is to be selected from least a in inorganic boric acid and salt, metatitanic acid and salt thereof, aluminic acid and salt thereof, phosphoric acid and its esters, organic boron, organic titanium, organo-aluminium, organic phosphor, the organic zirconate.
5. watersoluble cleaning sterilization gel according to claim 1 is characterized in that, described bactericide is to be selected from pyrithione salt, parachlorometaxylenol, bronopol, Hexetidine, chlohexidine, C 12-C 22Alkyl trimethyl ammonium or Dimethyl Ammonium bromide and chloride, Chlorphenesin, hydrochloric acid poly-(1-hexamethylene biguan-ide), dibromo be miaow, polyquaternium, Phenoxyethanol, at least a in U.S., iodine propilolic alcohol butyl mephenesin Carbamate, triclosan, o-phthalaldehyde(OPA), glutaraldehyde, isothiazolinone or nipagin esters and the salt extremely.
6. watersoluble cleaning sterilization gel according to claim 1, it is characterized in that described adjuvant is to be selected from least a in ethanol, enzyme preparation, emulsifier, penetrant, the antifreeze of preserving moisture, pH regulator agent, colouring agent, deodorant tune, odor absorber, lubricant, softening agent, filler or the thickener.
7. watersoluble cleaning sterilization gel according to claim 6 is characterized in that, described enzyme preparation is lysozyme or muramidase.
8. watersoluble cleaning sterilization gel according to claim 6 is characterized in that, described emulsifier is anion, cation, both sexes or non-ionic surfactant emulsifier.
9. watersoluble cleaning sterilization gel according to claim 6 is characterized in that, the described antifreeze of preserving moisture is to be selected from least a in glycerine, propane diols or the sorbierite.
10. watersoluble cleaning sterilization gel according to claim 6 is characterized in that, described pH regulator agent is hydrophosphate or citrate.
11. watersoluble cleaning sterilization gel according to claim 6 is characterized in that, described odor absorber is active carbon, bamboo charcoal or charcoal.
12. watersoluble cleaning sterilization gel according to claim 6 is characterized in that, described lubricant is hydrophilic silicone oil or fatty acid.
13. watersoluble cleaning sterilization gel according to claim 6 is characterized in that, described thickener is to be selected from least a in cellulose ether, linseed glue, tragacanth, xanthans or the tamarind gum.
14. a watersoluble cleaning sterilization gel is characterized in that, comprises following component by weight percentage:
Water 70.5~95.2%
Sizing material 1.1~1 3%
Gelling agent 0.2~2.5%
Bactericide 0.3~1.5%
Adjuvant 0.1~18.8%,
Wherein, the content of described gelling agent is in active ingredient; Described sizing material is to be selected from sesbania gum, PVAC polyvinylalcohol BF05 #, PVAC polyvinylalcohol 1799 #, at least a in hydroxypropyl guar bean gum, locust bean gum or the guar gum; Described gelling agent is to be selected from least a in Boratex, borax pentahydrate, borax decahydrate, boric acid, sodium aluminate, sodium hydrogen phosphate, sodium dihydrogen phosphate or the chelating titanium; Described bactericide is to be selected from sodium omadine, dodecyl dimethyl ammonium chloride, Dodecyl trimethyl ammonium chloride, extremely U.S., methyl hydroxybenzoate, chlorhexidine gluconate, hydrochloric acid poly-(1-hexamethylene biguan-ide), Hexetidine, Chlorphenesin, polyquaternium-15 #, at least a in Phenoxyethanol, iodine propilolic alcohol butyl mephenesin Carbamate, triclosan, glutaraldehyde or the bronopol; Described adjuvant is to be selected from least a in ethanol, glycerine, citric acid, titanium dioxide, water-soluble silicon oil, dodecyl sulfobetaines, lysozyme, propane diols, bamboo charcoal, essence, coconut oleoyl amine diethanol amine, pearl essence or the toner.
CNA2008100650555A 2008-01-14 2008-01-14 Watersoluble cleaning sterilization gel Pending CN101233844A (en)

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