CN101196477B - Anti-rust defect detecting liquid and its preparing technique - Google Patents
Anti-rust defect detecting liquid and its preparing technique Download PDFInfo
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- CN101196477B CN101196477B CN2007103025956A CN200710302595A CN101196477B CN 101196477 B CN101196477 B CN 101196477B CN 2007103025956 A CN2007103025956 A CN 2007103025956A CN 200710302595 A CN200710302595 A CN 200710302595A CN 101196477 B CN101196477 B CN 101196477B
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Abstract
The invention relates to a rust prevention fault detection liquid and the manufacturing technics. The rust prevention fault detection liquid comprises the following composites and the weight percentage composition are as follows: carboxylic ester 0.8 to 5.0 percent; polylol 2.0 to20.0 percent; nonferrous metal antiseptic 0.2 to 1.0 percent; ionic surface active agent 1.0 to 10.0 percent; alkylphenol cyclochlorotine polymer 1.0 to 10.0 percent; dispersing agent 4.0 to 30.0 percent; magnetic sorbent 1.0 to 10.0 percent; developer 3.0 to 10.0 percent; foam inhibitor 0.1 to 1.0 percent; water as margin. The preparation procedures are that: a. putting carboxylic and polylol into a reaction kettle, increasing the temperature into 70 to 90 DEG.C, and then stopping heating; b. after mixing evenly,adding non ferrous metal aseptic, and reducing the temperature into 40 to 50 DEG.C; c. then adding the ionic surface active agent, the alkylphenol cyclochlorotine polymer and the dispersing agent, and after a period of time, adding magnetic sorbent; d. mixing for a period of time, then adding the developer and the foam inhibitor, and adding sufficient water, and then mixing for a period of time.The invention has the advantages of high efficiency, economy, safety, noncorrosibility, cleanness and acceptance.
Description
Technical field
The present invention relates to the inspection technique field, especially relate to a kind of anti-rust defect detecting liquid and preparation technology thereof.
Background technology
Flaw detection is to check whether precision parts exists the necessary check program of defectives such as crackle, scar.Its method has two kinds: a kind of is to obtain a result after by ray workpiece being scanned.The method simple and effective, but the equipment input cost is too big.Another kind is by special Magnaglo is dissolved in the oil, and workpiece is immersed wherein, and whether workpiece absorption magnetic in conduction back exists defective so that naked eyes can be distinguished.The method drops into little, the most of the method that adopts of general enterprise, but also exist obviously not enough: be carrier 1, with lightweight volatile oil such as kerosene, volatile oil has degreasing, osmosis to human body skin, very easily cause allergic, and there is very direct injury in the oil gas that evaporates to workman's respiratory tract, lung etc., and the tendency of significantly causing a disease is arranged.2, kerosene flash point has only about 60 ℃, and is careless slightly, just causes fire easily, and this type of accident is of common occurrence, and present domestic oil price is more and more higher, and the flaw detection cost is also progressively soaring.3, pollute workpiece, workpiece is difficult to be cleaned, contaminated environment, and oiliness is polluted very difficult the elimination.
Chinese patent literature discloses a kind of flame resisting fluorescent penetration flaw detection liquid and preparation method thereof [application number: 200510029684.9], the compositing formula of this defect detecting liquid is by weight percentage: the odorlessness kerosene of 30%-70%, the hydrogenation machine oil of 10%-35%, the dibasic alcohol of 10%-16%, the dibutyl phthalate of 7%-12%, the foaming agent TSHN of 2%-5% and the Baeyer fluorescein of 1%-2%, be dissolved with foaming agent TSHN in the flame resisting fluorescent penetration flaw detection liquid of the present invention, when running into higher temperature, decompose immediately, constantly emit a large amount of nitrogen, penetrating fluid is covered, isolated with airborne oxygen; Perhaps the vapor phase of combustible component is mixed in nitrogen and the fluorescent penetrant, and the shared ratio of combustible component is descended, and flash-point improves, and is nonflammable, so just can reach significant fire-retardant effect.In addition, the foaming agent TSHN that adds in fluorescent penetrant is humble poison, the minimum reagent of environmental pollution, does not also contain harmful elements such as fluorine, chlorine, sulphur, sodium, phosphorus.But this scheme still can not solve the technical matters of above-mentioned existence fully.
Summary of the invention
The objective of the invention is at the problems referred to above, a kind of infiltration, good dispersion are provided, show that the magnetic trace is clear, highly sensitive, save a large amount of oils, avoid producing and pollute, reduce the anti-rust defect detecting liquid of flaw detection cost; Solved the existing poor effect of prior art, the technical matters that use cost is high.
Another object of the present invention is at the problems referred to above, a kind of not flammable, nothing volatilization is provided, effectively ensure production safety, avoid the allergic and respiratory tract of workman, safeguard employee's physical and mental health, significant anti-corrosion defencive function, the anti-rust defect detecting liquid of rust-proof life more than a week under mal-condition; It is relatively poor to have solved the existing in prior technology security, very easily causes allergicly, and there is very direct injury in the oil gas that evaporates to workman's respiratory tract, lung etc., and the technical matters of the tendency of significantly causing a disease etc. being arranged.
For achieving the above object, the present invention has adopted following technical proposal: this anti-rust defect detecting liquid is characterized in that component and weight percentage thereof that this anti-rust defect detecting liquid comprises are respectively: carboxylic esters 0.8-5.0%; Polyvalent alcohol 2.0-20.0%; Non-ferrous metal antiseptic 0.2-1.0%; Ionic surfactant 1.0-10.0%; Alkyl phenol ring chlorine polymkeric substance 1.0-10.0%; Spreading agent 4.0-30.0%; Magnetic adsorbent 1.0-10.0%; Developer 3.0-10.0%; Foam inhibitor 0.1-1.0%; Water is surplus.
Carboxylic esters and polyvalent alcohol are mainly used in the ferrous metal corrosion protection erosion among the present invention; The non-ferrous metal antiseptic is mainly used in the non-ferrous metal anticorrosion; Ionic surfactant and alkyl phenol ring chlorine polymkeric substance mainly play cleaning workpiece and help emulsification; Spreading agent is mainly used in magnetic adsorbent evenly to be disperseed in solution; Magnetic adsorbent is mainly used in and is adsorbed in crack surfaces so that observe; Developer helps that adsorbent is better must to be shown; Foam elimination in foam generation and the help system in the foam inhibitor inhibition system.
In above-mentioned anti-rust defect detecting liquid, described carboxylic esters is triethanolamine and decanedioic acid reaction product; Described polyvalent alcohol is triethanolamine or diethanolamine; Described non-ferrous metal antiseptic is thiadiazoles or benzene a pair of horses going side by side ribavirin; Described ionic surfactant is NP-10 and department's benzene-80 or is OP-10 and department's benzene-80; Described spreading agent is fatty alcohol and ethylene oxide condensate; Described magnetic adsorbent is polarity pigment or magnetic; Described developer is silver bromide and sodium thiosulfate; Described foam inhibitor is a dimethyl silicon oil.
Above-mentioned anti-rust defect detecting liquid makes by following technology: the anti-rust defect detecting liquid preparing process is characterized in that it comprises the steps: that a. puts into reactor with carboxylic esters and polyvalent alcohol earlier, is warming up to 70-90 ℃, stops heating then; B. stir evenly the back and add the non-ferrous metal antiseptic, be cooled to 40-50 ℃; C. add ionic surfactant, alkyl phenol ring chlorine polymkeric substance, spreading agent then, put into magnetic adsorbent after a period of time again; D. stir and add developer and foam inhibitor after a period of time, and add the water of capacity, promptly make anti-rust defect detecting liquid after stirring a period of time again.
In above-mentioned anti-rust defect detecting liquid, stir after 20～40 minutes among the described above-mentioned step c and put into magnetic adsorbent again.
In above-mentioned anti-rust defect detecting liquid, in the described above-mentioned steps d, stir adding developer and foam inhibitor after 40～80 minutes, stir again after 40～80 minutes and promptly make anti-rust defect detecting liquid.
Compared with prior art, this anti-rust defect detecting liquid and preparation technology's thereof advantage is: 1. high efficiency---infiltration, good dispersion show that the magnetic trace is clear, highly sensitive.2. saving---save a large amount of oils, avoid producing and pollute, reduce the flaw detection cost, and need not change water, for a long time with never degenerating.3. security---not flammable, nothing volatilization effectively ensures production safety, avoids the allergic and respiratory tract of workman, safeguards employee's physical and mental health.4. anti-corrosive properties---significant anti-corrosion defencive function, rust-proof life is more than a week under mal-condition.5. cleaning---can not pollute skin and clothing, it is convenient to clean, and no bubble produces.6. acceptance---add the friendly agent of import environmental protection especially, human body, equipment, environment are not had injury.
Embodiment
Component and weight percentage thereof that this anti-rust defect detecting liquid comprises are respectively: carboxylic esters 3.0%; Polyvalent alcohol 15.0%; Non-ferrous metal antiseptic 0.5%; Ionic surfactant 5.0%; Alkyl phenol ring chlorine polymkeric substance 5.0%; Spreading agent 20.0%; Magnetic adsorbent 5.0%; Developer 7.0%; Foam inhibitor 0.5%; Water is surplus.
Carboxylic esters is triethanolamine and decanedioic acid reaction product; Described polyvalent alcohol is triethanolamine or diethanolamine; Described non-ferrous metal antiseptic is thiadiazoles or benzene a pair of horses going side by side ribavirin; Described ionic surfactant is NP-10 and department's benzene-80 or is OP-10 and department's benzene-80; Described spreading agent is fatty alcohol and ethylene oxide condensate; Described magnetic adsorbent is polarity pigment or magnetic; Described developer is silver bromide and sodium thiosulfate; Described foam inhibitor is a dimethyl silicon oil.This anti-rust defect detecting liquid is the outstanding defect detecting liquid of a kind of novel hydromagnetic at the shortcoming of oils defect detecting liquid, is used for the usefulness of flaw detections such as precision parts, pipeline, is the ideal substitute of oiliness defect detecting liquid.
Above-mentioned anti-rust defect detecting liquid preparing process comprises the steps: that a. puts into reactor with carboxylic esters and polyvalent alcohol earlier, is warming up to 80 ℃, stops heating then; B. stir evenly the back and add the non-ferrous metal antiseptic, be cooled to 45 ℃; C. add ionic surfactant, alkyl phenol ring chlorine polymkeric substance, spreading agent then, put into magnetic adsorbent again after in half an hour; Stir adding developer and foam inhibitor after one hour, and add the water of capacity, stir again after one hour and promptly make anti-rust defect detecting liquid.
Using method is as follows: 1. use is poured out after before defect detecting liquid in the container fully being shaken up, and avoids the precipitation of a small amount of defect detecting liquid.2. before the defectoscope work defect detecting liquid was circulated about one minute earlier, so that defect detecting liquid is more even.3. regularly add, can add a small amount of tap water when being necessary.4. this anti-rust defect detecting liquid is applicable to parts such as cupric and alloy thereof.
Table one: the performance data table of anti-rust defect detecting liquid
Specific embodiment described herein only is that the present invention's spirit is illustrated.The technician of the technical field of the invention can make various modifications or replenishes or adopt similar mode to substitute described specific embodiment, but can't depart from spirit of the present invention or surmount the defined scope of appended claims.
Although this paper has used term morely, do not get rid of the possibility of using other term.Using these terms only is in order to describe and explain essence of the present invention more easily; They are construed to any additional restriction all is contrary with spirit of the present invention.
Claims (2)
1. an anti-rust defect detecting liquid is characterized in that, component and weight percentage thereof that this anti-rust defect detecting liquid comprises are respectively: weight percentage is 3.0% carboxylic esters, and carboxylic esters is triethanolamine and decanedioic acid reaction product; Weight percentage is 15.0% polyvalent alcohol, and polyvalent alcohol is triethanolamine or diethanolamine; Weight percentage is 0.5% non-ferrous metal antiseptic, and the non-ferrous metal antiseptic is thiadiazoles or benzene a pair of horses going side by side ribavirin; Weight percentage is 5.0% ionic surfactant, and ionic surfactant is NP-10 and department's benzene-80 or is 0P-10 and department's benzene-80; Weight percentage is 5.0% alkyl phenol ring chlorine polymkeric substance; Weight percentage is 20% spreading agent, and spreading agent is fatty alcohol and ethylene oxide condensate; Weight percentage is 5.0% magnetic adsorbent, and magnetic adsorbent is polarity pigment or magnetic; Weight percentage is 7.0% developer, and developer is silver bromide and sodium thiosulfate; Weight percentage is 0.5% foam inhibitor, and foam inhibitor is a dimethyl silicon oil; Water is surplus.
2. an anti-rust defect detecting liquid preparing process is characterized in that it comprises the steps:
A. earlier carboxylic esters and polyvalent alcohol are put into reactor, be warming up to 80 ℃, stop heating then; Wherein carboxylic esters is that triethanolamine and decanedioic acid reaction product and its weight percentage are 3.0%, and polyvalent alcohol is that triethanolamine or diethanolamine and its weight percentage are 15.0%;
B. stir evenly the back and add the non-ferrous metal antiseptic, be cooled to 45 ℃; Wherein the non-ferrous metal antiseptic is that thiadiazoles or benzene a pair of horses going side by side ribavirin and its weight percentage are 0.5%;
C. add ionic surfactant, alkyl phenol ring chlorine polymkeric substance, spreading agent then, stirring is put into magnetic adsorbent after half an hour again; Wherein ionic surfactant is NP-10 and department's benzene-80 or is that OP-10 is 5.0% with department's benzene-80 and its weight percentage, the weight percentage of alkyl phenol ring chlorine polymkeric substance is 5.0%, spreading agent is that fatty alcohol and ethylene oxide condensate and weight percentage are 20%, and magnetic adsorbent is that polarity pigment or magnetic and its weight percentage are 5.0%;
D. stir adding developer and foam inhibitor after one hour, and add the water of capacity, stir again after one hour and promptly make anti-rust defect detecting liquid; Wherein developer is that silver bromide and sodium thiosulfate and its weight percentage are 7.0%, and foam inhibitor is that dimethyl silicon oil and its weight percentage are 0.5%.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2007103025956A CN101196477B (en) | 2007-12-29 | 2007-12-29 | Anti-rust defect detecting liquid and its preparing technique |
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| CN2007103025956A CN101196477B (en) | 2007-12-29 | 2007-12-29 | Anti-rust defect detecting liquid and its preparing technique |
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| CN101196477A CN101196477A (en) | 2008-06-11 |
| CN101196477B true CN101196477B (en) | 2010-06-02 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103343347B (en) * | 2013-06-27 | 2015-07-15 | 陈德辉 | Production method of oil removal agent for stainless steel |
| CN108444958B (en) * | 2018-02-08 | 2020-10-23 | 浙江绿岛科技有限公司 | Nondestructive flaw detection aerosol |
| CN113358663B (en) * | 2021-05-12 | 2023-02-17 | 江西中电投新能源发电有限公司 | Wind power blade crack detection device and detection method thereof |
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| US4072618A (en) * | 1976-08-27 | 1978-02-07 | Mobil Oil Corporation | Metal working lubricant |
| CN85104229A (en) * | 1985-05-31 | 1986-07-09 | 南开大学 | The dual-purpose penetrating fluid of flaw detection of painted-fluorescence |
| WO1989000981A1 (en) * | 1987-07-31 | 1989-02-09 | Frenzelit-Werke Gmbh & Co. Kg | Process for dyeing silicic acid glass fibres and products so obtained |
| EP0430624A1 (en) * | 1989-11-27 | 1991-06-05 | Ethyl Petroleum Additives, Inc. | Gear oils and additives therefor |
| CN1932489A (en) * | 2005-09-15 | 2007-03-21 | 沪东中华造船(集团)有限公司 | Flame resisting fluorescent penetration flaw detection liquid and producing process thereof |
| CN1959386A (en) * | 2006-11-17 | 2007-05-09 | 中国第二重型机械集团公司 | Water based anticorrosive penetrant inspection agent, and preparation method |
-
2007
- 2007-12-29 CN CN2007103025956A patent/CN101196477B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4072618A (en) * | 1976-08-27 | 1978-02-07 | Mobil Oil Corporation | Metal working lubricant |
| CN85104229A (en) * | 1985-05-31 | 1986-07-09 | 南开大学 | The dual-purpose penetrating fluid of flaw detection of painted-fluorescence |
| WO1989000981A1 (en) * | 1987-07-31 | 1989-02-09 | Frenzelit-Werke Gmbh & Co. Kg | Process for dyeing silicic acid glass fibres and products so obtained |
| EP0430624A1 (en) * | 1989-11-27 | 1991-06-05 | Ethyl Petroleum Additives, Inc. | Gear oils and additives therefor |
| CN1932489A (en) * | 2005-09-15 | 2007-03-21 | 沪东中华造船(集团)有限公司 | Flame resisting fluorescent penetration flaw detection liquid and producing process thereof |
| CN1959386A (en) * | 2006-11-17 | 2007-05-09 | 中国第二重型机械集团公司 | Water based anticorrosive penetrant inspection agent, and preparation method |
Non-Patent Citations (3)
| Title |
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| 伏喜胜.齿轮油防锈剂的研究.润滑油12 3.1997,12(3),27-30. |
| 华秀菱 |
| 华秀菱;伏喜胜.齿轮油防锈剂的研究.润滑油12 3.1997,12(3),27-30. * |
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