CN101023105A - 金属茂化合物、它们制备中使用的配体,1-丁烯聚合物的制备和由此得到的1-丁烯聚合物 - Google Patents

金属茂化合物、它们制备中使用的配体,1-丁烯聚合物的制备和由此得到的1-丁烯聚合物 Download PDF

Info

Publication number
CN101023105A
CN101023105A CNA200580030481XA CN200580030481A CN101023105A CN 101023105 A CN101023105 A CN 101023105A CN A200580030481X A CNA200580030481X A CN A200580030481XA CN 200580030481 A CN200580030481 A CN 200580030481A CN 101023105 A CN101023105 A CN 101023105A
Authority
CN
China
Prior art keywords
formula
alkyl
butylene
compound
randomly
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA200580030481XA
Other languages
English (en)
Chinese (zh)
Inventor
L·雷斯科尼
F·莫尔哈德
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Basell Polyolefine GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine GmbH filed Critical Basell Polyolefine GmbH
Publication of CN101023105A publication Critical patent/CN101023105A/zh
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D495/00Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/02Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D495/04Ortho-condensed systems
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D333/00Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/50Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
    • C07D333/78Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems condensed with rings other than six-membered or with ring systems containing such rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/08Butenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/08Butenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/08Butenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00Metallocene catalysts
    • C08F2420/06Cp analog where at least one of the carbon atoms of the non-coordinating part of the condensed ring is replaced by a heteroatom
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CNA200580030481XA 2004-07-13 2005-05-31 金属茂化合物、它们制备中使用的配体,1-丁烯聚合物的制备和由此得到的1-丁烯聚合物 Pending CN101023105A (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP04103351.5 2004-07-13
EP04103351 2004-07-13
US59066004P 2004-07-23 2004-07-23
US60/590,660 2004-07-23

Publications (1)

Publication Number Publication Date
CN101023105A true CN101023105A (zh) 2007-08-22

Family

ID=35115855

Family Applications (1)

Application Number Title Priority Date Filing Date
CNA200580030481XA Pending CN101023105A (zh) 2004-07-13 2005-05-31 金属茂化合物、它们制备中使用的配体,1-丁烯聚合物的制备和由此得到的1-丁烯聚合物

Country Status (5)

Country Link
US (1) US8003743B2 (https=)
EP (1) EP1765886A1 (https=)
JP (1) JP5006783B2 (https=)
CN (1) CN101023105A (https=)
WO (1) WO2006005648A1 (https=)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109312130A (zh) * 2016-07-07 2019-02-05 巴塞尔聚烯烃意大利有限公司 具有高熔融流速的1-丁烯聚合物组合物
CN109312129A (zh) * 2016-07-07 2019-02-05 巴塞尔聚烯烃意大利有限公司 具有高熔融流速的1-丁烯聚合物组合物
CN113637036A (zh) * 2016-03-04 2021-11-12 日本聚乙烯株式会社 茂金属化合物、烯烃聚合用催化剂组分和烯烃聚合用催化剂、和生产烯烃聚合物的方法

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005517773A (ja) 2002-02-25 2005-06-16 バセル ポリオレフィン ジーエムビーエイチ エチレンの共重合方法
ATE543870T1 (de) * 2008-03-20 2012-02-15 Basell Poliolefine Srl Zusammensetzungen aus polymeren auf 1-buten-basis
BRPI0910453A2 (pt) * 2008-04-22 2018-03-27 Basell Poliolefine Italia S.R.L terpolímeros de 1-buteno
JP6264808B2 (ja) * 2013-09-26 2018-01-24 日本ポリプロ株式会社 メタロセン化合物及びそれを使用する重合触媒によるオレフィン重合体の製造方法
US9803037B1 (en) * 2016-05-03 2017-10-31 Exxonmobil Chemical Patents Inc. Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof
WO2022128793A1 (en) * 2020-12-16 2022-06-23 Basell Poliolefine Italia S.R.L. Flexible butene-1 copolymer for pipes
IL301347B2 (en) 2023-03-13 2026-04-01 Tadiran Consumer And Tech Products Ltd Apparatus and method for treating air

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3474673D1 (en) 1984-08-30 1988-11-24 Mitsui Petrochemical Ind 1-butene polymer and its use
USH179H (en) * 1984-11-28 1986-12-02 Polybutylene
AU6158390A (en) 1989-08-03 1991-03-11 Exxon Chemical Patents Inc. Very high molecular weight polyethylene
RU2118203C1 (ru) 1990-06-22 1998-08-27 Экксон Кэмикал Пейтентс Инк. Каталитическая система для получения полиолефинов и композиция, используемая для полимеризации олефинов
US6559252B1 (en) 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
JP4540755B2 (ja) 1997-11-12 2010-09-08 バセル テクノロジー カンパニー ベスローテン フェンノートシャップ メタロセンおよびオレフィン重合用の触媒
DE19804970A1 (de) * 1998-02-07 1999-08-12 Aventis Res & Tech Gmbh & Co Katalysatorsystem
EP0980396B2 (en) 1998-03-05 2009-08-19 Basell Poliolefine Italia S.r.l. Polybutene-1 (co)polymers and process for their preparation
BR0014616A (pt) 1999-09-22 2002-06-18 Basell Technology Co Bv Sistema catalìtico e processo para a polimerização de olefinas
US6444833B1 (en) 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
DE19962910A1 (de) 1999-12-23 2001-07-05 Targor Gmbh Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
DE19962814A1 (de) 1999-12-23 2001-06-28 Targor Gmbh Neues Katalysatorsystem und dessen Verwendung
EP1157046B1 (en) * 1999-12-28 2005-12-07 Basell Polyolefine GmbH Process for the preparation of ethylene polymers
US6864333B2 (en) 1999-12-28 2005-03-08 Basel Polyolefine Gmbh Process for the preparation of ethylene polymers
WO2001047939A1 (en) * 1999-12-28 2001-07-05 Basell Technology Company B.V. Heterocyclic metallocene compounds and use thereof in catalyst systems for producing olefin polymers
WO2001062764A1 (en) 2000-02-24 2001-08-30 Basell Technology Company B.V. Organometallic compound useful as cocatalyst for polymerizing olefins
KR20020007419A (ko) * 2000-03-22 2002-01-26 간디 지오프레이 에이치. 이소택틱 프로필렌 중합체 및 감소된 이소택틱성을 갖는유연성 프로필렌 중합체의 열가소성 조성물 및 그 제조방법
EP2264077B1 (en) 2000-08-22 2012-06-13 Idemitsu Kosan Co., Ltd. 1-Butene based polymer and the product formed therefrom
US7459511B2 (en) 2001-06-12 2008-12-02 Basell Polyolefine Gmbh Process for the polymerization of 1-butene
EP1446429B1 (en) 2001-06-12 2009-10-07 Basell Polyolefine GmbH Process for the polymerization of 1-butene
ATE321061T1 (de) 2001-06-22 2006-04-15 Basell Polyolefine Gmbh Metallocene, verwendung in katalysatoren für olefinpolymerisation
JP2005501841A (ja) 2001-08-01 2005-01-20 バセル ポリオレフィン ジーエムビーエイチ 複素環式ペンタレン誘導体の製造方法
ATE353343T1 (de) * 2001-11-12 2007-02-15 Basell Polyolefine Gmbh Verfahren zur polymerisation von 1-buten und 1- buten polymeren
JP2005517773A (ja) 2002-02-25 2005-06-16 バセル ポリオレフィン ジーエムビーエイチ エチレンの共重合方法
DE60309020T2 (de) 2002-05-29 2007-05-10 Basell Poliolefine Italia S.R.L. Buten-1-(co)polymere und verfahren zu ihrer herstellung
US7390862B2 (en) * 2003-05-12 2008-06-24 Basell Polyolefine Gmbh Process for polymerizing 1-butene
US7943716B2 (en) * 2004-03-12 2011-05-17 Basell Polyolefine Gmbh Process for polymerizing 1-hexene or higher alpha-olefins
BRPI0511801A (pt) * 2004-06-04 2008-01-15 Basell Polyolefine Gmbh composto de metal de transição, sistema ligante, sistema catalisador e processo para preparar poliolefinas

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113637036A (zh) * 2016-03-04 2021-11-12 日本聚乙烯株式会社 茂金属化合物、烯烃聚合用催化剂组分和烯烃聚合用催化剂、和生产烯烃聚合物的方法
CN109312130A (zh) * 2016-07-07 2019-02-05 巴塞尔聚烯烃意大利有限公司 具有高熔融流速的1-丁烯聚合物组合物
CN109312129A (zh) * 2016-07-07 2019-02-05 巴塞尔聚烯烃意大利有限公司 具有高熔融流速的1-丁烯聚合物组合物
US10894850B2 (en) 2016-07-07 2021-01-19 Basell Poliolefine Italia S.R.L. Butene-1 polymer composition having a high melt flow rate
US11015090B2 (en) 2016-07-07 2021-05-25 Basell Poliolefine Italia S.R.L. Butene-1 polymer composition having a high melt flow rate
CN109312129B (zh) * 2016-07-07 2022-01-14 巴塞尔聚烯烃意大利有限公司 具有高熔融流速的1-丁烯聚合物组合物
CN109312130B (zh) * 2016-07-07 2022-01-18 巴塞尔聚烯烃意大利有限公司 具有高熔融流速的1-丁烯聚合物组合物

Also Published As

Publication number Publication date
US20080139762A1 (en) 2008-06-12
WO2006005648A1 (en) 2006-01-19
JP2008506663A (ja) 2008-03-06
EP1765886A1 (en) 2007-03-28
JP5006783B2 (ja) 2012-08-22
US8003743B2 (en) 2011-08-23

Similar Documents

Publication Publication Date Title
KR101060985B1 (ko) 1-부텐의 중합 방법
AU700256B2 (en) Metallocene compounds, process for their prepration, and their use in catalysts for the polymerization of olefins
KR101514378B1 (ko) 1-부텐 에틸렌 공중합체
CN101309927B (zh) 镧系元素的氢硼化茂金属配合物、包括所述配合物的催化体系、使用相同配合物的聚合方法和使用所述方法获得的乙烯-丁二烯共聚物
US7964679B2 (en) Process for the polymerization of alpha olefins
KR101059401B1 (ko) 1-부텐 중합체 제조 방법
US7943716B2 (en) Process for polymerizing 1-hexene or higher alpha-olefins
WO2005095468A2 (en) Catalyst system for the polymerization of olefin
CN100567338C (zh) 制备可分级的1-丁烯聚合物的方法
KR20010034211A (ko) 올레핀-중합-촉매로서 비스(테트라히드로-인데닐)메탈로센
CN101023105A (zh) 金属茂化合物、它们制备中使用的配体,1-丁烯聚合物的制备和由此得到的1-丁烯聚合物
US20080027190A1 (en) Process for Producing Fractionable 1-Butene Polymers
KR20110000742A (ko) 1-부텐 삼원중합체
JP3506563B2 (ja) オレフィン重合用触媒、オレフィン重合体の製造方法およびオレフィン重合体
KR20170074678A (ko) 신규한 전이금속 화합물
KR20070032012A (ko) 메탈로센 화합물, 그의 제조에 사용되는 리간드, 1-부텐중합체의 제조 및 이로부터 제조된 1-부텐 중합체
KR20170068330A (ko) 신규한 전이금속 화합물

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Open date: 20070822