CN101107317B - 阻燃热塑性组合物及包含它的制品 - Google Patents
阻燃热塑性组合物及包含它的制品 Download PDFInfo
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- CN101107317B CN101107317B CN200680003285.8A CN200680003285A CN101107317B CN 101107317 B CN101107317 B CN 101107317B CN 200680003285 A CN200680003285 A CN 200680003285A CN 101107317 B CN101107317 B CN 101107317B
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- weight
- phosphoric acid
- organophosphate
- acid salt
- amount
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 187
- 239000003063 flame retardant Substances 0.000 title claims abstract description 141
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 101
- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 99
- 239000004416 thermosoftening plastic Substances 0.000 title claims abstract description 99
- 150000003016 phosphoric acids Chemical class 0.000 claims abstract description 70
- 229910000000 metal hydroxide Inorganic materials 0.000 claims abstract description 66
- 150000004692 metal hydroxides Chemical class 0.000 claims abstract description 66
- 229920000137 polyphosphoric acid Polymers 0.000 claims abstract description 36
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 24
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 21
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 claims abstract description 20
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims abstract description 18
- 150000001408 amides Chemical class 0.000 claims abstract description 17
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims abstract description 15
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims abstract description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 77
- 229920001577 copolymer Polymers 0.000 claims description 54
- 239000004609 Impact Modifier Substances 0.000 claims description 43
- 229920000098 polyolefin Polymers 0.000 claims description 36
- -1 aryl alkene Chemical class 0.000 claims description 30
- 239000004020 conductor Substances 0.000 claims description 29
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 28
- 239000004793 Polystyrene Substances 0.000 claims description 25
- 229920002223 polystyrene Polymers 0.000 claims description 25
- 238000009826 distribution Methods 0.000 claims description 18
- 150000002148 esters Chemical class 0.000 claims description 18
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 14
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 14
- 235000011007 phosphoric acid Nutrition 0.000 claims description 14
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 14
- UZGKAASZIMOAMU-UHFFFAOYSA-N 124177-85-1 Chemical compound NP(=O)=O UZGKAASZIMOAMU-UHFFFAOYSA-N 0.000 claims description 13
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 13
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 13
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 13
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical group CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 12
- 239000004305 biphenyl Substances 0.000 claims description 12
- 235000010290 biphenyl Nutrition 0.000 claims description 11
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 11
- 125000006267 biphenyl group Chemical group 0.000 claims description 10
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 10
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 8
- 239000000347 magnesium hydroxide Substances 0.000 claims description 8
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 8
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 claims description 6
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 4
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 claims description 3
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 3
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 claims description 3
- RWGFKTVRMDUZSP-UHFFFAOYSA-N isopropyl-benzene Natural products CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 claims description 3
- OCKPCBLVNKHBMX-UHFFFAOYSA-N n-butyl-benzene Natural products CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 claims description 3
- 229910021518 metal oxyhydroxide Inorganic materials 0.000 claims 1
- 239000000654 additive Substances 0.000 abstract description 45
- 230000000996 additive effect Effects 0.000 abstract description 43
- 229910019142 PO4 Inorganic materials 0.000 abstract description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 4
- 239000010452 phosphate Substances 0.000 abstract description 4
- 229920000388 Polyphosphate Polymers 0.000 abstract 2
- 239000001205 polyphosphate Substances 0.000 abstract 2
- 235000011176 polyphosphates Nutrition 0.000 abstract 2
- 239000005696 Diammonium phosphate Substances 0.000 abstract 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 abstract 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 abstract 1
- 235000019838 diammonium phosphate Nutrition 0.000 abstract 1
- 235000019837 monoammonium phosphate Nutrition 0.000 abstract 1
- 239000006012 monoammonium phosphate Substances 0.000 abstract 1
- PTMHPRAIXMAOOB-UHFFFAOYSA-N phosphoramidic acid Chemical compound NP(O)(O)=O PTMHPRAIXMAOOB-UHFFFAOYSA-N 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 42
- 150000001875 compounds Chemical class 0.000 description 36
- 239000000463 material Substances 0.000 description 29
- 238000000034 method Methods 0.000 description 18
- 238000002156 mixing Methods 0.000 description 18
- 239000000126 substance Substances 0.000 description 16
- 238000002844 melting Methods 0.000 description 15
- 239000012815 thermoplastic material Substances 0.000 description 15
- 125000003118 aryl group Chemical group 0.000 description 14
- 239000000178 monomer Substances 0.000 description 14
- 229920005989 resin Polymers 0.000 description 14
- 239000011347 resin Substances 0.000 description 14
- 229920001083 polybutene Polymers 0.000 description 13
- 229920002633 Kraton (polymer) Polymers 0.000 description 12
- 229920000092 linear low density polyethylene Polymers 0.000 description 12
- 239000004707 linear low-density polyethylene Substances 0.000 description 12
- 230000008018 melting Effects 0.000 description 12
- 229920001955 polyphenylene ether Polymers 0.000 description 12
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 12
- 125000000217 alkyl group Chemical group 0.000 description 11
- 125000001118 alkylidene group Chemical group 0.000 description 10
- 229920001971 elastomer Polymers 0.000 description 10
- 229920013636 polyphenyl ether polymer Polymers 0.000 description 10
- 239000005060 rubber Substances 0.000 description 10
- 239000004594 Masterbatch (MB) Substances 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 9
- 238000002485 combustion reaction Methods 0.000 description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 9
- 238000012545 processing Methods 0.000 description 9
- PVNUIRUAPVSSOK-UHFFFAOYSA-N tert-butylimino(tripyrrolidin-1-yl)-$l^{5}-phosphane Chemical compound C1CCCN1P(N1CCCC1)(=NC(C)(C)C)N1CCCC1 PVNUIRUAPVSSOK-UHFFFAOYSA-N 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000002131 composite material Substances 0.000 description 8
- 239000011777 magnesium Substances 0.000 description 8
- 230000005012 migration Effects 0.000 description 8
- 238000013508 migration Methods 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 150000003014 phosphoric acid esters Chemical class 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
- 229910019440 Mg(OH) Inorganic materials 0.000 description 6
- 125000004103 aminoalkyl group Chemical group 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
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- 150000001336 alkenes Chemical class 0.000 description 5
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- 229910052736 halogen Inorganic materials 0.000 description 5
- 150000002367 halogens Chemical class 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
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- 239000003607 modifier Substances 0.000 description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
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- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
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- 229920002943 EPDM rubber Polymers 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 238000011109 contamination Methods 0.000 description 4
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- 239000010949 copper Substances 0.000 description 4
- 239000003085 diluting agent Substances 0.000 description 4
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- 125000000524 functional group Chemical group 0.000 description 4
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- 229910052757 nitrogen Inorganic materials 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
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- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
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- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
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- OLFGLCWOBHGNQA-UHFFFAOYSA-N (2-dodecyl-4-methylphenyl) dihydrogen phosphate Chemical compound CCCCCCCCCCCCC1=CC(C)=CC=C1OP(O)(O)=O OLFGLCWOBHGNQA-UHFFFAOYSA-N 0.000 description 1
- BGGGMYCMZTXZBY-UHFFFAOYSA-N (3-hydroxyphenyl) phosphono hydrogen phosphate Chemical compound OC1=CC=CC(OP(O)(=O)OP(O)(O)=O)=C1 BGGGMYCMZTXZBY-UHFFFAOYSA-N 0.000 description 1
- JEFSTMHERNSDBC-UHFFFAOYSA-N 1,2-dimethylcyclohexa-2,4-dien-1-ol Chemical compound CC1=CC=CCC1(C)O JEFSTMHERNSDBC-UHFFFAOYSA-N 0.000 description 1
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- WAEOXIOXMKNFLQ-UHFFFAOYSA-N 1-methyl-4-prop-2-enylbenzene Chemical group CC1=CC=C(CC=C)C=C1 WAEOXIOXMKNFLQ-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- ZNRLMGFXSPUZNR-UHFFFAOYSA-N 2,2,4-trimethyl-1h-quinoline Chemical group C1=CC=C2C(C)=CC(C)(C)NC2=C1 ZNRLMGFXSPUZNR-UHFFFAOYSA-N 0.000 description 1
- GXURZKWLMYOCDX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphite Chemical class OP(O)OP(O)O.OCC(CO)(CO)CO GXURZKWLMYOCDX-UHFFFAOYSA-N 0.000 description 1
- ANUKUXHGGBMTJS-UHFFFAOYSA-N 2,2-dimethylpropyl dihydrogen phosphate Chemical compound CC(C)(C)COP(O)(O)=O ANUKUXHGGBMTJS-UHFFFAOYSA-N 0.000 description 1
- QZRMKGRPCTVXBS-UHFFFAOYSA-N 2,6,8-trimethylnonan-4-yl dihydrogen phosphate Chemical class CC(C)CC(C)CC(CC(C)C)OP(O)(O)=O QZRMKGRPCTVXBS-UHFFFAOYSA-N 0.000 description 1
- PANIBUVGEJDJGE-UHFFFAOYSA-N 2-(2-sulfophenoxy)benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1OC1=CC=CC=C1S(O)(=O)=O PANIBUVGEJDJGE-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 description 1
- YZEZMSPGIPTEBA-UHFFFAOYSA-N 2-n-(4,6-diamino-1,3,5-triazin-2-yl)-1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(NC=2N=C(N)N=C(N)N=2)=N1 YZEZMSPGIPTEBA-UHFFFAOYSA-N 0.000 description 1
- 125000003504 2-oxazolinyl group Chemical group O1C(=NCC1)* 0.000 description 1
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical group N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 description 1
- PZRWFKGUFWPFID-UHFFFAOYSA-N 3,9-dioctadecoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C1OP(OCCCCCCCCCCCCCCCCCC)OCC21COP(OCCCCCCCCCCCCCCCCCC)OC2 PZRWFKGUFWPFID-UHFFFAOYSA-N 0.000 description 1
- WPMYUUITDBHVQZ-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-N 0.000 description 1
- NGAVZFBDWDNHFD-UHFFFAOYSA-N 3-(3-tert-butyl-2-hydroxy-5-methylphenyl)propanoic acid Chemical compound CC1=CC(CCC(O)=O)=C(O)C(C(C)(C)C)=C1 NGAVZFBDWDNHFD-UHFFFAOYSA-N 0.000 description 1
- 125000000590 4-methylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
- BSYNRYMUTXBXSQ-FOQJRBATSA-N 59096-14-9 Chemical compound CC(=O)OC1=CC=CC=C1[14C](O)=O BSYNRYMUTXBXSQ-FOQJRBATSA-N 0.000 description 1
- 108700015862 A-B-A triblock copolymer Proteins 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229920003314 Elvaloy® Polymers 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- CGSLYBDCEGBZCG-UHFFFAOYSA-N Octicizer Chemical compound C=1C=CC=CC=1OP(=O)(OCC(CC)CCCC)OC1=CC=CC=C1 CGSLYBDCEGBZCG-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 229920013623 Solprene Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001263 acyl chlorides Chemical class 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 238000005917 acylation reaction Methods 0.000 description 1
- 239000004596 additive masterbatch Substances 0.000 description 1
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000004414 alkyl thio group Chemical group 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 125000005038 alkynylalkyl group Chemical group 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- RREGISFBPQOLTM-UHFFFAOYSA-N alumane;trihydrate Chemical compound O.O.O.[AlH3] RREGISFBPQOLTM-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical compound [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000008064 anhydrides Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- CUBCNYWQJHBXIY-UHFFFAOYSA-N benzoic acid;2-hydroxybenzoic acid Chemical class OC(=O)C1=CC=CC=C1.OC(=O)C1=CC=CC=C1O CUBCNYWQJHBXIY-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 238000012661 block copolymerization Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 description 1
- 230000006208 butylation Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001869 cobalt compounds Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- MIHINWMALJZIBX-UHFFFAOYSA-N cyclohexa-2,4-dien-1-ol Chemical compound OC1CC=CC=C1 MIHINWMALJZIBX-UHFFFAOYSA-N 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 125000002897 diene group Chemical group 0.000 description 1
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 150000001261 hydroxy acids Chemical group 0.000 description 1
- 230000000415 inactivating effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229920000831 ionic polymer Polymers 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 description 1
- YSRVJVDFHZYRPA-UHFFFAOYSA-N melem Chemical compound NC1=NC(N23)=NC(N)=NC2=NC(N)=NC3=N1 YSRVJVDFHZYRPA-UHFFFAOYSA-N 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 210000002445 nipple Anatomy 0.000 description 1
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 1
- 239000000615 nonconductor Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 125000005461 organic phosphorous group Chemical group 0.000 description 1
- 150000002924 oxiranes Chemical group 0.000 description 1
- AZQWKYJCGOJGHM-UHFFFAOYSA-N para-benzoquinone Natural products O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 1
- 229960000969 phenyl salicylate Drugs 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 229910001392 phosphorus oxide Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003251 poly(α-methylstyrene) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000646 scanning calorimetry Methods 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 150000003527 tetrahydropyrans Chemical class 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
- 125000004665 trialkylsilyl group Chemical group 0.000 description 1
- KYLIMUJRJDIPPF-UHFFFAOYSA-N trisalicylate Chemical compound O=C1OC2=CC=CC=C2C(=O)OC2=CC=CC=C2C(=O)OC2=CC=CC=C12 KYLIMUJRJDIPPF-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Images
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Insulated Conductors (AREA)
- Fireproofing Substances (AREA)
- Inorganic Insulating Materials (AREA)
- Organic Insulating Materials (AREA)
Abstract
Description
组分 | 描述/供应商 |
PPE | 聚(亚苯基醚),其在25℃的氯仿中测量时具有0.46g/dl的特性粘度 |
SEBS I | 聚苯乙烯-聚(乙烯-丁烯)-聚苯乙烯,其聚苯乙烯含量为13重量%,可从Kraton Polymers Ltd以商品名Kraton G 1657买到。 |
SEBS II | 聚苯乙烯-聚(乙烯-丁烯)-聚苯乙烯,其聚苯乙烯含量为30重量%,可从Kraton Polymers Ltd以商品名Kraton G 1650买到。 |
SEBS III | 聚苯乙烯-聚(乙烯-丁烯-苯乙烯)-聚苯乙烯,其聚苯乙烯含量为39重量%,可从Kraton PolymersLtd以商品名Kraton A,规格RP 6936买到。 |
SEBS IV | 聚苯乙烯-聚(乙烯-丁烯)-聚苯乙烯,其聚苯乙烯含量为30重量%,可从Kraton Polymers Ltd以商品名Kraton G 1652买到。 |
SEBS V | 聚苯乙烯-聚(乙烯-丁烯)-聚苯乙烯、乙烯-丙烯共聚物和矿物油的共混物,其可从SumitomoChemical以商品名SB-2400买到。 |
LLDPE | 线型低密度聚乙烯,其可从Nippon Unicar Co.Ltd以商品名NUCG5381买到。 |
聚丁烯I | 聚丁烯,其在100℃具有200-235cSt的粘度,其可从BP Chemical以商品名Indopol,规格H100买到。 |
聚丁烯II | 聚丁烯,其在100℃具有100-115cSt的粘度,其可从BP Chemical以商品名Indopol,规格H50买到。 |
RDP | 间苯二酚双二苯基磷酸酯,其可从Great LakesChemical Co.Ltd.以商品名Reofos RDP买到。 |
MPP | 聚磷酸三聚氰胺,其可从Ciba Specialty ChemicalCo.Ltd以商品名Melapur 200买到。 |
MP | 焦磷酸三聚氰胺,其可从Budenheil以商品名Budit 311MPP买到。 |
Mg(OH)2 | 氢氧化镁,其可从Kyowa Chemical Industry Co.Ltd.以商品名Kisuma 5A买到。 |
BTPP | 丁基化的磷酸三苯酯,其可从Akzo NobelChemical Inc.以商品名Phosflex71B买到。 |
TPP | 磷酸三苯酯,其可从Akzo Nobel Chemical Inc.以商品名Phosflex TPP买到。 |
BPADP | 双酚A双-二苯基磷酸酯,其可从Akzo NobelChemical Inc.以商品名Fyroflex BDP买到。 |
LDPE | 低密度聚乙烯,其可从Nippon Unicar Co.Ltd以商品名NUC8042买到。 |
EVA | 乙烯-乙酸乙烯酯共聚物,其可从Dupont MitsuiPolymer Co Ltd以商品名Elvaloy A710买到。 |
EEA | 乙烯-丙烯酸乙酯共聚物,其可从Nippon UnicarCo.Ltd以商品名NUC8451买到。 |
实施例 | RDP | MPP | Mg(OH)2 | 燃烧时间 | UL94等级 |
1* | 19.3 | 19.3 | 0 | 燃烧 | NA |
2 | 19.3 | 19.3 | 8.3 | 5.5 | V0 |
3 | 19.3 | 19.3 | 13.9 | 1.5 | V0 |
4* | 27.7 | 16.6 | 0 | 燃烧 | NA |
5 | 27.7 | 11.1 | 8.3 | 3.8 | V0 |
6* | 24.9 | 0 | 12.5 | 燃烧 | NA |
7* | 0 | 27.7 | 8.3 | 燃烧 | NA |
8* | 23.8 | 19.1 | 0 | 燃烧 | NA |
9* | 22.2 | 19.4 | 0 | 燃烧 | NA |
实施例 | BTPP | RDP | MPP | Mg(OH)2 | 燃烧时间 | UL94等级 |
10 | 3.9 | 19.3 | 11.4 | 7.7 | 5.2 | V0 |
11 | 0 | 19.3 | 11.4 | 7.7 | 17.4 | V1 |
12 | 0 | 24.4 | 12.8 | 7.7 | 2.9 | V0 |
13 | 0 | 25.7 | 7.7 | 7.7 | 1.9 | V0 |
14 | 6.4 | 19.3 | 11.4 | 11.4 | 24.2 | V1 |
15 | 10.3 | 15.4 | 7.7 | 10.3 | 8.8 | V0 |
实施例 | PE共聚物 | BTPP | RDP | MPP | Mg(OH)2 | 燃烧时间 | UL94等级 |
16 | LDPE | 8.0 | 12.0 | 5.0 | 7.0 | 3.4 | V0 |
17 | LLDPE | 8.0 | 12.0 | 5.0 | 7.0 | 9.5 | V1 |
18 | EEA | 8.0 | 12.0 | 5.0 | 7.0 | 3.1 | V0 |
19 | EVA | 8.0 | 12.0 | 5.0 | 7.0 | 12.3 | V2 |
实施例 | PPE | SEBS I | SEBS II | LLDPE | EEA | LDPE | PB | MPP | Mg(OH)2 | BTPP | RDP |
21 | 25.2 | 29.1 | - | - | 13.6 | - | 2.9 | 4.9 | 6.8 | 7.8 | 9.7 |
22 | 25.9 | 23.5 | 3.0 | - | 14.3 | - | 2.7 | 5.4 | 7.0 | 7.1 | 10.7 |
23 | 25.0 | 25.5 | 3.8 | - | 10.6 | - | 2.9 | 5.3 | 7.7 | 7.7 | 11.5 |
24 | 25.2 | 26.2 | 1.9 | - | 14.6 | - | 2.9 | 4.9 | 5.8 | 8.7 | 9.7 |
25 | 25.2 | 26.2 | 1.9 | 2.9 | 14.6 | - | - | 4.9 | 5.8 | 8.7 | 9.7 |
26 | 25.2 | 28.2 | - | - | 17.5 | - | - | 5.3 | 5.3 | 8.7 | 9.7 |
27 | 30.8 | 21.5 | - | 15.0 | - | - | 2.8 | 5.6 | 5.6 | - | 18.7 |
28 | 26.1 | 23.4 | - | 17.1 | - | - | 2.7 | 8.1 | 4.5 | 4.5 | 13.5 |
29 | 32.0 | 35.0 | - | - | 5.0 | - | - | 5.0 | 6.0 | - | 17.0 |
30 | 35.0 | 20.0 | - | - | 17.0 | - | - | 5.0 | 6.0 | - | 17.0 |
31 | 35.0 | 22.0 | 10.0 | - | 5.0 | - | - | 5.0 | 6.0 | - | 17.0 |
32 | 26.0 | 27.0 | - | - | - | 14.0 | 2.0 | 5.0 | 6.0 | 9.0 | 11.0 |
33 | 25.1 | 28.2 | - | - | 14.6 | - | 2.9 | 4.9 | 6.8 | 7.8 | 9.7 |
实施例 | 抗拉强度(MPa) | 拉伸伸长率(%) | 挠曲模量(MPa) | 肖氏硬度(Shore A) | UL94V等级 |
21 | 8.7 | 173 | 81 | 82 | V1 |
22 | 12.4 | 179 | 257 | 88 | V1 |
23 | 11.3 | 192 | 246 | 88 | V1 |
24 | 11.0 | 187 | 150 | 85 | V0 |
25 | 11.2 | 175 | 214 | 89 | V0 |
26 | 10.7 | 164 | 196 | 87 | V1 |
27 | 13.9 | 114 | 328 | 92 | V1 |
28 | 9.5 | 155 | 161 | 88 | V1 |
29 | 14.3 | 175 | 310 | 91 | V1 |
30 | 17.6 | 103 | 530 | 95 | V0 |
31 | 18.1 | 105 | 666 | 97 | V0 |
32 | 13.4 | 163 | 322 | 91 | V0 |
33 | 9.0 | 170 | 102 | 83 | V1 |
实施例 | PPE | SEBSIII | EEA | LLDPE | PB | MPP | Mg(OH)2 | RDP |
34 | 19.0 | 30.0 | - | 19.0 | 6.0 | 5.0 | 6.0 | 15.0 |
35 | 25.8 | 28.3 | 12.9 | - | 5.3 | 4.8 | 5.7 | 17.2 |
36 | 23.0 | 31.1 | 12.9 | - | 5.3 | 4.8 | 5.7 | 17.2 |
37 | 25.8 | 31.1 | 10.1 | - | 5.3 | 4.8 | 5.7 | 17.2 |
实施例 | 抗拉强度(MPa) | 拉伸伸长率(%) | 挠曲模量(MPa) | 肖氏硬度(Shore A) | UL94V等级 |
34 | 13.8 | 292 | 210- | 89 | V1 |
35 | 15.8 | 227 | 306 | 92 | V0 |
36 | 13.5 | 279 | 235 | 89 | V0 |
37 | 15.9 | 224 | 290 | 91 | V0 |
实施例 | PPE | SEBS1 | SEBSIV | SEBSIII | EEA | LLDPE | PB | MPP | Mg(OH)2 | RDP |
38 | 20.0 | - | - | 29.0 | - | 18.0 | 7.0 | 5.0 | 6.0 | 15.0 |
39 | 29.0 | 5.0 | - | 27.0 | 10.0 | - | 6.5 | 4.0 | 4.5 | 14.0 |
40 | 31.7 | 26.2 | - | - | - | 13.4 | 2.0 | 54 | 5.4 | 15.8 |
41 | 35.3 | 28.7 | 3.9 | - | - | 3.9 | 2.9 | 4.0 | 4.6 | 16.7 |
42 | 30.5 | 11.0 | - | 20.0 | 6.5 | - | 6.0 | 5.0 | 5.0 | 16.0 |
实施例 | 抗拉强度(MPa) | 拉伸伸长率(%) | 挠曲模量(MPa) | 肖氏硬度(ShoreA) | UL94V等级 | 涂层抗拉强度 | 断裂伸长率(%) | UL1581VW-1 |
38 | 13.5 | 245 | 195 | 89 | V1 | 14.7 | 260 | 通过 |
39 | 13.4 | 170 | 117 | 84 | V2 | 21.0 | 245 | 通过 |
40 | 14.2 | 125 | 210 | 89 | V0 | 16.4 | 134 | 通过 |
41 | 16.5 | 110 | 300 | 91 | V0 | 20.0 | 165 | 通过 |
42 | 15.0 | 120 | 227 | 90 | V0 | 18.9 | 193 | 通过 |
Claims (20)
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US11/091,277 | 2005-03-28 | ||
US11/091,277 US7417083B2 (en) | 2004-04-01 | 2005-03-28 | Flame retardant composition |
US11/291,467 US7582692B2 (en) | 2004-04-01 | 2005-11-30 | Flame retardant thermoplastic composition and articles comprising the same |
US11/291,467 | 2005-11-30 | ||
PCT/US2006/010462 WO2006104811A1 (en) | 2005-03-28 | 2006-03-21 | Flame retardant thermoplastic composition and articles comprising the same |
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WO2011011921A1 (en) * | 2009-07-31 | 2011-02-03 | Dow Global Technologies Inc. | Flame retardant thermoplastic elastomer |
JP5529551B2 (ja) * | 2009-10-06 | 2014-06-25 | 住友電気工業株式会社 | 絶縁チューブ及び熱収縮チューブ |
JP5556183B2 (ja) * | 2009-10-06 | 2014-07-23 | 住友電気工業株式会社 | 難燃性樹脂組成物及びそれを用いた絶縁電線、フラットケーブル、成形品 |
US20130065051A1 (en) * | 2010-04-14 | 2013-03-14 | Given Jing Chen | Styrenic Block Copolymer-Based Composition with Enhanced Flame-Retardant Properties |
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CN102807877A (zh) * | 2012-07-18 | 2012-12-05 | 苏州萃智新技术开发有限公司 | 一种防腐阻燃剂 |
CN102775998A (zh) * | 2012-07-19 | 2012-11-14 | 苏州萃智新技术开发有限公司 | 一种环保阻燃剂 |
JP6319870B2 (ja) * | 2013-09-06 | 2018-05-09 | Dic株式会社 | 光ファイバコードまたは光ファイバケーブルおよびそれらに用いられる非ハロゲン系難燃性樹脂組成物 |
KR20150102715A (ko) * | 2014-02-28 | 2015-09-07 | 주식회사 엘지화학 | 난연성 열가소성 수지 조성물 및 이를 포함하는 전선 |
EP3372645B1 (en) * | 2015-11-06 | 2020-02-05 | Asahi Kasei Kabushiki Kaisha | Poly(phenylene ether) flame-retardant resin composition |
KR101729075B1 (ko) * | 2015-11-12 | 2017-04-21 | 주식회사 케이씨씨 | 발포성 내화도료 조성물 |
CN106832884A (zh) * | 2017-01-22 | 2017-06-13 | 江苏欣润塑胶有限公司 | 一种无卤素阻燃tpu |
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