CN101024704B - 烷基取代环己烷二羧酸及其衍生物的用途 - Google Patents
烷基取代环己烷二羧酸及其衍生物的用途 Download PDFInfo
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- CN101024704B CN101024704B CN2007100913715A CN200710091371A CN101024704B CN 101024704 B CN101024704 B CN 101024704B CN 2007100913715 A CN2007100913715 A CN 2007100913715A CN 200710091371 A CN200710091371 A CN 200710091371A CN 101024704 B CN101024704 B CN 101024704B
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- mixture
- alkyl
- anhydride
- dicarboxylic acid
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- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical class OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 239000000203 mixture Substances 0.000 claims abstract description 112
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 76
- 150000002148 esters Chemical class 0.000 claims abstract description 57
- 238000000034 method Methods 0.000 claims abstract description 49
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- 239000004033 plastic Substances 0.000 claims abstract description 21
- 238000006243 chemical reaction Methods 0.000 claims description 71
- 125000000217 alkyl group Chemical group 0.000 claims description 62
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- -1 cyclohexane dicarboxylic acid acid anhydride Chemical class 0.000 claims description 28
- 238000005984 hydrogenation reaction Methods 0.000 claims description 28
- 239000004902 Softening Agent Substances 0.000 claims description 20
- 230000001112 coagulating effect Effects 0.000 claims description 18
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 15
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- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 8
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 7
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 4
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 claims description 4
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- YWVFNWVZBAWOOY-UHFFFAOYSA-N 4-methylcyclohexane-1,2-dicarboxylic acid Chemical compound CC1CCC(C(O)=O)C(C(O)=O)C1 YWVFNWVZBAWOOY-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
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- 150000008065 acid anhydrides Chemical class 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 3
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 3
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- GOQYKNQRPGWPLP-UHFFFAOYSA-N heptadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 3
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- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
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- 238000003786 synthesis reaction Methods 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- 229940057402 undecyl alcohol Drugs 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/54—Preparation of carboxylic acid anhydrides
- C07C51/567—Preparation of carboxylic acid anhydrides by reactions not involving carboxylic acid anhydride groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10107366 | 2001-02-16 | ||
| DE10107366.6 | 2001-02-16 | ||
| DE2001131260 DE10131260A1 (de) | 2001-06-29 | 2001-06-29 | Verfahren zur Herstellung von Cyclohexandicarbonsäuren deren Derivaten |
| DE10131260.1 | 2001-06-29 | ||
| DE2001161010 DE10161010A1 (de) | 2001-12-12 | 2001-12-12 | Verfahren zur Herstellung von Cyclohexandicarbonsäuren und deren Derivaten |
| DE10161010.6 | 2001-12-12 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB028050991A Division CN1318372C (zh) | 2001-02-16 | 2002-02-15 | 环己烷二羧酸及其衍生物的制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101024704A CN101024704A (zh) | 2007-08-29 |
| CN101024704B true CN101024704B (zh) | 2010-08-18 |
Family
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Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007100913715A Expired - Fee Related CN101024704B (zh) | 2001-02-16 | 2002-02-15 | 烷基取代环己烷二羧酸及其衍生物的用途 |
| CN200710091372XA Expired - Fee Related CN101024705B (zh) | 2001-02-16 | 2002-02-15 | 环己烷二羧酸及其衍生物的制备方法 |
| CNB028050991A Expired - Fee Related CN1318372C (zh) | 2001-02-16 | 2002-02-15 | 环己烷二羧酸及其衍生物的制备方法 |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200710091372XA Expired - Fee Related CN101024705B (zh) | 2001-02-16 | 2002-02-15 | 环己烷二羧酸及其衍生物的制备方法 |
| CNB028050991A Expired - Fee Related CN1318372C (zh) | 2001-02-16 | 2002-02-15 | 环己烷二羧酸及其衍生物的制备方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7319161B2 (enExample) |
| EP (1) | EP1363868B1 (enExample) |
| JP (1) | JP4898079B2 (enExample) |
| KR (1) | KR100634254B1 (enExample) |
| CN (3) | CN101024704B (enExample) |
| AU (1) | AU2002234635A1 (enExample) |
| ES (1) | ES2657652T3 (enExample) |
| PL (1) | PL207365B1 (enExample) |
| WO (1) | WO2002066412A1 (enExample) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0227087D0 (en) * | 2002-11-20 | 2002-12-24 | Exxonmobil Chem Patents Inc | Hydrogenation of benzene polycarboxylic acids or derivatives thereof |
| DE102004063673A1 (de) * | 2004-12-31 | 2006-07-13 | Oxeno Olefinchemie Gmbh | Verfahren zur kontinuierlichen katalytischen Hydrierung von hydrierbaren Verbindungen an festen, im Festbett angeordneten Katalysatoren mit einem wasserstoffhaltigen Gas |
| US20090149584A1 (en) * | 2006-04-21 | 2009-06-11 | Klemens Massonne | Use of hexahydrophthalimide combinations as softener |
| CN1962736B (zh) * | 2006-11-16 | 2010-10-06 | 南亚塑胶工业股份有限公司 | 一种环己烷-1,2-二羧酸异壬酯增塑剂的制造方法 |
| US20100028528A1 (en) * | 2006-12-19 | 2010-02-04 | Basf Se | Use of cyclohexane polycarbonic acid esters for the production of coating materials for the coil coating method and the production of coated coils |
| CN101990560A (zh) * | 2007-12-21 | 2011-03-23 | 埃克森美孚化学专利公司 | 助增塑剂体系 |
| DE102008001655A1 (de) * | 2008-05-08 | 2009-11-12 | Kuraray Europe Gmbh | Weichmacherhaltige Folien aus Polyvinylacetal mit Cyclohexan-1,2-dicarbon-säureestern als Weichmacher |
| US20100113664A1 (en) * | 2008-06-11 | 2010-05-06 | Ferro Corporation | Asymmetric Cyclic Diester Compounds |
| CN101343381B (zh) * | 2008-08-27 | 2011-12-21 | 南亚塑胶工业股份有限公司 | 一种六氢邻苯二甲酸酯化合物及其制备方法 |
| WO2010148081A2 (en) | 2009-06-16 | 2010-12-23 | Draths Corporation | Novel terephthalic and trimellitic based acids and carboxylate derivatives thereof |
| US8367859B2 (en) | 2009-06-16 | 2013-02-05 | Amyris, Inc. | Cyclohexane 1,4 carboxylates |
| WO2010148070A2 (en) | 2009-06-16 | 2010-12-23 | Draths Corporation | Biobased polyesters |
| US8426639B2 (en) * | 2009-06-16 | 2013-04-23 | Amyris, Inc. | Preparation of trans, trans muconic acid and trans, trans muconates |
| CN101696200B (zh) * | 2009-10-30 | 2011-09-07 | 濮阳惠成化工有限公司 | 内亚甲基六氢邻苯二甲酸酐及其生产方法 |
| MX2012007944A (es) | 2010-01-08 | 2012-08-15 | Amyris Inc | Metodos para producir isomeros de acido muconico y sales de muconato. |
| CN101863768B (zh) * | 2010-05-14 | 2013-06-05 | 中国林业科学研究院林产化学工业研究所 | 半干性油或干性油全质利用制备增塑剂及润滑剂的方法 |
| DE102010061867A1 (de) | 2010-11-24 | 2012-05-24 | Evonik Oxeno Gmbh | Verwendung von Di(isononyl)cyclohexansäureester (DINCH) in verschäumbaren PVC-Formulierungen |
| EP2655511B1 (de) | 2010-12-23 | 2016-04-06 | INEOS Styrolution Europe GmbH | Thermoplastische elastomer-zusammensetzung und verfahren zu deren herstellung |
| WO2012158250A1 (en) | 2011-05-13 | 2012-11-22 | Amyris, Inc. | Plasticizers |
| US20130171385A1 (en) * | 2011-12-29 | 2013-07-04 | Exxonmobil Research And Engineering Company | Reacting cyclopentadiene and maleic anhydride for the production of plasticizers |
| ITMI20120634A1 (it) | 2012-04-17 | 2013-10-18 | Bio On S R L | Composizione comprendente almeno un polimero biodegradabile e almeno un plastificante |
| WO2016099062A1 (ko) * | 2014-12-18 | 2016-06-23 | 한화케미칼 주식회사 | 스트리핑 방법 |
| KR101833982B1 (ko) | 2014-12-18 | 2018-04-13 | 한화케미칼 주식회사 | 스트리핑 방법 |
| EP3405518B1 (de) | 2016-01-20 | 2019-11-06 | Basf Se | Weichmacher-zusammensetzung, die aliphatische dicarbonsäureester und diester, die unter 1,2-cyclohexandicarbonsäureestern und terephthalsäureestern ausgewählt sind, enthält |
| KR102090294B1 (ko) * | 2016-04-22 | 2020-03-17 | 주식회사 엘지화학 | 가소제 조성물 및 이를 포함하는 수지 조성물 |
| JP7242635B2 (ja) * | 2018-03-27 | 2023-03-20 | 出光興産株式会社 | 潤滑油基油、該潤滑油基油を含有する潤滑油組成物、及び該潤滑油組成物を用いた無段変速機 |
| RU2691739C1 (ru) * | 2018-05-08 | 2019-06-18 | Сергей Николаевич Лакеев | Способ получения нефталатного смесевого пластификатора |
| KR102122003B1 (ko) * | 2018-11-26 | 2020-06-11 | 상명대학교산학협력단 | 스크린 타입의 노보난 유도체 화합물, 이의 제조 방법 및 이의 용도 |
| RU2754913C1 (ru) * | 2020-12-08 | 2021-09-08 | Общество с ограниченной ответственностью "Экологичная нефтехимия" | Способ селективного получения экзо,экзо- и эндо,эндо-ди(2-этилгексил)норборнен-2,3-дикарбоксилатов из с5 фракции жидких продуктов пиролиза |
| CN112851920B (zh) * | 2020-12-31 | 2021-12-07 | 东胜化学(上海)有限公司 | 一种醇酸树脂及其制备方法 |
| WO2024256670A1 (de) | 2023-06-15 | 2024-12-19 | Basf Se | Weichmacher-zusammensetzung |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1263296B (de) * | 1963-08-30 | 1968-03-14 | Union Carbide Corp | Weichmachen von Mischpolymerisaten aus AEthylen und Vinylestern |
| DE2823165A1 (de) * | 1978-05-26 | 1979-11-29 | Bayer Ag | Verfahren zur herstellung von cycloaliphatischen carbonsaeureestern |
| CN1099744A (zh) * | 1993-06-15 | 1995-03-08 | 伊斯曼化学公司 | 生产环巳烷二羟酸酯的低压工艺 |
| WO1999032427A1 (de) * | 1997-12-19 | 1999-07-01 | Basf Aktiengesellschaft | Verfahren zur hydrierung von benzolpolycarbonsäuren oder derivaten davon unter verwendung eines makroporen aufweisenden katalysators |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2794811A (en) * | 1954-06-03 | 1957-06-04 | Allied Chem & Dye Corp | Production of cis-cyclohexane-1, 2-dicarboxylic anhydride |
| JP3142651B2 (ja) | 1992-07-14 | 2001-03-07 | 東燃ゼネラル石油株式会社 | 飽和脂環式ジカルボン酸無水物の製造法 |
| JP3106411B2 (ja) * | 1992-12-21 | 2000-11-06 | 東和化成工業株式会社 | １，４−シクロヘキサンジカルボン酸の製造方法 |
| JPH10212285A (ja) | 1997-01-30 | 1998-08-11 | Yuka Shell Epoxy Kk | 無水カルボン酸の製造方法 |
| DE19927978A1 (de) | 1999-06-18 | 2000-12-21 | Basf Ag | Ausgewählte Cyclohexan-1,3- und 1,4-dicarbonsäureester |
| DE19927977A1 (de) * | 1999-06-18 | 2000-12-21 | Basf Ag | Verwendung von Cyclohexanpolycarbonsäuren als Weichmacher zur Herstellung toxikologisch günstig zu bewertender Kunststoffe |
-
2002
- 2002-02-15 CN CN2007100913715A patent/CN101024704B/zh not_active Expired - Fee Related
- 2002-02-15 WO PCT/EP2002/001661 patent/WO2002066412A1/de not_active Ceased
- 2002-02-15 CN CN200710091372XA patent/CN101024705B/zh not_active Expired - Fee Related
- 2002-02-15 ES ES02701282.2T patent/ES2657652T3/es not_active Expired - Lifetime
- 2002-02-15 KR KR1020037010716A patent/KR100634254B1/ko not_active Expired - Fee Related
- 2002-02-15 EP EP02701282.2A patent/EP1363868B1/de not_active Expired - Lifetime
- 2002-02-15 JP JP2002565930A patent/JP4898079B2/ja not_active Expired - Fee Related
- 2002-02-15 PL PL371671A patent/PL207365B1/pl unknown
- 2002-02-15 AU AU2002234635A patent/AU2002234635A1/en not_active Abandoned
- 2002-02-15 US US10/467,234 patent/US7319161B2/en not_active Expired - Fee Related
- 2002-02-15 CN CNB028050991A patent/CN1318372C/zh not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1263296B (de) * | 1963-08-30 | 1968-03-14 | Union Carbide Corp | Weichmachen von Mischpolymerisaten aus AEthylen und Vinylestern |
| DE2823165A1 (de) * | 1978-05-26 | 1979-11-29 | Bayer Ag | Verfahren zur herstellung von cycloaliphatischen carbonsaeureestern |
| CN1099744A (zh) * | 1993-06-15 | 1995-03-08 | 伊斯曼化学公司 | 生产环巳烷二羟酸酯的低压工艺 |
| WO1999032427A1 (de) * | 1997-12-19 | 1999-07-01 | Basf Aktiengesellschaft | Verfahren zur hydrierung von benzolpolycarbonsäuren oder derivaten davon unter verwendung eines makroporen aufweisenden katalysators |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20030078919A (ko) | 2003-10-08 |
| CN101024705B (zh) | 2012-06-20 |
| KR100634254B1 (ko) | 2006-10-16 |
| CN1318372C (zh) | 2007-05-30 |
| JP4898079B2 (ja) | 2012-03-14 |
| US20040054220A1 (en) | 2004-03-18 |
| PL371671A1 (en) | 2005-06-27 |
| EP1363868B1 (de) | 2017-11-01 |
| WO2002066412A1 (de) | 2002-08-29 |
| JP2004538252A (ja) | 2004-12-24 |
| CN1501905A (zh) | 2004-06-02 |
| CN101024704A (zh) | 2007-08-29 |
| PL207365B1 (pl) | 2010-12-31 |
| AU2002234635A1 (en) | 2002-09-04 |
| ES2657652T3 (es) | 2018-03-06 |
| EP1363868A1 (de) | 2003-11-26 |
| US7319161B2 (en) | 2008-01-15 |
| CN101024705A (zh) | 2007-08-29 |
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