CN101186713A - 聚苯乙烯窗口膜的制造方法 - Google Patents
聚苯乙烯窗口膜的制造方法 Download PDFInfo
- Publication number
- CN101186713A CN101186713A CNA2007100313684A CN200710031368A CN101186713A CN 101186713 A CN101186713 A CN 101186713A CN A2007100313684 A CNA2007100313684 A CN A2007100313684A CN 200710031368 A CN200710031368 A CN 200710031368A CN 101186713 A CN101186713 A CN 101186713A
- Authority
- CN
- China
- Prior art keywords
- polystyrene
- polystyrene resin
- diaphragm
- toughner
- vinylbenzene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004793 Polystyrene Substances 0.000 title claims abstract description 43
- 229920002223 polystyrene Polymers 0.000 title claims abstract description 38
- 238000000034 method Methods 0.000 title claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 56
- 229920005669 high impact polystyrene Polymers 0.000 claims abstract description 20
- 239000010410 layer Substances 0.000 claims abstract description 19
- 239000004797 high-impact polystyrene Substances 0.000 claims abstract description 15
- 229920005990 polystyrene resin Polymers 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 10
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 32
- 238000001816 cooling Methods 0.000 claims description 22
- 238000007493 shaping process Methods 0.000 claims description 16
- 239000003112 inhibitor Substances 0.000 claims description 15
- 239000000314 lubricant Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 15
- 230000003068 static effect Effects 0.000 claims description 15
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 13
- 238000002844 melting Methods 0.000 claims description 12
- 230000008018 melting Effects 0.000 claims description 12
- 238000006116 polymerization reaction Methods 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 7
- 239000002344 surface layer Substances 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 6
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 4
- 238000005520 cutting process Methods 0.000 claims description 4
- 230000004927 fusion Effects 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Natural products CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 3
- -1 amine salt Chemical class 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 3
- 238000003851 corona treatment Methods 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000010298 pulverizing process Methods 0.000 claims description 3
- 238000005096 rolling process Methods 0.000 claims description 3
- ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- 150000003016 phosphoric acids Chemical class 0.000 claims description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims 2
- 150000003014 phosphoric acid esters Chemical class 0.000 claims 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims 1
- 235000013305 food Nutrition 0.000 abstract description 3
- 239000002356 single layer Substances 0.000 abstract 2
- 239000012752 auxiliary agent Substances 0.000 abstract 1
- 230000008033 biological extinction Effects 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- 239000012745 toughening agent Substances 0.000 abstract 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 16
- 239000003595 mist Substances 0.000 description 6
- 239000004033 plastic Substances 0.000 description 6
- 229920003023 plastic Polymers 0.000 description 6
- 238000012856 packing Methods 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 229920001971 elastomer Polymers 0.000 description 4
- 239000005060 rubber Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000004798 oriented polystyrene Substances 0.000 description 3
- 230000032683 aging Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical group CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- 229920009204 Methacrylate-butadiene-styrene Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920013649 Paracril Polymers 0.000 description 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- UCMIRNVEIXFBKS-UHFFFAOYSA-N beta-alanine Chemical class NCCC(O)=O UCMIRNVEIXFBKS-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- BZDKYAZTCWRUDZ-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate;prop-2-enenitrile;styrene Chemical compound C=CC=C.C=CC#N.COC(=O)C(C)=C.C=CC1=CC=CC=C1 BZDKYAZTCWRUDZ-UHFFFAOYSA-N 0.000 description 1
- 235000019219 chocolate Nutrition 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 229920012128 methyl methacrylate acrylonitrile butadiene styrene Polymers 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- 229940113162 oleylamide Drugs 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000003923 scrap metal Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
- B29C48/08—Flat, e.g. panels flexible, e.g. films
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2007100313684A CN101186713B (zh) | 2007-11-08 | 2007-11-08 | 聚苯乙烯窗口膜的制造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2007100313684A CN101186713B (zh) | 2007-11-08 | 2007-11-08 | 聚苯乙烯窗口膜的制造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101186713A true CN101186713A (zh) | 2008-05-28 |
CN101186713B CN101186713B (zh) | 2010-08-11 |
Family
ID=39479351
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2007100313684A Expired - Fee Related CN101186713B (zh) | 2007-11-08 | 2007-11-08 | 聚苯乙烯窗口膜的制造方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101186713B (zh) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102115571A (zh) * | 2010-12-30 | 2011-07-06 | 佛山市顺德区圆融新材料有限公司 | 一种耐候高抗冲聚苯乙烯材料及其制备方法 |
CN102275317A (zh) * | 2011-08-12 | 2011-12-14 | 重庆和泰塑胶有限公司 | 流延膜三级拉伸工艺 |
CN102380918A (zh) * | 2010-09-03 | 2012-03-21 | 中化蓝天集团有限公司 | 一种聚氟乙烯薄膜边角料回收技术 |
CN104530581A (zh) * | 2014-12-26 | 2015-04-22 | 深圳永合高分子材料有限公司 | 黄色聚苯乙烯片材及其制造方法 |
CN105623133A (zh) * | 2014-10-30 | 2016-06-01 | 中国石油化工股份有限公司 | 双向拉伸聚苯乙烯组合物、制备方法及应用 |
CN107446256A (zh) * | 2017-09-12 | 2017-12-08 | 贵州通汇塑料科技有限公司 | 一种增韧聚苯乙烯填充母料及其制备方法 |
CN113276377A (zh) * | 2021-05-26 | 2021-08-20 | 广东工业大学 | 一种高强高韧聚苯乙烯薄膜的制备方法 |
CN114085320A (zh) * | 2021-12-06 | 2022-02-25 | 宁波大学 | 一种改性丁苯橡胶的制备方法 |
US11807746B2 (en) | 2021-08-05 | 2023-11-07 | Industrial Technology Research Institute | Impact-resistant polystyrene resin |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004182849A (ja) * | 2002-12-03 | 2004-07-02 | Asahi Kasei Life & Living Corp | スチレン系樹脂フィルム |
CN1321151C (zh) * | 2005-06-03 | 2007-06-13 | 广东华业包装材料有限公司 | 一种双向拉伸聚苯乙烯薄膜的生产方法 |
-
2007
- 2007-11-08 CN CN2007100313684A patent/CN101186713B/zh not_active Expired - Fee Related
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102380918A (zh) * | 2010-09-03 | 2012-03-21 | 中化蓝天集团有限公司 | 一种聚氟乙烯薄膜边角料回收技术 |
CN102380918B (zh) * | 2010-09-03 | 2014-03-12 | 中化蓝天集团有限公司 | 一种聚氟乙烯薄膜边角料回收技术 |
CN102115571A (zh) * | 2010-12-30 | 2011-07-06 | 佛山市顺德区圆融新材料有限公司 | 一种耐候高抗冲聚苯乙烯材料及其制备方法 |
CN102275317A (zh) * | 2011-08-12 | 2011-12-14 | 重庆和泰塑胶有限公司 | 流延膜三级拉伸工艺 |
CN102275317B (zh) * | 2011-08-12 | 2014-04-23 | 重庆和泰塑胶有限公司 | 流延膜三级拉伸工艺 |
CN105623133A (zh) * | 2014-10-30 | 2016-06-01 | 中国石油化工股份有限公司 | 双向拉伸聚苯乙烯组合物、制备方法及应用 |
CN105623133B (zh) * | 2014-10-30 | 2018-12-28 | 中国石油化工股份有限公司 | 双向拉伸聚苯乙烯组合物、制备方法及应用 |
CN104530581A (zh) * | 2014-12-26 | 2015-04-22 | 深圳永合高分子材料有限公司 | 黄色聚苯乙烯片材及其制造方法 |
CN107446256A (zh) * | 2017-09-12 | 2017-12-08 | 贵州通汇塑料科技有限公司 | 一种增韧聚苯乙烯填充母料及其制备方法 |
CN107446256B (zh) * | 2017-09-12 | 2020-07-21 | 江苏中信国安新材料有限公司 | 一种增韧聚苯乙烯填充母料及其制备方法 |
CN113276377A (zh) * | 2021-05-26 | 2021-08-20 | 广东工业大学 | 一种高强高韧聚苯乙烯薄膜的制备方法 |
US11807746B2 (en) | 2021-08-05 | 2023-11-07 | Industrial Technology Research Institute | Impact-resistant polystyrene resin |
CN114085320A (zh) * | 2021-12-06 | 2022-02-25 | 宁波大学 | 一种改性丁苯橡胶的制备方法 |
CN114085320B (zh) * | 2021-12-06 | 2023-05-12 | 宁波大学 | 一种改性丁苯橡胶的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN101186713B (zh) | 2010-08-11 |
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GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Method for manufacturing polystyrene window film Effective date of registration: 20150215 Granted publication date: 20100811 Pledgee: Bank of Communications Ltd Chaozhou branch Pledgor: Huaye Packing Materials Co., Ltd., Guangdong Registration number: 2015990000151 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20210120 Granted publication date: 20100811 Pledgee: Bank of Communications Ltd Chaozhou branch Pledgor: GUANGDONG HUAYE PACKING MATERIAL Co.,Ltd. Registration number: 2015990000151 |
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