CN101060927B - 二氧化钛混合物在生产催化剂中的用途 - Google Patents

二氧化钛混合物在生产催化剂中的用途 Download PDF

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Publication number
CN101060927B
CN101060927B CN2005800395594A CN200580039559A CN101060927B CN 101060927 B CN101060927 B CN 101060927B CN 2005800395594 A CN2005800395594 A CN 2005800395594A CN 200580039559 A CN200580039559 A CN 200580039559A CN 101060927 B CN101060927 B CN 101060927B
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China
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weight
titanium dioxide
catalyst
anatase
surface area
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Expired - Fee Related
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CN2005800395594A
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Chinese (zh)
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CN101060927A (zh
Inventor
S·内托
S·施特克
J·齐尔克
F·罗索夫斯基
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BASF SE
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BASF SE
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0232—Coating by pulverisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Furan Compounds (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN2005800395594A 2004-11-18 2005-11-16 二氧化钛混合物在生产催化剂中的用途 Expired - Fee Related CN101060927B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102004055807.8 2004-11-18
DE102004055807 2004-11-18
PCT/EP2005/012283 WO2006053732A1 (de) 2004-11-18 2005-11-16 Verwendung von titandioxidgemischen zur herstellung von katalysatoren

Publications (2)

Publication Number Publication Date
CN101060927A CN101060927A (zh) 2007-10-24
CN101060927B true CN101060927B (zh) 2011-05-11

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CN2005800395594A Expired - Fee Related CN101060927B (zh) 2004-11-18 2005-11-16 二氧化钛混合物在生产催化剂中的用途

Country Status (10)

Country Link
US (1) US7851398B2 (https=)
EP (1) EP1814660A1 (https=)
JP (1) JP5174462B2 (https=)
KR (1) KR101308197B1 (https=)
CN (1) CN101060927B (https=)
BR (1) BRPI0517850A (https=)
MX (1) MX2007005850A (https=)
RU (1) RU2007122282A (https=)
TW (1) TWI378823B (https=)
WO (1) WO2006053732A1 (https=)

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DE10334132A1 (de) 2003-07-25 2005-04-07 Basf Ag Silber, Vanadium und ein Promotormetall enthaltendes Multimetalloxid und dessen Verwendung
US8097558B2 (en) * 2004-05-29 2012-01-17 Sud-Chemie Ag Catalyst and method for producing phthalic anhydride
DE102004026472A1 (de) * 2004-05-29 2005-12-22 Süd-Chemie AG Mehrlagen-Katalysator zur Herstellung von Phthalsäureanhydrid
DE102005009473A1 (de) * 2005-03-02 2006-09-07 Süd-Chemie AG Mehrlagen-Katalysator zur Herstellung von Phthalsäureanhydrid
CN101090769B (zh) * 2005-03-02 2011-09-28 苏德-化学股份公司 用于制备邻苯二甲酸酐的多层催化剂的生产方法
US7968491B2 (en) * 2005-05-22 2011-06-28 Sud-Chemie Ag Multi-layer catalyst for producing phthalic anhydride
JP2009533211A (ja) * 2006-04-12 2009-09-17 ビーエーエスエフ ソシエタス・ヨーロピア カルボン酸及び／又はカルボン酸無水物を製造するための触媒系
DE102008011011A1 (de) * 2008-02-01 2009-08-06 Breimair, Josef, Dr. Katalysator für die katalytische Gasphasenoxidation von aromatischen Kohlenwasserstoffen zu Aldehyden, Carbonsäuren und/oder Carbonsäureanhydriden, insbesondere zu Phthalsäureanhydrid
CN102811808A (zh) * 2010-03-19 2012-12-05 巴斯夫欧洲公司 基于贫硫和钙的二氧化钛的气相氧化用催化剂
US20110230668A1 (en) * 2010-03-19 2011-09-22 Basf Se Catalyst for gas phase oxidations based on low-sulfur and low-calcium titanium dioxide
DE112011102205A5 (de) * 2010-06-30 2013-06-27 Basf Se Mehrlagenkatalysator zur Herstellung von Phthalsäureanhydrid und Verfahren zur Herstellung von Phthalsäureanhydrid
US8652988B2 (en) * 2011-04-27 2014-02-18 Celanese International Corporation Catalyst for producing acrylic acids and acrylates
US8642498B2 (en) * 2011-05-11 2014-02-04 Celanese International Corporation Catalysts for producing acrylic acids and acrylates
US8883672B2 (en) * 2011-09-16 2014-11-11 Eastman Chemical Company Process for preparing modified V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids
WO2013137935A1 (en) * 2012-03-13 2013-09-19 Celanese International Corporation Catalyst for producing acrylic acids and acrylates comprising vanadium, titanium and tungsten
DE102013000648A1 (de) * 2013-01-16 2014-07-17 Clariant International Ltd. Verfahren zur Optimierung der Aktivmassenbeladung eines Phthalsäureanhydrid-Katalysators
US9656983B2 (en) 2013-06-26 2017-05-23 Basf Se Process for starting up a gas phase oxidation reactor

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0539878A2 (en) * 1991-10-25 1993-05-05 Nippon Shokubai Co., Ltd. Method for production of phthalic anhydride by vapor-phase oxidation of mixture of ortho-xylene with naphthalene
EP0985648A1 (en) * 1996-10-23 2000-03-15 Nippon Steel Chemical Co., Ltd. Gas-phase oxidization process and process for the preparation of phthalic anhydride
CN1248929A (zh) * 1997-02-27 2000-03-29 巴斯福股份公司 邻苯二甲酸酐的制备方法及用于此的含钛－钒－铯的涂覆催化剂
CN1280979A (zh) * 1999-06-24 2001-01-24 株式会社日本触媒 用于生产邻苯二甲酸酐的方法

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DE2005969A1 (en) 1970-02-10 1971-08-26 Badische Anilin & Soda Fabrik AG, 6700 Ludwigshafen Dicarboxylic acids/and acid anhydridespreparation by isothe - process
DE2106796C3 (de) 1971-02-12 1981-09-24 Wacker-Chemie GmbH, 8000 München Verfahren zur Herstellung Festbettkatalysatoren mit einem Überzug aus Vanadiumpentoxid und Titandioxid
DE2925682A1 (de) * 1979-06-26 1981-01-29 Basf Ag Vanadinpentoxid, titandioxid, phosphor, rubidium und/oder caesium und ggf. zirkondioxid enthaltender traegerkatalysator
DE3114492A1 (de) * 1981-04-10 1982-10-28 Degussa Ag, 6000 Frankfurt Zahnpflegemittel
JPS63253080A (ja) * 1987-04-10 1988-10-20 Nippon Steel Chem Co Ltd 無水フタル酸の製造方法
FR2678807A1 (fr) * 1991-07-09 1993-01-15 Rhone Poulenc Chimie Melanges aqueux homogenes, stables et versables et utilisation desdits melanges pour preparer des dispersions de substances insolubles dans l'eau.
US5235071A (en) * 1991-07-10 1993-08-10 Nippon Shokubai Co., Ltd. Catalyst for producing phthalic anhydride and process by using the same
DE19519172A1 (de) 1995-05-24 1996-11-28 Consortium Elektrochem Ind Trägerkatalysator für Gasphasenoxidationsreaktoren
SE9700655L (sv) 1997-02-25 1998-05-11 Neste Oy Förfarande för framställning av ftalsyraanhydrid
DE19823262A1 (de) * 1998-05-26 1999-12-02 Basf Ag Verfahren zur Herstellung von Phthalsäureanhydrid
DE19824532A1 (de) * 1998-06-03 1999-12-09 Basf Ag Verfahren zur Herstellung von Schalenkatalysatoren für die katalytische Gasphasenoxidation von aromatischen Kohlenwasserstoffen und so erhältliche Katalysatoren
DE19839001A1 (de) * 1998-08-27 2000-03-02 Basf Ag Schalenkatalysatoren für die katalytische Gasphasenoxidation von aromatischen Kohlenwasserstoffen
JP4180316B2 (ja) * 2002-07-05 2008-11-12 日揮触媒化成株式会社 管状酸化チタン粒子および管状酸化チタン粒子の製造方法
DE10323818A1 (de) * 2003-05-23 2004-12-09 Basf Ag Katalysatorsysteme zur Herstellung von Phthalsäureanhydrid
DE10323817A1 (de) * 2003-05-23 2004-12-09 Basf Ag Verfahren zur Herstellung von Phthalsäureanhydrid
DE10323461A1 (de) 2003-05-23 2004-12-09 Basf Ag Herstellung von Aldehyden, Carbonsäuren und/oder Carbonsäureanhydriden mittels Vanadiumoxid, Titandioxid und Antimonoxid enthaltender Katalysatoren
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Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0539878A2 (en) * 1991-10-25 1993-05-05 Nippon Shokubai Co., Ltd. Method for production of phthalic anhydride by vapor-phase oxidation of mixture of ortho-xylene with naphthalene
EP0985648A1 (en) * 1996-10-23 2000-03-15 Nippon Steel Chemical Co., Ltd. Gas-phase oxidization process and process for the preparation of phthalic anhydride
CN1248929A (zh) * 1997-02-27 2000-03-29 巴斯福股份公司 邻苯二甲酸酐的制备方法及用于此的含钛－钒－铯的涂覆催化剂
CN1280979A (zh) * 1999-06-24 2001-01-24 株式会社日本触媒 用于生产邻苯二甲酸酐的方法

Also Published As

Publication number Publication date
KR20070086369A (ko) 2007-08-27
RU2007122282A (ru) 2008-12-27
JP5174462B2 (ja) 2013-04-03
WO2006053732A1 (de) 2006-05-26
JP2008520418A (ja) 2008-06-19
EP1814660A1 (de) 2007-08-08
TW200626232A (en) 2006-08-01
TWI378823B (en) 2012-12-11
US7851398B2 (en) 2010-12-14
BRPI0517850A (pt) 2008-10-21
CN101060927A (zh) 2007-10-24
US20080064594A1 (en) 2008-03-13
KR101308197B1 (ko) 2013-09-13
MX2007005850A (es) 2007-06-15

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