CN101023105A - 金属茂化合物、它们制备中使用的配体,1-丁烯聚合物的制备和由此得到的1-丁烯聚合物 - Google Patents

金属茂化合物、它们制备中使用的配体,1-丁烯聚合物的制备和由此得到的1-丁烯聚合物 Download PDF

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Publication number
CN101023105A
CN101023105A CNA200580030481XA CN200580030481A CN101023105A CN 101023105 A CN101023105 A CN 101023105A CN A200580030481X A CNA200580030481X A CN A200580030481XA CN 200580030481 A CN200580030481 A CN 200580030481A CN 101023105 A CN101023105 A CN 101023105A
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China
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formula
alkyl
butylene
compound
randomly
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CNA200580030481XA
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Chinese (zh)
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L·雷斯科尼
F·莫尔哈德
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Basell Polyolefine GmbH
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Basell Polyolefine GmbH
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D495/00Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/02Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D495/04Ortho-condensed systems
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D333/00Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/50Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
    • C07D333/78Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems condensed with rings other than six-membered or with ring systems containing such rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/08Butenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/08Butenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/08Butenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00Metallocene catalysts
    • C08F2420/06Cp analog where at least one of the carbon atoms of the non-coordinating part of the condensed ring is replaced by a heteroatom
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CNA200580030481XA 2004-07-13 2005-05-31 金属茂化合物、它们制备中使用的配体,1-丁烯聚合物的制备和由此得到的1-丁烯聚合物 Pending CN101023105A (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP04103351 2004-07-13
EP04103351.5 2004-07-13
US59066004P 2004-07-23 2004-07-23
US60/590,660 2004-07-23

Publications (1)

Publication Number Publication Date
CN101023105A true CN101023105A (zh) 2007-08-22

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CNA200580030481XA Pending CN101023105A (zh) 2004-07-13 2005-05-31 金属茂化合物、它们制备中使用的配体,1-丁烯聚合物的制备和由此得到的1-丁烯聚合物

Country Status (5)

Country Link
US (1) US8003743B2 (https=)
EP (1) EP1765886A1 (https=)
JP (1) JP5006783B2 (https=)
CN (1) CN101023105A (https=)
WO (1) WO2006005648A1 (https=)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109312130A (zh) * 2016-07-07 2019-02-05 巴塞尔聚烯烃意大利有限公司 具有高熔融流速的1-丁烯聚合物组合物
CN109312129A (zh) * 2016-07-07 2019-02-05 巴塞尔聚烯烃意大利有限公司 具有高熔融流速的1-丁烯聚合物组合物
CN113637036A (zh) * 2016-03-04 2021-11-12 日本聚乙烯株式会社 茂金属化合物、烯烃聚合用催化剂组分和烯烃聚合用催化剂、和生产烯烃聚合物的方法

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005517773A (ja) 2002-02-25 2005-06-16 バセル ポリオレフィン ジーエムビーエイチ エチレンの共重合方法
EP2254946B1 (en) * 2008-03-20 2012-02-01 Basell Poliolefine Italia S.r.l. Compositions of 1-butene based polymers
JP5346075B2 (ja) * 2008-04-22 2013-11-20 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ 1−ブテンターポリマー
JP6264808B2 (ja) * 2013-09-26 2018-01-24 日本ポリプロ株式会社 メタロセン化合物及びそれを使用する重合触媒によるオレフィン重合体の製造方法
US9803037B1 (en) * 2016-05-03 2017-10-31 Exxonmobil Chemical Patents Inc. Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof
US20240034870A1 (en) * 2020-12-16 2024-02-01 Basell Poliolefine Italia S.R.L. Flexible butene-1 copolymer for pipes
IL301347B2 (en) 2023-03-13 2026-04-01 Tadiran Consumer And Tech Products Ltd Apparatus and method for treating air

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE38044T1 (de) 1984-08-30 1988-11-15 Mitsui Petrochemical Ind Buten-1-polymer und seine verwendung.
USH179H (en) * 1984-11-28 1986-12-02 Polybutylene
IL95278A0 (en) 1989-08-03 1991-06-30 Exxon Chemical Patents Inc Very high molecular weight polyethylene
RU2118203C1 (ru) 1990-06-22 1998-08-27 Экксон Кэмикал Пейтентс Инк. Каталитическая система для получения полиолефинов и композиция, используемая для полимеризации олефинов
US6559252B1 (en) 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
AU1870999A (en) 1997-11-12 1999-05-31 Montell Technology Company B.V. Metallocenes and catalysts for olefin-polymerisation
DE19804970A1 (de) * 1998-02-07 1999-08-12 Aventis Res & Tech Gmbh & Co Katalysatorsystem
DE69910511T2 (de) 1998-03-05 2004-06-17 Basell Poliolefine Italia S.P.A. Polybutene-1 (co)polymere und verfahren zu ihrer herstellung
BR0014616A (pt) 1999-09-22 2002-06-18 Basell Technology Co Bv Sistema catalìtico e processo para a polimerização de olefinas
US6444833B1 (en) 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
DE19962910A1 (de) * 1999-12-23 2001-07-05 Targor Gmbh Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
DE19962814A1 (de) 1999-12-23 2001-06-28 Targor Gmbh Neues Katalysatorsystem und dessen Verwendung
DE60029464T2 (de) * 1999-12-28 2007-07-26 Basell Polyolefine Gmbh Verfahren zur herstellung von ethylen polymeren
JP4358470B2 (ja) * 1999-12-28 2009-11-04 バセル テクノロジー カンパニー ビー.ブイ. メタロセン化合物、リガンド、触媒、ポリマーの製造方法及びプロピレンホモポリマー
EP1157046B1 (en) 1999-12-28 2005-12-07 Basell Polyolefine GmbH Process for the preparation of ethylene polymers
DE60103702T2 (de) 2000-02-24 2005-06-23 Basell Polyolefine Gmbh Organometallische Verbindungen die als Cokatalysator bei der Polymerisation von Olefinen verwendet ist
PL353055A1 (en) * 2000-03-22 2003-10-06 Basell Technology Company B.V. Thermoplastic compositions of isotactic propylene polymers and flexible propylene polymers having reduced isotacticity and a process for the preparation thereof
EP1260525B1 (en) 2000-08-22 2012-12-12 Idemitsu Kosan Co., Ltd. 1-butene polymer and molded product consisting of the polymer
JP4332029B2 (ja) 2001-06-12 2009-09-16 バーゼル・ポリオレフィン・ゲーエムベーハー 1−ブテンの重合方法
WO2002100908A1 (en) 2001-06-12 2002-12-19 Basell Polyolefine Gmbh Process for the polymerization of 1-butene
WO2003000706A1 (en) * 2001-06-22 2003-01-03 Basell Polyolefine Gmbh Metallocenes, use in catalyst systems for producing olefin polymers
DE60208683T2 (de) 2001-08-01 2006-11-02 Basell Polyolefine Gmbh Verfahren zur herstellung von heterocyclischen pentalen derivaten
DE60218059T2 (de) * 2001-11-12 2007-08-30 Basell Polyolefine Gmbh Verfahren zur polymerisation von 1-buten und 1-buten polymeren
JP2005517773A (ja) * 2002-02-25 2005-06-16 バセル ポリオレフィン ジーエムビーエイチ エチレンの共重合方法
EP1507806B1 (en) 2002-05-29 2006-10-11 Basell Poliolefine Italia S.r.l. Butene-1 (co)polymers and process for their preparation
KR101060985B1 (ko) 2003-05-12 2011-08-31 바젤 폴리올레핀 게엠베하 1-부텐의 중합 방법
EP1723184A1 (en) * 2004-03-12 2006-11-22 Basell Polyolefine GmbH Process for polymerizing 1-hexene or higher alpha-olefins
JP2008501659A (ja) * 2004-06-04 2008-01-24 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング 遷移金属化合物、リガンド、触媒組成物及びポリオレフィンを製造する方法

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113637036A (zh) * 2016-03-04 2021-11-12 日本聚乙烯株式会社 茂金属化合物、烯烃聚合用催化剂组分和烯烃聚合用催化剂、和生产烯烃聚合物的方法
CN109312130A (zh) * 2016-07-07 2019-02-05 巴塞尔聚烯烃意大利有限公司 具有高熔融流速的1-丁烯聚合物组合物
CN109312129A (zh) * 2016-07-07 2019-02-05 巴塞尔聚烯烃意大利有限公司 具有高熔融流速的1-丁烯聚合物组合物
US10894850B2 (en) 2016-07-07 2021-01-19 Basell Poliolefine Italia S.R.L. Butene-1 polymer composition having a high melt flow rate
US11015090B2 (en) 2016-07-07 2021-05-25 Basell Poliolefine Italia S.R.L. Butene-1 polymer composition having a high melt flow rate
CN109312129B (zh) * 2016-07-07 2022-01-14 巴塞尔聚烯烃意大利有限公司 具有高熔融流速的1-丁烯聚合物组合物
CN109312130B (zh) * 2016-07-07 2022-01-18 巴塞尔聚烯烃意大利有限公司 具有高熔融流速的1-丁烯聚合物组合物

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Publication number Publication date
JP5006783B2 (ja) 2012-08-22
EP1765886A1 (en) 2007-03-28
JP2008506663A (ja) 2008-03-06
US20080139762A1 (en) 2008-06-12
WO2006005648A1 (en) 2006-01-19
US8003743B2 (en) 2011-08-23

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Open date: 20070822