CN101003586B - 齐格勒-纳塔型固体催化组分和催化体系、其制备方法及其在1-烯烃聚合中的应用 - Google Patents

齐格勒-纳塔型固体催化组分和催化体系、其制备方法及其在1-烯烃聚合中的应用 Download PDF

Info

Publication number
CN101003586B
CN101003586B CN2007100017017A CN200710001701A CN101003586B CN 101003586 B CN101003586 B CN 101003586B CN 2007100017017 A CN2007100017017 A CN 2007100017017A CN 200710001701 A CN200710001701 A CN 200710001701A CN 101003586 B CN101003586 B CN 101003586B
Authority
CN
China
Prior art keywords
compound
catalytic component
solid
electron donor
solid catalytic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2007100017017A
Other languages
English (en)
Chinese (zh)
Other versions
CN101003586A (zh
Inventor
W·斯帕瑟
J·林奇
J·罗施
R·赫梅里驰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novolen Technology Holdings CV
Original Assignee
Novolen Technology Holdings CV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Novolen Technology Holdings CV filed Critical Novolen Technology Holdings CV
Publication of CN101003586A publication Critical patent/CN101003586A/zh
Application granted granted Critical
Publication of CN101003586B publication Critical patent/CN101003586B/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN2007100017017A 2002-02-14 2003-01-28 齐格勒-纳塔型固体催化组分和催化体系、其制备方法及其在1-烯烃聚合中的应用 Expired - Fee Related CN101003586B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP02075579A EP1336625A1 (en) 2002-02-14 2002-02-14 Solid catalytic component and catalytic system of the Ziegler-Natta type, process for their preparation and their use in the polymerisation of alk-1-enes
EP02075579.9 2002-02-14

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CNA038068087A Division CN1643001A (zh) 2002-02-14 2003-01-28 齐格勒－纳塔型固体催化组分和催化体系、其制备方法及其在1－烯烃聚合中的应用

Publications (2)

Publication Number Publication Date
CN101003586A CN101003586A (zh) 2007-07-25
CN101003586B true CN101003586B (zh) 2010-10-06

Family

ID=27619163

Family Applications (3)

Application Number Title Priority Date Filing Date
CN2007100017017A Expired - Fee Related CN101003586B (zh) 2002-02-14 2003-01-28 齐格勒-纳塔型固体催化组分和催化体系、其制备方法及其在1-烯烃聚合中的应用
CNA038068087A Pending CN1643001A (zh) 2002-02-14 2003-01-28 齐格勒－纳塔型固体催化组分和催化体系、其制备方法及其在1－烯烃聚合中的应用
CN200910163479A Pending CN101659716A (zh) 2002-02-14 2003-01-28 齐格勒-纳塔型固体催化组分和催化体系、其制备方法及其在1-烯烃聚合中的应用

Family Applications After (2)

Application Number Title Priority Date Filing Date
CNA038068087A Pending CN1643001A (zh) 2002-02-14 2003-01-28 齐格勒－纳塔型固体催化组分和催化体系、其制备方法及其在1－烯烃聚合中的应用
CN200910163479A Pending CN101659716A (zh) 2002-02-14 2003-01-28 齐格勒-纳塔型固体催化组分和催化体系、其制备方法及其在1-烯烃聚合中的应用

Country Status (11)

Country Link
US (1) US7232785B2 (https=)
EP (2) EP1336625A1 (https=)
JP (1) JP2005517748A (https=)
KR (1) KR20040082434A (https=)
CN (3) CN101003586B (https=)
AU (1) AU2003202834A1 (https=)
BR (1) BR0307725A (https=)
CO (1) CO5611202A2 (https=)
MX (1) MXPA04007887A (https=)
WO (1) WO2003068830A1 (https=)
ZA (1) ZA200406484B (https=)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4982365B2 (ja) 2004-07-30 2012-07-25 サウディ ベーシック インダストリーズ コーポレイション 高透明性のプロピレンコポリマー組成物
FR2921368B1 (fr) 2007-09-25 2012-10-12 Pf Medicament Nouveau procede de synthese de derives anticancereux de (poly) aminoalkylaminoacetamide d'epipodophyllotoxine.
ES2536744T3 (es) * 2009-01-07 2015-05-28 Toho Titanium Co., Ltd. Procedimiento de fabricación de componente catalítico sólido y de catalizador para la polimerización de olefinas
US7619049B1 (en) * 2009-04-13 2009-11-17 Formosa Plastics Corporation, U.S.A. Cyclic organosilicon compounds as electron donors for polyolefin catalysts
CN102375045A (zh) * 2010-08-17 2012-03-14 中国石油化工股份有限公司 一种聚丙烯合成催化剂的评价方法
EP2751059B1 (en) 2011-08-29 2015-09-16 Saudi Basic Industries Corporation Process for preparing di-substituted succinates
KR101677694B1 (ko) 2012-09-24 2016-11-18 인디언 오일 코퍼레이션 리미티드 올레핀의 중합을 위한 촉매 및 이의 제조 방법
US9481741B2 (en) 2012-11-26 2016-11-01 Lummus Novolen Technology Gmbh High performance Ziegler-Natta catalyst systems, process for producing such supported catalysts and use thereof
CN103113499B (zh) 2013-01-30 2015-01-21 中国石油天然气股份有限公司 一种宽分布聚烯烃催化剂及其制备和应用
WO2015091151A1 (en) 2013-12-20 2015-06-25 Saudi Basic Industries Corporation Polyolefin composition
US10696829B2 (en) 2013-12-20 2020-06-30 Saudi Basic Industries Corporation Heterophasic propylene copolymer
CN104356264B (zh) * 2014-10-22 2017-01-11 上海化工研究院 一种烯烃聚合催化剂及其制备方法和应用
CN113527555B (zh) * 2020-04-21 2023-04-11 中国石油化工股份有限公司 含环氧树脂的催化剂组分及其制备方法和应用
CN115975077B (zh) * 2021-10-15 2024-06-04 中国石油化工股份有限公司 一种用于烯烃聚合的催化剂组分及催化剂和应用

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4263168A (en) * 1979-01-10 1981-04-21 Imperial Chemical Industries Limited Olefine polymerization catalyst
US4983694A (en) * 1988-05-31 1991-01-08 Mobil Oil Corporation Process for polymerizing olefins to form polymers of narrow molecular weight distribution
US5025072A (en) * 1981-12-04 1991-06-18 Mobil Oil Corporation Highly active catalyst composition for polymerizing alpha-olefins
CN1135191A (zh) * 1993-11-15 1996-11-06 美孚石油公司 共聚乙烯的催化剂组合物
US6200922B1 (en) * 1996-06-11 2001-03-13 Basf Aktiengesellschaft Catalyst systems of the Ziegler-Natta type

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5441985A (en) * 1977-09-09 1979-04-03 Mitsui Petrochem Ind Ltd Polymerization or copolymerization of olefin
JPS6037804B2 (ja) * 1979-04-11 1985-08-28 三井化学株式会社 オレフイン重合触媒用担体の製法
JPS5611908A (en) * 1979-07-11 1981-02-05 Mitsui Petrochem Ind Ltd Preparation of olefin polymer
JPS5950246B2 (ja) * 1979-10-16 1984-12-07 三井化学株式会社 成形用オレフイン共重合体の製法
US4481301A (en) 1981-12-04 1984-11-06 Mobil Oil Corporation Highly active catalyst composition for polymerizing alpha-olefins
US4605638A (en) 1981-12-04 1986-08-12 Mobil Oil Corporation Highly active catalyst composition for polymerizing alpha-olefins
US5330949A (en) * 1985-06-17 1994-07-19 Idemitsu Petrochemical Company, Ltd. Method for producing polyolefin
EP0240254A3 (en) * 1986-03-31 1989-07-26 Exxon Chemical Patents Inc. Polymerization catalyst, production and use
FI76099C (fi) * 1986-09-29 1988-09-09 Neste Oy Katalytkomponenter foer polymerisationskatalyter foer -olefiner och foerfarande foer framstaellning av dessa.
DE3730717A1 (de) * 1987-09-12 1989-03-23 Basf Ag Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-natta-katalysatorsystems
US5126302A (en) * 1990-04-30 1992-06-30 Quantum Chemical Corporation Olefin polymerization catalyst and methods
US5064796A (en) * 1991-01-07 1991-11-12 Exxon Chemical Patents Inc. Support adjuvant for improved vanadium polymerization catalyst
US6291384B1 (en) * 1991-11-06 2001-09-18 Mobil Oil Corporation High activity catalyst prepared with alkoxysilanes
US5336652A (en) 1991-11-06 1994-08-09 Mobil Oil Corporation High activity polyethylene catalysts prepared with alkoxysilane reagents
US5514634A (en) 1991-11-06 1996-05-07 Mobil Oil Corporation High activity polyethylene catalysts
US5939348A (en) 1991-11-06 1999-08-17 Mobil Oil Corporation Catalyst for the manufacture of polythylene with a narrow molecular weight distribution
JPH05214034A (ja) * 1992-02-04 1993-08-24 Ube Ind Ltd エチレン共重合体の製造方法
US5529965A (en) * 1994-10-28 1996-06-25 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US6218331B1 (en) * 1995-03-29 2001-04-17 Equistar Chemicals, L.P. Polymer-supported catalyst for olefin polymerization
ES2114335T3 (es) 1995-08-09 1998-05-16 Basf Ag Sistemas catalizadores del tipo de los catalizadores de ziegler-natta.
CA2233659C (en) * 1995-10-06 2007-12-04 Mobil Oil Corporation Catalyst for the manufacture of polyethylene with a narrow molecular weight distribution
DE19722569A1 (de) * 1997-05-28 1998-12-03 Basf Ag Statistische Propylencopolymerisate
US6825293B1 (en) * 2001-08-20 2004-11-30 Nova Chemicals (International) S.A. Polymer control through co-catalyst
US6831032B2 (en) * 2002-08-19 2004-12-14 Novolen Technology Holdings C.V. Ziegler-Natta catalyst and methods of making and using same
US7838605B2 (en) * 2003-10-17 2010-11-23 Univation Technologies, Llc Polymerization monitoring and control using improved leading indicators

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4263168A (en) * 1979-01-10 1981-04-21 Imperial Chemical Industries Limited Olefine polymerization catalyst
US5025072A (en) * 1981-12-04 1991-06-18 Mobil Oil Corporation Highly active catalyst composition for polymerizing alpha-olefins
US4983694A (en) * 1988-05-31 1991-01-08 Mobil Oil Corporation Process for polymerizing olefins to form polymers of narrow molecular weight distribution
CN1135191A (zh) * 1993-11-15 1996-11-06 美孚石油公司 共聚乙烯的催化剂组合物
US6200922B1 (en) * 1996-06-11 2001-03-13 Basf Aktiengesellschaft Catalyst systems of the Ziegler-Natta type

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
US 4983694 A,全文.

Also Published As

Publication number Publication date
EP1336625A1 (en) 2003-08-20
CN101659716A (zh) 2010-03-03
CO5611202A2 (es) 2006-02-28
WO2003068830A1 (en) 2003-08-21
AU2003202834A1 (en) 2003-09-04
CN101003586A (zh) 2007-07-25
ZA200406484B (en) 2005-06-21
EP1476479A1 (en) 2004-11-17
US20050202959A1 (en) 2005-09-15
BR0307725A (pt) 2005-01-25
MXPA04007887A (es) 2005-06-17
US7232785B2 (en) 2007-06-19
JP2005517748A (ja) 2005-06-16
CN1643001A (zh) 2005-07-20
KR20040082434A (ko) 2004-09-24

Similar Documents

Publication Publication Date Title
US6831032B2 (en) Ziegler-Natta catalyst and methods of making and using same
US7893175B2 (en) Ziegler-natta catalyst, preparation, and use for the polymerization of alkenes
CN104918971B (zh) 高性能齐格勒‑纳塔催化剂体系，这种负载型催化剂的生产方法及其用途
CN101003586B (zh) 齐格勒-纳塔型固体催化组分和催化体系、其制备方法及其在1-烯烃聚合中的应用
WO1996032426A1 (en) Method for the preparation of a catalyst suitable for the polymerisation of an olefine
FI108442B (fi) Olefiinien polymerointiin soveltuvia katalysaattorikomponentteja
SK60594A3 (en) Catalyst carrier and catalyst for polymerization of alpha- -olefins, method of their preparation and use
JP2012508278A (ja) プロピレンの単独重合及び共重合触媒並びにこれらの調整方法及び使用
JP5873930B2 (ja) オレフィンの重合に使用するためのアルミナ担持触媒及びその調製法
KR102749512B1 (ko) 폴리올레핀 중합 촉매용 담체 조성물, 담체 제조방법 및 이를 포함하는 촉매 조성물
EP0525003B1 (en) Procatalyst composition for the polymerization of olefins, its preparation and use
JP2005531675A (ja) オレフィンの重合用触媒系
HU213866B (en) Process for producing catalyst and catalyst component usable for polymerization of olefins and process for polymerization of olefins
JP2001247614A (ja) チーグラー−ナッタ型の新規触媒組成物
EP3397660A1 (en) Process for making a solid catalyst component for ethylene polymerization and copolymerization
WO2017114813A1 (en) Process for making a solid catalyst component for ethylene polymerization and copolymerization

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20101006

Termination date: 20110128