CN101054187A - 一种废弃锌锰电池的选择性挥发回收工艺及其回收系统 - Google Patents
一种废弃锌锰电池的选择性挥发回收工艺及其回收系统 Download PDFInfo
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- CN101054187A CN101054187A CNA200710073916XA CN200710073916A CN101054187A CN 101054187 A CN101054187 A CN 101054187A CN A200710073916X A CNA200710073916X A CN A200710073916XA CN 200710073916 A CN200710073916 A CN 200710073916A CN 101054187 A CN101054187 A CN 101054187A
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- zinc
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- manganese
- battery
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- WJZHMLNIAZSFDO-UHFFFAOYSA-N manganese zinc Chemical compound [Mn].[Zn] WJZHMLNIAZSFDO-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 239000002699 waste material Substances 0.000 title claims abstract description 45
- 238000011084 recovery Methods 0.000 title claims abstract description 39
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims abstract description 38
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000011701 zinc Substances 0.000 claims abstract description 33
- 238000010438 heat treatment Methods 0.000 claims abstract description 30
- 239000000463 material Substances 0.000 claims abstract description 29
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000002253 acid Substances 0.000 claims abstract description 27
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 26
- 238000001816 cooling Methods 0.000 claims abstract description 25
- 239000007787 solid Substances 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 238000009833 condensation Methods 0.000 claims abstract description 21
- 230000005494 condensation Effects 0.000 claims abstract description 21
- 239000002344 surface layer Substances 0.000 claims abstract description 21
- 235000019270 ammonium chloride Nutrition 0.000 claims abstract description 19
- 229940099596 manganese sulfate Drugs 0.000 claims abstract description 18
- 239000011702 manganese sulphate Substances 0.000 claims abstract description 18
- 235000007079 manganese sulphate Nutrition 0.000 claims abstract description 18
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims abstract description 18
- 238000005406 washing Methods 0.000 claims abstract description 17
- 238000000197 pyrolysis Methods 0.000 claims abstract description 16
- 239000003513 alkali Substances 0.000 claims abstract description 14
- 238000000926 separation method Methods 0.000 claims abstract description 14
- 239000011572 manganese Substances 0.000 claims abstract description 13
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 12
- AMWRITDGCCNYAT-UHFFFAOYSA-L manganese oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims abstract description 11
- 238000004090 dissolution Methods 0.000 claims abstract description 10
- 238000004821 distillation Methods 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 10
- 239000011787 zinc oxide Substances 0.000 claims abstract description 10
- 238000001556 precipitation Methods 0.000 claims abstract description 9
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 239000012141 concentrate Substances 0.000 claims abstract description 7
- 230000003647 oxidation Effects 0.000 claims abstract description 7
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 7
- 239000007789 gas Substances 0.000 claims description 72
- 238000000034 method Methods 0.000 claims description 38
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 30
- 229910052799 carbon Inorganic materials 0.000 claims description 28
- 239000007788 liquid Substances 0.000 claims description 22
- 230000008569 process Effects 0.000 claims description 22
- 239000000126 substance Substances 0.000 claims description 21
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 15
- 239000003546 flue gas Substances 0.000 claims description 14
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 11
- 229910052753 mercury Inorganic materials 0.000 claims description 11
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- 238000001914 filtration Methods 0.000 claims description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- 239000000428 dust Substances 0.000 claims description 6
- 230000009467 reduction Effects 0.000 claims description 6
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- 230000001590 oxidative effect Effects 0.000 claims description 4
- 239000013049 sediment Substances 0.000 claims description 4
- 239000010926 waste battery Substances 0.000 claims description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical group O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 3
- 229910002090 carbon oxide Inorganic materials 0.000 claims description 3
- 239000003638 chemical reducing agent Substances 0.000 claims description 3
- 238000002485 combustion reaction Methods 0.000 claims description 3
- 230000005484 gravity Effects 0.000 claims description 3
- 235000011837 pasties Nutrition 0.000 claims description 3
- 230000001376 precipitating effect Effects 0.000 claims description 3
- 238000001514 detection method Methods 0.000 claims description 2
- 239000007800 oxidant agent Substances 0.000 claims description 2
- 230000000149 penetrating effect Effects 0.000 claims description 2
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical compound [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 claims description 2
- 238000005336 cracking Methods 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 30
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical group [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 238000004064 recycling Methods 0.000 description 9
- 229910052748 manganese Inorganic materials 0.000 description 8
- 229960001296 zinc oxide Drugs 0.000 description 8
- 238000005868 electrolysis reaction Methods 0.000 description 7
- 239000003792 electrolyte Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- OQVYMXCRDHDTTH-UHFFFAOYSA-N 4-(diethoxyphosphorylmethyl)-2-[4-(diethoxyphosphorylmethyl)pyridin-2-yl]pyridine Chemical compound CCOP(=O)(OCC)CC1=CC=NC(C=2N=CC=C(CP(=O)(OCC)OCC)C=2)=C1 OQVYMXCRDHDTTH-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 150000002697 manganese compounds Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000007773 negative electrode material Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000007774 positive electrode material Substances 0.000 description 2
- 239000012286 potassium permanganate Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000011112 process operation Methods 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- 241000271510 Agkistrodon contortrix Species 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 239000011335 coal coke Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
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- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
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- 230000006872 improvement Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 238000007885 magnetic separation Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- PPNAOCWZXJOHFK-UHFFFAOYSA-N manganese(2+);oxygen(2-) Chemical class [O-2].[Mn+2] PPNAOCWZXJOHFK-UHFFFAOYSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000010742 number 1 fuel oil Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
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- 238000011069 regeneration method Methods 0.000 description 1
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- 239000000779 smoke Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
- SZKTYYIADWRVSA-UHFFFAOYSA-N zinc manganese(2+) oxygen(2-) Chemical compound [O--].[O--].[Mn++].[Zn++] SZKTYYIADWRVSA-UHFFFAOYSA-N 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
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- Primary Cells (AREA)
- Processing Of Solid Wastes (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Abstract
Description
本发明实施例序号 | 一 | 二 | 三 |
主要工艺条件 | T0:50℃,T1:150℃,T2;360,T3:1000℃,N 40%,T4:390℃,T5:80℃,X:2.5小时, | T0:60℃,T1:450℃,T2;380,T3:1100℃,N 45%,T4:280℃,T5:95℃,X:3.5小时, | T0:80℃,T1:600℃,T2;390,T3:1300℃,N 35%,T4:185℃,T5:85℃,X:4.5小时, |
中温干馏气体得汞纯度 | ≥96% | ≥98% | ≥99% |
中温干馏气体得氯化铵纯度 | ≥85% | ≥85% | ≥85% |
高温干馏气体得锌/氧化锌纯度 | ≥92% | ≥93% | ≥95% |
酸溶得硫酸锰产品纯度 | ≥90% | ≥92% | ≥95% |
Claims (10)
Priority Applications (1)
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CNB200710073916XA CN100480184C (zh) | 2007-04-03 | 2007-04-03 | 一种废弃锌锰电池的选择性挥发回收工艺 |
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CNB200710073916XA CN100480184C (zh) | 2007-04-03 | 2007-04-03 | 一种废弃锌锰电池的选择性挥发回收工艺 |
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Publication Number | Publication Date |
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CN101054187A true CN101054187A (zh) | 2007-10-17 |
CN100480184C CN100480184C (zh) | 2009-04-22 |
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CNB200710073916XA Active CN100480184C (zh) | 2007-04-03 | 2007-04-03 | 一种废弃锌锰电池的选择性挥发回收工艺 |
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Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102136583A (zh) * | 2011-02-14 | 2011-07-27 | 华南师范大学 | 一种废旧碱性锌锰电池负极材料锌粉的再生方法 |
CN104779403A (zh) * | 2015-04-24 | 2015-07-15 | 桂林理工大学 | 应用超声波技术提高废旧锌锰电池中锰浸出率的方法 |
CN107134603A (zh) * | 2017-04-18 | 2017-09-05 | 东北大学 | 一种废锌锰电池的回收利用方法 |
CN107804876A (zh) * | 2017-12-05 | 2018-03-16 | 王龙 | 一种废弃电池中二氧化锰与氯化铵提取装置 |
CN108123144A (zh) * | 2017-12-22 | 2018-06-05 | 横琴国际知识产权交易中心有限公司 | 城市节能环保式社区用智能废干电池回收装置及方法 |
CN108808033A (zh) * | 2018-06-01 | 2018-11-13 | 南京信息工程大学 | 一种利用废旧锌锰电池制备超级电容器电极材料的方法 |
CN110016562A (zh) * | 2019-04-23 | 2019-07-16 | 重庆大学 | 一种脱除电解锰阳极泥中铅的方法 |
CN110092398A (zh) * | 2019-04-23 | 2019-08-06 | 北京科技大学 | 一种废旧锂离子电池焙烧尾气资源化利用的方法 |
CN110402294A (zh) * | 2017-03-15 | 2019-11-01 | 杰富意钢铁株式会社 | 金属锰的制造方法 |
CN110431245A (zh) * | 2017-03-15 | 2019-11-08 | 杰富意钢铁株式会社 | 金属锰的制造方法 |
CN111628234A (zh) * | 2020-05-27 | 2020-09-04 | 云南省能源研究院有限公司 | 一种废旧电池回收系统及其回收方法 |
CN111684634A (zh) * | 2018-02-05 | 2020-09-18 | 微量元素生长有限公司 | 从废旧碱性电池生产微量营养素的方法 |
CN112728941A (zh) * | 2021-01-05 | 2021-04-30 | 长沙有色冶金设计研究院有限公司 | 电池材料焙烧纯化系统 |
CN113564362A (zh) * | 2021-06-28 | 2021-10-29 | 中山大学 | 一种从镍超富集植物中分离回收镍、钴的方法 |
CN113943865A (zh) * | 2021-10-15 | 2022-01-18 | 刘佳杉 | 一种干电池回收环保清理设备及工艺 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT381808B (de) * | 1984-04-10 | 1986-12-10 | Voest Alpine Ag | Verfahren zur rueckgewinnung von zink und mangan aus entladenen zink-kohle-manganoxidbatterien |
CN1120592A (zh) * | 1994-10-08 | 1996-04-17 | 包智香 | 从废干电池中提取锌和二氧化锰的方法 |
CN201038237Y (zh) * | 2007-04-03 | 2008-03-19 | 深圳市格林美高新技术股份有限公司 | 废弃锌锰电池的选择性挥发回收系统 |
-
2007
- 2007-04-03 CN CNB200710073916XA patent/CN100480184C/zh active Active
Cited By (22)
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CN102136583A (zh) * | 2011-02-14 | 2011-07-27 | 华南师范大学 | 一种废旧碱性锌锰电池负极材料锌粉的再生方法 |
CN104779403A (zh) * | 2015-04-24 | 2015-07-15 | 桂林理工大学 | 应用超声波技术提高废旧锌锰电池中锰浸出率的方法 |
CN110431245B (zh) * | 2017-03-15 | 2022-08-12 | 杰富意钢铁株式会社 | 金属锰的制造方法 |
CN110402294A (zh) * | 2017-03-15 | 2019-11-01 | 杰富意钢铁株式会社 | 金属锰的制造方法 |
CN110431245A (zh) * | 2017-03-15 | 2019-11-08 | 杰富意钢铁株式会社 | 金属锰的制造方法 |
CN110402294B (zh) * | 2017-03-15 | 2022-05-03 | 杰富意钢铁株式会社 | 金属锰的制造方法 |
CN107134603A (zh) * | 2017-04-18 | 2017-09-05 | 东北大学 | 一种废锌锰电池的回收利用方法 |
CN107134603B (zh) * | 2017-04-18 | 2019-05-03 | 东北大学 | 一种废锌锰电池的回收利用方法 |
CN107804876A (zh) * | 2017-12-05 | 2018-03-16 | 王龙 | 一种废弃电池中二氧化锰与氯化铵提取装置 |
CN108123144A (zh) * | 2017-12-22 | 2018-06-05 | 横琴国际知识产权交易中心有限公司 | 城市节能环保式社区用智能废干电池回收装置及方法 |
CN111684634A (zh) * | 2018-02-05 | 2020-09-18 | 微量元素生长有限公司 | 从废旧碱性电池生产微量营养素的方法 |
CN111684634B (zh) * | 2018-02-05 | 2024-05-28 | 微量元素生长有限公司 | 从废旧碱性电池生产微量营养素的方法 |
CN108808033A (zh) * | 2018-06-01 | 2018-11-13 | 南京信息工程大学 | 一种利用废旧锌锰电池制备超级电容器电极材料的方法 |
CN110092398A (zh) * | 2019-04-23 | 2019-08-06 | 北京科技大学 | 一种废旧锂离子电池焙烧尾气资源化利用的方法 |
CN110016562A (zh) * | 2019-04-23 | 2019-07-16 | 重庆大学 | 一种脱除电解锰阳极泥中铅的方法 |
CN111628234A (zh) * | 2020-05-27 | 2020-09-04 | 云南省能源研究院有限公司 | 一种废旧电池回收系统及其回收方法 |
CN112728941A (zh) * | 2021-01-05 | 2021-04-30 | 长沙有色冶金设计研究院有限公司 | 电池材料焙烧纯化系统 |
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